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Pigments in Wall Painting: An Archaeometric Study

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Cross-Field Chemistry".

Deadline for manuscript submissions: closed (30 June 2022) | Viewed by 2044

Special Issue Editor


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Guest Editor
Department of Organic Chemistry, University Institute for Research in Fine Chemistry and Nanochemistry, University of Cordoba, 14071 Cordoba, Spain
Interests: Raman spectroscopy; wall painting; pigments; microscopy; organic binders

Special Issue Information

Dear Colleagues,

Identifying the pigments used in a wall painting is of doubtless interest as it allows the painting to be associated to a specific historical period. In addition, it can be useful to improve existing knowledge about social tastes and styles at a given placed and time and about the social and economic context where the painting was created. Identifying pigments requires using instrumental techniques of analysis. Some such techniques have experienced dramatic developments over the past two decades and enabled the identification at the molecular level of pigments used in different historical times. Especially prominent among such instrumental techniques are Fourier transform infrared (FTIR), X-ray fluorescence (XRF) and Raman spectroscopies, and also scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM-EDS) and X-ray diffraction (XRD). Some identification techniques involve solvent extraction and derivatization of compounds whose subsequent analysis by gas or liquid chromatography is useful to identify pigment binders. Often, the previous instrumental techniques are additionally useful with a view to developing effective strategies for conserving and restoring wall paintings.

Prof. Dr. José R. Ruiz
Guest Editor

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Keywords

  • wall painting
  • pigments
  • archaeometry
  • spectroscopic techniques
  • SEM-EDS

Published Papers (1 paper)

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Research

14 pages, 7236 KiB  
Article
Characterization of Wall Paintings of the Harem Court in the Alhambra Monumental Ensemble: Advantages and Limitations of In Situ Analysis
by Paz Arjonilla, Ana Domínguez-Vidal, Ramón Rubio Domene, Elena Correa Gómez, María José de la Torre-López and María José Ayora-Cañada
Molecules 2022, 27(5), 1490; https://doi.org/10.3390/molecules27051490 - 23 Feb 2022
Cited by 6 | Viewed by 1664
Abstract
Non-invasive techniques (X-ray fluorescence, XRF, and Raman spectroscopy) were used for the study of the Hispano Muslim wall paintings. Principal component analysis (PCA) was performed on the semi-quantitative XRF results directly provided by the in-built factory calibrations with minimum user manipulation. The results [...] Read more.
Non-invasive techniques (X-ray fluorescence, XRF, and Raman spectroscopy) were used for the study of the Hispano Muslim wall paintings. Principal component analysis (PCA) was performed on the semi-quantitative XRF results directly provided by the in-built factory calibrations with minimum user manipulation. The results obtained were satisfactory and highlighted differences and similarities among the measurement points. In this way, it was possible to differentiate the decorations carried out on gypsum plasterwork and the wall paintings over lime plaster. The color palette, revealed by combining the results from XRF and Raman spectroscopies, comprised the pigments hematite, lapis lazuli, cinnabar (in poor conservation state), and possibly, carbon. Evidence of past interventions was also provided by PCA on XRF data, which detected the presence of Pb, Ba, and Zn in some areas. Furthermore, the preparation layers have been studied in detail on cross-sections of two microsamples. Several layers of lime plaster with a compact microstructure have been observed. The characteristic of the pictorial layer and the identification of calcium oxalate point to the use of a secco-technique. The main alteration identified was a gypsum surface layer covering the painting and signs of plaster deterioration due to gypsum migration to more internal areas. Finally, the comparison with the observations made by restorers in previous interventions on these paintings revealed the importance of the representativeness gained with the in situ study, which enabled the analysis of a high number of areas. Full article
(This article belongs to the Special Issue Pigments in Wall Painting: An Archaeometric Study)
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