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Keywords = Dolomite Alps

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22 pages, 2418 KB  
Article
Environmental Mercury Exposure in Residents and Occupational Groups of Coastal Areas of the Marano and Grado Lagoon (Northern Adriatic Sea, Italy)
by Luca Cegolon, Emilia Patriarca, Elisa Petranich, Giuseppe Mastrangelo, Francesca Larese Filon, Donatella Sansone and Stefano Covelli
Environments 2026, 13(3), 159; https://doi.org/10.3390/environments13030159 - 13 Mar 2026
Viewed by 1202
Abstract
The Marano and Grado lagoon (Northern Adriatic Sea, Italy) has been affected by long-standing mercury (Hg) pollution due to inputs from the Isonzo River—mainly in the form of cinnabar (HgS)—and inorganic Hg conveyed into the lagoon by discharges from the chlor-alkali plant of [...] Read more.
The Marano and Grado lagoon (Northern Adriatic Sea, Italy) has been affected by long-standing mercury (Hg) pollution due to inputs from the Isonzo River—mainly in the form of cinnabar (HgS)—and inorganic Hg conveyed into the lagoon by discharges from the chlor-alkali plant of Torviscosa. The present study compared different occupational sub-groups along the Marano and Grado lagoon against residents of the Dolomites Alps. Seventy-three local fishermen, 81 workers of the fish industry, and 76 local workers (52 employees of a large adhesive factory and 24 workers of an oil mill) of Porto Nogaro were recruited by convenience sampling. Hair mercury levels of the latter three groups were compared with those of 93 residents of the Dolomites Alps. Linear and logistic regression analyses were used to assess the association of hair mercury with various factors collected by a structured questionnaire. Median hair Hg levels were significantly lower in Dolomites’ residents (0.58 mg/Kg) compared to Porto Nogaro workers (1.31 mg/Kg), workers of the fish industry (2.32 mg/Kg) or fishermen (2.56 mg/Kg), following an upward trend. After adjusting for a number of potential confounders, the concentration of hair Hg progressively increased with fish intake at linear and logistic regression analysis. Advising to limit the consumption of locally caught fish to no more than one meal per week should not be restricted to pregnant women and children, but should also be extended to adults, in order to avoid the potential long-term neurological effects of low-dose Hg exposure. It is crucial to remain vigilant and continue monitoring Hg environmental contamination in the lagoon across various environmental matrices, such as sediments, water, fish, shellfish and birds. Regardless of Hg levels measured in the workplace, occupational health protocols of steel plants along the coastal area of the Marano and Grado lagoon should include biological monitoring of Hg, to disentangle the effect of occupational exposure from non-occupational exposure to the metal. Full article
(This article belongs to the Special Issue Environmental Chemical Exposure and Human Health)
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22 pages, 40180 KB  
Article
A Sentinel-1 Based Hybrid Interferometric Approach to Complement EGMS for Landslides Identification
by Matteo Mantovani, Federica Ceccotto, Angelo Ballaera, Emilia Bertorelle, Giulia Bossi, Gianluca Marcato and Alessandro Pasuto
Remote Sens. 2025, 17(23), 3849; https://doi.org/10.3390/rs17233849 - 27 Nov 2025
Viewed by 717
Abstract
This study introduces a Hybrid Interferometric Approach (HIA) tailored for the detection, mapping, and measurement of landslides using Sentinel-1 satellite data. The HIA is specifically designed to identify ground displacements that exceed the detection thresholds of the European Ground Motion Service (EGMS), offering [...] Read more.
This study introduces a Hybrid Interferometric Approach (HIA) tailored for the detection, mapping, and measurement of landslides using Sentinel-1 satellite data. The HIA is specifically designed to identify ground displacements that exceed the detection thresholds of the European Ground Motion Service (EGMS), offering an enhanced capacity for monitoring faster-moving landslides. The methodology integrates multi-baseline interferometric analysis, utilizing backscattered signals from both point-like and distributed radar targets at full spatial resolution. The approach utilizes ten interferometric datasets acquired between 2017 and 2021 from both ascending and descending orbits. Each annual dataset is restricted to a six-month observation window to reduce temporal decorrelation effects. The HIA was implemented in a landslide-prone sector of the Dolomites, a UNESCO World Heritage Site located in the Eastern Italian Alps. Comparative evaluation against EGMS ground motion products demonstrates that the HIA significantly broadens the range of detectable slope instabilities, thus providing a valuable supplement to existing ground motion monitoring services and contributing meaningfully to landslide hazard assessment and risk reduction efforts. Full article
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13 pages, 5283 KB  
Article
Assessing the Conservation Priority of Alpine Carabid Beetle Communities by Mapping the Index of Natural Value (INV) in Natura 2000 Habitats in the Brenta Dolomites (Italian Alps)
by Emiliano Peretti, Marco Armanini, Roberta Chirichella, Andrea Mustoni and Mauro Gobbi
Insects 2025, 16(6), 602; https://doi.org/10.3390/insects16060602 - 7 Jun 2025
Cited by 1 | Viewed by 1561
Abstract
The Dolomites (European Alps) are a UNESCO World Heritage Site known to harbor distinctive communities of carabid beetles adapted to high-altitude environments, whose composition is shaped mainly by landform and habitat type. We aimed to assess the conservation priority of carabid beetle communities [...] Read more.
The Dolomites (European Alps) are a UNESCO World Heritage Site known to harbor distinctive communities of carabid beetles adapted to high-altitude environments, whose composition is shaped mainly by landform and habitat type. We aimed to assess the conservation priority of carabid beetle communities in the Brenta mountain group (Italy). We used the Index of Natural Value (INV), based on the relative frequencies and abundances of highly specialized Alpine species, as a proxy of the sensitivity to disturbance, and, thus, to the vulnerability of the carabid beetle communities to extinction. We used information on Natura 2000 habitat cover to produce a map for identifying areas of the Brenta Dolomites inhabited by the carabid beetle communities most relevant for conservation. We also report on the main differences in terms of species composition between the investigated communities. We found a positive correlation between vulnerability and altitude. Specifically, the most vulnerable communities were recorded in high-altitude habitat types (limestone cliffs and pavements, calcareous and calcschist screes, and alpine calcareous grasslands). Alkaline fens resulted in having the least vulnerable community, while those in all other habitats (bush and forests) were found to have intermediate levels of vulnerability. Full article
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24 pages, 59583 KB  
Article
Proposed Solution for Stony Debris-Flow Control Works in Two Headwater Basins with Morphological Changes
by Mauro Boreggio, Matteo Barbini, Martino Bernard, Massimo Degetto and Carlo Gregoretti
GeoHazards 2024, 5(4), 1346-1369; https://doi.org/10.3390/geohazards5040064 - 18 Dec 2024
Cited by 1 | Viewed by 1680
Abstract
Stony debris flows originating from the two basins of Jaron di Sacomedan and Jaron dei Ross pose a significant threat to the inhabited area of Chiapuzza (Dolomites, Northeastern Italian Alps) and the national road SS 51. In the upper part of the Jaron [...] Read more.
Stony debris flows originating from the two basins of Jaron di Sacomedan and Jaron dei Ross pose a significant threat to the inhabited area of Chiapuzza (Dolomites, Northeastern Italian Alps) and the national road SS 51. In the upper part of the Jaron dei Ross basin, a large scree at the foot of a rocky amphitheater undergoes morphological changes due to frequent rockfalls. Previous mitigation efforts have proven inadequate, and after identifying the causes of their failure, new control measures are being planned. These works aim to direct debris flows towards a deposition area capable of intercepting flows from both the Jaron dei Ross and Jaron di Sacomedan basins. Essentially, the upper works in the Jaron dei Ross basin divert debris flows away from the populated area and channel them to a location where the sediment volume transported by debris flows from both basins can be stored. This solution is designed to protect both the Chiapuzza community and the SS51 national road. Full article
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11 pages, 2978 KB  
Article
Bedrock-Dependent Effects of Climate Change on Terricolous Lichens Along Elevational Gradients in the Alps
by Chiara Vallese, Luca Di Nuzzo, Luana Francesconi, Paolo Giordani, Daniel Spitale, Renato Benesperi, Gabriele Gheza, Petra Mair and Juri Nascimbene
J. Fungi 2024, 10(12), 836; https://doi.org/10.3390/jof10120836 - 3 Dec 2024
Cited by 2 | Viewed by 1759
Abstract
In this study, we focused on the bedrock-dependent effects of climate change on terricolous lichen communities along elevational gradients in the Alps. In particular, we contrasted between carbonatic and siliceous bedrock, hypothesizing more favourable conditions on siliceous than on carbonatic bedrock, where dryer [...] Read more.
In this study, we focused on the bedrock-dependent effects of climate change on terricolous lichen communities along elevational gradients in the Alps. In particular, we contrasted between carbonatic and siliceous bedrock, hypothesizing more favourable conditions on siliceous than on carbonatic bedrock, where dryer conditions may exacerbate the effects of climate change. To test this hypothesis, we compared terricolous lichen diversity patterns between the two bedrock types in terms of (1) species richness, (2) beta-diversity, (3) proportion of cryophilous species, and (4) functional diversity, also testing the effect of the elevational gradient as a proxy for expected climate warming. Our results indicate that the most cold-adapted part of the terricolus lichen biota of the Alps could be especially threatened in the near future, mainly on carbonatic bedrock. Actually, contrasting diversity patterns were found between carbonatic and siliceous bedrock, clearly revealing a bedrock-dependent effect of climate change on terricolous lichens of the Alps. As hypothesized, siliceous bedrock hosts a richer lichen biota than carbonatic bedrock, reflecting a general richness pattern at the national level. In general, siliceous bedrock seems to be less prone to rapid pauperization of its lichen biota, providing more suitable climatic refugia that can mitigate the effects of climate warming on terricolous lichens. Full article
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29 pages, 8926 KB  
Article
A Sentinel-2 Based Multi-Temporal Monitoring Framework for Wind and Bark Beetle Detection and Damage Mapping
by Anna Candotti, Michaela De Giglio, Marco Dubbini and Enrico Tomelleri
Remote Sens. 2022, 14(23), 6105; https://doi.org/10.3390/rs14236105 - 1 Dec 2022
Cited by 40 | Viewed by 7420
Abstract
The occurrence of extreme windstorms and increasing heat and drought events induced by climate change leads to severe damage and stress in coniferous forests, making trees more vulnerable to spruce bark beetle infestations. The combination of abiotic and biotic disturbances in forests can [...] Read more.
The occurrence of extreme windstorms and increasing heat and drought events induced by climate change leads to severe damage and stress in coniferous forests, making trees more vulnerable to spruce bark beetle infestations. The combination of abiotic and biotic disturbances in forests can cause drastic environmental and economic losses. The first step to containing such damage is establishing a monitoring framework for the early detection of vulnerable plots and distinguishing the cause of forest damage at scales from the management unit to the region. To develop and evaluate the functionality of such a monitoring framework, we first selected an area of interest affected by windthrow damage and bark beetles at the border between Italy and Austria in the Friulian Dolomites, Carnic and Julian Alps and the Carinthian Gailtal. Secondly, we implemented a framework for time-series analysis with open-access Sentinel-2 data over four years (2017–2020) by quantifying single-band sensitivity to disturbances. Additionally, we enhanced the framework by deploying vegetation indices to monitor spectral changes and perform supervised image classification for change detection. A mean overall accuracy of 89% was achieved; thus, Sentinel-2 imagery proved to be suitable for distinguishing stressed stands, bark-beetle-attacked canopies and wind-felled patches. The advantages of our methodology are its large-scale applicability to monitoring forest health and forest-cover changes and its usability to support the development of forest management strategies for dealing with massive bark beetle outbreaks. Full article
(This article belongs to the Special Issue Remote Sensing for Mountain Ecosystems)
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24 pages, 70080 KB  
Article
Reaching the Monophyly: Re-Evaluation of the Enigmatic Species Tenuibiotus hyperonyx (Maucci, 1983) and the Genus Tenuibiotus (Eutardigrada)
by Daniel Stec and Witold Morek
Animals 2022, 12(3), 404; https://doi.org/10.3390/ani12030404 - 8 Feb 2022
Cited by 18 | Viewed by 3739
Abstract
Revisions and redescriptions of taxa described in the past and that are now categorized as insufficiently diagnosed often play a crucial role in making further progress in modern taxonomy in many groups of organisms. Here we revised an enigmatic tardigrade species Tenuibiotus hyperonyx [...] Read more.
Revisions and redescriptions of taxa described in the past and that are now categorized as insufficiently diagnosed often play a crucial role in making further progress in modern taxonomy in many groups of organisms. Here we revised an enigmatic tardigrade species Tenuibiotus hyperonyx (Maucci, 1983) based on the newly discovered topotypic population from the Italian Alps. We performed an integrative analysis of morphological and genetic data in order to present an upgraded species description and elucidate its phylogenetic position. Our results enabled us to confidently place T.hyperonyx within the family Richtersiusidae, as a member of the genus Diaforobiotus. This change, together with a re-assessment of microphotographs of the Tenuibiotus willardi (Pilato, 1977) and Tenuibiotus bozhkae Pilato, Kiosya, Lisi, Inshina & Biserov, 2011 types, led to the discussion on species composition with narrative taxa amendments for the taxonomic parties involved in the proposed alteration. Full article
(This article belongs to the Section Ecology and Conservation)
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11 pages, 2201 KB  
Article
Habitat and Landform Types Drive the Distribution of Carabid Beetles at High Altitudes
by Mauro Gobbi, Marco Armanini, Teresa Boscolo, Roberta Chirichella, Valeria Lencioni, Simone Ornaghi and Andrea Mustoni
Diversity 2021, 13(4), 142; https://doi.org/10.3390/d13040142 - 26 Mar 2021
Cited by 20 | Viewed by 3610
Abstract
The high altitude mountain slopes of the Dolomites (Italian Alps) are characterized by great habitat and landform heterogeneities. In this paper, we investigated the effect of Nature 2000 habitat and landform types in driving the high altitude ground beetle (Carabidae) distribution in the [...] Read more.
The high altitude mountain slopes of the Dolomites (Italian Alps) are characterized by great habitat and landform heterogeneities. In this paper, we investigated the effect of Nature 2000 habitat and landform types in driving the high altitude ground beetle (Carabidae) distribution in the Western Dolomites (Brenta group, Italy). We studied the carabid assemblages collected in 55 sampling points distributed in four Nature 2000 habitat types and four landform types located between 1860 and 2890 m above sea level (a.s.l.). Twenty-two species, half of them Alpine endemics, were sampled. Species richness and taxonomic distinctness did not show any significant difference among habitat types; conversely, these differences became significant when the landform type was considered. Total activity density and the frequency of brachypterous, endemic and predatory species showed significant differences between both habitat and landform types. Indicator species analysis identified twelve species linked to a specific habitat type and thirteen species linked to a specific landform type. Canonical correspondence analysis showed that altitude and vegetation cover drove the species distribution in each habitat and landform type while the aspect had a weak effect. Our results highlight the need for a geomorphological characterization of the sampling points when high altitude ground-dwelling arthropods are investigated. Full article
(This article belongs to the Special Issue Faunistical and Ecological Studies on Carabid Beetles)
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24 pages, 29398 KB  
Article
Geochemical and Dynamic Model of Repeated Hydrothermal Injections in Two Mesozoic Successions, Provençal Domain, Maritime Alps, SE-France
by Namam Salih, Howri Mansurbeg and Alain Préat
Minerals 2020, 10(9), 775; https://doi.org/10.3390/min10090775 - 31 Aug 2020
Cited by 11 | Viewed by 4912
Abstract
A field, petrographic and geochemical study of two Triassic–Jurassic carbonate successions from the Maritime Alps, SE France, indicates that dolomitization is related to episodic fracturing and the flow of hydrothermal fluids. The mechanism governing hydrothermal fluids has been documented with the best possible [...] Read more.
A field, petrographic and geochemical study of two Triassic–Jurassic carbonate successions from the Maritime Alps, SE France, indicates that dolomitization is related to episodic fracturing and the flow of hydrothermal fluids. The mechanism governing hydrothermal fluids has been documented with the best possible spatio-temporal resolutions specifying the migration and trapping of hydrothermal fluids as a function of depth. This is rarely reported in the literature, as it requires a very wide range of disciplines from facies analysis (petrography) to very diverse and advanced chemical methods (elemental analysis, isotope geochemistry, microthermometry). In most cases, our different recognized diagenetic phases were mechanically separated on a centimetric scale and analyzed separately. The wide range of the δ18OVPDB and 87Sr/86Sr values of diagenetic carbonates reflect three main diagenetic realms, including: (1) the formation of replacive dolomites (Type I) in the eogenetic realm, (2) formation of coarse to very coarse crystalline saddle dolomites (Types II and Type III) in the shallow to deep burial mesogenetic realm, respectively, and (3) telogenetic formation of a late calcite cement (C1) in the telogenetic realm due to the uplift incursion of meteoric waters. The Triassic dolomites show a lower 87Sr/86Sr ratio (mean = 0.709125) compared to the Jurassic dolomites (mean = 0.710065). The Jurassic calcite (C1J) shows lower Sr isotopic ratios than the Triassic C1T calcite. These are probably linked to the pulses of the seafloor’s hydrothermal activity and to an increase in the continental riverine input during Late Cretaceous and Early Cenozoic times. This study adds a new insight into the burial diagenetic conditions during multiple hydrothermal flow events. Full article
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28 pages, 4474 KB  
Article
The Role of Snowmelt on the Spatio-Temporal Variability of Spring Recharge in a Dolomitic Mountain Group, Italian Alps
by Giorgia Lucianetti, Daniele Penna, Lucia Mastrorillo and Roberto Mazza
Water 2020, 12(8), 2256; https://doi.org/10.3390/w12082256 - 11 Aug 2020
Cited by 32 | Viewed by 6050
Abstract
Springs play a key role in the hydrology of mountain catchments and their water supply has a considerable impact on regional livelihood, biodiversity, tourism, and power generation. However, there is still limited knowledge of how rain and snow contribute to the recharge of [...] Read more.
Springs play a key role in the hydrology of mountain catchments and their water supply has a considerable impact on regional livelihood, biodiversity, tourism, and power generation. However, there is still limited knowledge of how rain and snow contribute to the recharge of Alpine springs. This study presents a four-year investigation of stable isotopes in precipitation and spring water at the scale of a 240 km2 wide dolomitic massif (Dolomites, Italian Alps) with the aim of determining the proportions of snowmelt and rain in spring water and to provide insights on the variability of these contributions in space and time. Four precipitation sampling devices were installed along a strong elevation gradient (from 725 to 2660 m a.s.l.) and nine major springs were monitored seasonally. The monitoring period comprised three extreme weather conditions, i.e., an exceptional snowpack melting period following the highest snowfall in 30 years, an intense precipitation event (386.4 mm of rain in 48 h), and one of the driest periods ever observed in the region. Isotope-based mixing analysis revealed that rain and snowmelt contributions to spring water were noticeably variable, with two main recharge time windows: a late spring–summer snowmelt recharge period with an average snowmelt fraction in spring water up to 94 ± 9%, and a late autumn–early winter period with a rain fraction in spring water up to 68 ± 17%. Overall, during the monitoring period, snowmelt produced high-flow conditions and sustained baseflow more than rain. We argue that the seasonal variability of the snowmelt and rain fractions during the monitoring period reflects the relatively rapid and climate-dependent storage processes occurring in the aquifer. Our results also showed that snowmelt fractions in spring water vary in space around the mountain group as a function of the elevation of their recharge areas. High-altitude recharge areas, above 2500 m a.s.l., are characterized by a predominance of the snowmelt fraction (72% ± 29%) over the rain contribution. Recharge altitudes of approximately 2400 m a.s.l. also show a snow predominance (65 ± 31%), while springs recharged below 2000 m a.s.l. are recharged mostly from rain (snowmelt fraction of 46 ± 26%). Results from this study may be used to develop more accurate water management strategies in mountain catchments and to cope with future climate-change predictions that indicate a decline in the snow volume and duration in Alpine regions. Full article
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20 pages, 4682 KB  
Article
Hydrogeochemical Characterization of a Warm Spring System in a Carbonate Mountain Range of the Eastern Julian Alps, Slovenia
by Luka Serianz, Nina Rman and Mihael Brenčič
Water 2020, 12(5), 1427; https://doi.org/10.3390/w12051427 - 17 May 2020
Cited by 11 | Viewed by 5474
Abstract
The Alps represent an area where many deep groundwater circulations occur as thermal springs. In the Bled case study, the thermal water temperature, at it is discharged to the surface, is between 19–23 °C. In order to determine the extent (e.g., geometry) and [...] Read more.
The Alps represent an area where many deep groundwater circulations occur as thermal springs. In the Bled case study, the thermal water temperature, at it is discharged to the surface, is between 19–23 °C. In order to determine the extent (e.g., geometry) and the origin of the pronounced deep circulation system in the Bled area, chemical and isotopic measurements of waters from different hydrogeological systems were performed (e.g., surface water, thermal water, fresh groundwater). Hydrogeochemical methods were used to tie together the above-mentioned parameters. The results have shown that thermal outflow in Bled is determined by the presence of a deep-water circulation system, where the dissolution of carbonates minerals is the main hydrogeochemical process affecting chemical components of natural water flow. The correlation of the major ions suggests that the recharge area is represented by both limestone and dolomite rocks. Moreover, the results of δ18O and δ2H of all samples indicate that the recharge is mainly meteoric precipitation. The recharge altitude was estimated for two sampled fresh groundwater springs. The isotopic compositions of those two springs suggest the range from δ18O = −8.68‰, δ2H = −57.4‰ at an elevation of 629 m to δ18O = −9.30‰, δ2H = −60.1‰ at an elevation of 1216 m. The isotopic analysis has confirmed that the thermal water recharges from altitudes of 1282–1620 m a.s.l. Full article
(This article belongs to the Section Hydrology)
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21 pages, 8230 KB  
Article
Autochthonous Micrite to Aphanodolomite: The Microbialites in the Dolomitization Processes
by Adriano Guido, Franco Russo, Domenico Miriello and Adelaide Mastandrea
Geosciences 2018, 8(12), 451; https://doi.org/10.3390/geosciences8120451 - 3 Dec 2018
Cited by 16 | Viewed by 5183
Abstract
In the present paper, we examine the influence of micrite types, autochthonous or allochthonous, on the dolomitization processes. The recrystallized and dolomitized Carnian samples from Rifugio Vallandro and Alpe di Specie erratic boulders (South Tyrol, Italy) offer a unique example for studying the [...] Read more.
In the present paper, we examine the influence of micrite types, autochthonous or allochthonous, on the dolomitization processes. The recrystallized and dolomitized Carnian samples from Rifugio Vallandro and Alpe di Specie erratic boulders (South Tyrol, Italy) offer a unique example for studying the relationship between microbialites and dolomitization processes. The comparison between the carbonates of the well-preserved erratic boulders of Alpe di Specie and the isochronous, recrystallized, and dolomitized, samples of Rifugio Vallandro, allows for hypothesizing the role of microbialites on dolomitization processes. The Rifugio Vallandro samples represent variously dolomitized boundstone (made of corals, sponges, and peloidal crusts) with a fine texture (aphanodolomite) which contain organic matter relics, suggesting microbial-mediated mineralization. Geomicrobiological characterization of the microbialites from Alpe di Specie indicates that they formed through microbial metabolic activity of sulfate-reducing bacteria, which thrive on organic matter accumulated in the suboxic to anoxic interspaces of the skeletal framework. Similar processes can be hypothesized for the microbialite precursor of Rifugio Vallandro. Extracellular polymeric substance (EPS) and other organic compounds trapped inside the fine crystal matrix can have a role in the dolomitization processes of the microbialites. High pH and high alkalinity, derived from the degradation of organic matter, may be critical in promoting the dolomitization of microbialites because the high pH increases the concentration and activity of the dissolved CO32−, thereby increasing the dolomite supersaturation and reaction rates. This process produces very fine dolomite (aphanodolomite) that replaces the original organic-rich micrite, while the fine crystalline dolomite forming larger euhedral crystals seems to derive from the allochthonous micrite due to the presence of a large amount of siliciclastics and the absence of organic remains. Full article
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10 pages, 4175 KB  
Article
Lead–Antimony Sulfosalts from Tuscany (Italy). XXIV. Crystal Structure of Thallium-Bearing Chovanite, TlPb26(Sb,As)31S72O, from the Monte Arsiccio Mine, Apuan Alps
by Cristian Biagioni, Yves Moëlo, Natale Perchiazzi, Nicola Demitri and Giovanni Orazio Lepore
Minerals 2018, 8(11), 535; https://doi.org/10.3390/min8110535 - 18 Nov 2018
Cited by 6 | Viewed by 4655
Abstract
A thallium-bearing variety of the lead–antimony oxysulfosalt chovanite from the Monte Arsiccio mine (Apuan Alps, Tuscany, Italy) has been reexamined. It occurs as thin, ribbon-like crystals, black in color, up to 5 mm in length in vugs of dolomite ± baryte ± quartz [...] Read more.
A thallium-bearing variety of the lead–antimony oxysulfosalt chovanite from the Monte Arsiccio mine (Apuan Alps, Tuscany, Italy) has been reexamined. It occurs as thin, ribbon-like crystals, black in color, up to 5 mm in length in vugs of dolomite ± baryte ± quartz veins embedded in the metadolostone of the Sant’Olga level. Associated minerals are rouxelite, robinsonite, sphalerite, valentinite, baryte, dolomite, quartz, and Ba-rich K-feldspar. Chemical analysis pointed to contents of Tl up to 0.86 apfu, corresponding to the ideal chemical formula TlPb26(Sb,As)31S72O. The structural role of thallium has been investigated using single-crystal X-ray diffraction using synchrotron radiation (λ = 0.59040 Å). Thallium-rich chovanite is monoclinic, space group P21/c, with unit-cell parameters a = 34.280(3), b = 8.2430(7), c = 48.457(4) Å, β = 106.290(4)°, and V = 13143(2) Å3. The crystal structure was refined to a final R1 = 0.083 for 12,052 reflections with Fo > 4σ(Fo) and 1210 refined parameters. The general features of thallium-rich chovanite agree with those of chovanite. Thallium is present as Tl+; it is disordered among two mixed (Pb/Tl) positions, with a Tl/Pb atomic ratio below 1, that precludes this compound to be a new species. Full article
(This article belongs to the Special Issue Thallium: Mineralogy, Geochemistry and Ore Processes)
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15 pages, 502 KB  
Article
Genetic Variation of the Endangered Gentiana lutea L. var. aurantiaca (Gentianaceae) in Populations from the Northwest Iberian Peninsula
by Oscar González-López, Carlos Polanco, Zsuzsanna György, Andrzej Pedryc and Pedro A. Casquero
Int. J. Mol. Sci. 2014, 15(6), 10052-10066; https://doi.org/10.3390/ijms150610052 - 5 Jun 2014
Cited by 20 | Viewed by 7985
Abstract
Gentiana lutea L. (G. lutea L.) is an endangered plant, patchily distributed along the mountains of Central and Southern Europe. In this study, inter-simple sequence repeat (ISSR) markers were used to investigate the genetic variation in this species within and among populations [...] Read more.
Gentiana lutea L. (G. lutea L.) is an endangered plant, patchily distributed along the mountains of Central and Southern Europe. In this study, inter-simple sequence repeat (ISSR) markers were used to investigate the genetic variation in this species within and among populations of G. lutea L. var. aurantiaca of the Cantabrian Mountains (Northwest Iberian Peninsula). Samples of G. lutea L. collected at different locations of the Pyrenees and samples of G. lutea L. subsp. vardjanii of the Dolomites Alps were also analyzed for comparison. Using nine ISSR primers, 106 bands were generated, and 89.6% of those were polymorphic. The populations from the Northwest Iberian Peninsula were clustered in three different groups, with a significant correlation between genetic and geographic distances. Gentiana lutea L. var. aurantiaca showed 19.8% private loci and demonstrated a remarkable level of genetic variation, both among populations and within populations; those populations with the highest level of isolation show the lowest genetic variation within populations. The low number of individuals, as well as the observed genetic structure of the analyzed populations makes it necessary to protect them to ensure their survival before they are too small to persist naturally. Full article
(This article belongs to the Section Biochemistry)
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