Raman Spectroscopy Characterization of Fossil Organic Matter, Char and Graphite

A special issue of Minerals (ISSN 2075-163X). This special issue belongs to the section "Crystallography and Physical Chemistry of Minerals & Nanominerals".

Deadline for manuscript submissions: closed (16 December 2022) | Viewed by 2472

Special Issue Editors


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Departamento de Geociências, Ambiente e Ordenamento do Território, Faculdade de Ciências, Universidade do Porto and Instituto de Ciências da Terra, 4169-007 Porto, Portugal
Interests: mineral analytical techniques; mineralogy of fly ash and bottom ash; ore deposits
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Guest Editor
Departamento de Geociências, Ambiente e Ordenamento do Território, Faculdade de Ciências, Universidade do Porto and Instituto de Ciências da Terra, 4169-007 Porto, Portugal
Interests: organic petrology; ashes; spent LIB; circularity
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Department of Geology and Geophysics, University of Aberdeen, Aberdeen, 8AB243UE, UK
Interests: basin analysis; dispersed organic matter; Raman spectroscopy; clay mineralogy
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Different types of fossil organic matter and carbonaceous products from gasification, pyrolysis and combustion processes of fossil and organic biomass, as well as natural and synthetic graphite and amorphous carbon, display Raman spectral features that allow us to obtain structural information of these materials. This Special Issue aims to present investigations in relation to the application of the Raman spectroscopy analysis of these carbonaceous materials either occurring in rocks of different geological contexts, or as industry products or by-products of other processes (e.g., char from coal combustion and gasification, among others).

We invite researchers to contribute to the Special Issue: “Raman Spectroscopy Characterization of Fossil Organic Matter, Char and Graphite”.

Dr. Alexandra Guedes
Dr. Bruno Valentim
Dr. Andrea Schito
Guest Editors

Manuscript Submission Information

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Keywords

  • coal
  • dispersed organic matter
  • carbonaceous matter
  • carbon
  • char biomass

Published Papers (1 paper)

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Research

19 pages, 2125 KiB  
Article
Calibrating Carbonization Temperatures of Wood Fragments Embedded within Pyroclastic Density Currents through Raman Spectroscopy
by Andrea Schito, Alessandra Pensa, Claudia Romano, Sveva Corrado, Alessandro Vona, Matteo Trolese, Daniele Morgavi and Guido Giordano
Minerals 2022, 12(2), 203; https://doi.org/10.3390/min12020203 - 5 Feb 2022
Cited by 5 | Viewed by 1754
Abstract
The study of the structural order of charcoals embedded in pyroclastic density currents provides information on their emplacement temperature during volcanic eruptions. In the present work, a set of charcoals from three distinct pyroclastic density currents deposits whose temperatures have been previously estimated [...] Read more.
The study of the structural order of charcoals embedded in pyroclastic density currents provides information on their emplacement temperature during volcanic eruptions. In the present work, a set of charcoals from three distinct pyroclastic density currents deposits whose temperatures have been previously estimated by charcoal reflectance analyses to lie between 250 °C and 550 °C, was studied by means of Raman spectroscopy. The analyses reveal a very disordered structural ordering of the charcoals, similar to kerogen matured under diagenetic conditions. Changes in Raman spectra at increasing temperatures reflect depolymerization and an increase of aromaticity and can be expressed by parameters derived from a simplified fitting method. Based on this approach, a second order polynomial regression with a high degree of correlation and a minimum error was derived to predict paleotemperatures of pyroclastic deposits. Our results show that Raman spectroscopy can provide a reliable and powerful tool for volcanological studies and volcanic hazard assessment given its advantage of minimum samples preparation, rapid acquisition processes and high precision. Full article
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