Search Results (207)

Chromium–aluminum nitride (CrAlN) coatings were deposited on polished H13 tool steel substrates using direct current (DC) magnetron sputtering. The Cr/Al composition in the target was varied by inserting either four or eight chromium (Cr) plugs into cavities machined into an aluminum (Al) plate target. Nitrogen was introduced as a reactive gas to facilitate the formation of the nitride phase. Coatings were deposited at substrate bias voltages of −30 V, −50 V, and −60 V to study the combined effects of composition and ion energy on coating properties. Compositional analysis of coatings deposited at a −50 V bias revealed Cr/Al ratios of approximately 0.8 and 1.7 for the 4- and 8-plug configurations, respectively. This increase in the Cr/Al ratio led to a 2.6-fold improvement in coating hardness. Coatings produced using the eight-Cr-plug target exhibited a nearly linear increase in hardness with increasing substrate bias voltage. Cross-sectional scanning electron microscopy revealed a uniform bilayer structure consisting of an approximately 0.5 µm metal interlayer beneath a 2–3 µm CrAlN coating. Surface morphology analysis indicated the presence of coarse microdroplets in coatings with the lower Cr/Al ratio. These microdroplets were significantly suppressed in coatings with higher Cr/Al content, especially at increased bias voltages. This suppression is likely due to enhanced ion bombardment associated with the increased Cr content, attributed to Cr’s relatively higher atomic mass compared to Al. Coatings with lower hardness exhibited greater scratch resistance, likely due to the influence of residual compressive stresses. The findings highlight the critical role of both Cr/Al content and substrate bias in tailoring the tribo-mechanical performance of PVD CrAlN coatings for wear-resistant applications. Full article

Electrochemical treatment by means of direct current (DC) is usually used as a measure for steel rebar corrosion protection, e.g., cathodic protection (CP), electrochemical chloride extraction (ECE), and re-alkalization (RA). However, the passage of an electrical charge through the pore system of concrete or mortar, coupled with the migration of ions, concentration changes, and resulting phase changes, may alter its chloride penetration resistance and, subsequently, the time until rebar corrosion activation. Porosity changes in hardened Portland cement mortar were studied by means of mercury intrusion porosimetry (MIP) and electrochemical impedance spectroscopy (EIS), and alterations in the mortar surface phase composition were observed by means of X-ray diffraction (XRD). In order to innovatively investigate the impact of DC treatment on the properties of the mortar–electrolyte interface, the cathode-facing mortar surface and the anode-facing mortar surface were analyzed separately. The corrosion of steel coupons embedded in DC-treated hardened mortar was monitored by means of the free corrosion potential (E_oc) and polarization resistance (R_p). The results showed that the DC treatment affected the surface porosity of the hardened Portland cement mortar at the nanoscale. Up to two-thirds of the small pores (0.001–0.01 µm) were replaced by medium-sized pores (0.01–0.06 µm), which may be significant for chloride ingress. Although the porosity and phase composition alterations were confirmed using other techniques (EIS and XRD), corrosion tests revealed that they did not significantly affect the time until the corrosion activation of the steel coupons in the mortar. Full article

Steel surface defect detection is a crucial step in ensuring industrial production quality. However, due to significant variations in scale and irregular geometric morphology of steel surface defects, existing detection algorithms show notable deficiencies in multi-scale feature representation and cross-layer multi-scale feature fusion efficiency. To address these challenges, this paper proposes an improved real-time steel surface defect detection model, NGD-YOLO, based on YOLOv5s, which achieves fast and high-precision defect detection under relatively low hardware conditions. Firstly, a lightweight and efficient Normalization-based Attention Module (NAM) is integrated into the C3 module to construct the C3NAM, enhancing multi-scale feature representation capabilities. Secondly, an efficient Gather–Distribute (GD) mechanism is introduced into the feature fusion component to build the GD-NAM network, thereby effectively reducing information loss during cross-layer multi-scale information fusion and adding a small target detection layer to enhance the detection performance of small defects. Finally, to mitigate the parameter increase caused by the GD-NAM network, a lightweight convolution module, DCConv, that integrates Efficient Channel Attention (ECA), is proposed and combined with the C3 module to construct the lightweight C3DC module. This approach improves detection speed and accuracy while reducing model parameters. Experimental results on the public NEU-DET dataset show that the proposed NGD-YOLO model achieves a detection accuracy of 79.2%, representing a 4.6% mAP improvement over the baseline YOLOv5s network with less than a quarter increase in parameters, and reaches 108.6 FPS, meeting the real-time monitoring requirements in industrial production environments. Full article

Stainless steel (SS) is one of the materials most commonly utilized for fabrication of medical implants and its properties are often improved by deposition of protective coatings. This study investigates certain physico-chemical and biological properties of SS substrate coated with multilayer thin film consisting of titanium nitride and silver layers (TiN-Ag film). TiN-Ag films were deposited on the surface of AISI 316 SS substrate by a combination of cathodic arc evaporation and DC magnetron sputtering. SS substrate was analyzed by TEM, while deposited coatings were analyzed by SEM, EDS and wettability measurements. Also, mitochondrial activity assay, and osteogenic and chondrogenic differentiation were performed on dental pulp stem cells (DPSCs). SEM and EDS revealed excellent adhesion between coatings’ layers, with the top layer predominantly composed of Ag, which is responsible for antibacterial properties. TiN-Ag film exhibited moderately hydrophilic behaviour which is desirable for orthopedic implant applications. Biological assays revealed significantly higher mitochondrial activity and enhanced osteogenic and chondrogenic differentiation of DPSC on TiN-Ag films compared to TiN films. The newly designed TiN-Ag coatings showed a great potential for the surface modification of SS implants, and further detailed investigations will explore their suitability for application in clinical practice. Full article

The future of the automotive industry appears to hinge on the integration of dissimilar materials, such as aluminum alloys and carbon steel. However, this combination can lead to galvanic corrosion, compromising the structural integrity. In this study, laser-welded joints of 6013-T4 aluminum alloy and DP980 steel were evaluated for their morphology, microhardness, and corrosion resistance. Corrosion resistance was assessed using the electrochemical noise technique over time in 0.1 M Na₂SO₄ and 3.5% NaCl solutions. The wavelet function was applied to remove the DC trend, and energy diagrams were generated to identify the type of corrosive process occurring on the electrodes. Corrosion on the electrodes was also monitored using photomicrographic images. Analysis revealed an aluminum–steel mixture in the melting zone, along with the presence of AlFe, AlFe₃, and AlI₃Fe₄ intermetallic compounds. The highest Vickers microhardness was observed in the heat-affected zone, adjacent to the melt zone, where a martensitic microstructure was identified. The 6013-T4 aluminum alloy demonstrated the highest corrosion resistance in both media. Conversely, the electrochemical noise resistance was similar for the DP980 steel and the weld bead, indicating that the laser welding process does not significantly impact this property. The energy diagrams showed that localized pitting corrosion was the predominant form of corrosion. However, generalized and mixed corrosion were also observed, which corroborated the macroscopic analysis of the electrodes. Full article

This study investigated the effects of alternating current (AC) interference on pipeline steel under cathodic protection (CP). In a simulated solution, real-time electrochemical measurements and corrosion rate analysis were conducted on two steel types (C1018 and X60) under various levels of AC interference with CP. Due to the complexity of AC-induced corrosion, relying on the shift in DC potential alone cannot accurately demonstrate the corrosion behavior in the presence of AC interference. In fact, such an approach may mislead the predictions of corrosion performance. It is observed that AC interference reduced the effectiveness of CP and increased the corrosion rate of the steel, both in weight loss and Tafel Extrapolation (Tafel) measurements. The study concluded that conventional CP standards used in the field were inadequate in the presence of high AC-level interference. Furthermore, this study found that a more negative CP current density (−0.75 A/m²) could reduce the effect of AC interference by 46–93%. This is particularly shown in the case of low-level AC interference, where the reduction can reach up to 93%. Utilizing the experimental data obtained by the two measurement methods, probabilistic models to predict the corrosion rate were developed with consideration of the uncertainty in the measurements. The sensitivity analysis showed how AC interference impacts the corrosion rate for a given CP level. Full article

This article presents the results of experimental studies aimed at determining the values of residual stresses and coefficient of friction (CoF) in bending under tension friction test, which simulates friction conditions in sheet metal forming. The influence of surface modification of the countersample and CoFs between the countersample and DC01 steel sheet on the residual stress were analysed. This study also focused on the influence of surface modification of countersamples on the change of the main parameters of DC01 steel sheets. The hole-drilling method was used to determine residual stresses. Electron beam melting, lead-ion implantation and a combination of these two techniques were used to modify the surface layer of 145Cr6 steel countersamples. The maximum value of the CoF, about 0.31, was found for the electron beam melted countersample. As a result of the surface modification process, this countersample was characterised by the lowest value of average roughness, which directly influenced the increase in the real contact area. The occurrence of residual tensile stresses was observed near the surface layer of the sheet strip in contact with the countersample. With the increase of the considered depth of residual stress measurement, the residual tensile stresses were transformed into compressive residual stresses with a value between −75 and −50 MPa, depending on the type of friction pair. SEM analyses allowed us to identify two main friction mechanisms for all friction pairs: adhesion and abrasive wear. Full article

In the present study, an approach for determining the different states of ball burnishing (BB) operations aimed at forming regular reliefs’ patterns on planar surfaces is introduced. The methodology involves acquiring multi-axis accelerometer data from CNC-driven milling machine to capture the dynamics of the BB tool and workpiece, mounted on the machine table. Following data acquisition from an AISI 304 stainless steel workpiece, which is subjected to BB treatments at different toolpaths and feed rates, the recorded signals are preprocessed through noise reduction techniques, DC component removal, and outlier correction. The refined data are then transformed using a root mean square (RMS) operation to simplify further analysis. A Gaussian Mixture Model (GMM) is subsequently employed to decompose the compressed RMS signal into distinct components corresponding to various operational states during BB. The experimental trials at feed rates of 500 and 1000 mm/min reveal that increased feed rates enhance the distinguishability of these states, thus leading to an augmented number of statistically significant components. The results obtained from the proposed GMM based algorithm applied on compressed RMS accelerations signals is compared with two other methods, i.e., Short-Time Fourier Transforms and Continuous Wavelet Transform. The results from the comparison show that the proposed GMM method has the advantage of segmenting three to five different states of the BB-process from nonstationary accelerations signals measured, while the other tested methods are capable only to distinguish the state of work of the deforming tool and state of its rapid (re-)positioning between the areas of working, when there is no contact between the BB-tool and workpiece. Full article

To address the challenges of small aperture size, limited scanning angles, and high fabrication costs in existing scanning micromirrors, this paper proposes a large-aperture biaxial electromagnetically driven scanning micromirror. The scanning micromirror utilizes a stainless-steel mirror structure and an actuation structure composed of arc-shaped permanent magnets (NdFeB 52), iron cores, and copper coils. By optimizing the magnet layout and coil design, it achieves large optical scanning angles in biaxial non-resonant scanning mode. Experimental results demonstrate that the optical scanning angles reach 61.4° (x-axis) under a DC driving current of ±18.1 mA and 61.1° (y-axis) under a DC driving current of ±25.2 mA with an effective mirror aperture of 9.54 mm × 10 mm. The resonant frequencies are 89 Hz (x-axis) and 63 Hz (y-axis). Experimental results verify the feasibility of biaxial independent control in non-resonant scanning mode. The design is fabricated using a low-cost computer numerical control (CNC) milling process and exhibits application potential in fields such as LiDAR, projection display, and optical communication, providing a novel approach for performance optimization of large-aperture scanning micromirrors. Full article

Investment casting is a precision casting technology that can produce complex shapes from various materials, particularly difficult-to-cast and difficult-to-machine metallic alloys. Meanwhile, electrical discharge machining (EDM) is a well-known technique for producing ultra-precise mechanical parts, and electrode quality is crucial. Few studies have explored how rapid prototyping (RP) pattern generation and investment casting influence the final product’s shape, dimensions, and surface roughness. This study investigates EDM electrode fabrication using investment casting and RP-generated epoxy resin patterns. We examine the effects of electrode materials (CuZn5, CuZn30, and FeCr24) on surface roughness, alongside the impact of ceramic shell thickness and RP pattern shrinkage on electrode quality. The EDM electrodes have a shrinkage of 0.8–1.9% and a surface roughness of 3.20–6.35 μm, depending on the material selections. Additionally, the probability of shell cracking decreases with increasing shell thickness, achieving stability at 16.00 mm. This research also applies investment casting electrodes to process DC53 steel. The results indicate that the surface roughness of the workpiece after EDM machining with different electrode materials is in the range of 4.71 µm to 9.88 µm. The result expands the use of investment casting in electrode fabrication, enabling the production of high-precision electrodes with complex profiles and challenging materials, potentially reducing both time and cost. Full article

Modern industrial systems and biomass-fired furnaces require surface treatments that can withstand aggressive chemical, thermal, and corrosive environments. This study investigates the corrosion and thermal resistance of plasma-sprayed Al₂O₃-TiO₂ coatings produced using a DC air–hydrogen plasma spray process. Coatings of compositions of Al₂O₃, Al₂O₃-3 wt.% TiO₂, Al₂O₃-13 wt.% TiO₂, and Al₂O₃-40 wt.% TiO₂ were deposited on steel substrates with a Ni/Cr bond layer by plasma spraying. The coatings were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD) to evaluate their morphology, elemental composition, and crystalline phases. Electrochemical tests were performed in a naturally aerated 0.5 mol/L NaCl solution and cyclic thermal–chemical exposure tests (500 °C using 35% KCl) to assess their corrosion kinetics and thermal stability. The results indicate that pure Al₂O₃ and low TiO₂ (3 wt.%) coatings exhibit fine barrier properties, while coatings with a higher TiO₂ content develop additional phases (e.g., Ti₃O₅, Al₂TiO₅) that improve thermal resistance but reduce chemical durability. Full article

This study presents a novel approach to evaluate the galvanic corrosion risk of mild steel coated with graphene-embedded epoxy coatings. The potential for graphene platelets to promote anodic dissolution of the underlying steel substrate via galvanic corrosion mechanisms was systematically assessed through the accelerated alternating current-direct current-alternating current (AC-DC-AC) technique and cathodic disbondment testing. The possible risk of displacing cathodic reactions from the coating–steel interface to the dispersed graphene platelets within the epoxy matrix was investigated by evaluating the degradation trend of the graphene-containing coating under the AC-DC-AC test. The degradation behaviour of both pure epoxy and graphene-embedded epoxy coatings during accelerated aging was characterized using electrochemical impedance spectroscopy (EIS) measurements. The finding highlighted the negligible catalytic effect of incorporated graphene platelets on the anodic dissolution of steel substrate. On the other hand, as an inert filler, graphene platelets contributed to the enhancement of the structural integrity of the epoxy matrix during the AC-DC-AC test and natural immersion in NaCl 3.5 wt % solution by enhancing the barrier performance of the coating. Despite their spectacular barrier performance, damaged graphene-containing coatings performed inferiorly against corrosion-induced delamination compared to pure epoxy. Samples underwent the cathodic disbondment test to eliminate the effect of substrate anodic dissolution from corrosion-induced delamination. The accelerated delamination of graphene-embedded epoxy coatings was attributed to the destructive impact of graphene platelets on the interfacial adhesion of the epoxy matrix to the steel substrate. Full article

The paper presents the results of oxidation tests on the alloy based on the intermetallic phase, Fe40Al5Cr0.2TiB, in the air at 700–1000 °C temperature. The kinetics of corrosion processes were determined, the surface condition after oxidation was assessed, and the type and morphology of the oxides formed were determined. In addition, the paper presents the possibility of applying the technology of surfacing Fe40Al5Cr0.2TiB alloy on the surface of steel grade S235JR as a protective coating that is resistant to high temperatures. The process was carried out using the TIG method by direct current (DC). After the surfacing, the structure of the surfacing weld made of the tested material on the base of structural steel grade S235JR was determined. It was found that a protective Al₂O₃ oxide layer is formed on the surface of the oxidized alloy based on the intermetallic phase from the FeAl system, and the oxidation kinetics have a parabolic course. Moreover, it was found that the morphology of the oxides formed on the surface varies depending on the oxidation temperature, which clearly indicates a different mechanism of oxide layer formation. The formation of a stable α-Al₂O₃ oxide variety on the surface of the Fe40Al5Cr0.2TiB alloy protects the material from further corrosion, which favors the application of this alloy on structures and fittings operating at elevated temperatures. The aim of the research was to use the Fe40Al5Cr0.2TiB alloy with very good oxidation resistance as a layer overlay on ordinary quality S235JR steel. In this way, conditions were created that fundamentally changed the surface condition (structure and physicochemical properties) of the system: steel as a substrate—intermetallic phase Fe40Al5Cr0.2TiB as a surfacing layer, in order to increase resistance to high-temperature corrosion and erosion (in the environment of gases and solid impurities in gases) often occurring in corrosive environments, especially in the power industry (boilers, pipes, installation elbows) and the chemical industry (fittings). At the same time, the surfacing method used is one of the cheapest methods of changing the surface properties of the material and regenerating or repairing the native material with a material with better properties, especially for applications in high-temperature corrosion conditions. Full article

Nanojoining, which utilizes nanoparticles for joining applications, is an interesting method that stands out from conventional processes by combining relatively low joining temperatures with high service temperatures. To use the nanoparticles for this purpose, it has proven useful to process them as a paste. The chemical composition of such a nanopaste has a certain influence on the properties ultimately achieved by the joint. While nickel nanoparticles represent the metal content of the here investigated nanopastes, a variety of substances can be utilized as organic components to form the actual paste-like suspension. Derived from the literature on nanoparticle synthesis, a variety of candidates were identified from which numerous paste compositions were developed for this work. So, high metal content (70 wt.%) nickel nanopastes were prepared from these solvent–stabilizer systems by ultrasound-enhanced mixing. The study evaluates the pastes in terms of manufacturability and handleability. The findings reveal insights into the effects of different chemical substances. Additionally, joining tests using the mild steel DC01 are presented, demonstrating the impact of the paste composition on the joining strength and the microstructure of the joint as well. Within this study, a paste consisting of terpineol and KD4 was the most favorable. Full article

This paper the flexural and compressive strengths of the reactive powder concrete (RPC) with steel scoria and quartz sand containing NaCl are investigated. Moreover, the RPC’s mass, the chloride ion permeability and the carbonation depth (D_c) are determined. The mass ratios of steel scoria and the NaCl are 0%~20% and 0%~0.25% by mass of binder materials and the quartz sand respectively. The RPC specimens are exposed to the NaCl erosion environment. The scanning electron microscope-energy dispersive spectrometer (SEM-EDS) and X-ray diffraction (XRD) spectrum are acquired for analyzing the mechanism of RPC’s performance. Results show that the flexural strength, the compressive strengths, the mass and the dynamic modulus of elasticity (RDME) of RPC decrease in the form of cubic function with the mass ratio of NaCl. When the mass ratio of steel scoria is 10%, the mechanical strengths and the RDME are the highest. The RPC’s flexural strength, the compressive strength and the RDME decrease by rates of 4.94%~42.28%, 5.11%~48.65% and 8.72%~226.1% after NaCl erosion. Meanwhile, the corresponding mass loss rate, the chloride ion permeability, the D_c are increased by rates of 1.32%~27.63%. RPC with 10% steel scoria shows the lowest performance degradation. The SEM-EDS results show that the pores and cracks inner RPC and the Cl and Ca elements are increased by the NaCl. The Fe and Ca elements are increased by the added steel scoria. The addition of steel scoria exhibit decreasing effect and the added NaCl shows increasing effect on the Ca (OH)₂ crystals respectively. Full article