Molecular (Super) Conductors

A special issue of Crystals (ISSN 2073-4352). This special issue belongs to the section "Organic Crystalline Materials".

Deadline for manuscript submissions: closed (30 June 2021) | Viewed by 2198

Special Issue Editor


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Guest Editor
Laboratoire de Physique des Solides, Université Paris-Saclay, CNRS,UMR 8502, 91405 Orsay, France
Interests: molecular conductors; superconductivity; low dimensional conductors

Special Issue Information

Dear Colleagues,

Fifty years after their discovery, the field of molecular conductors still remains very rich, thanks to the ability of the chemistry community to create new materials by fine-tuning the interactions between molecules with delocalized pi-electrons. The phase diagrams of these crystalline materials exhibit a wealth of ground states; some of them were not imagined at that time, nor observed before, in inorganic materials: superconductivity, Mott insulator, charge order insulator, spin liquids, chiral states, multiferroicity, and Dirac cones, for instance. These various properties interplay very often as a function of pressure, gate doping, light or the magnetic field. They may lead to inhomogeneous states at the border of metal-insulator phase transition, or near quantum critical points. However, forty years after the discovery of superconductivity in a molecular conductor, the question of its origin is not yet clear.

The purity of the available single crystals turns the molecular conductors into model systems in condensed matter physics for experimentalists, and theoreticians as well. They offer a rich playground for studying the role and the competition of lattice, charge and orbital degrees of freedom, thanks to the softness of the underlying structure and the ability of chemists to introduce specific functions on the molecules.

This Special Issue on molecular (super)conductors follows the two previous ones edited by Reizo Kato, in 2012, with 45 contributions on various aspects of “Molecular Conductors”, and Martin Dressel, in 2018, with 19 contributions on “Advances in Organic Conductors and Superconductors”, which both had a large impact. This Special Issue reports on new achievements in the field within the last three years.

Prof. Dr. Claude Pasquier
Guest Editor

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Keywords

  • Synthesis of molecules
  • Electrocrystallization (or crystal growth)
  • Charge transfer salts
  • Single molecule materials
  • Chiral materials
  • Low dimensionality
  • Superconductivity
  • Dirac cones
  • Strongly correlated electron systems
  • Mott transition
  • Charge order
  • Spin liquids
  • Ferroelectricity
  • Disorder effects
  • High Pressure
  • X-ray diffraction
  • Photo-induced transition
  • Thermodynamic properties
  • Electrical properties
  • Thermal properties
  • Dielectric properties
  • Optical properties
  • Spectroscopic techniques (NMR, ESR, Raman, STM…)
  • Dynamical mean field theory
  • Ab-initio calculations
  • Numerical techniques
  • Theoretical models

Published Papers (1 paper)

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Research

16 pages, 24094 KiB  
Article
Old Donors for New Molecular Conductors: Combining TMTSF and BEDT-TTF with Anionic (TaF6)1−x/(PF6)x Alloys
by Magali Allain, Cécile Mézière, Pascale Auban-Senzier and Narcis Avarvari
Crystals 2021, 11(4), 386; https://doi.org/10.3390/cryst11040386 - 07 Apr 2021
Cited by 5 | Viewed by 1671
Abstract
Tetramethyl-tetraselenafulvalene (TMTSF) and bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF) are flagship precursors in the field of molecular (super)conductors. The electrocrystallization of these donors in the presence of (n-Bu4N)TaF6 or mixtures of (n-Bu4N)TaF6 and (n-Bu4 [...] Read more.
Tetramethyl-tetraselenafulvalene (TMTSF) and bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF) are flagship precursors in the field of molecular (super)conductors. The electrocrystallization of these donors in the presence of (n-Bu4N)TaF6 or mixtures of (n-Bu4N)TaF6 and (n-Bu4N)PF6 provided Bechgaard salts formulated as (TMTSF)2(TaF6)0.84(PF6)0.16, (TMTSF)2(TaF6)0.56(PF6)0.44, (TMTSF)2(TaF6)0.44(PF6)0.56 and (TMTSF)2(TaF6)0.12(PF6)0.88, together with the monoclinic and orthorhombic phases δm-(BEDT-TTF)2(TaF6)0.94(PF6)0.06 and δo-(BEDT-TTF)2(TaF6)0.43(PF6)0.57, respectively. The use of BEDT-TTF and a mixture of (n-Bu4N)TaF6/TaF5 afforded the 1:1 phase (BEDT-TTF)2(TaF6)2·CH2Cl2. The precise Ta/P ratio in the alloys has been determined by an accurate single crystal X-ray data analysis and was corroborated with solution 19F NMR measurements. In the previously unknown crystalline phase (BEDT-TTF)2(TaF6)2·CH2Cl2 the donors organize in dimers interacting laterally yet no organic-inorganic segregation is observed. Single crystal resistivity measurements on the TMTSF based materials show typical behavior of the Bechgaard phases with room temperature conductivity σ ≈ 100 S/cm and localization below 12 K indicative of a spin density wave transition. The orthorhombic phase δo-(BEDT-TTF)2(TaF6)0.43(PF6)0.57 is semiconducting with the room temperature conductivity estimated to be σ ≈ 0.16–0.5 S/cm while the compound (BEDT-TTF)2(TaF6)2·CH2Cl2 is also a semiconductor, yet with a much lower room temperature conductivity value of 0.001 to 0.0025 S/cm, in agreement with the +1 oxidation state and strong dimerization of the donors. Full article
(This article belongs to the Special Issue Molecular (Super) Conductors)
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