Synthesis, Performance and Applications of Cementitious Materials

A special issue of Processes (ISSN 2227-9717). This special issue belongs to the section "Sustainable Processes".

Deadline for manuscript submissions: 31 May 2026 | Viewed by 2089

Special Issue Editors


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Guest Editor
Department of Civil and Environmental Engineering, Hong Kong Polytechnic University, Hong Kong, China
Interests: mechanical behavior and failure mechanisms of concrete; low-carbon concrete and cementitious materials; carbonation resource utilization of solid waste
Department of Civil and Environmental Engineering, Hong Kong Polytechnic University, Hong Kong, China
Interests: FRP reinforced concrete structure durability; research on the utilization of solid waste materials in building materials
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Guest Editor
State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures, Guangxi University, Nanning 530004, China
Interests: chemistry of cement; geopolymer and alkali-activated materials; functional building materials; corrosion protection

Special Issue Information

Dear Colleagues,

Synthesis, performance, and application of cementitious materials aim to gather frontier research and breakthroughs in this field, addressing the growing challenges related to material performance in modern engineering construction. While traditional cementitious materials are widely used, their high energy consumption and environmental impact have driven global scholars to focus on developing more sustainable, high-performance binder systems.

This Special Issue focuses on the design of novel cementitious materials through advanced synthesis methods and processes, including chemical activation, low-temperature preparation, nanomodification, and resource utilization of solid waste. We anticipate that the research will not only uncover the formation mechanisms and evolution law—from microstructure to macroscopic performance—but also delve into the durability, intelligent response characteristics, and optimization of mechanical properties under extreme environmental conditions. Notably, these outcomes are expected to provide valuable guidance for the practical application and industrialization of these materials in critical infrastructure, 3D printing, carbon sequestration technologies, and functional buildings, driving cementitious materials toward high performance, functionality, and sustainability, while laying a strong scientific foundation for the sustainable development of the construction industry.

Topics include, but are not limited to, the following:

  • Synthesis and preparation processes of novel cementitious materials.
  • Green development and sustainability of cementitious materials.
  • Development and application of intelligent and functional cementitious materials.
  • Structure-performance relationships of cementitious materials at both micro and macro scales.
  • Mechanical property enhancement and optimization design of cementitious materials.
  • Durability and long-term performance of cement-based materials in harsh environments.

Thanks, and we hope you consider participating in this Special Issue.

Dr. Qinglong Qin
Dr. Weiwei Wu
Dr. Xue-Sen Lyu
Guest Editors

Manuscript Submission Information

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Processes is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2400 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • cementitious materials
  • synthesis and preparation
  • performance regulation
  • microstructure
  • durability
  • green and low-carbon
  • resource utilization of solid waste

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Published Papers (4 papers)

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Research

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20 pages, 2587 KB  
Article
Effects of Ion on the Properties of Seawater Slurry and Development of Salt-Tolerant Polymer Seawater Slurry
by Kexiong Wu, Haodong Liu, Lina Luo, Junwen Chen, Yang Ming, Yunhang Yin and Jinxuan Hu
Processes 2026, 14(3), 422; https://doi.org/10.3390/pr14030422 - 25 Jan 2026
Viewed by 229
Abstract
To address the significant deterioration in the performance of traditional drilling slurries due to seawater intrusion, this study developed a novel salt-tolerant polymer slurry (MXC) utilizing grafting modification techniques. The performance of MXC was systematically evaluated and compared with two commercial slurries, PAC [...] Read more.
To address the significant deterioration in the performance of traditional drilling slurries due to seawater intrusion, this study developed a novel salt-tolerant polymer slurry (MXC) utilizing grafting modification techniques. The performance of MXC was systematically evaluated and compared with two commercial slurries, PAC and Flowz, through simulated formation filtration experiments. The results indicate that the MXC slurry exhibited the lowest filtration loss and was capable of forming a thinner, denser filter cake, thereby providing optimal wall protection. Mechanistic analysis revealed that grafting modification optimized the hydrophobic interactions between polymer molecules, constructing a dynamic physical cross-linking network and a rigid double-helical structure within the solution. This significantly enhanced the system’s viscosity and resistance to ionic interference, ultimately resulting in the formation of a dense network structure during the filtration process. This study offers a novel material solution and theoretical foundation for the development of high-performance salt-tolerant slurries in marine engineering. Full article
(This article belongs to the Special Issue Synthesis, Performance and Applications of Cementitious Materials)
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14 pages, 7949 KB  
Article
Regulation Mechanism of Alkanolamines on Hydration and Microstructural Evolution of Thermally Treated Volcanic Rock Powder–Cement System
by Jingbin Yang, Shaojiang Wang, Fanyuan Mu and Zhenping Sun
Processes 2026, 14(1), 22; https://doi.org/10.3390/pr14010022 - 20 Dec 2025
Cited by 1 | Viewed by 440
Abstract
Utilizing abundant volcanic rock resources as supplementary cementitious materials is a critical pathway for regional low-carbon construction. However, the high crystallinity of natural volcanic rocks limits their reactivity. This study systematically investigates the regulation mechanisms of Triethanolamine (TEA) and Triisopropanolamine (TIPA) on the [...] Read more.
Utilizing abundant volcanic rock resources as supplementary cementitious materials is a critical pathway for regional low-carbon construction. However, the high crystallinity of natural volcanic rocks limits their reactivity. This study systematically investigates the regulation mechanisms of Triethanolamine (TEA) and Triisopropanolamine (TIPA) on the hydration kinetics and microstructure of a cement system containing Volcanic Rock Powder (VRP) thermally treated at 700 °C. Dissolution kinetics reveal that both TEA and TIPA inhibit Si release but exhibit distinct structural selectivity in promoting metal ion dissolution: TEA demonstrates superior efficiency in promoting the release of Al and Ca ions due to lower steric hindrance, whereas TIPA exhibits a stronger specific activation capacity for insoluble Fe, which is likely attributed to the electron-donating inductive effect. Macroscopic tests show that TEA at 0.05% dosage significantly improved the 28-day compressive strength by 20.4%, attributed to the synergistic effect of efficient chemical activation and pore structure refinement. In contrast, the stronger surface activity of TIPA introduced substantial detrimental macropores; this deterioration in physical structure severely offset its chemical contributions, leading to slow late-age strength development. The study highlights the critical trade-off between chemical activation and microstructural evolution, confirming that TEA is a more suitable activator than TIPA for the Al/Fe-rich thermally treated VRP. Full article
(This article belongs to the Special Issue Synthesis, Performance and Applications of Cementitious Materials)
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15 pages, 4759 KB  
Article
Mechanical and Shrinkage Properties of Alkali-Activated Binder-Stabilized Expansive Soils
by Yongke Wei, Weibo Tan, Jiann-Wen Woody Ju, Yinghui Tian, Shouzhong Feng, Changbai Wang, Qiang Wang and Peiyuan Chen
Processes 2026, 14(1), 3; https://doi.org/10.3390/pr14010003 - 19 Dec 2025
Viewed by 367
Abstract
Expansive soil is prone to significant swelling and shrinkage deformation with changes in moisture conditions, posing serious safety hazards to engineering construction. This study focuses on alkali-activated self-compacting fluid-solidified soil (ASFS) and systematically explores the regulatory effect of expansive soil with different dosages [...] Read more.
Expansive soil is prone to significant swelling and shrinkage deformation with changes in moisture conditions, posing serious safety hazards to engineering construction. This study focuses on alkali-activated self-compacting fluid-solidified soil (ASFS) and systematically explores the regulatory effect of expansive soil with different dosages (0–100%) on its properties. This study analyzes the influence of expansive soil on the setting time, hydration characteristics, autogenous shrinkage, and compressive strength of ASFS while verifying the feasibility of this method for solidifying expansive soil through microstructural analysis. The results show that, with the increase in content of expansive soil, the initial and final setting times of ASFS were prolonged by 0.08–1.58 times and 0.08–1.29 times, respectively. Although expansive soil inhibited the hydration of ASFS, it could compensate for autogenous shrinkage through the expansion effect of clay minerals, reducing the autogenous shrinkage by 13.4–51.2%. Furthermore, the optimal dosage of expansive soil in ASFS is 60%. Compared with the control group, the 7d compressive strength of ASFS increases by 52.4%, the strength after 3d water immersion rises by 62.6%, and the strength after eight wet–dry cycles still remains 10% higher. This optimal dosage achieves the best balance between mechanical properties, water stability, and shrinkage resistance of ASFS, providing a reliable technical reference for the efficient utilization of expansive soil in engineering. Full article
(This article belongs to the Special Issue Synthesis, Performance and Applications of Cementitious Materials)
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Review

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25 pages, 3529 KB  
Review
Progress Analysis and Prospect on the Influence of Early-Age Carbonation Curing on Properties of Cement-Based Materials
by Junwen Chen, Lei Tang, Jin Yi, Kexiong Wu and Jiwang Zhang
Processes 2026, 14(1), 97; https://doi.org/10.3390/pr14010097 - 27 Dec 2025
Viewed by 710
Abstract
As a cutting-edge technology in the field of cement-based materials, early carbonation curing enables industrial carbon sequestration and functional modification, and the optimization of process parameters is the key to advancing the development of this technology. This paper reviews the mechanism of action [...] Read more.
As a cutting-edge technology in the field of cement-based materials, early carbonation curing enables industrial carbon sequestration and functional modification, and the optimization of process parameters is the key to advancing the development of this technology. This paper reviews the mechanism of action and influencing factors of early carbonation curing (including moisture content, carbon dioxide concentration, pre-hydration degree, etc.), its effects on the mechanical properties and durability of materials, as well as the resulting changes in microstructure. Meanwhile, this review also covers content such as the hydration–carbonation coupling mechanism, mentions the relevant conditions of carbonation products and microstructure, analyzes the performance enhancement of the interfacial transition zone (ITZ), and provides relevant support for the low-carbon development of cement-based materials by combining the application practice of prefabricated components and the comparison of technical routes. Although early carbonation can significantly improve material properties and optimize microstructure, current research still has shortcomings: the exploration of mineral carbonation–hydration activity, microstructure evolution law, and product combination mechanism is relatively insufficient, and the understanding of carbonation–hydration coupling kinetics is still not in-depth enough, all of which are areas requiring further research in the future. Full article
(This article belongs to the Special Issue Synthesis, Performance and Applications of Cementitious Materials)
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