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Material-Process-Structure Integrated Design for Advanced Polymeric Composites, 2nd Edition

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Composites and Nanocomposites".

Deadline for manuscript submissions: 30 June 2026 | Viewed by 1102

Special Issue Editors

School of Automobile, Chang'an University, Middle Section of Nan Erhuan Road, Xi'an 710064, China
Interests: composite materials; fiber-reinforced polymer; crashworthiness; optimization design; numerical simulation
Special Issues, Collections and Topics in MDPI journals
School of Automobile, Chang'an University, Middle Section of Nan Erhuan Road, Xi'an 710064, China
Interests: composite structures; polymer composite; mechanics of lattice materials; multi-scale modeling; crashworthiness; lghtweight design
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

With the widespread application of advanced polymer composites in aerospace, new energy vehicles, and biomedicine, the collaborative design of materials, processes, and structures has become a key pathway to improve material performance and functionality. This Special Issue aims to explore in depth the integrated research methods from microscopic material design to macroscopic structural performance, focusing on core issues, such as multi-scale modeling, intelligent fabrication processes, performance prediction, and optimization. The scope of submissions covers (but is not limited to) the following areas: constitutive models and multi-field coupling behavior of novel polymer composites; advanced molding processes such as additive manufacturing and automated fabrication; integrated structure-function design and performance verification; material design and process optimization driven by machine learning and data; and sustainability and circular design strategies for composite materials. We sincerely invite scholars, engineers, and industry experts from home and abroad to contribute original research papers, reviews, and case studies to jointly promote the innovative development of polymer composite design theory and engineering applications.

Dr. Zhen Wang
Dr. Guohua Zhu
Guest Editors

Manuscript Submission Information

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Keywords

  • fiber-reinforced polymers
  • multi-scale
  • integrated model
  • optimization algorithm
  • collaborative design
  • lightweight

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Published Papers (2 papers)

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Research

14 pages, 3785 KB  
Article
Topology-Induced Reduction in the Order–Disorder Transition in AB Block Copolymer: A Unit-Matched Comparison of Diblock, Multiblock, Comb, and Star Architectures
by June Huh
Polymers 2026, 18(7), 869; https://doi.org/10.3390/polym18070869 - 1 Apr 2026
Viewed by 443
Abstract
Chain topology offers a chemistry-preserving route to tune block copolymer (BCP) self-assembly by modifying intrachain correlations and relaxation pathways without changing monomer interactions. Here, we perform a unit-matched comparison of four lamella-forming AB architectures reconstructed from an identical constitutive diblock unit ( [...] Read more.
Chain topology offers a chemistry-preserving route to tune block copolymer (BCP) self-assembly by modifying intrachain correlations and relaxation pathways without changing monomer interactions. Here, we perform a unit-matched comparison of four lamella-forming AB architectures reconstructed from an identical constitutive diblock unit (N0): a linear diblock (DB), a linear multiblock (MB), a comb-like architecture (CB), and a star-like architecture (SB). Using dynamical density functional theory (DDFT), we quantify topology-dependent bulk ordering thresholds and show that architectural reconfiguration systematically stabilizes the ordered phase, reducing the order–disorder transition relative to DB (MB/CB/SB 0.793/0.762/0.752 of the diblock value), in semi-quantitative agreement with random phase approximation (RPA) spinodal trends. We also compare topology-dependent directed self-assembly in a common trench geometry under matched reduced quench depth Δ(χN0)=χN0(χN0)ODT, thereby isolating kinetic differences at comparable thermodynamic distance from bulk ordering. A Fourier-based alignment order parameter α(t) reveals sigmoidal alignment kinetics over decades in time and is well captured by a logistic form in lnt, enabling compact descriptors (t50, t90, and a steepness parameter k) that separate alignment onset from late-stage defect annihilation, while selective sidewalls robustly template sidewall-parallel lamellae across all topologies, the late-stage kinetics remain strongly connectivity dependent and can exhibit long-tailed completion associated with slow late-stage defect annihilation. These results demonstrate a dual role of topology in DSA: lowering the segregation strength required for bulk ordering while reshaping defect-mediated alignment pathways under confinement. Full article
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24 pages, 8627 KB  
Article
Machine-Learning-Assisted Viscoelastic Characterization of PC/ABS Blends via Multi-Frequency Dynamic Mechanical Analysis
by Yancai Sun, Wenzhong Deng, Haoran Wang, Ranran Jian, Wenjuan Bai, Dianming Chu, Peiwu Hou and Yan He
Polymers 2026, 18(5), 599; https://doi.org/10.3390/polym18050599 - 28 Feb 2026
Viewed by 366
Abstract
This study combines multi-frequency dynamic mechanical analysis (DMA) with machine learning (ML) to characterize and predict the viscoelastic properties of a commercial polycarbonate/acrylonitrile–butadiene–styrene (PC/ABS) blend. DMA temperature sweeps at four frequencies (1–10 Hz) in single cantilever mode yielded a glass transition range of [...] Read more.
This study combines multi-frequency dynamic mechanical analysis (DMA) with machine learning (ML) to characterize and predict the viscoelastic properties of a commercial polycarbonate/acrylonitrile–butadiene–styrene (PC/ABS) blend. DMA temperature sweeps at four frequencies (1–10 Hz) in single cantilever mode yielded a glass transition range of 115.8–123.2 °C (E peak), frequency sensitivity of 7.18 °C/decade, and an apparent activation energy of 335±85 kJ mol1. Time–temperature superposition master curves were parameterized with a six-term Prony series (R2=0.998). Four data-driven models (RF, XGB, SVR, MLP) and a physics-informed NeuralWLF model were evaluated through a hierarchical validation framework. Temperature-blocked CV ranked MLP (R2¯=0.989) above RF (0.950) for interpolation; LOFO validation revealed that NeuralWLF achieved the best cross-frequency generalization (R2>0.92 for all targets) with interpretable WLF parameters (C112.2, C251.7 °C). A systematic block size sweep (5–30 °C) revealed a validation inflation effect in which MLP tanδR2 dropped from 0.986 to 0.592 as the gap-to-FWHM ratio increased from 0.5 to 3.1, establishing the gap/FWHM ratio as a quantitative validation stringency criterion. A physics–data crossover was identified at gap/FWHM 2: beyond this threshold, NeuralWLF outperformed all data-driven models in tanδ prediction by up to +0.300 in R2, while curriculum learning (freezing the WLF layer for 300 epochs) further improved the most stringent 30 °C validation from R2=0.660 to 0.731. The integrated framework demonstrates that honest evaluation of DMA–ML models requires validation gaps exceeding the characteristic feature width and introduces a quantifiable physics-data crossover criterion for selecting between data-driven and physics-informed architectures. Full article
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