Nanoindentation in Wood

A special issue of Forests (ISSN 1999-4907). This special issue belongs to the section "Wood Science and Forest Products".

Deadline for manuscript submissions: closed (25 June 2021) | Viewed by 5753

Special Issue Editor


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Guest Editor
Forest Biopolymers Science and Engineering, USDA Forest Service, Forest Products Laboratory, One Gifford Pinchot Drive, Madison, WI 53726, USA
Interests: wood cell wall mechanical properties; diffusion in wood cell walls; swelling of wood cell walls; wood cell wall structure-property relationships; nanoindentation; X-ray fluorescence microscopy; X-ray absorption spectroscopy

Special Issue Information

Dear Colleagues,

Over the past 25 years, nanoindentation has become a valuable tool in wood science and engineering research. Nanoindentation is a type of instrumented indentation experiment used most often to measure mechanical properties, such as hardness and elastic modulus. An advantage of nanoindentation over other mechanical testing techniques is its ability to probe small, often submicron, volumes of materials. This makes nanoindentation ideally suited to probe the properties of individual wood cell wall layers, as well as other micron-scale features in wood-based materials, such as wood-adhesive bondlines and wood coatings. Nanoindentation is also capable of assessing changes in properties associated with changes in moisture and temperature. Indeed, about 200 research papers have been published on the topic of nanoindentation in wood. These papers provide valuable information over a wide range of research areas, including fundamental cell wall properties, wood adhesives, wood composites, nanocellulose, biodegradation, modified wood, biogenesis, pulp and paper, and others.

Despite the wide range of valuable information already gained from nanoindentation studies in wood, numerous challenges remain. For example, many of the nanoindentation methods applied to wood have their origin in inorganic materials research studying bulk or thin film specimens. These methods likely have limitations when applied to wood, which is a cellular polymeric material with time-, temperature-, and moisture-dependent properties. Another particular challenge is making useful comparisons between different research studies because they often employ different nanoindentation protocols that make direct comparisons difficult, if not impossible.

This Special Issue of Forests aims to bring together a collection of papers spanning the past, present, and future of nanoindentation in wood and similar lignocellulosic materials. Review papers are sought that summarize and critically analyze nanoindentation results in specific wood science research areas. Articles with current original nanoindentation research are also welcome. In particular, papers that include perspectives about future nanoindentation directions and best practices in wood are especially desired.

Dr. Joseph E. Jakes
Guest Editor

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Keywords

  • nanoindentation
  • wood
  • hardness
  • elastic modulus
  • moisture
  • temperature
  • adhesives
  • cell wall
  • mechanical properties

Published Papers (2 papers)

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14 pages, 4594 KiB  
Article
Temperature-Dependent Creep Behavior and Quasi-Static Mechanical Properties of Heat-Treated Wood
by Dong Xing, Xinzhou Wang and Siqun Wang
Forests 2021, 12(8), 968; https://doi.org/10.3390/f12080968 - 22 Jul 2021
Cited by 8 | Viewed by 1967
Abstract
In this paper, Berkovich depth-sensing indentation has been used to study the effects of the temperature-dependent quasi-static mechanical properties and creep deformation of heat-treated wood at temperatures from 20 °C to 180 °C. The characteristics of the load–depth curve, creep strain rate, creep [...] Read more.
In this paper, Berkovich depth-sensing indentation has been used to study the effects of the temperature-dependent quasi-static mechanical properties and creep deformation of heat-treated wood at temperatures from 20 °C to 180 °C. The characteristics of the load–depth curve, creep strain rate, creep compliance, and creep stress exponent of heat-treated wood are evaluated. The results showed that high temperature heat treatment improved the hardness of wood cell walls and reduced the creep rate of wood cell walls. This is mainly due to the improvement of the crystallinity of the cellulose, and the recondensation and crosslinking reaction of the lignocellulose structure. The Burgers model is well fitted to study the creep behavior of heat-treated wood cell walls under different temperatures. Full article
(This article belongs to the Special Issue Nanoindentation in Wood)
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41 pages, 18727 KiB  
Perspective
Best Practices for Quasistatic Berkovich Nanoindentation of Wood Cell Walls
by Joseph E. Jakes and Donald S. Stone
Forests 2021, 12(12), 1696; https://doi.org/10.3390/f12121696 - 3 Dec 2021
Cited by 14 | Viewed by 3241
Abstract
For wood and forest products to reach their full potential as structural materials, experimental techniques are needed to measure mechanical properties across all length scales. Nanoindentation is uniquely suited to probe in situ mechanical properties of micrometer-scale features in forest products, such as [...] Read more.
For wood and forest products to reach their full potential as structural materials, experimental techniques are needed to measure mechanical properties across all length scales. Nanoindentation is uniquely suited to probe in situ mechanical properties of micrometer-scale features in forest products, such as individual wood cell wall layers and adhesive bondlines. However, wood science researchers most commonly employ traditional nanoindentation methods that were originally developed for testing hard, inorganic materials, such as metals and ceramics. These traditional methods assume that the tested specimen is rigidly supported, homogeneous, and semi-infinite. Large systematic errors may affect the results when these traditional methods are used to test complex polymeric materials, such as wood cell walls. Wood cell walls have a small, finite size, and nanoindentations can be affected by nearby edges. Wood cell walls are also not rigidly supported, and the cellular structure can flex under loading. Additionally, wood cell walls are softer and more prone to surface detection errors than harder inorganic materials. In this paper, nanoindentation methods for performing quasistatic Berkovich nanoindentations, the most commonly applied nanoindentation technique in forest products research, are presented specifically for making more accurate nanoindentation measurements in materials such as wood cell walls. The improved protocols employ multiload nanoindentations and an analysis algorithm to correct and detect errors associated with surface detection errors and structural compliances arising from edges and specimen-scale flexing. The algorithm also diagnoses other potential issues arising from dirty probes, nanoindenter performance or calibration issues, and displacement drift. The efficacy of the methods was demonstrated using nanoindentations in loblolly pine (Pinus taeda) S2 cell wall layers (S2) and compound corner middle lamellae (CCML). The nanoindentations spanned a large range of sizes. The results also provide new guidelines about the minimum size of nanoindentations needed to make reliable nanoindentation measurements in S2 and CCML. Full article
(This article belongs to the Special Issue Nanoindentation in Wood)
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