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Multifunctional Nanomaterials: Synthesis, Properties, and Applications 3.0
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Multifunctional Nanomaterials: Synthesis, Properties, and Applications 3.0

A special issue of International Journal of Molecular Sciences (ISSN 1422-0067). This special issue belongs to the section "Molecular Nanoscience".

Deadline for manuscript submissions: closed (20 June 2024) | Viewed by 13753

Special Issue Editor

Dr. Raghvendra Singh Yadav

E-Mail Website
Guest Editor
Centre of Polymer Systems, Tomas Bata University in Zlin, Trida Tomase Bati 5678, 76001 Zlin, Czech Republic
Interests: magnetic materials; dielectric materials; electrical properties; luminescent nanomaterials; micro-wave absorbing materials; ceramics; materials chemistry; soft matter; nanostructured materials; materials for energy; semiconductor materials; nano-bio composite materials; metals and alloys; nanocomposites; functional materials; optical materials; graphene; polymer nanocomposites; graphene nanocomposites; graphene quantum dots; nanoparticles; structural properties; magnetic properties; dielectric properties; magnetically recoverable efficient photo-catalysts; data storage; gas sensing; magnetoresistance; other physical properties; synthesis; characterization; hyperthermia cancer treatment; drug delivery; magnetic resonance imaging (MRI) contrast agents; magnetic refrigeration (MR); spintronic devices; ferro-fluids; anode materials for Li-ion batteries; microwave devices; water splitting for hydrogen production; paint industry; super-capacitors; elect
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Special Issue Information

Dear Colleagues,

Multifunctional nanomaterials consist of smart nanoparticles with two or more engineered properties/characteristics. These multifunctional nanomaterials exhibit remarkable structural and physical properties, which have led to an increase in their industrial applications. In addition, biomolecules can be functionalized on the surface of nanoparticles for their potential applications in the biomedical field.

This Special Issue focuses on the development, characterization, and analysis of advanced multifunctional nanomaterials for various applications, including photocatalysts, anode materials for Li-ion batteries, supercapacitors, solar cells, photovoltaics, data storage, gas sensing, chemical sensors, biosensors, magnetoresistance, hyperthermia cancer treatment, drug delivery, magnetic resonance imaging (MRI) contrast agents, magnetic refrigeration (MR), spintronic devices, ferrofluids, microwave devices, water splitting for hydrogen production, the paint industry, electromagnetic interference shielding or microwave absorbers, etc. 

For this Special Issue, we would like to invite researchers to contribute original research articles as well as review articles on ‘‘Multifunctional Nanomaterials’’ focusing on synthesis, properties, and applications.

Dr. Raghvendra Singh Yadav
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. International Journal of Molecular Sciences is an international peer-reviewed open access semimonthly journal published by MDPI.

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Keywords

  • photocatalysis
  • anode materials for Li-ion batteries
  • photovoltaics
  • sensors
  • biomedical applications
  • environmental applications
  • energy storage applications
  • energy harvesting applications
  • biomolecules functionalized on the surface of nanoparticles

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Published Papers (5 papers)

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Research

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14 pages, 5739 KiB  
Article
Bifunctional Silica-Supported Ionic Liquid Phase (SILP) Catalysts in Silane Production: Their Synthesis, Characterization and Catalytic Activity
by Nataliia V. Abarbanel, Sergey S. Suvorov, Anton N. Petukhov, Artem S. Belousov, Artem N. Markov, Dmitriy M. Zarubin, Alexandra V. Barysheva, Ilya V. Vorotyntsev, Alexander A. Kapinos, Artem D. Kulikov and Andrey V. Vorotyntsev
Int. J. Mol. Sci. 2024, 25(1), 68; https://doi.org/10.3390/ijms25010068 - 20 Dec 2023
Cited by 1 | Viewed by 1702
Abstract
A mesoporous silica support was synthesized using the sol–gel method from trichlorosilane. There is a tendency for the specific surface area and the proportion of silica particles mesopores to increase during all stages of sol–gel synthesis. It has been shown that the insertion [...] Read more.
A mesoporous silica support was synthesized using the sol–gel method from trichlorosilane. There is a tendency for the specific surface area and the proportion of silica particles mesopores to increase during all stages of sol–gel synthesis. It has been shown that the insertion of hexane and toluene, as additional solvents, into the structure-forming polyethylene glycol, makes it possible to regulate the pore size and specific surface area of silica. Silica functionalization was carried out using SILP technology. The activities of the catalytic systems based on polymer and inorganic supports immobilized by imidazole-based ionic liquids during the trichlorosilane disproportionation reaction were compared. There is a tendency for the monosilane yield for catalytic systems based on an inorganic support to increase. We identified the most promising catalyst in terms of monosilane yield and proposed a bifunctional catalyst that exhibited activity in two parallel reactions: trichlorosilane disproportionation and silicon tetrachloride hydrogenation. Full article
(This article belongs to the Special Issue Multifunctional Nanomaterials: Synthesis, Properties, and Applications 3.0)
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15 pages, 9888 KiB  
Article
Hierarchical Ni-Mn LDHs@CuC2O4 Nanosheet Arrays-Modified Copper Mesh: A Dual-Functional Material for Enhancing Oil/Water Separation and Supercapacitors
by Yue Wu, Guangyuan Lu, Ping Xu, Tian C. Zhang, Huaqiang He and Shaojun Yuan
Int. J. Mol. Sci. 2023, 24(18), 14085; https://doi.org/10.3390/ijms241814085 - 14 Sep 2023
Cited by 1 | Viewed by 1814
Abstract
The pursuit of superhydrophilic materials with hierarchical structures has garnered significant attention across diverse application domains. In this study, we have successfully crafted Ni-Mn LDHs@CuC2O4 nanosheet arrays on a copper mesh (CM) through a synergistic process involving chemical oxidation and [...] Read more.
The pursuit of superhydrophilic materials with hierarchical structures has garnered significant attention across diverse application domains. In this study, we have successfully crafted Ni-Mn LDHs@CuC2O4 nanosheet arrays on a copper mesh (CM) through a synergistic process involving chemical oxidation and hydrothermal deposition. Initially, CuC2O4 nanosheets were synthesized on the copper mesh, closely followed by the growth of Ni-Mn LDHs nanosheets, culminating in the establishment of a multi-tiered surface architecture with exceptional superhydrophilicity and remarkable underwater superoleophobicity. The resultant Ni-Mn LDHs@CuC2O4 CM membrane showcased an unparalleled amalgamation of traits, including superhydrophilicity, underwater superoleophobicity, and the ability to harness photocatalytic forces for self-cleaning actions, making it an advanced oil-water separation membrane. The membrane’s performance was impressive, manifesting in a remarkable water flux range (70 kL·m−2·h−1) and an efficient oil separation capability for both oil/water mixture and surfactant-stabilized emulsions (below 60 ppm). Moreover, the innate superhydrophilic characteristics of the membrane rendered it a prime candidate for deployment as a supercapacitor cathode material. Evidenced by a capacitance of 5080 mF·cm−2 at a current density of 6 mA cm−2 in a 6 M KOH electrolyte, the membrane’s potential extended beyond oil-water separation. This work not only introduces a cutting-edge oil-water separation membrane and supercapacitor electrode but also offers a promising blueprint for the deliberate engineering of hierarchical structure arrays to cater to a spectrum of related applications. Full article
(This article belongs to the Special Issue Multifunctional Nanomaterials: Synthesis, Properties, and Applications 3.0)
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Review

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20 pages, 3106 KiB  
Review
Convergence of Nanotechnology and Machine Learning: The State of the Art, Challenges, and Perspectives
by Arnav Tripathy, Akshata Y. Patne, Subhra Mohapatra and Shyam S. Mohapatra
Int. J. Mol. Sci. 2024, 25(22), 12368; https://doi.org/10.3390/ijms252212368 - 18 Nov 2024
Cited by 2 | Viewed by 4003
Abstract
Nanotechnology and machine learning (ML) are rapidly emerging fields with numerous real-world applications in medicine, materials science, computer engineering, and data processing. ML enhances nanotechnology by facilitating the processing of dataset in nanomaterial synthesis, characterization, and optimization of nanoscale properties. Conversely, nanotechnology improves [...] Read more.
Nanotechnology and machine learning (ML) are rapidly emerging fields with numerous real-world applications in medicine, materials science, computer engineering, and data processing. ML enhances nanotechnology by facilitating the processing of dataset in nanomaterial synthesis, characterization, and optimization of nanoscale properties. Conversely, nanotechnology improves the speed and efficiency of computing power, which is crucial for ML algorithms. Although the capabilities of nanotechnology and ML are still in their infancy, a review of the research literature provides insights into the exciting frontiers of these fields and suggests that their integration can be transformative. Future research directions include developing tools for manipulating nanomaterials and ensuring ethical and unbiased data collection for ML models. This review emphasizes the importance of the coevolution of these technologies and their mutual reinforcement to advance scientific and societal goals. Full article
(This article belongs to the Special Issue Multifunctional Nanomaterials: Synthesis, Properties, and Applications 3.0)
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56 pages, 72921 KiB  
Review
The Latest Advances in Ink-Based Nanogenerators: From Materials to Applications
by Bingqian Shao, Zhitao Chen, Hengzhe Su, Shuzhe Peng and Mingxin Song
Int. J. Mol. Sci. 2024, 25(11), 6152; https://doi.org/10.3390/ijms25116152 - 3 Jun 2024
Cited by 3 | Viewed by 1791
Abstract
Nanogenerators possess the capability to harvest faint energy from the environment. Among them, thermoelectric (TE), triboelectric, piezoelectric (PE), and moisture-enabled nanogenerators represent promising approaches to micro–nano energy collection. These nanogenerators have seen considerable progress in material optimization and structural design. Printing technology has [...] Read more.
Nanogenerators possess the capability to harvest faint energy from the environment. Among them, thermoelectric (TE), triboelectric, piezoelectric (PE), and moisture-enabled nanogenerators represent promising approaches to micro–nano energy collection. These nanogenerators have seen considerable progress in material optimization and structural design. Printing technology has facilitated the large-scale manufacturing of nanogenerators. Although inks can be compatible with most traditional functional materials, this inevitably leads to a decrease in the electrical performance of the materials, necessitating control over the rheological properties of the inks. Furthermore, printing technology offers increased structural design flexibility. This review provides a comprehensive framework for ink-based nanogenerators, encompassing ink material optimization and device structural design, including improvements in ink performance, control of rheological properties, and efficient energy harvesting structures. Additionally, it highlights ink-based nanogenerators that incorporate textile technology and hybrid energy technologies, reviewing their latest advancements in energy collection and self-powered sensing. The discussion also addresses the main challenges faced and future directions for development. Full article
(This article belongs to the Special Issue Multifunctional Nanomaterials: Synthesis, Properties, and Applications 3.0)
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19 pages, 2131 KiB  
Review
Phototoxic or Photoprotective?—Advances and Limitations of Titanium (IV) Oxide in Dermal Formulations—A Review
by Michał Gackowski, Tomasz Osmałek, Anna Froelich, Filip Otto, Raphaël Schneider and Janina Lulek
Int. J. Mol. Sci. 2023, 24(9), 8159; https://doi.org/10.3390/ijms24098159 - 2 May 2023
Cited by 7 | Viewed by 3606
Abstract
The widespread role of titanium (IV) oxide (TiO2) in many industries makes this substance of broad scientific interest. TiO2 can act as both a photoprotector and photocatalyst, and the potential for its role in both applications increases when present in [...] Read more.
The widespread role of titanium (IV) oxide (TiO2) in many industries makes this substance of broad scientific interest. TiO2 can act as both a photoprotector and photocatalyst, and the potential for its role in both applications increases when present in nanometer-sized crystals. Its sunlight-scattering properties are used extensively in sunscreens. Furthermore, attempts have been made to incorporate TiO2 into dermal formulations of photolabile drugs. However, the propensity to generate reactive oxygen species (ROS) rendering this material potentially cytotoxic limits its role. Therefore, modifications of TiO2 nanoparticles (e.g., its polymorphic form, size, shape, and surface modifications) are used in an effort to reduce its photocatalytic effects. This review provides an overview of the potential risks arising from and opportunities presented by the use of TiO2 in skin care formulations. Full article
(This article belongs to the Special Issue Multifunctional Nanomaterials: Synthesis, Properties, and Applications 3.0)
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