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30 pages, 5091 KB  
Article
Seasonal Dynamics and Vertical Structure of the Atmospheric Transport of Industrial Emissions to Lake Baikal
by Yelena Molozhnikova, Ivan Tyurnev and Maxim Shikhovtsev
Sustainability 2026, 18(15), 7712; https://doi.org/10.3390/su18157712 - 30 Jul 2026
Viewed by 411
Abstract
Lake Baikal is a UNESCO World Heritage Site and the largest freshwater reservoir on the planet. It is located in the center of Eurasia, in an industrially developing region—Eastern Siberia. Although a regulatory and legal framework exists, quantitative estimates of the pathways of [...] Read more.
Lake Baikal is a UNESCO World Heritage Site and the largest freshwater reservoir on the planet. It is located in the center of Eurasia, in an industrially developing region—Eastern Siberia. Although a regulatory and legal framework exists, quantitative estimates of the pathways of pollutant transport from industrial sources to the lake water area remain insufficiently studied, particularly in the context of seasonal dynamics and the influence of developing industrial sectors. In the present work, a quantitative analysis of the direct atmospheric transport of pollutants from three groups of stationary sources (the Irkutsk agglomeration, the Republic of Buryatia, and the oil-and-gas production areas of Irkutsk Oblast) to the lake surface was carried out for the first time using the HYSPLIT model for the period 2005–2025. About 4.7 million forward trajectories were computed at three heights (250, 500, 1000 m AGL) for each group of sources. It was established that conditions favorable for the transport of impurities to the lake occur in more than half of the cases. However, the spatial distribution of the impact on the Baikal air basin is heterogeneous: the Irkutsk agglomeration accounts for 67.5% of the “hits” (the main contribution being to the air basin of the Southern Basin), the Republic of Buryatia 18.8% (to the Central Basin), and the oil-and-gas areas 19.9% (to the Northern Basin). On the basis of a multifactor analysis, a combined Potential Impact (PI) index was developed that makes it possible to rank regional sources by the degree of their impact on the lake ecosystem, taking into account the emission volume, the probability of delivery, the residence time, and the height of trajectory passage. The results form a scientific basis for optimizing the spatial placement of environmental monitoring networks and for preliminary zoning of environmental risk assessment over the Lake Baikal water area. Ultimately, this study contributes to the sustainable management of the Baikal Natural Territory by providing actionable insights for balancing regional industrial growth with the long-term ecological preservation of the planet’s largest freshwater reservoir. Full article
(This article belongs to the Section Air, Climate Change and Sustainability)
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30 pages, 9485 KB  
Article
Long-Term Monitoring of Influenza A Viruses in Wild Waterfowl: Evidence from the Lake Baikal Basin (2018–2024)
by Nikita Kasianov, Kirill Sharshov, Anastasiya Derko, Nikita Dubovitskiy, Junki Mine, Yuko Uchida, Evgeniya Badmaeva, Lopson Bazarov, Marina Gulyaeva, Arina Loginova, Maxim Grigoriev, Daria Kasianova, Tatiana Murashkina, Ivan Sobolev, Sachin Kumar, Wen Wang, Jianjun Chen and Alexander Shestopalov
Viruses 2026, 18(7), 761; https://doi.org/10.3390/v18070761 - 11 Jul 2026
Viewed by 812
Abstract
Wild waterfowl constitute the primary natural reservoir of influenza A viruses, and wetlands at the convergence of major migratory flyways serve as critical hubs for viral genetic exchange. Baikal Siberia, situated at the intersection of the East African–West Asian, Central Asian, and East [...] Read more.
Wild waterfowl constitute the primary natural reservoir of influenza A viruses, and wetlands at the convergence of major migratory flyways serve as critical hubs for viral genetic exchange. Baikal Siberia, situated at the intersection of the East African–West Asian, Central Asian, and East Asian–Australasian flyways, represents a unique yet understudied region in this context. Here we report the results of long-term virological surveillance of wild birds in the Lake Baikal basin conducted between 2018 and 2024. A total of 1036 cloacal swab samples from 28 bird species were screened, yielding 42 influenza A virus isolates belonging to 12 HA/NA subtype combinations: H1N1, H3N1, H3N2, H3N5, H3N6, H3N8, H4N6, H6N1, H6N2, H6N3, H6N8, and H12N5. Among the detected subtypes, H6 viruses—identified with four distinct neuraminidase combinations (N1, N2, N3, N8)—are of particular public health relevance owing to their documented capacity for dual-receptor binding and potential for zoonotic transmission to mammals, including humans. Full-genome sequencing followed by cluster analysis of internal gene segments identified 16 distinct segment constellations, indicating extensive reassortment. BLAST searches against the GISAID database revealed closest genetic relatives in Mongolia, South Korea, Japan, China, and Western Siberia, with more distant links to Bangladesh, Europe, and a possible intercontinental connection via the Pacific flyway. Maximum-likelihood phylogenetic analysis of the HA and NA segments confirmed that all isolates belong to the Eurasian genetic lineage, yet they are distributed across multiple clades rather than forming a single monophyletic group, reflecting the role of Buryatia as a mixing zone for genetically diverse viral populations. These findings substantially expand the understanding of influenza A virus ecology in the Lake Baikal basin and underscore the importance of continued surveillance at this key migratory crossroads in Northern Asia. Full article
(This article belongs to the Special Issue Influenza Viruses in Wildlife 2026)
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17 pages, 16343 KB  
Review
The Hydrological Dynamics, Resource Exploitation, and Ecological Risks of Lake Baikal: Implications for Future Protection and Water Governance
by Shengjie Yang, Jianlong Li, He Yang, Liang Zhong, Tao Liu and Zhengguo Sun
Water 2026, 18(10), 1139; https://doi.org/10.3390/w18101139 - 10 May 2026
Viewed by 1037
Abstract
Water scarcity is an increasingly pressing global concern, making the sustainable development of water resources a critical priority. Revered as the “Sacred Sea,” Lake Baikal holds the largest volume of freshwater in any single lake in the world, with exceptional water quality, conferring [...] Read more.
Water scarcity is an increasingly pressing global concern, making the sustainable development of water resources a critical priority. Revered as the “Sacred Sea,” Lake Baikal holds the largest volume of freshwater in any single lake in the world, with exceptional water quality, conferring it with considerable global strategic importance. This study reviews the hydrological dynamics of Lake Baikal, including water level fluctuations and runoff patterns, and examines water resource utilization (including virtual water and long-distance diversion), along with its potential, challenges, and associated ecological risks, in an integrated manner. Previous studies reveal an interannual cycle of fluctuating water levels, with annual peaks typically occurring between September and October. Outflow runoff closely depends on lake water levels, while inflow runoff exhibits considerable variability. The Selenga River, the largest tributary originating from the Mongolian Plateau, significantly influences the lake’s hydrology and ecological integrity. Current water uses primarily include domestic supply, regional industry, and fisheries, while agricultural water use is relatively limited and mainly occurs within tributary catchments. Emerging options, such as virtual water trade, may offer relatively more manageable alternatives to large-scale transboundary water transfers in certain contexts. Given the multiple disturbances and potential impacts on the Lake Baikal ecosystem, this study advocates prioritizing ecological protection in water resource utilization and underscores the necessity of comprehensive, system-level assessments prior to any water extraction or diversion activities. Full article
(This article belongs to the Special Issue Working Across Borders to Address Water Scarcity)
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16 pages, 2878 KB  
Article
Genomic Features of the Micropredator Lysobacter sp. Hz25 Isolated from the Rhizosphere of Hedysarum zundukii
by Ivan S. Petrushin, Yulia V. Nurminskaya and Yulia A. Markova
Int. J. Mol. Sci. 2026, 27(9), 3800; https://doi.org/10.3390/ijms27093800 - 24 Apr 2026
Viewed by 849
Abstract
Lysobacter antibioticus Hz25 is a novel strain that was isolated from the rhizosphere of the relict endemic plant Hedysarum zundukii Peschkova (Fabaceae), which grows on carbonate soils in the Baikal region of Russia. This work presents the complete genome sequence of Hz25 (5.98 [...] Read more.
Lysobacter antibioticus Hz25 is a novel strain that was isolated from the rhizosphere of the relict endemic plant Hedysarum zundukii Peschkova (Fabaceae), which grows on carbonate soils in the Baikal region of Russia. This work presents the complete genome sequence of Hz25 (5.98 Mb, 66.94% GC), which was obtained using a hybrid assembly method combining Oxford Nanopore and Illumina sequencing. Phylogenetic analysis based on 47 Lysobacter genomes and an average nucleotide identity (ANI) value of 96% confirmed its affiliation with L. antibioticus. A comparative pan-genome analysis with three closely related strains (13-6, 76, and ATCC 29479) identified 554 strain-specific genes. This significant genomic plasticity likely reflects adaptation to the sharply continental climate, high insolation, and low free iron content of the native soil. The genome encodes a comprehensive micropredator arsenal, including: seven chitinase genes (GH18 and GH19 families); bacteriolytic enzymes (Blp, L1, L4, Ami); a complete type III secretion system (T3SS) with predicted effectors; type IV pili (including the PilZ-PilB regulatory complex); and siderophore biosynthesis genes (lysochelin). The genome contains genes ars of an arsenic resistance system, but lacks the ACR3 efflux pump, suggesting that these genes may have alternative functions. Genes involved in calcium homeostasis (Excalibur domain, Na+/Ca2+ antiporter) were also identified. These features make Hz25 a promising candidate for biocontrol applications in cold climates and metal-contaminated environments. Full article
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22 pages, 1483 KB  
Article
13C-NMR Spectroscopy and Elemental Composition of Humic Acids of Brown Forest Soils and Sod-Brownzems of the Southern Vitim Plateau (Russia, Baikal Region)
by Erzhena Chimitdorzhieva, Tsypilma Korsunova, Yurii Tsybenov, Nimbu Baldanov and Elena Valova
Molecules 2026, 31(4), 606; https://doi.org/10.3390/molecules31040606 - 9 Feb 2026
Cited by 1 | Viewed by 1137
Abstract
This study shows that the structural features of humic acids reflect the specific characteristics of organic matter in permafrost soils of the southern Vitim Plateau. The region’s extracontinental climate determines the rate of decomposition, the depth of humification, and the chemical structure of [...] Read more.
This study shows that the structural features of humic acids reflect the specific characteristics of organic matter in permafrost soils of the southern Vitim Plateau. The region’s extracontinental climate determines the rate of decomposition, the depth of humification, and the chemical structure of humic acids. Brown forest soils (Haplic Cambisols) and sod-brownzems (Leptic Cambisols Skeletic) contain high amounts of organic carbon and total nitrogen in their upper horizons but differ in their vertical distribution. Brown forest soils are characterized by a sharp decrease in organic carbon content with depth and the presence of humus pockets enriched in carbon and exchangeable bases. Sod-brownzems contain more organic carbon with increase in acidity and base loss with depth. Both soil types retain satisfactory natural fertility. 13C nuclear magnetic resonance spectroscopy data reveal marked differences in the structural maturity of humic acids. Humic acids from the A horizons of brown forest soils contain an equilibrium combination of aliphatic and aromatic structures, a well-developed system of oxygen-containing groups, and moderate condensation, indicating an intermediate stage of humification. Humic acids from humus pockets are more aromatic and highly humified. They reflect an advanced stage of humification and possess high chemical stability. Humic acids from sod-brownzems also exhibit high aromaticity, which facilitates the formation of stable organomineral complexes. A comparison of the samples reveals a consistent increase in aromaticity, condensation, and stability from the A horizons of brown forest soils to the A horizons of sod-brownzems and further to humus pockets. This progression corresponds to an increase in humification and a decrease in the mobility and bioavailability of organic matter. These results confirm that the structural characteristics of humic acids are determined by soil type and formation conditions. Elemental composition revealed that humic acids from brown forest soils are characterized by the highest aromaticity and maturity, while humic acids from HA-brown forest soils-A have a less condensed structure. Humic acids from sod-brownzems occupy an intermediate position, combining high aromatization with a moderate degree of humification. Overall, the obtained elemental composition data are fully consistent with the results of 13C NMR spectroscopy, mutually confirming the identified structural features and the degree of transformation of soil organic matter. Full article
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15 pages, 1435 KB  
Article
Towards a Framework for Sustainable Winter Tourism at Lake Baikal: A Case Study of the Ice Sculpture Festival “Olkhon Ice Fest”
by Zinaida Eremko, Darima Budaeva, Sayana Dymbrylova, Tatyana Khrebtova, Nadezhda Botoeva, Alyona Andreeva, Natalia Lubsanova, Lyudmila Maksanova and Semen Mayor
Sustainability 2026, 18(3), 1241; https://doi.org/10.3390/su18031241 - 26 Jan 2026
Viewed by 1327
Abstract
Ice and snow tourism (IST) is a significant global trend, offering Russia opportunities for tourism growth and seasonal diversification. This study investigates the potential of ice and snow art as a distinct subcategory of IST on Lake Baikal. Our research is based on [...] Read more.
Ice and snow tourism (IST) is a significant global trend, offering Russia opportunities for tourism growth and seasonal diversification. This study investigates the potential of ice and snow art as a distinct subcategory of IST on Lake Baikal. Our research is based on an analysis of academic publications and official policy documents, field surveys conducted in winter 2025, and stakeholder consultations, with the “Olkhon Ice Fest” serving as a case study. The findings indicate a clear shift toward IST, with the number of winter tourists on Olkhon Island increasing by 70% between 2021 and 2024. The festival’s key features—its use of the natural ice landscape, a unique artistic technique, an explicit ecological focus, and strong entrepreneurial initiative—support the development of a conceptual model of IST on Lake Baikal grounded in ecotourism principles. Ensuring the long-term sustainable development of IST in the region requires improved governance, infrastructure, and transport systems, as well as support for green businesses and increased environmental awareness among tourists. This study contributes to the ongoing discourse on sustainable winter tourism by demonstrating the interconnections among environmental sustainability, socioeconomic benefits, and cultural innovation, thereby situating local IST practices within the broader framework of the United Nations Sustainable Development Goals (SDGs). Full article
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20 pages, 3687 KB  
Article
Evaluation of Cloud Fraction Data for Modelling Daily Surface Solar Radiation: Application to the Lake Baikal Region
by Dmitry Golubets, Nadezhda Voropay, Egor Dyukarev and Ilya Aslamov
Atmosphere 2025, 16(12), 1405; https://doi.org/10.3390/atmos16121405 - 16 Dec 2025
Viewed by 1445
Abstract
Accurately modelling surface solar radiation (SSR) is essential for environmental research but remains a significant challenge in topographically complex regions like Lake Baikal, where ground measurements are sparse. This study evaluates the performance of various open-access cloud cover products—from satellite sensors (AVHRR, MODIS) [...] Read more.
Accurately modelling surface solar radiation (SSR) is essential for environmental research but remains a significant challenge in topographically complex regions like Lake Baikal, where ground measurements are sparse. This study evaluates the performance of various open-access cloud cover products—from satellite sensors (AVHRR, MODIS) and ground-based observations—for modelling daily SSR totals, using a physical radiation model validated against in-situ measurements from 10 coastal stations. The results demonstrate that the choice of cloud data critically impacts model accuracy. The AVHRR satellite product yields the most reliable estimates (R2 = 0.54, RMSE = 4.538 MJ/m2), significantly outperforming both ground-based cloudiness observations and the ERA5 reanalysis dataset. This finding underscores that spatially continuous satellite data provide a superior representation of cloud attenuation for regional modelling than point-based ground observations or reanalysis. Consequently, a physical model driven by high-quality satellite cloud masks is recommended as an effective methodology for generating reliable SSR fields. Full article
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23 pages, 5315 KB  
Article
Results of a Comprehensive Study on Atmospheric Pollution at the Tankhoi Observation Point (Southeastern Coast of Lake Baikal, Russia): Temporal Variability and Identification of Sources
by Yelena Molozhnikova, Maxim Shikhovtsev and Tamara Khodzher
Environments 2025, 12(12), 462; https://doi.org/10.3390/environments12120462 - 1 Dec 2025
Cited by 7 | Viewed by 1313
Abstract
This study is based on data obtained as part of continuous monitoring of small gas impurities (SO2, NO2, NO), mass concentration of aerosol particles PM2.5 and meteorological parameters, which was first implemented at the Tankhoi observation point (southeastern [...] Read more.
This study is based on data obtained as part of continuous monitoring of small gas impurities (SO2, NO2, NO), mass concentration of aerosol particles PM2.5 and meteorological parameters, which was first implemented at the Tankhoi observation point (southeastern coast of Lake Baikal, Russia) from October 2023 to May 2025. Statistical methods and the non-parametric wind regression receptor model (NWR) were used to analyze temporal variability and identify sources of pollution. It was found that the concentrations of gas impurities have a clearly pronounced winter maximum: the median values for sulfur dioxide and nitrogen in winter reached 9.2 μg/m3 and 13.8 μg/m3, respectively, which is associated with emissions from coal-fired thermal power plants and unfavorable meteorological conditions (inversions, low boundary layer height). In contrast to gases, PM2.5 demonstrated a summer peak up to 43.5 μg/m3 in July–August 2024 due to abnormally hot weather and forest fires. The daily course of sulfur dioxide was characterized by an atypical daily maximum caused by the convective transport of polluted air masses from the upper layers of the boundary layer. During this period, higher concentrations of sulfur dioxide caused by long-range high-altitude transport of emissions from regional thermal power plants can reach the ground surface, leading to an increase in their concentration in the near-surface layer. Using the NWR model, the influence of regional thermal power plants located 100–150 km northwest of the station on the levels of SO2 and NO2 was confirmed. The results also highlight the contribution of local sources, such as vehicles, stoves, and shipping, to the formation of NO and PM2.5. Full article
(This article belongs to the Special Issue Ambient Air Pollution, Built Environment, and Public Health)
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30 pages, 3695 KB  
Article
Microbial Diversity of the Baikal Rift Zone Freshwater Alkaline Hot Springs and the Ecology of Polyextremophilic Dissimilatory Iron-Reducing Bacteria
by Anastasia I. Maltseva, Alexander G. Elcheninov, Alexandra A. Klyukina, Alexandra V. Gololobova, Elena V. Lavrentyeva, Tuyana G. Banzaraktsaeva, Vyacheslav B. Dambaev, Darima D. Barkhutova, Daria G. Zavarzina and Evgenii N. Frolov
Biology 2025, 14(12), 1716; https://doi.org/10.3390/biology14121716 - 1 Dec 2025
Cited by 1 | Viewed by 1715
Abstract
Polyextremophilic microbial communities of Baikal Rift Zone hot springs have been studied fragmentarily, and these studies have typically focused on either phototrophic microbial mats or on the whole microbial community from one or a few sites. In our work, we conducted the first [...] Read more.
Polyextremophilic microbial communities of Baikal Rift Zone hot springs have been studied fragmentarily, and these studies have typically focused on either phototrophic microbial mats or on the whole microbial community from one or a few sites. In our work, we conducted the first large-scale screening of microbial communities from seven hot spring groups in the Baikal Rift Zone, using metabarcoding of the V3-V4 regions of the 16S rRNA gene. Analysis of alpha and beta diversity, as well as co-occurrence network analysis, revealed that the microbial diversity of the studied springs is highly dependent on temperature values. This approach allowed classifying microbial communities into four distinct groups, characterized by significantly different taxa representing the key functional roles of primary producers, heterotrophic consumers, and terminal destructors of organic matter. Sulfate-reducing bacteria constituted a major metabolic group driving the final stage of organic matter mineralization. Moreover, the presence of alkalithermophilic dissimilatory iron reducers, whose existence was debatable, was proved in the studied samples by cultural methods. The phylotypes that gained an advantage on selective media with synthesized ferrihydrite and hydrogen or acetate added as an electron donor belonged to the genus Parvivirga of the order Anaerosomatales and several unknown representatives of the phylum Bacillota. Full article
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21 pages, 8925 KB  
Article
Zr-Th-REE Mineralization Associated with Albite–Aegirine-Bearing Rocks of the Burpala Alkaline Intrusion (North Baikal Region, South Margin of the Siberian Craton)
by Ivan Aleksandrovich Izbrodin, Anna Gennadievna Doroshkevich, Anastasia Evgenyevna Starikova, Alexandra Vladislavovna Malyutina, Tatyana Nikolaevna Moroz and Igor Sergeevich Sharygin
Minerals 2025, 15(7), 742; https://doi.org/10.3390/min15070742 - 16 Jul 2025
Cited by 1 | Viewed by 1199
Abstract
The rocks of the Burpala alkaline intrusion contain a wide range of rare minerals that concentrate rare earth elements (REEs), Nb, Th, Li, and other incompatible elements. One of the examples of the occurrence of such mineralization is albite–aegirine rocks located at the [...] Read more.
The rocks of the Burpala alkaline intrusion contain a wide range of rare minerals that concentrate rare earth elements (REEs), Nb, Th, Li, and other incompatible elements. One of the examples of the occurrence of such mineralization is albite–aegirine rocks located at the contact zone between the intrusion and the host terrigenous–sedimentary rock. In albite–aegirine rocks, cubic crystals of “metaloparite”, partially or completely substituted by bastnäsite-(Ce) and polymorphic TiO2 phases (anatase and rutile) mainly represent the rare metal minerals. In albite–aegirine rocks, trace element minerals are predominantly represented by cubic crystals of “metaloparite”, which are partially or completely replaced by bastnäsite-(Ce) and polymorphic TiO2 phases such as anatase and rutile. Additionally, Th-bearing zircon (up to 17.7 wt% ThO2) and a variety of unidentified minerals containing REEs, Th, and Nb were detected. The obtained data indicate that bastnäsite-(Ce) is the result of the recrystallization of “metaloparite” accompanied by the formation of Th-bearing zircon and Nb-bearing rutile (up to 9.9 wt% Nb2O5) and the separation of various undiagnosed, unidentified LREE phases. Our studies show that remobilization of LREEs, HFSEs, and local enrichment of rocks in these elements occurred due to the effects of residual fluid enriched in fluorine and carbon dioxide. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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19 pages, 1214 KB  
Article
Physical and Chemical Characteristics of Different Aerosol Fractions in the Southern Baikal Region (Russia) During the Warm Season
by Liudmila P. Golobokova, Tamara V. Khodzher, Vladimir A. Obolkin, Vladimir L. Potemkin and Natalia A. Onischuk
Atmosphere 2025, 16(7), 829; https://doi.org/10.3390/atmos16070829 - 8 Jul 2025
Cited by 1 | Viewed by 948
Abstract
The Baikal region, including areas with poor environmental conditions, has significant clean background zones. In the summer of 2023, we analyzed the physical and chemical parameters of aerosol particles with different size fractions at Irkutsk and Listvyanka monitoring stations. Reduced wildfires and minimal [...] Read more.
The Baikal region, including areas with poor environmental conditions, has significant clean background zones. In the summer of 2023, we analyzed the physical and chemical parameters of aerosol particles with different size fractions at Irkutsk and Listvyanka monitoring stations. Reduced wildfires and minimal impact from fuel and energy industries allowed us to observe regional and transboundary pollution transport. A large data array indicated that, during the shift of cyclones from Mongolia to the south of the Baikal region, the concentrations of Na+, Ca2+, Mg2+, K+, and Cl ions increased at the Irkutsk station, dominated by NH4+ and SO42−. The growth of the ionic concentrations at the Listvyanka station was observed in aerosol particles during the northwesterly transport. When air masses arrived from the southerly direction, the atmosphere was the cleanest. The analysis of 27 elements in aerosols revealed that Al, Fe, Mn, Cu, and Zn made the greatest contribution to air pollution at the Irkutsk station, while Fe, Al, Cu, Cr, Mn, and Ni made the greatest contribution to air pollution at the Listvyanka station. The dynamics of the investigated elements were mainly due to natural processes in the air under various synoptic situations and weather conditions in the region, although anthropogenic factors also affected the formation of aerosol composition wth certain directions of air mass transport. Full article
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18 pages, 4181 KB  
Article
Crystal Structure Features, Spectroscopic Characteristics and Thermal Conversions of Sulfur-Bearing Groups: New Natural Commensurately Modulated Haüyne Analogue, Na6Ca2−x(Si6Al6O24)(SO42−,HS,S2●−,S4,S3●−,S52−)2−y
by Nikita V. Chukanov, Natalia V. Zubkova, Roman Yu. Shendrik, Anatoly N. Sapozhnikov, Igor V. Pekov, Marina F. Vigasina, Nadezhda A. Chervonnaya, Dmitry A. Varlamov, Nadezhda B. Bolotina, Dmitry A. Ksenofontov and Dmitry Yu. Pushcharovsky
Minerals 2025, 15(7), 709; https://doi.org/10.3390/min15070709 - 3 Jul 2025
Cited by 3 | Viewed by 1469
Abstract
A multimethodic approach based on infrared, Raman, electron spin resonance and photoluminescence spectroscopy, absorption spectroscopy in near infrared, visible and ultraviolet regions, single-crystal X-ray diffraction as well as electron microprobe analyses was applied to the characterization of a new commensurately modulated cubic haüyne [...] Read more.
A multimethodic approach based on infrared, Raman, electron spin resonance and photoluminescence spectroscopy, absorption spectroscopy in near infrared, visible and ultraviolet regions, single-crystal X-ray diffraction as well as electron microprobe analyses was applied to the characterization of a new commensurately modulated cubic haüyne analogue with the modulation parameter of 0.2 and unit-cell parameter of 45.3629(3) Å (designated as haüyne-45Å) from the Malobystrinskoe lazurite deposit, in the Baikal Lake area, Siberia, Russia, as well as associated SO32−-bearing afghanite. Haüyne-45Å is the second member, after vladimirivanovite, of the sodalite group with a commensurately modulated structure. The average structure is based on the tetrahedral aluminosilicate sodalite-type framework with sodalite cages of different sizes. The simplified formula of haüyne-45Å is Na6Ca2−x(Si6Al6O24)(SO42−,HS,S2●−,S4,S3●−,S52−)2−y. The structural modulations of the haüyne-45Å framework are presumably related to the regular alternation of SO42− anions with polysulfide S2●−, S3●−, S4, and S52− groups detected by the spectroscopic methods. Mechanisms of thermal conversions of S-bearing groups in haüyne-45Å under oxidizing and reducing conditions at temperatures up to 800 °C are studied, and their geochemical importance is discussed. Full article
(This article belongs to the Special Issue Crystal Chemistry of Sulfate Minerals and Synthetic Compounds)
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22 pages, 11167 KB  
Article
Determination of the Main Factors Influencing the Chemical Composition of Atmospheric Deposition in the Territory of the Southern Baikal Region (Eastern Siberia, Russia)
by Yelena Molozhnikova, Maxim Shikhovtsev, Viktor Kalinchuk, Olga Netsvetaeva and Tamara Khodzher
Sustainability 2025, 17(13), 6062; https://doi.org/10.3390/su17136062 - 2 Jul 2025
Cited by 4 | Viewed by 1145
Abstract
In this study, a large portion of data on the chemical composition of precipitation falling in the South Baikal region shows the main factors determining their formation in 2017–2024. Taking into account the high variability of meteorological conditions in the region, both in [...] Read more.
In this study, a large portion of data on the chemical composition of precipitation falling in the South Baikal region shows the main factors determining their formation in 2017–2024. Taking into account the high variability of meteorological conditions in the region, both in time and in space, a method of observing the chemical composition of atmospheric precipitation has been developed, which makes it possible to determine its composition depending on the conditions of air mass formation. Using statistical analysis, marker substances characterizing the main groups of sources influencing the composition of atmospheric precipitation were identified. Joint analysis of air mass trajectories and data on chemical composition of precipitation allowed for establishing the areas of location of potential sources of precipitation pollution. All precipitation events were categorized based on the similarity of air mass formation conditions and chemical composition. Precipitation composition data collected on the shores of Lake Baikal reflect the influence of different types of pollutants such as industrial emissions, motor vehicles, dust storms, and forest fires. The results of the study are relevant for air quality assessment in the region and demonstrate the potential of using precipitation chemistry data to understand the long-range transport of pollutants, which contributes to sustainable development by increasing the availability of air quality data in ecologically significant regions such as Lake Baikal. Full article
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17 pages, 6087 KB  
Article
Application of Modern Low-Cost Sensors for Monitoring of Particle Matter in Temperate Latitudes: An Example from the Southern Baikal Region
by Maxim Yu. Shikhovtsev, Mikhail M. Makarov, Ilya A. Aslamov, Ivan N. Tyurnev and Yelena V. Molozhnikova
Sustainability 2025, 17(8), 3585; https://doi.org/10.3390/su17083585 - 16 Apr 2025
Cited by 20 | Viewed by 1546
Abstract
The aim of this study was to expand the monitoring network and evaluate the accuracy of inexpensive WoMaster ES-104 sensors for monitoring particulate matter (PM) in temperate latitudes, using the example of the Southern Baikal region. The research methods included continuous measurements of [...] Read more.
The aim of this study was to expand the monitoring network and evaluate the accuracy of inexpensive WoMaster ES-104 sensors for monitoring particulate matter (PM) in temperate latitudes, using the example of the Southern Baikal region. The research methods included continuous measurements of PM2.5 and PM10 concentrations, temperature, and humidity at three stations (Listvyanka, Patrony, and Tankhoy) from October 2023 to October 2024, using the LCS WoMaster ES-104. ERA5-Land reanalysis data and the HYSPLIT model were used to analyze meteorological conditions and air mass trajectories. The results of this study showed a high correlation between the WoMaster ES-104 and the DustTrak 8533; the correlation coefficient was 0.94 (R2 = 0.85) for both fractions. The seasonal dynamics of PM2.5 and PM10 were characterized by a dual-mode distribution with maxima in summer (secondary aerosols, high humidity) and winter (anthropogenic emissions, inversions). The diurnal cycles showed morning/evening peaks associated with transport activity and atmospheric stratification. Extreme concentrations were recorded in anticyclonal weather (weak north-westerly winds, stable atmosphere). This study confirms the suitability of the LCS WoMaster ES-104 for real-time monitoring of PM2.5 and PM10, which contributes to sustainable development by increasing the availability of air quality data for ecologically significant regions such as Lake Baikal. Full article
(This article belongs to the Special Issue Air Pollution Control and Sustainable Urban Climate Resilience)
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23 pages, 1809 KB  
Article
Modeling and Numerical Analysis of the Severobaikalsk Section of the Baikal–Amur Mainline Considering Environmental Points
by Igor Bychkov, Alexander Kazakov, Anna Lempert and Maxim Zharkov
Sustainability 2025, 17(2), 392; https://doi.org/10.3390/su17020392 - 7 Jan 2025
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Abstract
The article addresses the problem of increasing the capacity of the Baikal–Amur Mainline, which is part of the Northern Eurasian Corridor and provides the shortest route from Europe to the countries of the Asia-Pacific region via the ports of the Russian Far East. [...] Read more.
The article addresses the problem of increasing the capacity of the Baikal–Amur Mainline, which is part of the Northern Eurasian Corridor and provides the shortest route from Europe to the countries of the Asia-Pacific region via the ports of the Russian Far East. A key focus of the study is the Severobaikalsk section, which currently operates as a single-track system and is located in a specially protected natural area. In this regard, it is a limiting element since its reconstruction projects require environmental expertise. To tackle this issue, we develop a mathematical model based on semi-open queuing networks as a research tool. This modeling apparatus allows us to describe the features of the considered transport system, including single-track traffic, long sections between stations, which leads to the appearance of additional sidings, the presence of through and ring routes, and the significant influence of random factors on train operation. Based on the results of a numerical study of the model, we evaluate the current and maximum permissible section loads and point out bottlenecks in its structure. We compare two alternative ways of increasing the section capacity: creating a double-track connection on the most problematic sections and using a partially batch train schedule. Based on the results of the calculations, we conclude about the possibility and conditions of their implementation. Full article
(This article belongs to the Section Sustainable Transportation)
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