Radiation-Induced Modification in Synthesized Polymeric Nano-Composite Films

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Smart and Functional Polymers".

Deadline for manuscript submissions: closed (10 June 2022) | Viewed by 1799

Special Issue Editor


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Guest Editor
Department of Physics, Taibah University, Madinah 30002, Saudi Arabia
Interests: polymers; nanocomposites; radiation; physical properties

Special Issue Information

Dear Colleagues,

Polymers (ISSN 0032-3861, IF 4.430), an open access journal, will publish a Special Issue entitled “Radiation-Induced Modification in Synthesized Polymeric Nano-Composite Films”, for which I will be acting as guest editor. The Special Issue will focus on recent progresses in the field of polymer composite nanofilms, improving their performance in numerous industrial applications using irradiation. It is thus my pleasure to invite you to submit a paper to this exciting new Special Issue. The submission deadline is 5 June 2022. hope this invitation will receive your favorable consideration.

Many thanks!
Prof. Dr. Samir A. Nouh
Guest Editor

Manuscript Submission Information

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Keywords

  • nanocomposite
  • radiation
  • optical characterization
  • thermal characterization
  • electrical
  • mechanical
  • structural characterization

Published Papers (1 paper)

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Research

15 pages, 3703 KiB  
Article
Structural, Thermal, and Optical Studies of Gamma Irradiated Polyvinyl Alcohol-, Lignosulfonate-, and Palladium Nanocomposite Film
by Foued Gharbi, Kaoutar Benthami, Tarfa. H. Alsheddi, Mai M. E. Barakat, Nisrin Alnaim, Adil Alshoaibi and Samir A. Nouh
Polymers 2022, 14(13), 2613; https://doi.org/10.3390/polym14132613 - 28 Jun 2022
Cited by 2 | Viewed by 1583
Abstract
Nanocomposite (NC) films of polyvinyl alcohol (PVA), lignosulfonate (Lg), and nanosized palladium (Pd) were synthesized by ex-situ casting method. Samples from the synthesized PVA-Lg/Pd NC films were irradiated with 5–100 kGy γ doses. The effect of γ doses on the structural, thermal, and [...] Read more.
Nanocomposite (NC) films of polyvinyl alcohol (PVA), lignosulfonate (Lg), and nanosized palladium (Pd) were synthesized by ex-situ casting method. Samples from the synthesized PVA-Lg/Pd NC films were irradiated with 5–100 kGy γ doses. The effect of γ doses on the structural, thermal, and optical characteristics of the NC films were studied using different characterization techniques. The results indicated that the γ irradiation improves the decomposition temperature from 227 to 239 °C, signifying an increase in the thermal stability of the NC films. This was accompanied by a reduction of the melting temperature due to the increase of the amorphous phase. This can be attributed to the dominance of crosslinking. On the other hand, the refractive index increased from 2.21 to 2.32 while increasing the γ dose up to 100 kGy. This was associated with a reduction of the optical bandgap from 3.49 to 3.30 eV, which could be attributed to the increase in the amorphous phase as a result of crosslinking. This indicates an enhancement of the spreading of the NPs inside the blend matrix due to γ irradiation. This results in a more compacted construction of the PVA-Lg/Pd NC films. Furthermore, we used the Commission Internationale de E’Claire (CIE) method to estimate the change in color among the irradiated NC films and the pristine film. The PVA-Lg/Pd NC attained a significant color difference value greater than five, meaning permanent color changes. Full article
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