Search Results (68)

The integration of inverter-based resources (IBRs) is reshaping power grid operation by reducing system inertia, which impacts small-signal rotor angle stability and increases low-frequency oscillations (LFOs). While power-electronics-based flexible AC transmission systems (FACTSs) have been the primary solution, the shift of IBR control toward grid forming (GFM) is changing this approach. GFM control inherently provides inertia and affects small-signal stability, but implementing power oscillation damping (POD) algorithms in these inverters presents challenges, particularly regarding active-power-based ones (POD-P). Although various POD-P solutions are emerging for GFM inverters, few studies have evaluated their impact on the GFM device itself and their inherent capabilities, such as inertia and damping. This paper proposes that any design methodology should consider, besides the impact of POD controls on the grid, their effect on the properties of GFM devices. It introduces a theoretical framework using the network frequency perturbation (NFP) approach to assess this impact. Additionally, a simple POD-P control method is proposed for GFM controllers, with simplicity as its key advantage. The desired damping effect, along with the absence of impact on other frequency components, is verified through NFP analysis. The theoretical findings are experimentally validated with test bench results. Full article

BiFeO₃/LaFeO₃ (BFO/LFO) epitaxial superlattices (SLs) with different bilayer thicknesses were grown via pulsed laser deposition on a (001)-SrTiO₃ substrate buffered with a SrRuO₃ bottom electrode. Room-temperature X-ray diffraction demonstrated strong structural changes in tuning the bilayer thickness while keeping the total thickness constant. Superlattices with thin periods were characterized by an antiferroelectric Pnma-like phase, while thick bilayers of the SLs were more likely to be described by a mixed state, including a rhombohedral ferroelectric bulk-like phase. Raman scattering analysis further confirmed the structural behaviour deduced by X-ray diffraction. Strain relaxation and symmetry changes were moreover accompanied by modifications in the dielectric properties correlated with the deduced (anti)ferroic structural phases. Full article

Rhododendron decorum, a widely distributed Rhododendron species in southwestern China, is recognized not only for its significant ornamental value but also as a culinary resource for local tribes. However, the defense mechanisms underlying the ecological adaptations of R. decorum remain to be elucidated. In this study, we conducted comparative transcriptomic analyses of various organs (corolla, androecium/gynoecium and leaves) of R. decorum collected from two distinct two regions. Approximately 186.98 Gb of clean data were generated from three organs of R. decorum across these regions. Through de novo assembly, a total of 92,025 unigenes were obtained and nearly half of them (43,515 unigenes) were successfully annotated. Enrichment analysis of differentially expressed genes (DEGs) within three comparative groups of different organs (HQI/LFI, HQO/LFO and HQL/LFL, respectively) revealed that the distribution of R. decorum in the Heqing region exhibited an increased requirement for plant immunity, including resistance to diseases, insects, and herbivores across various plant organs. Conversely, R. decorum in the Lijiang region showed a greater reliance on environmental factors, such as cold tolerance, aromatic compounds production, and the attraction of pollinating insects. Notably, the validation of 21 pivotal genes identified from significantly regulated enrichment pathways across different organs showed functional consistency in the KEGG enrichment analysis among different organs in these two regions. The functional disparities observed in the transcriptome of R. decorum across distinct regions provide valuable insight into the understanding of its adaptive defense mechanism. Full article

Most Nuclear Power Plants (NPPs) are designed for baseload operations, maintaining a steady power output at 100%, except during planned maintenance and refueling. However, in countries like France, Slovakia, and Korea, where nuclear power is a major source of electricity, integrating nuclear energy with intermittent renewables is crucial for stable power generation. This integration necessitates daily power adjustments by NPPs in response to grid demands, a process known as a Load Follow Operation (LFO). Such a process introduces strong interdependencies between thermal–hydraulic and neutron–kinetic parameters, coupled with the three-dimensional movement of Control Element Assemblies (CEAs) and Xenon dynamics, which pose safety challenges due to shifts in core power distribution. To address these complexities, a multi-physics approach is employed using the multi-physics package RELAP5/3DKIN and implementing two strategies. The first strategy uses a mechanical shim, adjusting the reactor power exclusively through CEAs. The second strategy combines CEA movement with adjustments in soluble boron concentration. Both strategies are evaluated against axial offset and 3D power peaking safety limits to ensure compliance with operational safety requirements. Full article

Perovskite oxide LaFeO₃(LFO) emerges as a potential candidate for formaldehyde (HCHO) detection due to its exceptional electrical conductivity and abundant active metal sites. However, the sensitivity of the LFO sensor needs to be further enhanced. Herein, a series of La_xIn_1-xFeO₃ (x = 1.0, 0.9, 0.8, and 0.7) nanofibers (L_xIn_1-xFO NFs) with different ratios of La/In were obtained via the electrospinning method followed by a calcination process. Among all these L_xIn_1-xFO NFs sensors, the sensor based on the L_0.8In_0.2FO NFs possessed the maximum response value of 18.8 to 100 ppm HCHO at the operating temperature of 180 °C, which was 4.47 times higher than that based on pristine LFO NFs (4.2). Furthermore, the L_0.8In_0.2FO NFs sensor also exhibited a rapid response/recovery time (2 s/22 s), exceptional repeatability, and long-term stability. This excellent gas sensing performance of the L_0.8In_0.2FO NFs can be attributed to the large number of oxygen vacancies induced by the replacement of the A-site La³⁺ by In³⁺, the large specific surface area, and the porous structure. This research presents an approach to enhance the HCHO gas sensing capabilities by adjusting the introduced oxygen vacancies through the doping of A-sites in perovskite oxides. Full article

Low-frequency oscillation (LFO) poses significant challenges to the dynamic performance of hydropower unit regulation systems (HURS) in hydropower units sharing a tailwater system. Previous methods have struggled to effectively suppress LFO, due to limitations in governor parameter optimization strategies. To address this issue, this paper proposes a governor parameter optimization strategy based on the crayfish optimization algorithm (COA). Considering the actual water diversion layout (WDL) of a HURS, a comprehensive mathematical model of the WDL is constructed and, combined with models of the governor, turbine, and generator, an overall HURS model for the shared tailwater system is derived. By utilizing the efficient optimization performance of the COA, the optimal PID parameters for the HURS controller are quickly obtained, providing robust support for PID parameter tuning. Simulation results showed that the proposed strategy effectively suppressed LFOs and significantly enhanced the dynamic performance of the HURS under grid-connected conditions. Specifically, compared to before optimization, the optimized system reduced the oscillation amplitude by at least 30% and improved the stabilization time by at least 25%. Additionally, the impact of the power grid system parameters on oscillations was studied, providing guidance for the optimization and tuning of specific system parameters. Full article

In this paper, a Takagi–Sugeno fuzzy parallel distributed compensation control (TS-PDCC) is proposed for low-frequency oscillation (LFO) suppression in wind energy-penetrated power systems. Firstly, the fuzzy C-mean algorithm (FCMA) is applied to cluster the daily average wind speed of the wind farm, and the obtained wind speed clustering center is used as the premise variable of TS-PDCC, which increases the freedom of parameter setting of the TS fuzzy model and is closer to the actual working environment. Secondly, based on the TS fuzzy model, the TS-PDCC is designed to adjust the active power output of the wind turbine for LFO suppression. To facilitate the computation of controller parameters, the stability conditions are transformed into a set of Linear Matrix Inequalities (LMIs) via the Schur complement. Subsequently, a Lyapunov function is designed to verify the stability of the wind energy-penetrated power system and obtain the parameter ranges. Simulation cases are conducted to verify the validity and superior performance of the proposed TS-PDCC under different operating conditions. Full article

The formation of cross-linked enzyme aggregates (CLEAs) using macromolecular cross-linkers improves substrate accessibility and enhances enzyme retention. However, there have been few studies exploring the use of macromolecular cross-linkers due to the challenges related to cross-linker screening. In compliance with our previous computational and experimental screening, dextran is the optimal macromolecular cross-linker to develop CLEAs of endolevanase from Bacillus lehensis G1 (rlevblg1-dex-CLEA) for levan-type-fructooligosaccharides (L-FOS) production. In this study, rlevblg1-dex-CLEAs was optimized, and the activity recovery continued to increase and reached 90.5%. Subsequently, the rlevblg1-dex-CLEAs were characterized and they displayed higher thermal stability after 1 h of incubation in comparison to the free enzyme. Moreover, the rlevblg1-dex-CLEAs were reusable for five cycles and exhibited greater storage stability over 180 days at 4 °C (60.9%) than that of free rlevblg1. In addition, the rlevblg1-dex-CLEAs demonstrated similar catalytic efficiency as the free enzyme and generated a substantial amount of L-FOS with a longer degree of polymerization, which is more beneficial for industrial use. Full article

It is of great academic significance to understand the influence that the atomic-scale structure of interfaces and boundaries within materials has on magnetic coupling characteristics and promote the innovation of advanced magnetic devices. Here, we carried out a systematic investigation of the atomic and electronic structures of twin boundaries (TBs) in Li_0.5Fe_2.5O₄ (LFO) thin films and determined their concurrent magnetic couplings using atomic-resolution transmission electron microscopy and first-principle calculations at the atomic scale. The results show that ferromagnetic or antiferromagnetic coupling can exist across the different TBs in LFO thin films, and electrical structures within a few atomic layers directly rely on the atom arrangement across the TB. Uncovering one-to-one relationships between the magnetic coupling properties of individual TBs and atomic-scale structures can clarify a thorough comprehension of numerous fascinating magnetic properties of commonly utilized magnetic materials, which will undoubtedly encourage the progress of sophisticated magnetic materials and devices. Full article

Thin films of lithium spinel ferrite, LiFe₅O₈, have attracted much scientific attention because of their potential for efficient excitation, the manipulation and propagation of spin currents due to their insulating character, high-saturation magnetization, and Curie temperature, as well as their ultra-low damping value. In addition, LiFe₅O₈ is currently one of the most interesting materials in terms of developing spintronic devices based on the ionic control of magnetism, for which it is crucial to control the lithium’s atomic content. In this work, we demonstrate that dual ion beam sputtering is a suitable technique to tailor the lithium content of thin films of lithium ferrite (LFO) by using the different energies of the assisting ion beam formed by Ar⁺ and O₂⁺ ions during the growth process. Without assistance, a disordered rock-salt LFO phase (i.e., LiFeO₂) can be identified as the principal phase. Under beam assistance, highly out-of-plane-oriented (111) thin LFO films have been obtained on (0001) Al₂O₃ substrates with a disordered spinel structure as the main phase and with lithium concentrations higher and lower than the stoichiometric spinel phase, i.e., LiFe₅O₈. After post-annealing of the films at 1025 K, a highly ordered ferromagnetic spinel LFO phase was found when the lithium concentration was higher than the stoichiometric value. With lower lithium contents, the antiferromagnetic hematite (α-Fe₂O₃) phase emerged and coexisted in films with the ferromagnetic Li_xFe_6-xO₈. These results open up the possibility of controlling the properties of thin lithium ferrite-based films to enable their use in advanced spintronic devices. Full article

The ground state of correlated electrons in complex oxide films can be controlled by applying epitaxial strain, offering the potential to produce unexpected phenomena applicable to modern spintronic devices. In this study, we demonstrate that substrate-induced strain strongly affects the coupling mode of interfacial magnetic moments in a ferromagnetic (FM)/antiferromagnetic (AFM) system. In an epitaxial bilayer comprising AFM LaFeO₃ (LFO) and FM La_0.7Sr_0.3MnO₃ (LSMO), samples grown on a LaAlO₃ (LAO) substrate exhibit a larger exchange bias field than those grown on a SrTiO₃ substrate. Our results indicate a transition in the alignment of magnetic moments from perpendicular to collinear due to the large compressive strain exerted by the LAO substrate. Collinear magnetic moments at the LSMO/LFO interface generate strong exchange coupling, leading to a considerable exchange bias effect. Thus, our findings provide a method for tailoring and manipulating the orientations of magnetic moments at the FM/AFM heterogeneous interface using strain engineering, thereby augmenting methods for exchange bias generation. Full article

A frequency up-conversion piezoelectric energy harvester (FUC-PEH) consists of a force amplifier, a piezoelectric stack, a low-frequency oscillator (LFO), and a stop limiter. The force amplifier generates the amplification of stress on the piezoelectric stack. The LFO, comprising a spring and a mass block, impacts the stop limiter during vibration to induce high-frequency oscillations within the piezoelectric stack. In this paper, we represent and simplify the FUC-PEH as a lumped-parameter model based on piezoelectric material constitutive equations and structural dynamic theories. Using the electromechanical analogy, we developed an equivalent circuit model (ECM) of the FUC-PEH. A parametric study was performed to investigate the impact of system parameters, such as spring stiffness and concentrated mass, on the FUC-PEH performance. The collision-induced amplitude truncation (AT) effect enlarges the operation bandwidth. ECM simulations show that low-frequency input excitation is converted into a high-frequency output response, enhancing the energy conversion efficiency. Furthermore, we aimed to improve the FUC-PEH’s performance using a synchronous electric charge extraction (SECE) circuit. Using the ECM approach, we established a system-level model that considers the electromechanical coupling behavior. The simulation results provide insights into the performance of FUC harvesters with SECE circuits and offer valuable design guidance. Full article

This study synthesizes Ni-doped perovskite-structured LaFeO₃ composite materials via a one-step hydrothermal method, characterizes the morphology and structure of the materials, and tests their gas sensing performance. The test results show that compared to pure LaFeO₃ material, the gas sensing performance of Ni-doped LaFeO₃ material is improved in all aspects. Specifically, LFO-Ni2% exhibits a response as high as 102 towards 100 ppm of triethylamine at 190 °C, along with better selectivity and stability. Furthermore, the gas sensing mechanism is investigated. On one hand, doping with an appropriate proportion of Ni can lead to the formation of more-complete and smaller-sized microsphere structures with pores. This is beneficial for the adsorption of oxygen from the air onto the material surface, as well as for the diffusion of the target gas to the surface of the material, thereby enhancing gas sensitivity performance. On the other hand, the doped Ni enters the interior of the LaFeO₃ crystal, replacing some of the cations in LaFeO₃, increasing the concentration of charge carriers in the material, and reducing the material’s resistance. The sample can adsorb more oxygen, promoting the reaction between adsorbed oxygen and the target gas, and thereby improving the gas sensitivity performance of the sample. Full article

The effect of oxygen reduction on the magnetic properties of LaFeO_3−δ (LFO) thin films was studied to better understand the viability of LFO as a candidate for magnetoionic memory. Differences in the amount of oxygen lost by LFO and its magnetic behavior were observed in nominally identical LFO films grown on substrates prepared using different common methods. In an LFO film grown on as-received SrTiO₃ (STO) substrate, the original perovskite film structure was preserved following reduction, and remnant magnetization was only seen at low temperatures. In a LFO film grown on annealed STO, the LFO lost significantly more oxygen and the microstructure decomposed into La- and Fe-rich regions with remnant magnetization that persisted up to room temperature. These results demonstrate an ability to access multiple, distinct magnetic states via oxygen reduction in the same starting material and suggest LFO may be a suitable materials platform for nonvolatile multistate memory. Full article

The strain engineering effects induced by different means, e.g., the substrate lattice mismatch and/or chemical doping, on the functional properties of perovskite thin films have triggered interest in the use of these materials in different applications such as energy storage/generation or photonics. The effects of the film’s thickness and strain state of the structure for the lead-free perovskite ferrite-based materials (BiFeO₃-BFO; Y-doped BiFeO₃-BYFO; LaFeO₃-LFO) on their functional properties are highlighted here. As was previously demonstrated, the dielectric properties of BFO epitaxial thin films are strongly affected by the film thickness and by the epitaxial strain induced by the lattice mismatch between substrate and film. Doping the BiFeO₃ ferroelectric perovskite with rare-earth elements or inducing a high level of structural deformation into the crystalline structure of LaFeO₃ thin films have allowed the tuning of functional properties of these materials, such as dielectric, optical or photocatalytic ones. These changes are presented in relation to the appearance of complex ensembles of nanoscale phase/nanodomains within the epitaxial films due to strain engineering. However, it is a challenge to maintain the same level of epitaxial strain present in ultrathin films (<10 nm) and to preserve or tune the positive effects in films of thicknesses usually higher than 30 nm. Full article