Photophysical Processes in Non-fullerene Organic Solar Cells

A special issue of Photonics (ISSN 2304-6732).

Deadline for manuscript submissions: 15 July 2024 | Viewed by 1098

Special Issue Editors

School of Physics and Materials Science, Guangzhou University, Guangzhou 510006, China
Interests: polymer solar cells; nanostructured materials; ultrafast spectroscopy; ultrafast dynamics; carrier recombination
Special Issues, Collections and Topics in MDPI journals
Material Science and Engineering / New Materials Research Institute, Chongqing University of Arts and Science, Chongqing 402171, China
Interests: organic photovoltaic devices; spectroelectrochemistry; time-resolved spectrum; interface engineering; solvent processing; device service life

Special Issue Information

Dear Colleagues,

In the past few years, the development of non-fullerene acceptors represented by Y6 has greatly improved the power conversion efficiency of organic solar cells. At present, the power conversion efficiency of organic solar cells exceeds 19%, showing their broad commercial prospect. On the one hand, the improvement in the photoelectric conversion efficiency of non-fullerene solar cells benefits from the good photon absorption characteristics of non-fullerene materials in the near-infrared region; on the other hand, this is attributed to their unique photophysical properties, which differ from those of fullerene solar cells. For example, the exciton diffusion length of the newly emerging Y acceptors can exceed 50 nm, which is much longer than that of traditional acceptors and conducive to exciton dissociation in non-fullerene solar cells. In addition, the low driving force and better device stability in non-fullerene organic solar cells enables non-fullerene solar cells to be exploited for their advantages in practical applications. However, the physical processes underlying these issues need to be further clarified. In this Special Issue, we aim to discuss various topics related to the photophysical mechanism in non-fullerene solar cells, including advances in device physics and photoelectric conversion dynamics.

Both original research articles and reviews are welcome for this Special Issue. We look forward to receiving your contributions.

Dr. Wei Zhang
Dr. Rong Hu
Guest Editors

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Keywords

  • polymer solar cell
  • organics solar cell
  • charge photogeneration
  • carrier recombination
  • exciton diffusion
  • non-fullerene acceptors
  • all polymer solar cells

Published Papers (1 paper)

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Research

12 pages, 3828 KiB  
Article
Effects of Acceptors on the Charge Photogeneration Dynamics of PM6-Based Solar Cells
by Rong Hu, Liping Zhou, Yurong Liu, Zekai Cai, Guanzhao Wen and Wei Zhang
Photonics 2023, 10(9), 989; https://doi.org/10.3390/photonics10090989 - 30 Aug 2023
Viewed by 841
Abstract
In this work, we investigated the effects of different acceptors (IT−4F and PC71BM) on the charge dynamics in PM6-based solar cells. The correlation between different acceptors and the performance of organic solar cells was studied by atomic force microscope, steady-state absorption [...] Read more.
In this work, we investigated the effects of different acceptors (IT−4F and PC71BM) on the charge dynamics in PM6-based solar cells. The correlation between different acceptors and the performance of organic solar cells was studied by atomic force microscope, steady-state absorption spectrum, transient absorption spectrum, and electrical measurements. Optical absorption exhibited that IT−4F has strong absorption in the near-infrared region for the active layer. Transient absorption measurements showed that different acceptors (IT−4F and PC71BM) had a significant influence on the behaviors of PM6 excitons and charge dynamics. That is, the exciton dissociation rate and delocalized polaron transport in the PM6:IT−4F active layer were significantly faster than that in the PM6:PC71BM active layer. The lifetime of localized polaron in the PM6:PC71BM active layer was longer than that in the PM6:IT−4F active layer. Conversely, the lifetime of delocalized polaron in the PM6:IT−4F active layer was longer than that in the PM6:PC71BM active layer. Electrical measurement analysis indicated that lower bimolecular recombination, higher charge transport, and charge collection ability were shown in the PM6:IT−4F device compared with the PM6:PC71BM device. Therefore, PM6:IT−4F solar cells achieved a higher power conversion efficiency (12.82%) than PM6:PC71BM solar cells (8.78%). Full article
(This article belongs to the Special Issue Photophysical Processes in Non-fullerene Organic Solar Cells)
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