polymers-logo

Journal Browser

Journal Browser

Design, Synthesis and Application of Coordination-Driven Metal-Organic Supramolecular Polymers

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Applications".

Deadline for manuscript submissions: 31 October 2025 | Viewed by 1248

Special Issue Editor


E-Mail Website
Guest Editor
College of Chemistry and Chemical Engineering, Central South University, Changsha, China
Interests: coordination-driven self-assembly; metal–organic supramolecules; functional complexes; complex photocatalysis

Special Issue Information

Dear Colleagues,

Over recent decades, coordination-driven metal–organic supramolecular polymers have been researched extensively for the development of novel topological structures and functional materials. As the core driving force, the coordination bond combines metals and ligands to render well-organized aggregate architectures. This effectively harnesses the coordination configurations and physicochemical properties of metals and ligands, thereby endowing the resulting macromolecules or polymers with diverse appealing spatial structures (from one-dimensional to three-dimensional) and unique functions (optical, electrical, magnetic, catalysis, etc.). Therefore, there is enormous potential for the development of new structures and functions of self-assembled metal–organic supramolecular polymers due to the diversity of metals and ligands. Further research on their rational design (e.g., ligand structure, metal species, polymer architectures), assembly strategy, structural characterization, properties, and application developments are of great significance in promoting the advancement of metal–organic supramolecular polymers.

This Special Issue covers the design and synthesis of metal–organic supramolecular polymers (e.g., discrete macromolecules, 1D metallo-polymers, 2D nanosheets, 3D networks, coordination-driven supramolecular frameworks, metallo-gels, soft matter), their characterization methods (e.g., mass spectrometry, electron microscopy, scanning tunneling microscopy), and their applications (e.g., optical, electrical, magnetic, catalysis). The above list is only indicative and by no means exhaustive; any original work or review article relevant to coordination-driven metal–organic supramolecular polymers is welcome.

Dr. Die Liu
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Polymers is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • supramolecular self-assembly
  • metal-organic polymers
  • organic ligands design
  • coordination-assembled strategy
  • applications of metal-organic polymer

Benefits of Publishing in a Special Issue

  • Ease of navigation: Grouping papers by topic helps scholars navigate broad scope journals more efficiently.
  • Greater discoverability: Special Issues support the reach and impact of scientific research. Articles in Special Issues are more discoverable and cited more frequently.
  • Expansion of research network: Special Issues facilitate connections among authors, fostering scientific collaborations.
  • External promotion: Articles in Special Issues are often promoted through the journal's social media, increasing their visibility.
  • e-Book format: Special Issues with more than 10 articles can be published as dedicated e-books, ensuring wide and rapid dissemination.

Further information on MDPI's Special Issue policies can be found here.

Published Papers (1 paper)

Order results
Result details
Select all
Export citation of selected articles as:

Research

15 pages, 4833 KiB  
Article
Fluorescent Polymers via Coordination of bis-Terpyridine Ligands with Transition Metals and Their pH Response Properties
by Tao Zhang, Fengxue Liu, Yongxin Liu, Kaixiu Li, Zhengguang Li, Yaqin Li, Fan Fu, Mingliang Liu, Yiming Li, Die Liu and Pingshan Wang
Polymers 2025, 17(1), 87; https://doi.org/10.3390/polym17010087 - 31 Dec 2024
Viewed by 914
Abstract
Stimulus-responsive luminescent materials are pivotal in the field of sensing. Fluorescent transition metal complexes with a charge transfer excited state, especially terpyridine-coordinated polymers, are of particular interest due to their tunable emission. In this paper, a novel bis-terpyridine ligand was synthesized and assembled [...] Read more.
Stimulus-responsive luminescent materials are pivotal in the field of sensing. Fluorescent transition metal complexes with a charge transfer excited state, especially terpyridine-coordinated polymers, are of particular interest due to their tunable emission. In this paper, a novel bis-terpyridine ligand was synthesized and assembled into a coordination polymer, which showed intense visible light absorption and fluorescence emission in the solid state that could be regulated by an acidic or basic pH. After being protonated by acid, the fluorescence of the polymer P2 was quenched. The emission of the polymer split from 635 nm to two peaks of 674 and 440 nm, and then stabilized at 728 nm for 7 days, which showed a significant red-shift and good protonation stability. The fluorescence emission wavelength of the protonated polymers recovered after alkalization, and the fluorescence intensity of the polymer was greatly improved after alkalization, showing interesting acid–base-response luminescence characteristics. The sensitive response of the synthesized coordination polymers to acids and bases will contribute to expanding the application of linear coordination polymers in sensing and other fields. Full article
Show Figures

Figure 1

Back to TopTop