Nanomaterial-Mediated Green Catalysis

A special issue of Processes (ISSN 2227-9717). This special issue belongs to the section "Catalysis Enhanced Processes".

Deadline for manuscript submissions: 20 May 2025 | Viewed by 2844

Special Issue Editors


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Guest Editor
Department of Chemistry, Federal University of Viçosa, Viçosa 36.570-900, MG, Brazil
Interests: nanomaterials; biochar; hydrogen; green chemistry
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
Department of Chemistry, Institute of Natural Sciences, Federal University of Lavras, University Campus, Lavras 3037, MG, Brazil
Interests: adsorption; photocatalysis; carbon materials; water treatment; biomass conversion

Special Issue Information

Dear Colleagues,

Human ingenuity has driven exploration beyond borders in the pursuit of innovations for survival, comfort, and entertainment. The 18th century marked a pivotal shift towards large-scale production during the Industrial Revolution, bringing both progress and significant environmental challenges. For an extended period, the consequences were overlooked, but contemporary society now faces pressing challenges. Global leaders collaborate in pivotal events such as the signing of the Paris Agreement in 2015, representing a collective endeavor towards a sustainable future. The UN's Agenda 2030, conceived during the Paris Agreement, outlines 17 goals and 169 targets as a robust plan guiding the world towards a more sustainable trajectory by 2030.

In this context, the scientific community encounters innovative challenges in developing materials and processes that are more sustainable. This involves minimizing waste, enhancing catalyst performance through materials engineering, and, critically, substituting toxic solvents with more sustainable alternatives. Additionally, the priority is to seek a reduction in or minimization of effluents, with a focus on efficient water reuse and the utilization of residual biomass to obtain new products with added value, aligning with the fundamental principles of a circular economy.

In the energy sector, the transition to cleaner sources takes precedence, with the replacement of fossil fuel-based matrices. In this context, renewable sources play an essential role, with green hydrogen and water-splitting processes highlighted as promising alternatives aligned with the pursuit of a more sustainable and clean energy future.

This Special Issue, titled "Nanomaterial-Mediated Green Catalysis", aims to cover recent advances in the synthesis of new materials and processes aligned with the concept of green catalysis. Topics of interest for this Special Issue include the following:

  • Catalysis in Sustainable Hydrogen Production: Exploration of innovative catalytic methods for efficient and sustainable hydrogen production as a clean energy source.
  • Degradation of Emerging Contaminants through Catalysis: Investigation of catalytic approaches for the effective degradation of emerging contaminants, contributing to environmental remediation and the preservation of water and soil quality.
  • Catalytic Synthesis for Obtaining Value-Added Molecules: Development of innovative catalytic processes to obtain new molecules, emphasizing the creation of products with added value, promoting a circular and sustainable economy.
  • Carbon Dioxide (CO2) Capture: Exploration of advanced strategies for efficient carbon dioxide capture, aiming to reduce emissions and mitigate environmental impact.
  • Use of Biochar in Catalysis: Exploring Sustainable Alternatives: This topic explores the application of biochar in catalytic processes, highlighting its unique properties and contributions to a more environmentally friendly approach in catalysis.

Dr. Renata Lopes Moreira
Dr. Guilherme Max Dias Ferreira
Guest Editors

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Keywords

  • nanomaterials
  • catalysis
  • circular economy
  • green chemistry and sustainability

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Published Papers (2 papers)

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Research

18 pages, 7832 KiB  
Article
Research on the Chloramphenicol Removal Performance of Co-Doped Porous Carbon Materials Derived from Co-Zn Bimetallic ZIFs
by Ke-Hong Chen, Ao-Tian Gu, Liang Zhang, Hao Tang, Zhi-Ming Zhang, Yi-Ming Zhou, Yu-Qi Cheng and Yi Yang
Processes 2024, 12(12), 2670; https://doi.org/10.3390/pr12122670 - 26 Nov 2024
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Abstract
Chloramphenicol antibiotics (CAPs) are broad-spectrum antibiotics, and excessive consumption has led to increasingly dangerous residues in the environment. The accumulation of these highly toxic and difficult-to-biodegrade CAPs and their long-term exposure in ecological environments can pose insidious and long-term hazards to human health [...] Read more.
Chloramphenicol antibiotics (CAPs) are broad-spectrum antibiotics, and excessive consumption has led to increasingly dangerous residues in the environment. The accumulation of these highly toxic and difficult-to-biodegrade CAPs and their long-term exposure in ecological environments can pose insidious and long-term hazards to human health and aquatic organisms. In this study, co-carbon composite nanocatalysts (CoxZn10−x-NC) with many carbon nanotubes on the surface were prepared via the one-step pyrolysis of bimetallic CoxZn10−x-ZIF with different Co/Zn ratios and used for the degradation of trace amounts of CAPs in a water column. The microstructure and chemical composition of the prepared catalysts were fully characterized using SEM, TEM, and XPS. The CAP degradation experiments demonstrated that Co6Zn4-NC in CoxZn10−x-NC possessed the highest catalytic activity level, removing 100% of the CAPs in 60 min. The CAPs had a corresponding reaction rate constant of 0.22 min−1, and Co6Zn4-NC was able to completely mineralize 44.57% of them. Doping moderate amounts of Zn can effectively improve the carbon nanotube structure on the catalyst surface and promote the generation of monoatomic Co, thus improving catalytic activity. The results of the free-radical burst experiments and electron paramagnetic resonance (EPR) showed that the free-radical pathway mainly dominated within the Co6Zn4-NC+PMS system, in which SO4•− was the main ROS for CAP degradation. Full article
(This article belongs to the Special Issue Nanomaterial-Mediated Green Catalysis)
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15 pages, 3476 KiB  
Article
Synthesis of Ecofriendly Bimetallic Pt/Ni Nanoparticles on KNbO3 via Hydrothermal Process for Sustainable Hydrogen Evolution from NaBH4
by Tulho Martins dos Reis, Aléxia Caroline de Castro Alves, Victor Nogueira da Silva, Guilherme Oliveira Siqueira, Fabrício Vieira de Andrade, Geraldo Magela de Lima and Renata Pereira Lopes Moreira
Processes 2024, 12(11), 2340; https://doi.org/10.3390/pr12112340 - 24 Oct 2024
Cited by 1 | Viewed by 1656
Abstract
The performance of nickel and platinum bimetallic nanoparticles (NPs) supported on potassium niobate (KNbO3) is evaluated in the catalytic hydrolysis of sodium borohydride (NaBH4) to generate hydrogen (H2). KNbO3 was synthesized via a hydrothermal route using [...] Read more.
The performance of nickel and platinum bimetallic nanoparticles (NPs) supported on potassium niobate (KNbO3) is evaluated in the catalytic hydrolysis of sodium borohydride (NaBH4) to generate hydrogen (H2). KNbO3 was synthesized via a hydrothermal route using Nb2O5 and KOH as precursors. X-ray diffraction (XRD) confirmed the crystalline orthorhombic structure of KNbO3. The Ni/Pt NPs, with an average size of 4.66 nm and a spherical morphology, were uniformly dispersed on the surface of KNbO3 nanosheets. The N2 physisorption isotherms of KNbO3 and Ni/Pt NPs were classified as type V with H3 hysteresis, showing specific surface areas of 0.170 and 2.87 m2 g−1, respectively. Catalytic performance studies examined various Ni/Pt molar ratios, with the 1:3 ratio (mol/mol) demonstrating the highest efficiency. Kinetic analysis of NaBH4 hydrolysis showed that the data fit the pseudo-first-order model. An increase in temperature enhanced the hydrogen generation rate (HGR), reaching 2068.3 mL gcat−1 min−1 at 315.05 K. The apparent activation energy (Ea) was determined to be 29.9 kJ mol−1. Durability assays showed only an 11% decrease in activity after 11 catalytic cycles. Thus, a promising, easy-to-synthesize, and environmentally friendly catalyst for NaBH4 hydrolysis has been developed. Full article
(This article belongs to the Special Issue Nanomaterial-Mediated Green Catalysis)
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