materials-logo

Journal Browser

Journal Browser

Organic Materials and Hybrid Metal-Organic Materials

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Materials Chemistry".

Deadline for manuscript submissions: closed (31 December 2021) | Viewed by 8260

Special Issue Editor


E-Mail Website
Guest Editor
Politecnico di Milano, Italy.
Interests: solid-state chemistry, hybrid metal organic materials, metal organic frameworks, Dynamic behavior

Special Issue Information

Dear Colleagues,

It is our pleasure to invite you to publish your work in this Special Issue of Materials entitled “Organic Materials and Hybrid Metal-Organic Materials" as an original article or review. The Issue will focus on the solid-state chemistry and functional applications of organic and hybrid metal organic materials. In this Special Issue, solid-state reactivity in organic materials such as hydrogen-bonded/halogen-bonded solids and covalent organic frameworks (COFs)) is of interest. Solid-state reactions in hybrid metal organic materials should concern solids that by means of coordination bonds form discrete or polymeric structures, as in metal organic frameworks (MOFs)/coordination polymers (CPs) but also metal organic materials obtained via second sphere interactions between metal centers and organic molecules.

The aim of this Special Issue is to gather articles correlating solid-state reactivity and structure–function properties of new functional materials generated by external stimuli. Topics of interest include but are not limited to the following:

i) Solid-state reactions induced by temperature, pressure, light, or incoming molecules (i.e., guest reactivity, gas adsorption, and separation);

ii) Dynamic behavior of porous materials involving single-crystal-to-single-crystal transformations;

iii) Crystalline-to-amorphous-to-crystalline (CAC) reactions;

iv) Nonporous materials that adapt to external stimuli by adsorption or chemisorption of guest molecules;

v) Mechanochemically induced solid-state reactions not accessible by conventional solution chemistry;

vi) Cleavage and formation of chemical bonds in the solid state.

Prof. Javier Marti-Rujas
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • solid-state reactivity
  • single-crystal-to-single-crystal
  • dynamic amorphous phases
  • MOFs/CPs
  • mechanochemistry
  • crystal-to-polycrystal reactions
  • X-ray crystallography

Published Papers (1 paper)

Order results
Result details
Select all
Export citation of selected articles as:

Review

26 pages, 7282 KiB  
Review
Thermal Reactivity in Metal Organic Materials (MOMs): From Single-Crystal-to-Single-Crystal Reactions and Beyond
by Javier Martí-Rujas
Materials 2019, 12(24), 4088; https://doi.org/10.3390/ma12244088 - 07 Dec 2019
Cited by 12 | Viewed by 5762
Abstract
Thermal treatment is important in the solid-state chemistry of metal organic materials (MOMs) because it can create unexpected new structures with unique properties and applications that otherwise in the solution state are very difficult or impossible to achieve. Additionally, high-temperature solid-state reactivity provide [...] Read more.
Thermal treatment is important in the solid-state chemistry of metal organic materials (MOMs) because it can create unexpected new structures with unique properties and applications that otherwise in the solution state are very difficult or impossible to achieve. Additionally, high-temperature solid-state reactivity provide insights to better understand chemical processes taking place in the solid-state. This review article describes relevant thermally induced solid-state reactions in metal organic materials, which include metal organic frameworks (MOFs)/coordination polymers (CPs), and second coordination sphere adducts (SSCs). High temperature solid-state reactivity can occur in a single-crystal-to-single crystal manner (SCSC) usually for cases where there is small atomic motion, allowing full structural characterization by single crystal X-ray diffraction (SC-XRD) analysis. However, for the cases in which the structural transformations are severe, often the crystallinity of the metal-organic material is damaged, and this happens in a crystal-to-polycrystalline manner. For such cases, in the absence of suitable single crystals, structural characterization has to be carried out using ab initio powder X-ray diffraction analysis or pair distribution function (PDF) analysis when the product is amorphous. In this article, relevant thermally induced SCSC reactions and crystal-to-polycrystalline reactions in MOMs that involve significant structural transformations as a result of the molecular/atomic motion are described. Thermal reactivity focusing on cleavage and formation of coordination and covalent bonds, crystalline-to-amorphous-to-crystalline transformations, host–guest behavior and dehydrochlorination reactions in MOFs and SSCs will be discussed. Full article
(This article belongs to the Special Issue Organic Materials and Hybrid Metal-Organic Materials)
Show Figures

Graphical abstract

Back to TopTop