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23 pages, 1776 KiB  
Article
Assessment of Greenhouse Gas Emissions, Energy Demand and Solid Waste Generation Between Two Manufacturing Processes: A Case Study
by Fernando Nogueira Cardoso, João da Cruz Payão Filho, Margareth Nascimento de Souza Lira and Claudinei de Souza Guimarães
Recycling 2025, 10(4), 163; https://doi.org/10.3390/recycling10040163 - 13 Aug 2025
Abstract
Additive manufacturing (AM) is an Industry 4.0 technology that assists or replaces the conventional manufacturing (CM) of complex geometries in various sectors, including transport, steel, aerospace, military, and architecture. The aim is to improve processes, reduce energy consumption, atmospheric emissions, and solid waste, [...] Read more.
Additive manufacturing (AM) is an Industry 4.0 technology that assists or replaces the conventional manufacturing (CM) of complex geometries in various sectors, including transport, steel, aerospace, military, and architecture. The aim is to improve processes, reduce energy consumption, atmospheric emissions, and solid waste, and streamline stages while complying with the new environmental regulations. The main objective of this work was to carry out a cradle-to-gate Life Cycle Assessment (LCA), considering the raw material extraction, pre-processing, manufacturing, and post-processing stages, comparing two manufacturing methods for the same ER-90 metal flange part, conventional forging and wire and arc additive manufacturing (WAAM), all following the requirements and operations proposed by the ISO 14040/44 standard. WAAM is a Directed Energy Deposition (DED) technology that uses welding techniques to produce 3D objects with more complex geometries. Compared to the forging industry, which requires a lot of heat and kinetic energy in its metal part production stages, WAAM is a more sustainable and modern alternative because it does not require high temperatures and energy to produce the same parts. The environmental indicators compared in the process stages were energy consumption, greenhouse gas (GHG) emissions, and solid waste. The total energy consumption in AM was 18,846.61 MJ, the GHG emissions were 864.49 kgCO2-eq, and the solid waste generated was 142.34 kg, which were 63.8 %, 90.5%, and 31.6% lower than the environmental indicators calculated for CM, respectively. Full article
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29 pages, 1873 KiB  
Article
Robust Statistical Approaches for Stratified Data of Municipal Solid Waste Composition: A Case Study of the Czech Republic
by Radovan Šomplák, Veronika Smejkalová, Vlastimír Nevrlý and Jaroslav Pluskal
Recycling 2025, 10(4), 162; https://doi.org/10.3390/recycling10040162 - 12 Aug 2025
Abstract
Accurate information on waste composition is essential for strategic planning in waste management and developing environmental technologies. However, detailed analyses of individual waste containers are both time- and cost-intensive, resulting in a limited number of available samples. Therefore, it is crucial to apply [...] Read more.
Accurate information on waste composition is essential for strategic planning in waste management and developing environmental technologies. However, detailed analyses of individual waste containers are both time- and cost-intensive, resulting in a limited number of available samples. Therefore, it is crucial to apply statistical methods that enable reliable estimation of average waste composition and its variability, while accounting for territorial differences. This study presents a statistical approach based on territorial stratification, aggregating data from individual waste container analyses to higher geographic units. The methodology was applied in a case study conducted in the Czech Republic, where 19.4 tons of mixed municipal waste (MMW) were manually analyzed in selected representative municipalities. The method considers regional heterogeneity, monitors the precision of partial estimates, and supports reliable aggregation across stratified regions. Three alternative approaches for constructing interval estimates of individual waste components are presented. Each interval estimate addresses variability from the random selection of waste containers and the selection of strata representatives at multiple levels. The proposed statistical framework is particularly suited to situations where the number of samples is small, a common scenario in waste composition analysis. The approach provides a practical tool for generating statistically sound insights under limited data conditions. The main fractions of MMW identified in the Czech Republic were as follows: paper 6.7%, plastic 7.3%, glass 3.6%, bio-waste 28.4%, metal 2.1%, and textile 3.0%. The methodology is transferable to other regions with similar waste management systems. Full article
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22 pages, 895 KiB  
Article
Platform-Driven Sustainability in E-Commerce: Consumer Behavior Toward Recycled Fashion
by Eleni Sardianou and Maria Briana
Recycling 2025, 10(4), 161; https://doi.org/10.3390/recycling10040161 - 11 Aug 2025
Viewed by 164
Abstract
Digital platforms in fashion e-commerce are progressively shaping sustainable consumption practices. This research explores the interplay between consumer behaviors toward recycled and second-hand fashion, and the adoption of digital platform-driven innovations. The analysis is based on a structured questionnaire and an online survey [...] Read more.
Digital platforms in fashion e-commerce are progressively shaping sustainable consumption practices. This research explores the interplay between consumer behaviors toward recycled and second-hand fashion, and the adoption of digital platform-driven innovations. The analysis is based on a structured questionnaire and an online survey of 1000 consumers conducted in 2025, employing a combination of descriptive and inferential statistical techniques, including both cluster and factor analysis. The findings suggests that demographic factors—particularly age, education, and gender—significantly shape consumer attitudes toward digital innovations in fashion e-commerce apps. The analysis also confirms that the perceived effectiveness of AI and AR tools is significantly correlated with an increased interest in circular fashion options, including second-hand marketplaces and recycled clothing. The study emphasizes the strategic importance of platform features in fostering conscious fashion choices, thereby offering practical insights for retailers aiming to harmonize technological innovation with sustainability goals. Full article
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20 pages, 2007 KiB  
Article
Value-Added Recycling of Pre-Consumer Textile Waste: Performance Evaluation of Cotton Blend Knitted T-Shirts
by Muhammad Babar Ramzan, Sajida Ikram, Sheheryar Mohsin Qureshi, Muhammad Waqas Iqbal and Muhammad Qamar Khan
Recycling 2025, 10(4), 160; https://doi.org/10.3390/recycling10040160 - 8 Aug 2025
Viewed by 223
Abstract
This study investigates the effects of waste for value addition in form of use of textile waste to comfortable and durable garments based on blending recycled cotton fibers extracted from spinning, weaving, and cutting waste with virgin cotton in different ratios of 70:30, [...] Read more.
This study investigates the effects of waste for value addition in form of use of textile waste to comfortable and durable garments based on blending recycled cotton fibers extracted from spinning, weaving, and cutting waste with virgin cotton in different ratios of 70:30, 80:20, and 90:10 to produce yarns of 22/1 count, which are used to develop single jersey knitted T-Shirt, examining key properties such as mechanical and thermos-physiological properties. Grey fabric (unprocessed fabric) with a higher virgin cotton content and from spinning waste exhibited superior bursting strength, overall moisture management capacity, and thermal conductivity. In contrast, air permeability and water vapor permeability were highest in fabric made with weaving waste. After scouring and bleaching, the finished fabric (processed fabric) was compared with the grey fabrics. The results demonstrate that the finished fabric has slightly reduced bursting strength, water vapor permeability, and moisture management capacity while significantly enhancing air permeability and maintaining thermal conductivity. T-shirt properties were evaluated across various blend ratios and waste types over multiple washing cycles. Overall, the study demonstrates that recycled cotton fibers, particularly those from spinning waste, can be successfully produced into high-performance knitted t-shirts, offering a sustainable alternative to fully virgin cotton products without compromising performance significantly. Full article
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25 pages, 339 KiB  
Article
Pro-Environmental Behavior and Attitudes Towards Recycling in Slovak Republic
by Silvia Lorincová and Mária Osvaldová
Recycling 2025, 10(4), 159; https://doi.org/10.3390/recycling10040159 - 7 Aug 2025
Viewed by 171
Abstract
Climate changes have increased interest in the circular economy, an alternative model that seeks to minimize environmental impact and maximize resource reuse. A key element of this model is individuals’ behaviors and attitudes, which determine the overall efficiency of recycling processes. The study [...] Read more.
Climate changes have increased interest in the circular economy, an alternative model that seeks to minimize environmental impact and maximize resource reuse. A key element of this model is individuals’ behaviors and attitudes, which determine the overall efficiency of recycling processes. The study fills the gap by investigating how selected socio-demographic factors affect attitudes and intentions toward recycling and material reuse in the Slovak Republic, by using the Perceived Characteristics of Innovating (PCI) framework. Through a two-way ANOVA, we tested the hypotheses that higher education correlates with stronger recycling attitudes and that women are more willing than men to engage in circular practices. The results show that gender differences in consumer attitudes towards the circular economy do occur, but their magnitude is often conditioned by education level. Education proved to be the strongest predictor of ecological behavior: respondents with higher education reported stronger beliefs in the importance of recycling and a greater willingness to act sustainably. The interaction between gender and education revealed that university-educated women hold the most pronounced pro-environmental attitudes, underscoring the importance of gender-sensitive educational strategies. It is recommended that environmental education and outreach focus on less-educated groups, particularly women, who have high potential to influence their communities. Full article
16 pages, 1369 KiB  
Article
Recycling Waste Cottonseed Hulls to Biomaterials for Ammonia Adsorption
by Thomas Klasson, Bretlyn Pancio and Allen Torbert
Recycling 2025, 10(4), 158; https://doi.org/10.3390/recycling10040158 - 6 Aug 2025
Viewed by 287
Abstract
Ammonia emissions in poultry houses are common and pose health concerns for animals and workers. However, effective control of these emissions with sustainable products is lacking. Therefore, we investigated if an agricultural byproduct, cottonseed hulls, could be recycled through pyrolysis and used to [...] Read more.
Ammonia emissions in poultry houses are common and pose health concerns for animals and workers. However, effective control of these emissions with sustainable products is lacking. Therefore, we investigated if an agricultural byproduct, cottonseed hulls, could be recycled through pyrolysis and used to remove ammonia from air. In this study, the efficacy of ammonia removal was observed using cottonseed hull biomaterials pyrolyzed at seven different temperatures: 250, 300, 350, 400, 500, 600, and 700 °C. In this study, ammonia was passed through a column filled with pyrolyzed material, and ammonia in the filtered air was monitored. The results showed that materials pyrolyzed at intermediate temperatures of 350 and 400 °C were the most efficient at ammonia removal and were able to adsorb approximately 3.7 mg NH3/g of material. Despite extensive characterization, ammonia adsorption could not be linked to intrinsic material properties. Evaluation of the materials showed that the carbon in the pyrolyzed materials would be stable over time should the spent material be used as a soil amendment. Full article
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21 pages, 19752 KiB  
Article
Phase Characterisation for Recycling of Shredded Waste Printed Circuit Boards
by Laurance Donnelly, Duncan Pirrie, Matthew Power and Andrew Menzies
Recycling 2025, 10(4), 157; https://doi.org/10.3390/recycling10040157 - 6 Aug 2025
Viewed by 229
Abstract
In this study, we adopt a geometallurgical analytical approach common in mineral processing in the characterization of samples of shredded waste printed circuit board (PCB) E-waste, originating from Europe. Conventionally, bulk chemical analysis provides a value for E-waste; however, chemical analysis alone does [...] Read more.
In this study, we adopt a geometallurgical analytical approach common in mineral processing in the characterization of samples of shredded waste printed circuit board (PCB) E-waste, originating from Europe. Conventionally, bulk chemical analysis provides a value for E-waste; however, chemical analysis alone does not provide information on the textural variability, phase complexity, grain size, particle morphology, phase liberation and associations. To address this, we have integrated analysis using binocular microscopy, manual scanning electron microscopy, phase, textural and compositional analyses by automated (SEM-EDS), phase analysis based on (Automated Material Identification and Classification System (AMICS) software, and elemental analysis using micro-XRF. All methods used have strengths and limitations, but an integration of these analytical tools allows the detailed characterization of the texture and composition of the E-waste feeds, ahead of waste reprocessing. These data can then be used to aid the design of optimized processing circuits for the recovery of the key payable components, and assist in the commercial trading of e-scrap. Full article
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18 pages, 7363 KiB  
Article
Agronomic Evaluation of Compost Formulations Based on Mining Tailings and Microbial Mats from Geothermal Sources
by María Jesús Puy-Alquiza, Miren Yosune Miranda Puy, Raúl Miranda-Avilés, Pooja Vinod Kshirsagar and Cristina Daniela Moncada Sanchez
Recycling 2025, 10(4), 156; https://doi.org/10.3390/recycling10040156 - 5 Aug 2025
Viewed by 245
Abstract
This study, conducted in Mexico, evaluates the agricultural potential of three compost formulations BFS1, BFS2, and BFS3 produced from mining tailings and thermophilic microbial mats and collected from geothermal environments. The physicochemical characterization included pH, electrical conductivity (EC), macronutrients (N, P, K, Ca, [...] Read more.
This study, conducted in Mexico, evaluates the agricultural potential of three compost formulations BFS1, BFS2, and BFS3 produced from mining tailings and thermophilic microbial mats and collected from geothermal environments. The physicochemical characterization included pH, electrical conductivity (EC), macronutrients (N, P, K, Ca, Mg, and S), micronutrients (Fe, Zn, B, Cu, Mn, Mo, and Ni), organic matter (OM), and the carbon-to-nitrogen (C/N) ratio. All composts exhibited neutral pH values (7.38–7.52), high OM content (38.5–48.4%), and optimal C/N ratios (10.5–13.9), indicating maturity and chemical stability. Nitrogen ranged from 19 to 21 kg·t−1, while potassium and calcium were present in concentrations beneficial for crop development. However, EC values (3.43–3.66 dS/m) and boron levels (>160 ppm) were moderately high, requiring caution in saline soils or with boron-sensitive crops. A semi-quantitative Compost Quality Index (CQI) ranked BFS3 highest due to elevated OM and potassium content, followed by BFS1. BFS2, while rich in nitrogen, scored lower due to excessive boron. One-way ANOVA revealed no significant difference in nitrogen (p > 0.05), but it did reveal significant differences in potassium (p < 0.01) and boron (p < 0.001) among formulations. These results confirm the potential of mining tailings—microbial mat composts are low-cost, nutrient-rich biofertilizers. They are suitable for field crops or as components in nursery substrates, particularly when EC and boron are managed through dilution. This study promotes the circular reuse of geothermal and industrial residues and contributes to sustainable soil restoration practices in mining-affected regions through innovative composting strategies. Full article
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31 pages, 1741 KiB  
Review
Recycled Concrete Aggregate in Asphalt Mixtures: A Review
by Juan Gabriel Bastidas-Martínez, Hugo Alexander Rondón-Quintana and Luis Ángel Moreno-Anselmi
Recycling 2025, 10(4), 155; https://doi.org/10.3390/recycling10040155 - 2 Aug 2025
Viewed by 218
Abstract
Effective management and handling of construction and demolition waste (CDW) can yield significant technical and environmental benefits for road pavement construction. This article aims to provide a comprehensive and up-to-date chronological review of studies on the mechanical performance of asphalt mixtures—primarily hot mix [...] Read more.
Effective management and handling of construction and demolition waste (CDW) can yield significant technical and environmental benefits for road pavement construction. This article aims to provide a comprehensive and up-to-date chronological review of studies on the mechanical performance of asphalt mixtures—primarily hot mix asphalt (HMA)—incorporating recycled concrete aggregate (RCA). Since the main limitation of RCA is the presence of residual adhered mortar, the review also includes studies that applied various surface treatments (mechanical, chemical, and thermal, among others) to enhance mixture performance. The article summarizes the experimental procedures used and highlights the key findings and conclusions of the reviewed research. Although the results are varied and sometimes contradictory—mainly due to the source variability and heterogeneity of RCA—the use of these materials is technically viable. Moreover, their application can provide environmental, social, and economic advantages, particularly in the construction of low-traffic roadways. Finally, the article identifies research gaps and offers recommendations for future researches. Full article
(This article belongs to the Special Issue Recycled Materials in Sustainable Pavement Innovation)
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30 pages, 2603 KiB  
Review
Sugarcane Industry By-Products: A Decade of Research Using Biotechnological Approaches
by Serafín Pérez-Contreras, Francisco Hernández-Rosas, Manuel A. Lizardi-Jiménez, José A. Herrera-Corredor, Obdulia Baltazar-Bernal, Dora A. Avalos-de la Cruz and Ricardo Hernández-Martínez
Recycling 2025, 10(4), 154; https://doi.org/10.3390/recycling10040154 - 2 Aug 2025
Viewed by 428
Abstract
The sugarcane industry plays a crucial economic role worldwide, with sucrose and ethanol as its main products. However, its processing generates large volumes of by-products—such as bagasse, molasses, vinasse, and straw—that contain valuable components for biotechnological valorization. This review integrates approximately 100 original [...] Read more.
The sugarcane industry plays a crucial economic role worldwide, with sucrose and ethanol as its main products. However, its processing generates large volumes of by-products—such as bagasse, molasses, vinasse, and straw—that contain valuable components for biotechnological valorization. This review integrates approximately 100 original research articles published in JCR-indexed journals between 2015 and 2025, of which over 50% focus specifically on sugarcane-derived agroindustrial residues. The biotechnological approaches discussed include submerged fermentation, solid-state fermentation, enzymatic biocatalysis, and anaerobic digestion, highlighting their potential for the production of biofuels, enzymes, and high-value bioproducts. In addition to identifying current advances, this review addresses key technical challenges such as (i) the need for efficient pretreatment to release fermentable sugars from lignocellulosic biomass; (ii) the compositional variability of by-products like vinasse and molasses; (iii) the generation of metabolic inhibitors—such as furfural and hydroxymethylfurfural—during thermochemical processes; and (iv) the high costs related to inputs like hydrolytic enzymes. Special attention is given to detoxification strategies for inhibitory compounds and to the integration of multifunctional processes to improve overall system efficiency. The final section outlines emerging trends (2024–2025) such as the use of CRISPR-engineered microbial consortia, advanced pretreatments, and immobilization systems to enhance the productivity and sustainability of bioprocesses. In conclusion, the valorization of sugarcane by-products through biotechnology not only contributes to waste reduction but also supports circular economy principles and the development of sustainable production models. Full article
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19 pages, 4487 KiB  
Article
Recycling Volcanic Lapillus as a Supplementary Cementitious Material in Sustainable Mortars
by Fabiana Altimari, Luisa Barbieri, Andrea Saccani and Isabella Lancellotti
Recycling 2025, 10(4), 153; https://doi.org/10.3390/recycling10040153 - 1 Aug 2025
Viewed by 301
Abstract
This study investigates the feasibility of using volcanic lapillus as a supplementary cementitious material (SCM) in mortar production to improve the sustainability of the cement industry. Cement production is one of the main sources of CO2 emissions, mainly due to clinker production. [...] Read more.
This study investigates the feasibility of using volcanic lapillus as a supplementary cementitious material (SCM) in mortar production to improve the sustainability of the cement industry. Cement production is one of the main sources of CO2 emissions, mainly due to clinker production. Replacing clinker with SCMs, such as volcanic lapillus, can reduce the environmental impact while maintaining adequate mechanical properties. Experiments were conducted to replace up to 20 wt% of limestone Portland cement with volcanic lapillus. Workability, compressive strength, microstructure, resistance to alkali-silica reaction (ASR), sulfate, and chloride penetration were analyzed. The results showed that up to 10% replacement had a minimal effect on mechanical properties, while higher percentages resulted in reduced strength but still improved some durability features. The control sample cured 28 days showed a compressive strength of 43.05 MPa compared with 36.89 MPa for the sample containing 10% lapillus. After 90 days the respective values for the above samples were 44.76 MPa and 44.57 MPa. Scanning electron microscopy (SEM) revealed good gel–aggregate adhesion, and thermogravimetric analysis (TGA) confirmed reduced calcium hydroxide content, indicating pozzolanic activity. Overall, volcanic lapillus shows promise as a sustainable SCM, offering CO2 reduction and durability benefits, although higher replacement rates require further optimization. Full article
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23 pages, 4356 KiB  
Article
Quantifying Cotton Content in Post-Consumer Polyester/Cotton Blend Textiles via NIR Spectroscopy: Current Attainable Outcomes and Challenges in Practice
by Hana Stipanovic, Gerald Koinig, Thomas Fink, Christian B. Schimper, David Lilek, Jeannie Egan and Alexia Tischberger-Aldrian
Recycling 2025, 10(4), 152; https://doi.org/10.3390/recycling10040152 - 1 Aug 2025
Viewed by 260
Abstract
Rising volumes of textile waste necessitate the development of more efficient recycling systems, with a primary focus on the optimization of sorting technologies. Near-infrared (NIR) spectroscopy is a state-of-the-art method for fiber identification; however, its accuracy in quantifying textile blends, particularly common polyester/cotton [...] Read more.
Rising volumes of textile waste necessitate the development of more efficient recycling systems, with a primary focus on the optimization of sorting technologies. Near-infrared (NIR) spectroscopy is a state-of-the-art method for fiber identification; however, its accuracy in quantifying textile blends, particularly common polyester/cotton blend textiles, still requires refinement. This study explores the potential and limitations of NIR spectroscopy for quantifying cotton content in post-consumer textiles. A lab-scale NIR sorter and a handheld NIR spectrometer in complementary wavelength ranges were applied to a diverse range of post-consumer textile samples to test model accuracies. Results show that the commonly assumed 10% accuracy threshold in industrial sorting can be exceeded, especially when excluding textiles with <35% cotton content. Identifying and excluding the range of non-linearity significantly improved the model’s performance. The final models achieved an RMSEP of 6.6% and bias of −0.9% for the NIR sorter and an RMSEP of 3.1% and bias of −0.6% for the handheld NIR spectrometer. This study also assessed how textile characteristics—such as color, structure, product type, and alkaline treatment—affect spectral behavior and model accuracy, highlighting their importance for refining quantification when high-purity inputs are needed. By identifying current limitations and potential sources of errors, this study provides a foundation for improving NIR-based models. Full article
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20 pages, 1701 KiB  
Article
Life Cycle Assessment of Biomass Waste and Coal Co-Firing: Advancing Circular Economy in Energy Production
by Stiven J. Sofán-Germán, Miguel E. Doria-Oviedo, Jesus D. Rhenals-Julio and Jorge M. Mendoza-Fandiño
Recycling 2025, 10(4), 151; https://doi.org/10.3390/recycling10040151 - 1 Aug 2025
Viewed by 301
Abstract
This study uses life cycle analysis (LCA) to evaluate the environmental impacts of co-firing bituminous coal with agricultural biomass waste, such as coconut and rice husks, emphasising circular economy principles. Seven experimental scenarios with different coal-to-biomass ratios were designed, ranging from pure coal [...] Read more.
This study uses life cycle analysis (LCA) to evaluate the environmental impacts of co-firing bituminous coal with agricultural biomass waste, such as coconut and rice husks, emphasising circular economy principles. Seven experimental scenarios with different coal-to-biomass ratios were designed, ranging from pure coal to pure biomass. The results show that Scenario B (100% rice husk) achieved the best overall environmental performance, with the lowest global warming potential (300 kg CO2 equivalent), eutrophication potential (4.742 kg PO4 equivalent), and smog formation potential (0.012 kg C2H4 equivalent). Additionally, Scenario F (15% biomass mix) recorded the lowest acidification potential (57.39 kg SO2 eq), indicating that even partial substitution can yield significant environmental benefits. In contrast, Scenario C (100% coal) exhibited the highest acidification (164.08 kg SO2 eq) and eutrophication (8.82 kg PO4 eq) potential. Overall, the results demonstrate that co-firing biomass waste significantly reduces pollutant emissions compared to burning coal alone. This study highlights the effectiveness of biomass waste co-firing in mitigating environmental impacts, promoting resource recovery, and supporting a sustainable energy transition within a circular economy framework. Full article
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17 pages, 9519 KiB  
Article
Lead Recovery from Flue Dust by Using Ultrasonic-Enhanced Hydrogen Peroxide Water Washing
by Tian Wang, Yuxi Xie, Phan Duc Lenh, Thiquynhxuan Le and Libo Zhang
Recycling 2025, 10(4), 150; https://doi.org/10.3390/recycling10040150 - 1 Aug 2025
Viewed by 258
Abstract
An ultrasonic-enhanced hydrogen peroxide water-washing process was developed to recover lead from raw flue dust (RFD) under neutral conditions. At optimal parameters (40 °C, 30 min, 4 mL H2O2, liquid-to-solid ratio 2:1, 240 W ultrasound), the Pb mass fraction [...] Read more.
An ultrasonic-enhanced hydrogen peroxide water-washing process was developed to recover lead from raw flue dust (RFD) under neutral conditions. At optimal parameters (40 °C, 30 min, 4 mL H2O2, liquid-to-solid ratio 2:1, 240 W ultrasound), the Pb mass fraction in the solid residue increased from 41.68% in the RFD to 68.11%, accompanied by a Pb recovery rate of 97.1%. These values are significantly higher than those obtained under identical conditions without ultrasound (64.07% and 95.93%, respectively). Ultrasound promotes de-agglomeration and generates •OH radicals that accelerate the oxidation of PbSO3 to insoluble PbSO4 while concurrently removing impurity cadmium. This research offers a green and efficient alternative to traditional lead recovery methods, fostering sustainable development in the metallurgical industry. Full article
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21 pages, 2332 KiB  
Article
Evaluation of Spent Catalyst from Fluid Catalytic Cracking in Fly Ash and Blast Furnace Slag Based Alkali Activated Materials
by Yolanda Luna-Galiano, Domigo Cabrera-Gallardo, Mónica Rodríguez-Galán, Rui M. Novais, João A. Labrincha and Carlos Leiva Fernández
Recycling 2025, 10(4), 149; https://doi.org/10.3390/recycling10040149 - 1 Aug 2025
Viewed by 280
Abstract
The objective of this work is to evaluate how spent catalyst from fluid catalytic cracking (SCFCC) affects the physical, mechanical and durability properties of fly ash (FA) and blast furnace slag (BFS)-based alkali-activated materials (AAMs). Recycling of SCFCC by integrating it in a [...] Read more.
The objective of this work is to evaluate how spent catalyst from fluid catalytic cracking (SCFCC) affects the physical, mechanical and durability properties of fly ash (FA) and blast furnace slag (BFS)-based alkali-activated materials (AAMs). Recycling of SCFCC by integrating it in a AAM matrix offers several advantages: valorization of the material, reducing its disposal in landfills and the landfill cost, and minimizing the environmental impact. Mineralogical, physical and mechanical characterization were carried out. The durability of the specimens was studied by performing acid attack and thermal stability tests. Mass variation, compressive strength and porosity parameters were determined to assess the durability. BFS- and FA-based AAMs have a different chemical composition, which contribute to variations in microstructure and physical and mechanical properties. Acid neutralization capacity was also determined to analyse the acid attack results. Porosity, including the pore size distribution, and the acid neutralization capacity are crucial in explaining the resistance of the AAMs to sulfuric acid attack and thermal degradation. Herein, a novel route was explored, the use of SCFCC to enhance the durability of AAMs under harsh operating conditions since results show that the compositions containing SCFCC showed lower strength decay due to the lower macroporosity proportions in these compositions. Full article
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