Search Results (124)

Silica-modified electrodes possess physicochemical properties that make them valuable in electrochemical sensing and energy-related applications. Although intrinsically insulating, silica thin films can selectively interact with redox species, producing sieving effects that enhance electrochemical responses. We synthesized Class I hybrid silica matrices incorporating either negatively charged poly(4-styrene sulfonic acid) or positively charged poly(diallyl dimethylammonium chloride). These hybrid films were deposited onto ITO electrodes and evaluated via cyclic voltammetry in aqueous ferrocenium solutions. The polyelectrolyte charge played a key role in the electroassisted incorporation of ferrocene: silica-PSS films promoted accumulation, while silica-PDADMAC films hindered it due to electrostatic repulsion. In situ UV-vis spectroscopy confirmed that only a fraction of the embedded ferrocene was electroactive. Nevertheless, this fraction enabled effective mediated detection of cytochrome c in solution. These findings highlight the crucial role of ionic interactions and hybrid composition in electron transfer to redox proteins, providing valuable insights for the development of advanced bioelectronic sensors. Full article

This paper proposes a high-sensitivity U-shaped optical fiber sensor based on indium tin oxide (ITO) for surface plasmon resonance (SPR) sensing. Finite element simulations reveal that introducing ITO enhances the surface electric field strength by 1.15× compared to conventional designs, directly boosting sensitivity. The U-shaped structure optimizes evanescent wave–metal film interaction, further improving performance. In an external refractive index (RI) range of 1.334–1.374 RIU, the sensor achieves a sensitivity of 4333 nm/RIU (1.85× higher than traditional fiber sensors) and a figure of merit (FOM) of 21.7 RIU⁻¹ (1.68× improvement). Repeatability tests show a low relative standard deviation (RSD) of 0.4236% for RI measurements, with a maximum error of 0.00018 RIU, confirming excellent stability. The ITO coating’s strong adhesion ensures long-term reliability. With its simple structure, ease of fabrication, and superior sensitivity/FOM, this SPR sensor is well-suited for high-precision biochemical detection in intelligent sensing systems. Full article

This study investigates the development and sensing profile of synthetic melanin nanoparticle-coated electrodes for the electrochemical detection of heavy metals, including lead (Pb), cadmium (Cd), cobalt (Co), zinc (Zn), nickel (Ni), and iron (Fe). Synthetic melanin films were prepared in situ by the deacetylation of diacetoxy indole (DAI) to dihydroxy indole (DHI), followed by the deposition of DHI monomers onto indium tin oxide (ITO) and glassy carbon electrodes (GCE) using cyclic voltammetry (CV), forming a thin layer of synthetic melanin film. The deposition process was characterized by electrochemical quartz crystal microbalance (EQCM) in combination with linear sweep voltammetry (LSV) and amperometry to determine the mass and thickness of the deposited film. Surface morphology and elemental composition were examined using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX). In contrast, Fourier-transform infrared (FTIR) and UV–Vis spectroscopy confirmed the melanin’s chemical structure and its polyphenolic functional groups. Differential pulse voltammetry (DPV) and amperometry were employed to evaluate the melanin films’ electrochemical activity and sensitivity for detecting heavy metal ions. Reproducibility and repeatability were rigorously assessed, showing consistent electrochemical performance across multiple electrodes and trials. A comparative analysis of ITO, GCE, and graphite electrodes was conducted to identify the most suitable substrate for melanin film preparation, focusing on stability, electrochemical response, and metal ion sensing efficiency. Finally, the applicability of melanin-coated electrodes was tested on in-house heavy metal water samples, exploring their potential for practical environmental monitoring of toxic heavy metals. The findings highlight synthetic melanin-coated electrodes as a promising platform for sensitive and reliable detection of iron with a sensitivity of 106 nA/ppm and a limit of quantification as low as 1 ppm. Full article

Here, we consider the stochastic graphene sheets model (SGSM) forced by multiplicative noise in the Itô sense. We show that the exact solution of the SGSM may be obtained by solving some deterministic counterparts of the graphene sheets model and combining the result with a solution of stochastic ordinary differential equations. By applying the extended tanh function method, we obtain the soliton solutions for the deterministic counterparts of the graphene sheets model. Because graphene sheets are important in many fields, such as electronics, photonics, and energy storage, the solutions of the stochastic graphene sheets model are beneficial for understanding several fascinating scientific phenomena. Using the MATLAB program, we exhibit several 3D graphs that illustrate the impact of multiplicative noise on the exact solutions of the SGSM. By incorporating stochastic elements into the equations that govern the evolution of graphene sheets, researchers can gain insights into how these fluctuations impact the behavior of the material over time. Full article

Glucose (Glu) detection, as a fundamental analytical technique, has applications in medical diagnostics, clinical testing, bioanalysis and environmental monitoring. In this work, a solid-phase electrochemiluminescence (ECL) enzyme sensor was developed by immobilizing the ECL emitter in a stable manner within bipolar silica nanochannel array film (bp-SNA), enabling sensitive glucose detection. The sensor was constructed using an electrochemical-assisted self-assembly (EASA) method with various siloxane precursors to quickly modify the surface of indium tin oxide (ITO) electrodes with a bilayer SNA of different charge properties. The inner layer, including negatively charged SNA (n-SNA), attracted the positively charged ECL emitter tris(2,2′-bipyridyl)ruthenium(II) (Ru(bpy)₃²⁺) via electrostatic interaction, while the outer layer, including positively charged SNA (p-SNA), repelled it, forming a barrier that efficiently concentrated the Ru(bpy)₃²⁺ emitter in a stable manner. After modifying the amine groups on the p-SNA surface with aldehyde groups, glucose oxidase (GOx) was covalently immobilized, forming the enzyme electrode. In the presence of glucose, GOx catalyzed the conversion of glucose to hydrogen peroxide (H₂O₂), which acted as a quencher for the Ru(bpy)₃²⁺/triethanolamine (TPA) system, reducing the ECL signal and enabling quantitative glucose analysis. The sensor exhibited a wide linear range from 10 μM to 7.0 mM and a limit of detection (LOD) of 1 μM (S/N = 3). Glucose detection in fetal bovine serum was realized. By replacing the enzyme type on the electrode surface, this sensing strategy holds the potential to provide a universal platform for the detection of different metabolites. Full article

In this paper, a conformal UHF antenna with a wide-angle radar cross section (RCS) reduction capability is proposed. The radiator of the design is a planar monopole antenna. Since the large physical size of the antenna in UHF band can generate a scatter beam with a large RCS in the high operating frequency of radars and other sensing applications, i.e., the X band, two types of ITO (Indium Tin Oxide) meta-absorber are proposed and loaded onto the monopole antenna to suppress the scatter. For the incident beam around the direction orthogonal to the radiator plane, the periodical meta-absorber can realize around a 20 dB RCS reduction in the X band. The incident wave around the parallel direction of the radiator is absorbed by the taper meta-absorber, which can greatly suppress the surface and then reduce the RCS in the horizontal plane. The combined effect means the antenna can achieve a wide-angle RCS reduction. It should be noted that the antenna can still produce a high-efficiency omnidirectional beam after the lossy meta-absorber is loaded. In our opinion, the advantages of the proposed antenna design, including good radiation performance in UHF band and high RCS reduction in X band, make it a suitable candidate for airborne and drone applications. Full article

In this article, we look at the stochastic Wu–Zhang system (SWZS) forced by multiplicative Brownian motion in the Itô sense. The mapping method, which is an effective analytical method, is employed to investigate the exact wave solutions of the aforementioned equation. The proposed scheme provides new types of exact solutions including periodic solitons, kink solitons, singular solitons and so on, to describe the wave propagation in quantum mechanics and analyze a wide range of essential physical phenomena. In the absence of noise, we obtain some previously found solutions of SWZS. Additionally, using the MATLAB program, the impacts of the noise term on the analytical solution of the SWZS were demonstrated. Full article

Tactile sensing is currently a research hotspot in the fields of intelligent perception and robotics. The method of converting external stimuli into electrical signals for sensing is a very effective strategy. Herein, we proposed a self-powered, flexible, transparent tactile sensor integrating sliding and proximity sensing (SFTTS). The principle of electrostatic induction and contact electrification is used to achieve tactile response when external objects approach and slide. Experiments show that the material type, speed, and pressure of the perceived object can cause the changes of the electrical signal. In addition, fluorinated ethylene propylene (FEP) is used as the contact electrification layer, and indium tin oxide (ITO) is used as the electrostatic induction electrode to achieve transparency and flexibility of the entire device. By utilizing the transparency characteristics of this sensor to integrate with optical cameras, it is possible to achieve integrated perception of tactile and visual senses. This has great advantages for applications in the field of intelligent perception and is expected to be integrated with different types of optical sensors in the future to achieve multimodal intelligent perception and sensing technology, which will contribute to the intelligence and integration of robot sensing. Full article

In this study, a simple and easy synthesis strategy to realize the modification of AuHgPt nanoalloy materials on the surface of ITO glass at room temperature is presented. Gold nanoparticles as templates were obtained by electrochemical deposition, mercury was introduced as an intermediate to form an amalgam, and then a galvanic replacement reaction was utilized to successfully prepare gold–mercury–platinum (AuHgPt) nanoalloys. The obtained alloys were characterized by scanning electron microscopy, UV–Vis spectroscopy, X-ray photoelectron spectroscopy and X-ray diffraction techniques. The electrochemical sensing performance of the AuHgPt-modified electrode for hydrogen peroxide was evaluated by cyclic voltammetry and chronoamperometry. Under light conditions, the AuHgPt-modified electrode exhibited a desirable current response in the detection of hydrogen peroxide due to the synergistic effect of the localized surface plasmon resonance effect inherent in gold nanoparticles, and this synergistic effect improved the sensitivity of hydrogen peroxide detection. Meanwhile, the AuHgPt-modified electrode also exhibited better stability and reproducibility, which makes the modified electrode have great potential for various applications in the field of electrochemical sensing. Full article

NO₂ is a toxic gas that can damage the lungs with prolonged exposure and contribute to health conditions, such as asthma in children. Detecting NO₂ is therefore crucial for maintaining a healthy environment. Carbon nanotubes (CNTs) are promising materials for NO₂ gas sensors due to their excellent electronic properties and high adsorption energy for NO₂ molecules. However, conventional CNT-based sensors face challenges, including low responses at room temperature (RT) and slow recovery times. This study introduces a memristor-based NO₂ gas sensor comprising CNT/ZnO/ITO decorated with an N-[3-(trimethoxysilyl)propyl] ethylene diamine (en-APTAS) membrane to enhance room-temperature-sensing performance. The amine groups in the en-APTAS membrane increase adsorption sites and boost charge transfer interactions between NO₂ and the CNT surface. This modification improves the sensor’s response by 60% at 20 ppm compared to the undecorated counterpart. However, the high adsorption energy of NO₂ slows the recovery process. To overcome this, a pulse-recovery method was implemented, applying a −2.5 V pulse with a 1 ms width, enabling the sensor to return to its baseline within 1 ms. These findings highlight the effectiveness of en-APTAS decoration and pulse-recovery techniques in improving the sensitivity, response, and recovery of CNT-based gas sensors. Full article

Prostate cancer is one of the most prevalent cancers afflicting men worldwide, often detected at advanced stages, leading to increased mortality rates. Addressing this challenge, we present an innovative approach employing electrochemical biosensing for early-stage prostate cancer detection. This study used Indium–Tin Oxide (ITO) as a substrate and a deposited gold–graphene quantum dot (Au–GQD) nanohybrid to establish electrochemical sensing platforms for DNA-hybridization assays. A capturing DNA probe, PCA3, was covalently immobilized on the surface of the Au–GQDs and deposited electrochemically onto the ITO electrode surface. The Au–GQDs enabled the capturing of the target PCA3 biomarker probe. The sensor achieved a limit of detection (LoD) of up to 211 fM and presented a linear detection range spanning 1 µM to 100 fM. A rapid 5-min response time was also achieved. The tested shelf life of the pre-immobilized sensor was approximately 19 ± 1 days, with pronounced selectivity for its intended target amidst various interferants. The sensing device has the potential to revolutionize prostate cancer management by facilitating early-stage detection and screening with enhanced treatment efficacy. Full article

We establish a relationship between stochastic differential games (SDGs) and a unified forward–backward coupled stochastic partial differential equation (SPDE) with discontinuous Lévy Jumps. The SDGs have q players and are driven by a general-dimensional vector Lévy process. By establishing a vector-form Ito-Ventzell formula and a 4-tuple vector-field solution to the unified SPDE, we obtain a Pareto optimal Nash equilibrium policy process or a saddle point policy process to the SDG in a non-zero-sum or zero-sum sense. The unified SPDE is in both a general-dimensional vector form and forward–backward coupling manner. The partial differential operators in its drift, diffusion, and jump coefficients are in time-variable and position parameters over a domain. Since the unified SPDE is of general nonlinearity and a general high order, we extend our recent study from the existing Brownian motion (BM)-driven backward case to a general Lévy-driven forward–backward coupled case. In doing so, we construct a new topological space to support the proof of the existence and uniqueness of an adapted solution of the unified SPDE, which is in a 4-tuple strong sense. The construction of the topological space is through constructing a set of topological spaces associated with a set of exponents $\{{\gamma }_1,{\gamma }_2,\dots \}$ under a set of general localized conditions, which is significantly different from the construction of the single exponent case. Furthermore, due to the coupling from the forward SPDE and the involvement of the discontinuous Lévy jumps, our study is also significantly different from the BM-driven backward case. The coupling between forward and backward SPDEs essentially corresponds to the interaction between noise encoding and noise decoding in the current hot diffusion transformer model for generative AI. Full article

The promising possibility of an organic photodetector (OPD) is emerging in the field of sensing applications for its tunable absorption range, flexibility, and large-scale fabrication abilities. In this work, we fabricated a bulk heterojunction OPD with a device structure of glass/ITO/PEDOT:PSS/P3HT:PC₆₁BM/Al using the spin-coating process and characterized the dark and photocurrent densities at different applied bias conditions for red, green, and blue incident LEDs. The OPD photocurrent density exhibited a magnitude up to 2.5–3 orders higher compared to the dark current density at a −1 V bias while it increased by up to 3–4 orders at zero bias conditions for red, green, and blue lights, showing an increasing trend when a higher voltage is applied in the negative direction. Different OPD inner periphery shapes, the OPD to LED distance, and OPD area were also considered to bring the variation in the OPD dark and photocurrent densities, which can affect the on/off ratio of the OPD–LED hybrid system and is a critical phenomenon for any sensing application. Full article

CdS, CdTe, Hg_0.1Cd_0.9Te, CdTe, and Ag films were progressively electrodeposited on ITO-coated soda–lime glass to manufacture a short- and mid-wavelength infrared photodetector. A distinctive feature of the applied electrodeposition method is the use of a non-aqueous solution containing ethylene glycol (EG) as the electrolyte in a traditional three-electrode configuration for every film deposition. Using EG as a supplementary electrolyte and using the same deposition conditions with a potential below 0.75 V for all film coatings reduces their environmental incompatibility and offers a low-cost and low-energy route for fabricating the reported photodetector. The produced photodetector has a sensitivity of up to ≈957 nm with a detectivity (D*) of 2.86 × 10¹² cm Hz^1/2 W⁻¹ and a dark current density (J_dark) of 10⁻⁶ mA cm⁻². Furthermore, the manufactured photodiode exhibits self-powered performance because V_oc and J_sc are self-generated, unlike previously reported photodiodes. The presented all-layer electrodeposition assembly approach can easily be adapted to fabricate sensing devices for different applications. Full article

To obtain a high-performance extended gate field-effect transistor for pH detection, hafnium nitride (HfN) was first fabricated on an indium tin oxide on polyethylene terephthalate (ITO/PET) substrate using a high-power impulse magnetron sputter system (HiPIMS) in this study. It can be easily applied in biomedical diagnostic and environmental monitoring applications with the advantages of flexible, disposable, cost-effective, and reliable components. Various duty cycle conditions in HiPIMSs were designed to investigate the corresponding sensing performance and material properties including surface morphology and composition. As the duty cycle increased, the grain size of HfN increased. Additionally, X-ray photoelectron spectroscopy (XPS) analysis illustrated the presence of HfO_xN_y on the deposited HfN surface. Both behaviors could result in a better pH sensing performance based on the theory of the site-binding model. Subsequently, HfN with a 15% duty cycle exhibited excellent pH sensitivity and linearity, with values of 59.3 mV/pH and 99.8%, respectively; its hysteresis width and drift coefficient were −1 mV and 0.5 mV/h, respectively. Furthermore, this pH-sensing performance remained stable even after 2000 repeated bending cycles. These results indicate the potential and feasibility of this HiPIMS-deposited HfN for future wearable chemical applications. Full article