materials-logo

Journal Browser

Journal Browser

Electrode Materials for Advanced Photo-Supercapacitors

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Energy Materials".

Deadline for manuscript submissions: closed (30 June 2021) | Viewed by 3656

Special Issue Editors


E-Mail Website
Guest Editor
Gdańsk University of Technology, Gdansk, Poland
Interests: photoelectrochemistry; electrochemistry; nanomaterials; supercapacitors

E-Mail Website
Guest Editor
Gdańsk University of Technology, Gdansk, Poland
Interests: thin films; photoelectrochemical water splitting; materials for energy storage

Special Issue Information

Dear Colleagues,

The rapid growth of the population all over the world has caused an increase in global energy consumption, and the utilization of fossil fuels has led to changes in the Earth’s climate due to increased emissions of greenhouse gases. Thus, we are forced to produce systems that are designed for energy conversion and storage on a larger scale. Nowadays, batteries and supercapacitors are the essential energy storage devices that can be used in breakthrough electronic appliances. On the other hand, an alternative for depleting fossil fuels is renewable energy sources (RES). By definition, they are renewable sources—that means for us, inexhaustible. Their impact on environmental pollution is extremely reduced. Almost everything in this world ultimately derives its energy from the sun. Instead of obtaining the sun’s energy from indirect sources, researchers and worldwide organizations are looking to directly tap this unlimited source of energy. This has encouraged the development of photovoltaic (PV) devices, as prime energy production devices using the sun’s energy; however, they require separate systems for efficient storage of excess energy. The idea of coupling photoactive materials and supercapacitors as a complete energy conversion and storage device arose because the solar energy converted by photoactive materials can be efficiently transferred and stored as electrical energy by adopting supercapacitor electrodes in one device. The conversion and storage efficiency of a photo-supercapacitor is dependent on its photoactive material as well as the electrode material for the supercapacitor. A photo-supercapacitor (PSC) is a hybrid device, in which, during charging, photogenerated charge is transferred to the counter electrode and, in contrast to the photoelectrochemical cell, is not utilized for chemical reaction but is stored on the supercapacitor electrode. This device, when not exposed to sunlight, may release its accumulated energy while discharging the supercapacitor.

Thus, original research articles, review articles, and significant preliminary communications are invited, with a particular interest in articles describing photo-supercapacitors as a whole device or supercapacitors and photoactive electrode materials separately.

Dr. Mariusz Szkoda
Dr. Konrad Trzciński
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • photo-supercapacitors
  • supercapacitors
  • energy conversion and storage
  • photoactive electrode materials

Published Papers (1 paper)

Order results
Result details
Select all
Export citation of selected articles as:

Research

20 pages, 5435 KiB  
Article
Improving the Performance of a Graphite Foil/Polyaniline Electrode Material by a Thin PEDOT:PSS Layer for Application in Flexible, High Power Supercapacitors
by Zuzanna Zarach, Konrad Trzciński, Marcin Łapiński, Anna Lisowska-Oleksiak and Mariusz Szkoda
Materials 2020, 13(24), 5791; https://doi.org/10.3390/ma13245791 - 18 Dec 2020
Cited by 12 | Viewed by 3186
Abstract
In this study, we present a novel strategy for enhancing polyaniline stability and thus obtaining an electrode material with practical application in supercapacitors. A promising (graphite foil/polyaniline/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) GF/PANI/PEDOT:PSS) electrode material was characterized and used in the construction of a symmetric supercapacitor that provides [...] Read more.
In this study, we present a novel strategy for enhancing polyaniline stability and thus obtaining an electrode material with practical application in supercapacitors. A promising (graphite foil/polyaniline/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) GF/PANI/PEDOT:PSS) electrode material was characterized and used in the construction of a symmetric supercapacitor that provides an outstanding high power density. For this purpose, the electropolymerization of PANI was carried out on a graphite foil and then a thin protective layer of PEDOT:PSS was deposited. The presence of the nanometer PEDOT:PSS layer made it possible to widen the electroactivity potential range of the electrode material. Moreover, the synergy between materials positively affected the amount of accumulated charge, and thus the thin PEDOT:PSS layer contributed to enhancing the specific capacity of the electrode material. The electrochemical performance of the GF/PANI/PEDOT:PSS electrode, as well as the symmetrical supercapacitor, was investigated by cyclic voltammetry and galvanostatic charge/discharge cycles in 1 M H2SO4 at room temperature. The fabricated electrode material shows a high specific capacitance (Csp) of 557.4 Fg−1 and areal capacitance (Careal) of 2600 mF·cm−2 in 1 M H2SO4 at a current density of 200 mA·cm−2 (~4 A·g−1). The supercapacitor performance was studied and the results show that a thin PEDOT:PSS layer enables cycling stability improvement of the device from 54% to 67% after 10,000 cycles, and provides a high specific capacity (159.8 F·g−1) and a maximum specific power (18,043 W·kg−1) for practical applications. Full article
(This article belongs to the Special Issue Electrode Materials for Advanced Photo-Supercapacitors)
Show Figures

Graphical abstract

Back to TopTop