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Keywords = HRI materials

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19 pages, 2708 KB  
Article
A TPU-Based 3D Printed Robotic Hand: Design and Its Impact on Human–Robot Interaction
by Younglim Choi, Minho Lee, Seongmin Yea, Seunghwan Kim and Hyunseok Kim
Electronics 2026, 15(2), 262; https://doi.org/10.3390/electronics15020262 - 7 Jan 2026
Viewed by 2018
Abstract
This study outlines the design and evaluation of a biomimetic robotic hand tailored for Human–Robot Interaction (HRI), focusing on improvements in tactile fidelity driven by material choice. Thermoplastic polyurethane (TPU) was selected over polylactic acid (PLA) based on its reported elastomeric characteristics and [...] Read more.
This study outlines the design and evaluation of a biomimetic robotic hand tailored for Human–Robot Interaction (HRI), focusing on improvements in tactile fidelity driven by material choice. Thermoplastic polyurethane (TPU) was selected over polylactic acid (PLA) based on its reported elastomeric characteristics and mechanical compliance described in prior literature. Rather than directly matching human skin properties, TPU was perceived as providing a softer and more comfortable tactile interaction compared to rigid PLA. The robotic hand was anatomically reconstructed from an open-source model and integrated with AX-12A and MG90S actuators to simplify wiring and enhance motion precision. A custom PCB, built around an ATmega2560 microcontroller, enables real-time communication with ROS-based upper-level control systems. Angular displacement analysis of repeated gesture motions confirmed the high repeatability and consistency of the system. A repeated-measures user study involving 47 participants was conducted to compare the PLA- and TPU-based prototypes during interactive tasks such as handshakes and gesture commands. The TPU hand received significantly higher ratings in tactile realism, grip satisfaction, and perceived responsiveness (p < 0.05). Qualitative feedback further supported its superior emotional acceptance and comfort. These findings indicate that incorporating TPU in robotic hand design not only enhances mechanical performance but also plays a vital role in promoting emotionally engaging and natural human–robot interactions, making it a promising approach for affective HRI applications. Full article
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12 pages, 3302 KB  
Article
Selected Properties of Composite Materials Used for Dental Fillings—Methodological Development and Preliminary Results
by Katarzyna Piotrowska, Monika Madej, Joanna Wysokińska-Miszczuk and Michał Paulo
Materials 2026, 19(1), 146; https://doi.org/10.3390/ma19010146 - 31 Dec 2025
Cited by 2 | Viewed by 835
Abstract
Dental composites are widely used in restorative dentistry; however, their long-term clinical performance is strongly influenced by mechanical and tribological behavior under oral conditions. Understanding the relationship between material structure, surface characteristics, and functional properties is therefore essential. This preliminary methodological study evaluated [...] Read more.
Dental composites are widely used in restorative dentistry; however, their long-term clinical performance is strongly influenced by mechanical and tribological behavior under oral conditions. Understanding the relationship between material structure, surface characteristics, and functional properties is therefore essential. This preliminary methodological study evaluated the mechanical, tribological, and wetting properties of three light-cured dental composites—Enamel Plus HRi, Amaris, and Estelite Asteria—commonly used in clinical practice. The materials were characterized in terms of surface morphology, hardness, Young’s modulus, coefficient of friction, and wear resistance under controlled laboratory conditions. Instrumental indentation and tribological tests were performed, and results were expressed as mean values with standard deviations calculated from multiple measurements. The results demonstrated that filler composition and surface topography affected material performance. Estelite Asteria exhibited the highest hardness (HIT > 300 MPa), while Enamel Plus HRi showed the highest Young’s modulus (EIT ≈ 14.5 GPa). Materials with more complex surface morphology retained lubricating artificial saliva more effectively, resulting in lower friction coefficients (minimum µ = 0.85), although this did not reduce wear. The highest wear was observed for Estelite Asteria, with a wear scar approximately 62% greater than that of Enamel Plus HRi. These preliminary findings provide a methodological basis for further investigations under more clinically relevant conditions. Full article
(This article belongs to the Special Issue Properties and Applications of Oral Implant Biomaterials)
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20 pages, 6325 KB  
Article
Activation of Inflammatory and Apoptosis Pathways on Human Gingival Fibroblasts Exposed to Dental Resin Composites
by Francesco De Angelis, Edoardo Sorrentino, Antonella Mazzone, Ylenia Della Rocca, Jacopo Pizzicannella, Oriana Trubiani, Giovanna Iezzi, Camillo D’Arcangelo, Guya Diletta Marconi and Francesca Diomede
Polymers 2025, 17(20), 2779; https://doi.org/10.3390/polym17202779 - 17 Oct 2025
Viewed by 1216
Abstract
The use of dental composite resins has significantly increased over recent years, thanks to their esthetics and mechanical features, despite some doubts being raised about their biocompatibility. Residual methacrylate can be eluted from bulk composites, and its amount may significantly increase over time, [...] Read more.
The use of dental composite resins has significantly increased over recent years, thanks to their esthetics and mechanical features, despite some doubts being raised about their biocompatibility. Residual methacrylate can be eluted from bulk composites, and its amount may significantly increase over time, leading to cytotoxic effects that can involve several inflammatory patterns. The aim of this in vitro study was to evaluate the activation of the inflammatory pathway NFκB p65/MyD88/NALP3 and the apoptosis pathway of BCL-2/BAX/Caspase-3 (CASP-3) expression on human gingival fibroblasts (hGFs) after 24 h and 1-week exposure to the eluates of three heat-cured dental composite resins: GrandioSO, VOCO (GR); Enamel Plus HRi Biofunction, Micerium (BF); and Filtek universal restorative, 3M (FU). The results highlighted that NFκB p65/MyD88/NALP3 was activated after resin exposure in a time-dependent manner. Moreover, immunofluorescence and gene expression analyses showed that pro-apoptotic markers CASP-3 and BAX were elevated, while anti-apoptotic protein BCL-2 was suppressed in hGFs after dental resin exposure. The present in vitro study analyzed mechanisms related to cytotoxicity and apoptosis, suggesting ways to limit composite cytotoxicity through advancements in material technology. The activation of inflammation and apoptotic pathways appeared to be material-dependent, and was less pronounced with BF and FU, which could hypothetically indicate them being a safer clinical choice to preserve periodontal health in daily dental practice. Full article
(This article belongs to the Special Issue Advanced Polymeric Materials for Dental Applications III)
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17 pages, 11151 KB  
Article
Electrical Impedance Tomography-Based Electronic Skin for Multi-Touch Tactile Sensing Using Hydrogel Material and FISTA Algorithm
by Zhentao Jiang, Zhiyuan Xu, Mingfu Li, Hui Zeng, Fan Gong and Yuke Tang
Sensors 2024, 24(18), 5985; https://doi.org/10.3390/s24185985 - 15 Sep 2024
Cited by 9 | Viewed by 4024
Abstract
Flexible electronic skin (e-skin) can enable robots to have sensory forms similar to human skin, enhancing their ability to obtain more information from touch. The non-invasive nature of electrical impedance tomography (EIT) technology allows electrodes to be arranged only at the edges of [...] Read more.
Flexible electronic skin (e-skin) can enable robots to have sensory forms similar to human skin, enhancing their ability to obtain more information from touch. The non-invasive nature of electrical impedance tomography (EIT) technology allows electrodes to be arranged only at the edges of the skin, ensuring the stretchability and elasticity of the skin’s interior. However, the image quality reconstructed by EIT technology has deteriorated in multi-touch identification, where it is challenging to clearly reflect the number of touchpoints and accurately size the touch areas. This paper proposed an EIT-based flexible tactile sensor that employs self-made hydrogel material as the primary sensing medium. The sensor’s structure, fabrication process, and tactile imaging principle were elaborated. To improve the quality of image reconstruction, the fast iterative shrinkage-thresholding algorithm (FISTA) was embedded into the EIDORS toolkit. The performances of the e-skin in aspects of assessing the touching area, quantitative force sensing and multi-touch identification were examined. Results showed that the mean intersection over union (MIoU) of the reconstructed images was improved up to 0.84, and the tactile position can be accurately imaged in the case of the number of the touchpoints up to seven (larger than two to four touchpoints in existing studies), proving that the combination of the proposed sensor and imaging algorithm has high sensitivity and accuracy in multi-touch tactile sensing. The presented e-skin shows potential promise for the application in complex human–robot interaction (HRI) environments, such as prosthetics and wearable devices. Full article
(This article belongs to the Section Physical Sensors)
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11 pages, 8898 KB  
Article
The Evaluation of the Cervical Marginal Sealing of Direct vs. Indirect Composite Resin Restorations in MOD Cavities
by Bianca Tiron, Norina Consuela Forna, Ionuț Tărăboanță, Simona Stoleriu, Claudiu Topoliceanu, Mihaela Sălceanu, Răzvan Brânzan and Gianina Iovan
Dent. J. 2024, 12(4), 92; https://doi.org/10.3390/dj12040092 - 3 Apr 2024
Cited by 4 | Viewed by 3932
Abstract
Introduction: The aim of this in vitro study was to compare the quality of marginal sealing at the cervical margins of indirect and direct composite resin restorations in mesio-occluso-distal (MOD) cavities. Material and method: MOD preparations were performed on 30 extracted teeth. The [...] Read more.
Introduction: The aim of this in vitro study was to compare the quality of marginal sealing at the cervical margins of indirect and direct composite resin restorations in mesio-occluso-distal (MOD) cavities. Material and method: MOD preparations were performed on 30 extracted teeth. The mesial cervical margin of each tooth was relocated using a flow composite resin (Enamel Plus HRi Flow, Micerium, Avegno, GE, Italy), then the samples were divided into three groups. In group A, the cavities were directly restored using a nanohybrid composite resin (Miris 2 Coltène Whaledent, Altstaetten, Switzerland) and a universal adhesive (ScotchBond Universal, 3M ESPE, St. Paul, MN, USA) by the etch-and-rinse strategy, for group B, the restoration procedure was similar but the self-etch strategy was used, and the samples in group C were filled using the inlay technique. Each sample was stored for 48 h in a 2% methylene blue solution, then it was cut in a mesio-distal direction using a Struers Secotom 50 device (Cleveland, OH, USA). The marginal sealing and adhesive interface were assessed for each sample at the cervical margin by optical microscopy (OM) and scanning electron microscopy (SEM). One-way ANOVA and Bonferroni post-hoc tests were used with a significance level of 0.05. Results: Significant differences were recorded within groups A and C, between mesial and distal margins (p = 0.02 in group A and p = 0.043 in group C). Conclusions: The marginal sealing is more effective in MOD inlay restoration compared to direct restorations. Relocation of the cervical margin with flow composite resin and the use of different adhesive strategies do not improve the marginal sealing. Full article
(This article belongs to the Section Preventive Dentistry)
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14 pages, 1826 KB  
Article
Evaluation of the Clinical Variables Affecting Attachment Reproduction Accuracy during Clear Aligner Therapy
by Angela Mirea Bellocchio, Marco Portelli, Ludovica Ciraolo, Elia Ciancio, Angela Militi, Matteo Peditto, Serena Barbera and Riccardo Nucera
Materials 2023, 16(20), 6811; https://doi.org/10.3390/ma16206811 - 23 Oct 2023
Cited by 11 | Viewed by 3138
Abstract
Background: The purpose of this study was to evaluate some of the clinical variables that influence the accuracy of reproducing the planned attachment shape. The following clinical variables were considered: the template material, type of composite, and pressure application on the template during [...] Read more.
Background: The purpose of this study was to evaluate some of the clinical variables that influence the accuracy of reproducing the planned attachment shape. The following clinical variables were considered: the template material, type of composite, and pressure application on the template during attachment curing. Methods: In this study, the evaluated materials for the thermoplastic transfer template construction are Erkolen 0.8 (polyethylene: PE) and Erkodur 0.8 (polyethylene terephthalate glycol—PET-G), and two types of composite resins: Enaflow (light-curing low-viscosity composite resin) and Enamel plus dentina HRI (light-curing high-viscosity composite resin). Two different light-curing lamps were used: Valo cordless color with no pressure and push light pressure (SCS). The 26 models included in the study were imported into the 3 Shape Ortho System 2022 (ver. 85.0.20 3 Shape, Denmark), and attachments were virtually placed on the dental elements of the first premolar and on both sides of the first upper molars. The accuracy of the attachment reproduction was evaluated through linear and angular evaluations against the reference model (MCAD). Three physical models were obtained: model A (MA), which was printed with attachments; model B (MB) with attachments made with a PE template; and model C (MC) with attachments made with a PET-G template. Results: The results showed statistically significant differences (p < 0.05) between the PE and PET-G templates with greater precision using the PET-G template. Statistically significant differences (p < 0.05) were found among the high-viscosity composite and low-viscosity composite with pressure curing. Conclusions: In light of the obtained data, using a PET-G template is recommended. The pressure application during composite curing reduces the reproduction accuracy with a low-viscosity composite. Full article
(This article belongs to the Special Issue Advanced Dental Materials, Dental Technologies and Dental Care)
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12 pages, 3329 KB  
Article
In Vitro Evaluation of Candida albicans Adhesion on Heat-Cured Resin-Based Dental Composites
by Francesco De Angelis, Simonetta D’Ercole, Mara Di Giulio, Mirco Vadini, Virginia Biferi, Matteo Buonvivere, Lorenzo Vanini, Luigina Cellini, Silvia Di Lodovico and Camillo D’Arcangelo
Materials 2023, 16(17), 5818; https://doi.org/10.3390/ma16175818 - 25 Aug 2023
Cited by 3 | Viewed by 2109
Abstract
Microbial adhesion on dental restorative materials may jeopardize the restorative treatment long-term outcome. The goal of this in vitro study was to assess Candida albicans capability to adhere and form a biofilm on the surface of heat-cured dental composites having different formulations but [...] Read more.
Microbial adhesion on dental restorative materials may jeopardize the restorative treatment long-term outcome. The goal of this in vitro study was to assess Candida albicans capability to adhere and form a biofilm on the surface of heat-cured dental composites having different formulations but subjected to identical surface treatments and polymerization protocols. Three commercially available composites were evaluated: GrandioSO (GR), Venus Diamond (VD) and Enamel Plus HRi Biofunction (BF). Cylindrical specimens were prepared for quantitative determination of C. albicans S5 planktonic CFU count, sessile cells CFU count and biomass optical density (OD570 nm). Qualitative Concanavalin-A assays (for extracellular polymeric substances of a biofilm matrix) and Scanning Electron Microscope (SEM) analyses (for the morphology of sessile colonies) were also performed. Focusing on planktonic CFU count, a slight but not significant reduction was observed with VD as compared to GR. Regarding sessile cells CFU count and biomass OD570 nm, a significant increase was observed for VD compared to GR and BF. Concanavalin-A assays and SEM analyses confirmed the quantitative results. Different formulations of commercially available resin composites may differently interact with C. albicans. The present results showed a relatively more pronounced antiadhesive effect for BF and GR, with a reduction in sessile cells CFU count and biomass quantification. Full article
(This article belongs to the Special Issue Advanced Materials for Oral Application (Volume II))
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14 pages, 2427 KB  
Article
Evaluation of Artificial Intelligence-Calculated Hepatorenal Index for Diagnosing Mild and Moderate Hepatic Steatosis in Non-Alcoholic Fatty Liver Disease
by Zita Zsombor, Aladár D. Rónaszéki, Barbara Csongrády, Róbert Stollmayer, Bettina K. Budai, Anikó Folhoffer, Ildikó Kalina, Gabriella Győri, Viktor Bérczi, Pál Maurovich-Horvat, Krisztina Hagymási and Pál Novák Kaposi
Medicina 2023, 59(3), 469; https://doi.org/10.3390/medicina59030469 - 27 Feb 2023
Cited by 18 | Viewed by 4918
Abstract
Background and Objectives: This study aims to evaluate artificial intelligence-calculated hepatorenal index (AI-HRI) as a diagnostic method for hepatic steatosis. Materials and Methods: We prospectively enrolled 102 patients with clinically suspected non-alcoholic fatty liver disease (NAFLD). All patients had a quantitative [...] Read more.
Background and Objectives: This study aims to evaluate artificial intelligence-calculated hepatorenal index (AI-HRI) as a diagnostic method for hepatic steatosis. Materials and Methods: We prospectively enrolled 102 patients with clinically suspected non-alcoholic fatty liver disease (NAFLD). All patients had a quantitative ultrasound (QUS), including AI-HRI, ultrasound attenuation coefficient (AC,) and ultrasound backscatter-distribution coefficient (SC) measurements. The ultrasonographic fatty liver indicator (US-FLI) score was also calculated. The magnetic resonance imaging fat fraction (MRI-PDFF) was the reference to classify patients into four grades of steatosis: none < 5%, mild 5–10%, moderate 10–20%, and severe ≥ 20%. We compared AI-HRI between steatosis grades and calculated Spearman’s correlation (rs) between the methods. We determined the agreement between AI-HRI by two examiners using the intraclass correlation coefficient (ICC) of 68 cases. We performed a receiver operating characteristics (ROC) analysis to estimate the area under the curve (AUC) for AI-HRI. Results: The mean AI-HRI was 2.27 (standard deviation, ±0.96) in the patient cohort. The AI-HRI was significantly different between groups without (1.480 ± 0.607, p < 0.003) and with mild steatosis (2.155 ± 0.776), as well as between mild and moderate steatosis (2.777 ± 0.923, p < 0.018). AI-HRI showed moderate correlation with AC (rs = 0.597), SC (rs = 0.473), US-FLI (rs = 0.5), and MRI-PDFF (rs = 0.528). The agreement in AI-HRI was good between the two examiners (ICC = 0.635, 95% confidence interval (CI) = 0.411–0.774, p < 0.001). The AI-HRI could detect mild steatosis (AUC = 0.758, 95% CI = 0.621–0.894) with fair and moderate/severe steatosis (AUC = 0.803, 95% CI = 0.721–0.885) with good accuracy. However, the performance of AI-HRI was not significantly different (p < 0.578) between the two diagnostic tasks. Conclusions: AI-HRI is an easy-to-use, reproducible, and accurate QUS method for diagnosing mild and moderate hepatic steatosis. Full article
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12 pages, 2559 KB  
Article
Directional Scattering Switching from an All-Dielectric Phase Change Metasurface
by Gonzalo Santos, Maria Losurdo, Fernando Moreno and Yael Gutiérrez
Nanomaterials 2023, 13(3), 496; https://doi.org/10.3390/nano13030496 - 26 Jan 2023
Cited by 12 | Viewed by 4232
Abstract
All-dielectric metasurfaces are a blooming field with a wide range of new applications spanning from enhanced imaging to structural color, holography, planar sensors, and directionality scattering. These devices are nanopatterned structures of sub-wavelength dimensions whose optical behavior (absorption, reflection, and transmission) is determined [...] Read more.
All-dielectric metasurfaces are a blooming field with a wide range of new applications spanning from enhanced imaging to structural color, holography, planar sensors, and directionality scattering. These devices are nanopatterned structures of sub-wavelength dimensions whose optical behavior (absorption, reflection, and transmission) is determined by the dielectric composition, dimensions, and environment. However, the functionality of these metasurfaces is fixed at the fabrication step by the geometry and optical properties of the dielectric materials, limiting their potential as active reconfigurable devices. Herein, a reconfigurable all-dielectric metasurface based on two high refractive index (HRI) materials like silicon (Si) and the phase-change chalcogenide antimony triselenide (Sb2Se3) for the control of scattered light is proposed. It consists of a 2D array of Si–Sb2Se3–Si sandwich disks embedded in a SiO2 matrix. The tunability of the device is provided through the amorphous-to-crystalline transition of Sb2Se3. We demonstrate that in the Sb2Se3 amorphous state, all the light can be transmitted, as it is verified using the zero-backward condition, while in the crystalline phase most of the light is reflected due to a resonance whose origin is the contribution of the electric (ED) and magnetic (MD) dipoles and the anapole (AP) of the nanodisks. By this configuration, a contrast in transmission (ΔT) of 0.81 at a wavelength of 980 nm by governing the phase of Sb2Se3 can be achieved. Full article
(This article belongs to the Special Issue New Trends in Metamaterials)
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20 pages, 5903 KB  
Article
Health Risk of Heavy Metals Related to Consumption of Vegetables in Areas of Industrial Impact in the Republic of Kazakhstan—Case Study for Oskemen
by Laura Boluspayeva, Monika Jakubus, Waldemar Spychalski, Akhan Abzhalelov and Yertas Bitmanov
Int. J. Environ. Res. Public Health 2023, 20(1), 275; https://doi.org/10.3390/ijerph20010275 - 24 Dec 2022
Cited by 10 | Viewed by 3611
Abstract
Among various heavy metal sources the metallurgic industry is the most threatening because emitted metals presented are the chemical forms in which metals are found in soil are more bioavailable and thus very easily are introduced into the environment and spread in both [...] Read more.
Among various heavy metal sources the metallurgic industry is the most threatening because emitted metals presented are the chemical forms in which metals are found in soil are more bioavailable and thus very easily are introduced into the environment and spread in both soils and plants. In this study such a situation is presented and the potential negative effect of emitted metals on soil and vegetables is estimated. Therefore, the following indicators were used: bioconcentration factors calculated for the total amount of metals (BCF) as well as daily intake of metal (DIM) and health risk index (HRI). Analyzed soils and vegetables originated from allotment gardens located at different distances from local industrial plants. The greatest amounts of metals in investigated materials (soils and plants) were found for the industrial zone and the lowest for samples representing the suburban zone. Among the analyzed metals Zn showed the highest (223.94–2645.13 mg·kg−1 for soils and 9.14–49.28 mg·kg−1 for plants), and Cd the lowest levels (1.77–15.2 mg·kg−1 for soils and 0.05–0.46 mg·kg−1 for plants). Regardless of the metal, the lowest BCF values were calculated for plants from the industrial zone and the highest from the urban site. Generally, BCF values calculated for vegetables were low and comparable for carrots, tomatoes, and cabbage. BCF values obtained for beetroots were higher in comparison to other vegetables. Regardless of plants, DIM values for Cd and Pb were low and comparable. DIM values for Cu and Zn were higher, but simultaneously strongly differentiated depending on the analyzed vegetables. A similar tendency was found in the case of HRI. The highest values were recorded for Cu and Zn in tomatoes. Regardless of the individual metals, the calculated values for DIM and HRI indices increased in the following sequence: beetroot < cabbage < carrot < tomato. The Zn and Cu contents in the studied types of vegetables do not exceed the maximum permissible levels recommended by WHO/FAO. In contrast, Pb concentrations were higher than the imposed standards in all the analyzed vegetable samples. On the basis of obtained DIM and HRI indices, consumption of vegetables cultivated in industrial areas should be restricted due to health risks related to heavy metals contained in plants. Full article
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18 pages, 9221 KB  
Article
Cross-Modal Reconstruction for Tactile Signal in Human–Robot Interaction
by Mingkai Chen and Yu Xie
Sensors 2022, 22(17), 6517; https://doi.org/10.3390/s22176517 - 29 Aug 2022
Cited by 4 | Viewed by 3181
Abstract
A human can infer the magnitude of interaction force solely based on visual information because of prior knowledge in human–robot interaction (HRI). A method of reconstructing tactile information through cross-modal signal processing is proposed in this paper. In our method, visual information is [...] Read more.
A human can infer the magnitude of interaction force solely based on visual information because of prior knowledge in human–robot interaction (HRI). A method of reconstructing tactile information through cross-modal signal processing is proposed in this paper. In our method, visual information is added as an auxiliary source to tactile information. In this case, the receiver is only able to determine the tactile interaction force from the visual information provided. In our method, we first process groups of pictures (GOPs) and treat them as the input. Secondly, we use the low-rank foreground-based attention mechanism (LAM) to detect regions of interest (ROIs). Finally, we propose a linear regression convolutional neural network (LRCNN) to infer contact force in video frames. The experimental results show that our cross-modal reconstruction is indeed feasible. Furthermore, compared to other work, our method is able to reduce the complexity of the network and improve the material identification accuracy. Full article
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11 pages, 918 KB  
Article
Comparison of Mechanical Properties of a Self-Adhesive Composite Cement and a Heated Composite Material
by Anastazja Skapska, Zenon Komorek, Mariusz Cierech and Elzbieta Mierzwinska-Nastalska
Polymers 2022, 14(13), 2686; https://doi.org/10.3390/polym14132686 - 30 Jun 2022
Cited by 13 | Viewed by 3511
Abstract
(1) Background: Due to the limitations of composite cements, the authors carried out tests to compare such materials with preheated composite materials because the latter may be an alternative to cements in the adhesive cementation procedure. (2) Methods: The materials used in the [...] Read more.
(1) Background: Due to the limitations of composite cements, the authors carried out tests to compare such materials with preheated composite materials because the latter may be an alternative to cements in the adhesive cementation procedure. (2) Methods: The materials used in the adhesive cementation procedure, i.e., Enamel Plus Hri (Micerium, Avegno, Italy), a heated composite material, and RelyX U200 Automix (3M, Maplewood, MN, USA), a dual composite cement, were tested for microhardness, compressive strength, flexural strength, diametral compressive strength, and elastic modulus. Composite material was heated to the temperature of 50 degrees Celsius before polymerisation. (3) Results: Higher values of microhardness (by 67.36%), compressive strength (by 41.84%), elastic modulus (by 17.75%), flexural strength (by 36.03%), and diametral compressive strength (by 45.52%) were obtained using the Enamel Plus Hri composite material compared to the RelyX U200 self-adhesive cement. The survey results revealed statistically significant differences. (4) Conclusions: Due to its better mechanical properties, the heated composite material (Enamel Plus Hri) is a beneficial alternative to composite cements in the indirect restoration placement procedure. As the strength parameters of the heated composite material increase, a higher resistance to the compressive and bending forces present in the oral cavity, and hence a greater durability of the created prosthetic reconstructions can be expected. Full article
(This article belongs to the Special Issue Polymers Composites for Dental Applications)
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13 pages, 3210 KB  
Article
High Refractive Index Diphenyl Sulfide Photopolymers for Solar Cell Antireflection Coatings
by Jingran Zhang, Baozhu Li, Heran Song, Chen Zhao, Songfeng Liang, Zhurong Dong and Jie Yu
Energies 2022, 15(11), 3972; https://doi.org/10.3390/en15113972 - 27 May 2022
Cited by 13 | Viewed by 4773
Abstract
The anti-reflection film can effectively reduce the surface reflectivity of solar photovoltaics, increase the transmittance of light, and improve the photoelectric conversion efficiency. The high refractive index coating is an important part of the anti-reflection film. However, the traditional metal oxide coating has [...] Read more.
The anti-reflection film can effectively reduce the surface reflectivity of solar photovoltaics, increase the transmittance of light, and improve the photoelectric conversion efficiency. The high refractive index coating is an important part of the anti-reflection film. However, the traditional metal oxide coating has poor stability and complicated processes. To address this issue, we prepared two organic high refractive index (HRI) photopolymers by modifying epoxy acrylic acid with 4,4′-thiodibenzenethiol, which can be surface patterned by nanoimprinting to prepare antireflection coatings. As a result, two modified photopolymers with high refractive index (n > 1.63), high optical transmittance (T > 95%), and thermal stability (Tg > 100 °C) are obtained after curing. In particular, the diphenyl sulfide photopolymer modified by ethyl isocyanate acrylate has a refractive index up to 1.667 cured by UV light. Our work confirms that the organic HRI photopolymer can be obtained by introducing high molar refractive index groups, with potential to be applied as a PV cell power conversion efficiency material. Full article
(This article belongs to the Special Issue Advanced Research on Fuel Cells and Hydrogen Energy Conversion)
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14 pages, 5907 KB  
Article
A Reliable Method of Measuring the Conversion Degrees of Methacrylate Dental Resins
by Mirosław Kwaśny, Aneta Bombalska and Karolina Obroniecka
Sensors 2022, 22(6), 2170; https://doi.org/10.3390/s22062170 - 10 Mar 2022
Cited by 18 | Viewed by 4739
Abstract
The main aim of the study was to implement the most reliable method of measuring the degrees of conversion during photopolymerization of dental fillings. Contrary to the methods used so far, the method is based only on comparison with the monomer absorbance spectrum [...] Read more.
The main aim of the study was to implement the most reliable method of measuring the degrees of conversion during photopolymerization of dental fillings. Contrary to the methods used so far, the method is based only on comparison with the monomer absorbance spectrum without reference bands. Another aim of the study was to prepare a comparative analysis of the polymerization kinetics of dental resins under various light sources and different environmental conditions (irradiance, light dose, temperature), with estimation of the degrees of conversion (DC) of the resins being the main metric. HRi Universal Enamel (UE2) and HRi Universal Dentine (UD2) were examined under two different types of light sources used in dentistry, LED and halogen. DC was measured by Fourier transform infrared spectroscopy (FTIR) in transmission mode from 5 s up to 7 days. Spectra were recorded from the parallel optical layers of samples that were placed between the KBr crystals. The results are expressed by the changes in the absorbance spectrum during the polymerization and the calculated conversion rates. The results of each experiment were averaged from three separate measurements of three samples, during which the samples were illuminated under identical conditions. The data were analyzed by performing ANOVA test comparisons between sample groups at the significance level α = 0.05. The degree of conversion of the UD2 resin was higher than that of UE2 for each experimental condition, but there was no statistically significant difference between the DC of those materials (p > 0.05). There was statistically significant difference (p < 0.01) in the DC caused by LED and halogen light sources producing the same light doses (38 J/cm2). This was the result of different features of light transmission to the filler in the resin composite. The efficacy of the LED source is twice as high as that of the halogen light source. Maximal DC without any other differences in conditions, such as resin type or light source, reached around 70% for temperatures of 22–37 °C. For 37 °C, this took 24 h, which is a contrast to the 7 days it took for 23 °C. The influences of different conditions and factors on reaction kinetics are only strong in the early and the rapid stage of conversion. The optimal time of irradiance using either light source is 20 s for a monolayer, and its thickness should not exceed 2 mm. Full article
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19 pages, 6003 KB  
Article
Artificial Eyes with Emotion and Light Responsive Pupils for Realistic Humanoid Robots
by Carl Strathearn
Informatics 2021, 8(4), 64; https://doi.org/10.3390/informatics8040064 - 23 Sep 2021
Cited by 3 | Viewed by 9320
Abstract
This study employs a novel 3D engineered robotic eye system with dielectric elastomer actuator (DEA) pupils and a 3D sculpted and colourised gelatin iris membrane to replicate the appearance and materiality of the human eye. A camera system for facial expression analysis (FEA) [...] Read more.
This study employs a novel 3D engineered robotic eye system with dielectric elastomer actuator (DEA) pupils and a 3D sculpted and colourised gelatin iris membrane to replicate the appearance and materiality of the human eye. A camera system for facial expression analysis (FEA) was installed in the left eye, and a photo-resistor for measuring light frequencies in the right. Unlike previous prototypes, this configuration permits the robotic eyes to respond to both light and emotion proximal to a human eye. A series of experiments were undertaken using a pupil tracking headset to monitor test subjects when observing positive and negative video stimuli. A second test measured pupil dilation ranges to high and low light frequencies using a high-powered artificial light. This data was converted into a series of algorithms for servomotor triangulation to control the photosensitive and emotive pupil dilation sequences. The robotic eyes were evaluated against the pupillometric data and video feeds of the human eyes to determine operational accuracy. Finally, the dilating robotic eye system was installed in a realistic humanoid robot (RHR) and comparatively evaluated in a human-robot interaction (HRI) experiment. The results of this study show that the robotic eyes can emulate the average pupil reflex of the human eye under typical light conditions and to positive and negative emotive stimuli. However, the results of the HRI experiment indicate that replicating natural eye contact behaviour was more significant than emulating pupil dilation. Full article
(This article belongs to the Section Human-Computer Interaction)
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