Search Results (100)

In order to address vibration and noise challenges in modern industry while satisfying the lightweighting requirements for aerospace and transportation applications, the development of polymer elastomers integrating both lightweight and high-damping properties holds substantial significance. This study developed polyurethane (PU) with optimized damping and mechanical properties at room temperature through monomer composition optimization. Hollow glass microspheres (HGMs) were introduced into the PU matrix to increase stiffness and reduce density, though this resulted in decreased tensile strength (Rm) and loss factor (tanδ). To further improve mechanical and damping properties, we applied a carbon coating to the surface of the HGMs to optimize the interface between the HGMs and the PU matrix, and systematically investigated the energy dissipation and load-bearing behavior of PU composites. The effect of enhanced interface damping of HGM@C/PU resulted in broadening of the effective damping temperature range (tanδ ≥ 0.3) and higher maximum loss factor (tanδ_max) compared to HGM/PU at equivalent filler loading. The tensile and dynamic properties significantly improved due to optimized interfacial adhesion. In PU composites reinforced with 10 wt% HGM and HGM@C, a 46.8% improvement in Rm and 11.0% improvement in tanδ_max occurred after carbon coating. According to acoustic testing, average transmission loss of HGM/PU and HGM@C/PU with the same filler content showed a difference of 0.3–0.5 dB in 500–6300 Hz, confirming that the hollow structure of the HGMs was preserved during carbon coating. Full article

High-gradient magnetic separation is a key step in the pre-concentration of ilmenite before flotation, particularly in the gravity separation process. However, as the amount of weakly magnetic gangue minerals increases, the grade of the coarse concentrate from high-gradient magnetic separation decreases. This paper investigates the mineralogical factors affecting the enrichment efficiency of high-gradient magnetic separation. Additionally, a newly developed stirred fluidized bed device, an agitated reflux classifier (ARC), was successfully applied to remove weakly magnetic gangue minerals that are difficult to separate by high-gradient magnetic separation (HGMS). For low-grade ilmenite with a feed grade of 3.97%, a combined process of magnetic separation and gravity separation was employed, achieving a concentrate with a grade of 16.50% and a recovery rate of 54.11%. This concentrate meets the requirements for flotation feed. This study provides a new approach for the beneficiation of low-grade ilmenite. Full article

High-gradient magnetic separation (HGMS) is a conventional and effective method for processing weak magnetic materials. A multi-field dynamic coupling simulation method integrating the Finite Element Method (FEM), Computational Fluid Dynamics (CFD), and the Discrete Element Method (DEM) was employed to investigate the separation behavior in HGMS. The dynamic deposition process of magnetic particles under the interactions of magnetic fields, fluid flow fields, and particle–particle forces was simulated using a two-way fluid–solid coupling algorithm based on the FEM-CFD-DEM coupling approach. Experimental results demonstrated that the particle deposition profiles predicted by the double-wire medium model were in good agreement with the measured data. The research findings indicated that the separation process could be divided into three distinct stages—the adsorption stage, the closure stage, and the clogging stage—each characterized by unique dynamic behaviors and pressure-drop evolution patterns. Additionally, the effects of key parameters such as the feeding velocity and medium filling ratio on the separation process were analyzed, providing theoretical foundations and technical support for the optimization of HGMS processes and the enhancement of separation efficiency. Full article

In order to cope with the emergence of energy conservation and consumption reduction initiatives, we used an acrylic emulsion (as the adhesive), combined with silica aerogel (SA) and hollow glass microsphere (HGM) fillers, to synthesize thermal insulation coatings, which were found to have low thermal conductivity and excellent thermal insulation properties. These waterborne coatings are environmentally friendly and were synthesized without organic solvents. Comprehensive testing verified that the coatings met practical requirements. Specifically, the addition of 18% SA resulted in minimal thermal conductivity (0.0433 W/m·K), the lowest density (0.177 g/cm³), as well as a reduced gross calorific value. At a heating surface temperature of 200 °C, the 5 mm coating’s cooling surface temperature was 108.7 °C, yielding a 91.3 °C temperature difference and demonstrating remarkable thermal insulation performance. Furthermore, the coatings showed favorable results in terms of water resistance, corrosion resistance, wear resistance, and adhesion, achieving satisfactory engineering standards. In this work, the influence of different contents of SA on various properties of the coating was studied, with the aim of providing a reference for the modulation of the comprehensive performance of SA thermal insulation coatings. Full article

As a promising and sustainable construction material, alkali-activated slag lightweight high-strength concrete (AAS-LWHSC) may be influenced by lightweight aggregate (LWA) content. In this study, the effects of hollow glass microspheres (HGM) replacing granulated ground blast furnace slag (GGBFS) under varying LWA dosages on the workability, dry apparent density, mechanical properties, and microstructure of AAS-LWHSC were investigated. The results indicated that the dry density of concrete was significantly reduced by HGM, while the “ball-bearing” effect of HGM was observed to enhance workability at a dosage of 6%. The 7-day mechanical properties of AAS-LWHSC were found to decline progressively with increasing HGM content. However, at the shale ceramsite sand replacement rates of 35% and 65%, the incorporation of 6% HGM slightly improved the 28-day mechanical properties. Due to the absence of the water-releasing effect from shale ceramsite, the pozzolanic reactions of HGM were restricted, resulting in coarse hydration products and a reduction in the mechanical performance of AAS-LWHSC. Full article

With the continuous advancement of electromagnetic protection technologies, the development of lightweight electromagnetic wave-absorbing materials with excellent absorption performance has become a critical challenge in the field. In this study, commercially available hollow glass microspheres (HGMs) were employed as templates, and Ni²⁺/Co²⁺ metal ions were used to catalyze the polymerization of dopamine (PDA), forming HGM@Ni_xCo_y/PDA precursors. Subsequent high-temperature pyrolysis yielded lightweight composite absorbing materials, denoted as HGM@Ni_xCo_y/C. This material integrates dielectric loss, conductive loss, magnetic loss, and resonance absorption mechanisms, exhibiting outstanding electromagnetic wave absorption properties. The absorption performance can be effectively tuned by adjusting the Ni-to-Co ratio, with the optimal performance observed at an atomic ratio of 2:3. At a filler loading of 20 wt.%, HGM@Ni₂Co₃/C achieved an effective absorption bandwidth (EAB) of 6.83 GHz (ranging from 10.53 to 17.36 GHz) and a minimum reflection loss (RL_min) of −27.26 dB. These results demonstrate that the synergistic combination of hollow glass bubbles and carbon-based magnetic components not only significantly reduces the material density and required filler content but also enhances overall absorption performance, highlighting its great potential in the development of lightweight and high-efficiency electromagnetic wave absorbers. Full article

Highly heat-resistant and low-dielectric materials are crucial for achieving high-frequency communication, high-density integration, and high-temperature stability in modern electronics. In this work, surface modification of hollow silica microspheres (HGMs) using a silane coupling agent ((3-aminopropyl)triethoxysilane, KH550) yielded KHGM particles with a coating content of approximately 9.3 wt%, which were subsequently incorporated into high-performance polyarylene ether nitrile (PEN) polymers to fabricate composite films. The modified nanoparticles demonstrated significantly enhanced compatibility with the polymer matrix, while their hollow structure effectively reduced the dielectric constant of the composite film. When loaded with 50 wt% KHGM particles, the PEN-based composite film exhibited an elevated glass transition temperature of 198 °C and achieved a dielectric constant as low as 2.32 at 1 MHz frequency, coupled with dielectric loss below 0.016; compared with pure PEN, the dielectric constant of PEN/KHGM-50% decreased by 26.47%. Additionally, the composite demonstrated excellent water repellency. These advancements provide high-performance material support for applications in electronic communications, aerospace, and related fields. Full article

Stereolithography (SLA) is a popular additive manufacturing (AM) method frequently used in research and various industrial sectors. The acrylate resin used in this research is renowned for its flexibility and durability, enabling the creation of flawless 3D-printed parts with exceptional mechanical properties. This study aims to enhance the thermomechanical properties of 3D-printed hollow glass microballoon (HGM)-filled composite materials by adding minimal HGM into the acrylate resin. We investigated the material properties through uniaxial compression tests, dynamic mechanical analysis (DMA), and scanning electron microscopy (SEM). To validate the results, a numerical investigation and a machine learning (ML) approach were carried out and compared with the experimental results. Adding a small number of microballoons increases compressive strength and stiffness. The viscoelastic behavior of the samples also provides an estimate of resilience at higher temperatures, considering the addition of filler material into the resin. Our study shows that the addition of 0.04% of HGM increased compressive strength by around 99.30% compared to the neat sample, while the stiffness increased by around 31.42% compared to the neat sample at 0.05% of HGM. It can also be estimated that the suitable range of HGM addition for the resin we used exists between 0.04% and 0.05%, where the materials achieve their maximum strength and stiffness. In addition, a predictive machine learning (ML) model, namely Random Forest Regressor (RFR), shows low mean squared error (MSE), mean absolute error (MAE), and excellent R² scores, demonstrating the goodness of the model’s performance. This modern approach can guide us to selecting a suitable filler percentage for the photopolymer resin for 3D printing and making it applicable to different engineering prospects. Full article

The heat transfer mechanism of hollow glass microsphere/epoxy resin composites (HGM/ER) is intricate, and the formation of void structures during material preparation complicates the prediction of thermal conductivity. To investigate the microscopic heat transfer mechanisms of HGM/ER materials with void structures and analyze the impact of void variables on the overall thermal performance, this study addresses the issue of low packing density and poor uniformity in traditional cellular unit structures. An improved random sequential adsorption (RSA) algorithm is proposed, increasing the upper limit of particle fill rate by 25% relative to traditional RSA algorithms. The Benveniste equivalent microsphere thermal conductivity model is selected for thermal performance simulation, demonstrating its high correlation with the three-component model (air, glass, resin), with a maximum relative error of only 1.32%. A classification method for void types in HGM/ER materials is proposed, categorizing them into interfacial and free voids. The microscopic heat transfer mechanisms of HGM/ER materials are investigated under different voids levels and void types, and it was found that the effect of interfacial voids on thermal conductivity is 60% higher than that of free voids. Based on the measured voids of the material, this study provides a reference for the convenient prediction of thermal conductivity in practical engineering applications of HGM/ER composites. Full article

This study explores the synergistic development of natural gypsum-based composites (NGBCs) with enhanced multifunctional characteristics, employing hollow glass microspheres (HGMs) as density-reducing agents and sisal fibers (SFs) as mechanical reinforcement phases while maintaining superior whiteness properties. Five HGM variants with precisely graded particle sizes (20, 40, 60, 80, and 100 μm) were systematically incorporated into the composite matrix. Sisal fibers with controlled length parameters (10–15 mm) were uniformly dispersed within the gypsum matrix. The multifunctional effects of these additives were comprehensively assessed via integrated mechanical characterization, spectrophotometric whiteness evaluation, and microstructural interrogation. The findings revealed that the incorporation of HGMs resulted in a significant decrease in the NGBC density while concurrently enhancing whiteness; they also exerted an adverse impact on both processability and mechanical properties. Moreover, the fusion of HGMs and SFs within the NGBCs achieved an optimal balance between lightness and strength. The peak density of NGBCs was ascertained to be 1.41 g/cm³, complemented by flexural and compressive strengths of 6.12 and 9.78 MPa, respectively. Such optimizations were realized with HGMs at a particle size of 80 um and a composition of 20 vol.%, alongside sisal fibers present at a concentration of 0.3 vol.%. The current research affords significant revelations regarding the fabrication of architectural gypsum materials that are lightweight, possess high tensile strength, exhibit an aesthetically appealing finish, and demonstrate superior whiteness, presenting a prospective resolution for applications within the high-performance construction sector. Full article

Polydimethylsiloxane (PDMS) is known for its exceptional mechanical properties, chemical stability, and flexibility. Recent advancements have focused on developing functional PDMS composites by integrating various functional fillers, including polymers, ceramics, and metals, for advanced applications such as electronics, medical devices, and aerospace. Consequently, there is a growing need to investigate PDMS composites to achieve higher filler loadings offering enhanced mechanical performance. This study addresses this need by utilizing the high molecular weight (MW) PDMS resin we have developed, offering its high elongation capacity of up to >6500%. We incorporated boron (B), hollow glass microballoons (HGMs), and tungsten-coated hollow glass microballoons (WHGMs) into the developed high MW PDMS. The resulting composites demonstrated excellent elastic properties and significant compression resilience (35–80%) and elastic modulus (1.28–10.15 MPa) at high filler loadings (~60 vol.%). Specifically, B/PDMS composites achieved up to 67.6 vol.% of B, HGM/PDMS composites held up to 68.6 vol.% of HGM, and WHGM/PDMS composites incorporated up to 54.0 vol.% of WHGM. These findings highlight the potential of high MW PDMS for developing high-performance PDMS composites suitable for advanced applications such as aerospace, automotive, and medical devices. Full article

Transverse-field high-gradient magnetic separators (HGMSs) are an important complement to longitudinal-field HGMSs in mineral processing due to their several advantages. However, the processing capacity of the transverse-field HGMS is smaller than that of the longitudinal-field HGMS. Consequently, research on the optimization of the matrix box for improving the processing capacity is essential. This work investigates the optimization of the matrix box for the SSS^® HGMS to enhance the ilmenite separation efficiency and processing capacity. The results show that the matrix’s influence on separation performance is primarily influenced by the diameter of the rod matrix, the filling ratio, the depth of the matrix in the direction of slurry flow, and the ore unloading efficiency. Ilmenite pre-concentration tests are carried out using a test sample ore from Panzhihua, China. Pilot-scale validation research is carried out. The test results indicate that the depth of the matrix box should not be considerably thick, as an excessive number of layers increases the capture zone, but simultaneously reduces the unloading efficiency. The depth of the matrix box should neither be considerably thick nor particularly thin, as this would result in low processing capacity. Meanwhile, the segmented multi-layer matrix box should be used to balance the capturing and unloading performance. Finally, an optimal double-layer matrix ring is applied to the industrial transverse-field HGMS, and its inner and outer rings are equipped with matrix boxes with ϕ3 mm and ϕ2 mm rods, respectively, which improves its pre-concentrate efficiency and processing capacity. The concentrate indexes of the transverse-field HGMS is achieved with a TiO₂ grade of 18.01% and a recovery of 87.28%, which is better than the separation indexes of the longitudinal-field HGMS. Full article

Oxidative stress caused by reactive oxygen species (ROS) affects the aging process and increases the likelihood of several diseases. A new frontier in its prevention includes bioactive foods and natural extracts that can be introduced by the diet in combination with specific probiotics. Among the natural compounds that we can introduce by the diet, Panax ginseng extract is one of the most utilized since it contains a vast number of bioactive molecules such as phenolic acids, flavonoids, and polysaccharides that have been shown to possess antioxidant, anti-ageing, anti-cancer, and immunomodulatory activity. In this work, the ability of a P. ginseng extract in combination with a probiotic formulation was taken into consideration to evaluate its effects on the modulation of in vitro reconstructed human gut microbiota (HGM). After evaluating the growth of the individual strains on the ginseng extract, we tested the in vitro reconstructed HGM setup (probiotics, minimal core, and whole community) using 2% w/v ginseng as the only carbon and energy source. The probiotic strains reached the highest growth, while the minimal core and the whole community showed almost the same growth. Specifically, the presence of the ginseng extract favors L. plantarum and B. animalis subsp. lactis among the probiotics, while B. cellulosilyticus prevails over the other strains in the minimal core condition. In the presence of both probiotics and minimal core strains, L. plantarum, B. animalis subsp. lactis, and B. cellulosilyticus reach the highest growth values. The bacterial metabolites produced during ginseng extract fermentation in the three conditions were administered to human intestinal epithelial cells (HT-29) to investigate a potential antioxidant effect. Remarkably, our results highlighted a significant reduction in the total ROS and a slightly reduction in the cytosolic superoxide anion content in HT-29 cells treated with bacterial metabolites deriving from ginseng extract fermentation by the whole community. Full article

Hollow glass microsphere (HGM) reinforced composites are a suitable alternative to energy absorption materials in the automotive and aerospace industries, because of their high crush efficiency and energy absorption characteristics. In this study, a polyurethane elastomeric matrix was reinforced with HGMs for HGM loadings ranging from 0 to 70 vol% (volume fraction). Quasi-static uniaxial compression tests were performed, subjecting the composite to compressive strains of up to 65%, to assess stress vs. strain and energy absorption characteristics. The results reveal that samples with a higher concentration of spheres generally exhibit better crush efficiency. Specifically, the highest crush efficiency was observed in samples with a 70 vol% HGM loading. A similar relationship was reflected in the energy absorption efficiency results, with the highest energy absorption observed in the 65 vol% sample. A correlation exists between the concentration of HGMs and important metrics such as mean crush stress and energy absorption efficiency. However, it is crucial to note that the optimal choice of sphere concentration varies depending on the desired performance characteristics of the material. Full article

Background/Objectives: Diet significantly influences gut microbiota (GM), with variations in GM responses linked to the type and quantity of food consumed. These variations underscore the need for personalized nutrition. The Stance4Health (S4H) project developed the S4H Food Frequency Questionnaire (S4H-FFQ) and the i-Diet S4H app to assess dietary intake of foods affecting GM. This study aimed to validate the S4H-FFQ against the validated I.Family-FFQ and the i-Diet S4H app; Methods: The S4H-FFQ, with 200 food items across 14 food groups, evaluates dietary intake over the past month. Qualitative validation compared food group consumption frequencies from the S4H-FFQ and the I.Family-FFQ, while quantitative validation assessed nutrient and energy intake using the i-Diet S4H app. The S4H-GM score, a measure of GM-relevant food consumption, was evaluated through the S4H-FFQ and i-Diet S4H app; Results: Pearson correlations between the S4H-FFQ and the I.Family-FFQ ranged from 0.3 to 0.7 and were statistically significant across all the food groups. Quantitative validation showed lower but consistent correlations, comparable with other studies, confirming the S4H-FFQ’s ability to estimate food intake. A positive correlation was also found between the S4H-GM scores from the S4H-FFQ and the i-Diet S4H app (p < 0.001); Conclusions: The S4H-FFQ is a reliable tool for assessing dietary patterns that influence GM. Its application in nutritional studies can enhance personalized nutrition and support future research aimed at optimizing GM and improving health outcomes. Full article