Search Results (310)

Understanding the impact of rural digitalization on the resilience of the swine industry is crucial to promoting its transformation toward efficient and low-carbon production. However, existing research has not yet clarified how rural digitalization influences the resilience of the swine industry, and there is a particular lack of discussion regarding potential nonlinear relationships. Based on panel data from 30 Chinese provinces for the period 2011–2023, we employed the entropy method to measure the level of rural digitalization and the resilience of the swine industry. Two-way fixed-effects, mediation, and threshold models were adopted to empirically examine the relationship and underlying mechanisms. The findings indicated that rural digitalization significantly enhances the resilience of the swine industry, and this finding remained robust after multiple robustness checks and endogeneity treatments. This effect is primarily mediated by two pathways: industrial-scale expansion and industrial agglomeration. Additionally, well-designed environmental policies and higher rural household incomes can strengthen the beneficial effect of rural digitalization on industrial resilience. Heterogeneity analysis further reveals that the positive influence is stronger in regions with poor transportation infrastructure and in central and western China, where digitalization effectively strengthens the industry’s shock resistance and adaptive capacity. This study offers meaningful implications for policymakers seeking to accelerate rural digitalization and promote high-quality development of the swine industry in the digital age. Full article

Surface discharge-induced degradation poses a significant threat to the operational reliability of high-voltage insulation systems. This research investigates the dielectric endurance of polyester-based nanocomposites reinforced with seven distinct nano-additives: iron oxide (Fe₃O₄), copper oxide (CuO), titanium oxide (TiO₂), aluminum oxide (Al₂O₃), silicon dioxide (SiO₂), zinc borate (ZnB) and graphene oxide (GO). Specimens were fabricated at 0.5% and 0.75% weight concentrations and subjected to constant AC electrical stress of 4.5 kV at 50 Hz until failure using the first-plane tracking method. To accurately monitor the aging process, a sophisticated signal processing framework involving Hankel-matrix-enhanced Robust Principal Component Analysis (RPCA) was developed to extract high-frequency discharge features from captured leakage current signals. The degradation characteristics were quantified using various statistical metrics, including Kurtosis, RMS and Burst Discharge Index (BDI). Experimental findings demonstrate that the incorporation of nanoparticles significantly extends the time-to-failure compared to neat polyester, although the effectiveness is highly dependent on both additive type and concentration. At 0.5 wt.%, ZnB exhibited the superior performance in delaying carbonized track formation. However, at 0.75 wt.%, Al₂O₃ emerged as the most effective additive, achieving a maximum endurance time of 31.61 min. In contrast, certain additives like TiO₂ showed a performance decline at higher loadings, likely due to nanoparticle agglomeration. The Hankel-RPCA methodology successfully isolated discharge-specific signatures from background noise, establishing a strong correlation between signal features and material failure stages. This study confirms that the synergy between advanced nanomaterial modification and robust signal processing provides an effective diagnostic tool for monitoring insulation health, offering a vital pathway for the designing of high-performance dielectrics for real-world power system applications. Full article

Aim: The aim of this study was to explore the distribution and driving factors influencing the disparity of health professionals (HPs) at the Centers for Disease Control and Prevention (CDC) in China and to provide a reference for regional health planning and rational allocation of public health resources. Methods: The Gini coefficient was used to measure the equity of HP distribution at CDC sites at the provincial level during 2012–2023 in China. Moran’s I was used to analyze the spatial agglomeration effect, and the geographic detector model was used to explore the factors driving the allocation of HPs at CDC sites in different provinces. Results: The number of HPs at the CDC showed an increasing trend from 2012 to 2023 in China. The average Gini coefficients at the population and geographical areas were 0.16 and 0.58, respectively. The global Moran’s I statistic indicated a notable decline in spatial clustering for the population dimension, decreasing from 0.503 to 0.238; in contrast, spatial clustering for the geographical dimension remained relatively stable, ranging between 0.13 and 0.16. The local Moran’s I statistic revealed that provinces such as Qinghai in the western China consistently exhibited a “low–low” spatial clustering pattern. Six factors were found to explain the variability in the CDC HP distribution based on the 2020 data. In the context of factor interactions, the synergistic effects between education level and health expenditure share (q = 0.9781), and between population aging and per capita GDP (q = 0.9699), substantially exceed the explanatory power attributable to any single factor alone. Conclusions: A significant regional disparity was observed in the distribution of HPs among 31 provinces, with the distribution based on service area being less equitable than that based on population. The shortage of healthcare professionals in the western region is characterized by notably inadequate geographical distribution. Future policy initiatives should prioritize targeted spatial interventions and integrated, multi-factor collaborative strategies. Full article

This preliminary study investigates the viability of substituting high-performance Aalborg white Portland cement (CEM I 52.5 R) with five diverse industrial byproducts: wood ash, silica waste, clay brick, glass fibre, and calcined sewage sludge ash. Sewage sludge ash was produced in a laboratory from two different sludges from wastewater treatment plants in the Latvian cities of Jelgava and Liepaja. The research evaluates the influence of substitution levels ranging from 5% to 20% on the rheology of fresh material and its early-age mechanical performance (day 7). Results indicate that particle morphology largely dictates workability; porous and angular materials, such as wood ash, clay brick, and sewage sludge ash, reduce flowability, whereas non-absorbent milled glass fibres unexpectedly improve spread diameter. Regarding mechanical performance, glass fibre and clay brick waste demonstrated the highest potential, exceeding the 48–62 MPa reference compressive strengths by achieving up to 69 MPa at a 10% substitution level. Conversely, wood ash and silica waste exhibited significant strength degradation at higher substitution levels, due to agglomeration and high water demand. This approach not only identifies viable waste streams for cement substitution but also diverts significant industrial waste from landfills, thereby reducing CO₂e emissions and advancing more sustainable construction practices. Full article

The development of eco-efficient construction materials requires optimisation strategies that reduce cement consumption, valorise industrial by-products, and enhance performance without increasing material demand. Clay–cement sealing suspensions used in geotechnical engineering offer significant sustainability potential due to their high mineral content and compatibility with supplementary cementitious materials such as siliceous fly ash. The early-age rheological properties are essential for the design of geotechnical sealing barriers, yet the influence of chemical additive sequencing on flow behaviour remains poorly understood. This study examines how the priority of sodium silicate addition—introduced either before cement and siliceous fly ash (the “Prior” series) or after them (the “After” series)—affects the flow curves, yield stress, thixotropy, and equilibrium shear stress of clay–cement–fly ash sealing suspensions. Ascending flow curves were fitted to the Casson, Herschel–Bulkley, and Ostwald–de Waele models, and a shear-rate-resolved thixotropic power density analysis was applied to decompose the hysteresis behaviour. The results demonstrate that the Prior series produces deflocculated colloidal clay networks with localised cementitious agglomerates, exhibiting lower shear stresses at low shear rates but markedly higher yield stress amplitudes and larger hysteresis loop areas. The After series yields more uniformly distributed nucleation–coagulation networks with smaller hysteresis loops and pronounced structural rebuilding at low shear rates during the ramp-down phase. These findings provide a physicochemical framework for tailoring the early-age rheology of clay–cement suspensions through controlled additive sequencing, with direct implications for pumpability, injectability, and post-placement structural recovery in geotechnical applications. Full article

Benefiting from their outstanding porosity, considerable specific surface area, and natural flexibility, cellulose nanofibers (CNFs)/MOF materials have emerged as competitive candidates for advanced flexible energy storage devices. However, conventional CNFs/MOFs aerogels or films often suffer from poor recoverability under compression, bending, and folding, accompanied by severe plastic deformation that compromises the cycling and structural stability of devices. To address this issue, we report a rationally designed flexible PU/CNFs/ZIF-8/PANI composite foam with an interconnected micro-mesoporous structure. Using polyurethane foam as a soft substrate and CNFs/ZIF-8 as building blocks, the composite was fabricated through a combined strategy of impregnation, in situ ZIF-8 growth, hot-pressing, and in situ aniline polymerization with simultaneous etching of the ZIF-8. The incorporation of carboxylated CNFs enhances the hydrophilicity of the PU skeleton. This, in combination with the hot-pressed framework, establishes an interconnected 3D network, thereby effectively preventing the agglomeration of active materials. Meanwhile, the hierarchical pores derived from the sacrificial ZIF-8 template provide abundant electroactive sites, accelerate ion transport, and facilitate high PANI loading. By virtue of this synergistic architectural effect, the resultant electrode achieves a high specific capacitance of 449 F/g at 0.2 A/g, with 97% capacitance retention after 2000 cycles at 5 A/g. Furthermore, the composite foam demonstrates excellent mechanical flexibility, with a tensile strength of 0.87 MPa and an elongation at break of 230%. This work offers a feasible approach for developing high-performance flexible supercapacitors and provides novel perspectives for the rational design of portable energy storage devices. Full article

The invasive fall armyworm (Spodoptera frugiperda) threatens Philippine crops, highlighting the need for sustainable pest management. This study therefore optimizes the green synthesis of silver nanoparticles (AgNPs) from water hyacinth (Eichhornia crassipes), an abundant and problematic aquatic weed, as a potential pest control tool. Methanolic leaf extracts were prepared under varying methanol concentrations, temperatures, and extraction times, and total phenolic content was quantified using the Folin–Ciocalteu method. SEM–EDX confirmed the formation of silver nanoparticles synthesized from Eichhornia crassipes (Ec-AgNPs), with particles observed at ≤100 nm. Optimal extraction occurred at 47 °C, 90% methanol, and 76 min, maximizing phenolic yield. Overall, results suggest phenolic content and extract volume influence nanoparticle size and stability, with larger extract volumes increasing agglomeration risk. Pesticidal efficacy was not evaluated; further work is needed to assess pest control performance. Full article

Fiber-reinforced polymer (FRP) composites used in marine environments suffer progressive degradation due to hydrothermal aging, which undermines their structural, physical and morphological integrity. In this study, a novel polyester-based nano-gelcoat reinforced with hexagonal boron nitride (h-BN) nanoparticles was developed as an advanced FRP composite coating for marine applications. Glass fiber/epoxy laminates coated with h-BN/polyester nano-gelcoat were subjected to accelerated hydrothermal aging (immersion in 80 °C artificial seawater for 90 days). Mechanical (tensile/flexural tests), viscoelastic (creep and stress relaxation), thermal (DSC/TGA), and morphological (optical microscopy/SEM) analyses were performed on aged and unaged samples. The h-BN-enhanced nano-gelcoat increased the composite’s resistance to hydrothermal aging. In particular, the optimally doped nano-gelcoat (~1 wt% h-BN) retained the highest tensile and flexural strength and modulus, reducing the property losses seen in the unreinforced system by about half (flexural strength 531.29 MPa vs. 1070.52 MPa for the uncoated laminate). Thermal analysis indicated elevated decomposition onset temperatures and higher char yields with h-BN, confirming improved thermal stability. Morphological observations revealed well-dispersed h-BN at 1 wt% with minimal microcracking, whereas higher filler loadings led to agglomeration. Additionally, a TOPSIS-based multi-criteria decision-making (MCDM) analysis was performed across mechanical, viscoelastic, and thermal metrics, which identified the 1 wt% h-BN coating as the most balanced formulation after hydrothermal aging. Full article

Titanium dioxide nanoparticles (TiO₂ NPs) are incorporated into automotive coatings to enhance durability, corrosion, UV resistance, and, in some formulations, photocatalytic self-cleaning. While the toxicology of pristine TiO₂ is well studied, the behavior of TiO₂ NPs embedded in polymer matrices and subjected to real-world aging, maintenance, and removal remains poorly characterized. This narrative review synthesizes 24 publications spanning the lifecycle of TiO₂ nano-enabled automotive coatings, from synthesis and formulation through application, in-service weathering, repair, refinishing, and end-of-life environmental fate. Upstream properties, such as coating functionality and performance, have been examined as determinants of later-life release, exposure, and fate. Across studies, dispersion state, interfacial compatibility, and surface modification—together with transformations such as agglomeration, photocatalysis, weathering, and eco-corona formation—shape particle stability, release, exposure relevance, and toxicological risk. Evidence indicates that sanding and accelerated weathering predominantly generate matrix-associated, polymer-fragment-dominated aerosols rather than pristine TiO₂ NPs, while NP-specific exposure measurements during spray application remain limited. Hazard data suggest matrix embedding may attenuate, but does not eliminate, biological responses relative to pure particles. Wastewater treatment plants and biosolids have been shown to act as sinks with potential for soil accumulation following sludge application. Regulatory frameworks rarely account for aging, transformation, and release, stressing the need for synchronized testing of aged materials and nano-specific exposure metrics to support safer-by-design coatings and risk governance. Full article

To upgrade the mechanical properties and reduce the high brittleness of coral aggregate concrete (CAC), calcium sulfate whisker (CSW) has been innovatively used as a reinforcing material in this study. Five incorporation levels (0–4%) were designed to systematically investigate the evolution mechanism of CAC mechanical, microstructure, and pore characteristics at different curing ages. The results showed that CSW incorporation can significantly improve the mechanical properties of CAC; 1% CSW can bring 36.7% enhancement to 14-day compressive strength, and 11.9% improvement to 28-day splitting tensile strength with 2% CSW. Mechanism analysis revealed that appropriate CSW content effectively suppressed microcrack propagation through whisker bridging effects and remarkably enhanced the cement paste–coral aggregate interfacial bond strength by 71%, promoting a transition in failure mode from interfacial failure to aggregate fracture. At the same time, CSW improved the pore structure by reducing the proportion of macropores and increasing the micropore proportion to 76% with 1% CSW content. However, the performance deterioration of CAC caused by CSW excess (4%) was mainly due to the defect formation resulting from whisker agglomeration. The proposed strength prediction models (R² > 0.93) based on experimental data can reliably describe the enhancement effect of CSW. Full article

E-commerce has become the driving force of regional sustainable development in the digital age. E-commerce has generated considerable economic benefits, but its resource and environmental costs have not been given sufficient attention. This study utilizes the national e-commerce demonstration city (NEDC) as a quasi-natural experiment and employs the difference-in-differences (DID) model to examine the influence of e-commerce on urban electricity consumption. The results show that e-commerce significantly reduces urban electricity intensity. Further analysis reveals that population agglomeration, economic agglomeration, and green innovation are potential channels. Meanwhile, the effect of e-commerce has obvious urban heterogeneity. The promising government and efficient market can significantly regulate the role of e-commerce in electricity utilization. Moreover, with the addition of more pilot cities, the inhibitory effect of e-commerce on electricity intensity will be weakened. These findings provide empirical evidence and implications for understanding the digitalization and energy use. Full article

Population ageing is intensifying pressure on elderly-care provision in megacity suburbs, but spatially explicit evidence on who benefits and where gaps persist remains limited. Using Daxing District, Beijing, as a case study, under the 15-min community living circle framework, we integrate cleaned elderly-care facility POIs from the municipal government portal (209 points), census-calibrated age-stratified WorldPop 100 m grids, and an OpenStreetMap road network to evaluate walking-based supply–demand matching. Kernel density estimation (KDE) characterizes facility agglomeration; the Gaussian Two-Step Floating Catchment Area (Ga2SFCA) method (1 km threshold) measures accessibility for two cohorts (60–80 and 80+); and global Moran’s I with bivariate LISA identifies spatial coupling between accessibility and elderly population density. The results indicate the following: (1) pronounced spatial imbalance—facilities are concentrated in the northwest and east but remain sparse in central and southern areas, while elderly population density follows a center–periphery gradient, peaking at 12,000 persons/km² in core areas (e.g., Jiugong and Huangcun); (2) clear accessibility stratification—overall accessibility is low and spatially clustered, yet the 80+ cohort (13.6% of the elderly population) exhibits markedly higher accessibility than the 60–80 cohort; and (3) differentiated coupling types—global bivariate Moran’s I = 0.773143 (p < 0.01), with LISA dominated by low-demand–low-accessibility (LL) areas and additional high-demand–low-accessibility (HL) shortage zones and low-demand–high-accessibility (LH) potential redundancy zones, while HH areas are scarce. These diagnostics support zone-specific gap filling to mitigate spatial inequities and age–structural mismatches. Full article

To advance human society towards a fully inclusive and accessible digital future, it is essential to foster the comprehensive and balanced development of digital villages, thereby addressing rural residents’ aspirations for a digitally enriched life. This study systematically investigates the spatiotemporal differentiation patterns and spatial spillover effects of China’s Digital Rural Development (DRD). Utilizing panel data from 31 provinces in China from 2013 to 2022, we construct a comprehensive evaluation framework covering digital infrastructure, economic digitization, governance digitization, and life digitization. The empirical analysis integrates entropy weighting, Dagum Gini coefficient decomposition, Moran’s I index, and spatial Durbin models. The findings indicate that China’s DRD has exhibited sustained overall improvement, progressing through three distinct phases: slow growth, rapid advancement, and fluctuating ascent. Significant regional disparities persist, with eastern regions consistently outperforming central, western, and northeastern areas. Inter-regional differences constitute the primary source of overall variation, and this gap has progressively widened over time. Spatially, DRD demonstrates a significant positive agglomeration effect alongside a negative spatial spillover effect (ρ = −1.3209), suggesting that advancements in neighboring regions may inhibit local development progress. Mechanism analysis identifies technological innovation, rural population size, and age structure as key local determinants, whereas industrial upgrading generates significant positive spillover effects on surrounding regions. Based on these results, at the same time, in order to ensure the sustainable development of DRD, we propose the following policy recommendations: implement regionally differentiated interventions, enhance the alignment of core local drivers, establish interregional coordination mechanisms, and develop dynamic monitoring and adjustment systems. These measures are expected to promote more balanced urban–rural and regional development, offering empirical evidence and policy insights for other developing countries pursuing similar pathways of rural digital transformation. Full article

Amid rapid global population aging, developing age-friendly urban spaces centered on the “15-minute community life circle” has become a priority in planning research. Taking Shenhe District of Shenyang City, a region undergoing deep aging, as a case study, this research constructs a facility weighting system reflecting the actual needs of the elderly. Integrating multi-source spatial data, the XGBoost model and SHAP framework were applied to analyze the non-linear effects of socio-economic, functional, and land-use factors on facility convenience. Results indicate that: (1) facility convenience exhibits a distinct “west-high, east-low” spatial pattern, characterized by high agglomeration in the western core and significant deficits in the eastern fringe; (2) convenience levels vary across categories, with medical and health facilities showing the highest accessibility, while cultural and leisure (CALFs), life service, and elderly care service facilities (ECSFs) remain the primary deficiencies; and (3) influencing variables demonstrate complex non-linear mechanisms, wherein functional density and distance from the city center are critical drivers with non-monotonic effects, while road network density displays threshold effects, inhibiting ECSFs and CALFs at high densities. These findings provide a refined, quantitative basis for optimizing facility layouts and formulating urban renewal strategies to build age-friendly communities. Full article

Colloidal solutions containing silica-coated silver nanoparticles (Ag@SiO₂) were synthesized through a two-step process integrating physical and chemical mechanisms. In the first step, laser ablation of a silicon target submerged in deionized water generated an H₂O–SiO₂ colloid, termed the as-cast colloid. This contained nanometric SiO₂ particles alongside micrometer-sized or larger silicon fragments produced by laser shockwave-induced target surface fragmentation. To refine particle size distribution and elevate nanometric SiO₂ concentration, the as-cast colloid underwent secondary laser irradiation, effectively fragmenting larger particles. The second step involved adding ionic silver to both as-cast and irradiated colloids, yielding Ag@SiO₂ nanoparticles. Structural properties were probed via XRD and TEM; optical characteristics via UV–Vis spectroscopy; and electrophoretic mobility via zeta potential measurements, both pre- and post-silver incorporation, to elucidate irradiation’s influence on synthesis. For controlled agglomeration, AlCl₃ was used to modify surface charge, neutralizing silanol groups on the silica shell and minimizing electrostatic repulsion through aluminum ion interactions. These findings demonstrate tunable Ag@SiO₂ colloids with precise surface properties for future development of advanced nanomaterials suitable for microbicidal applications. Full article