Catalysis for Energy Storage and Batteries

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Electrocatalysis".

Deadline for manuscript submissions: 10 June 2025 | Viewed by 1169

Special Issue Editor

Institute for Advanced Study, Chengdu University, Chengdu, China
Interests: colloidal NPs; energy conversion & storage; electrocatalysis; batteries

Special Issue Information

Dear Colleagues,

This Special Issue of Catalysis for Energy Storage and Batteries explores innovative advancements in electrochemistry for sustainable energy solutions. With global energy demands surging, the reliance on non-renewable sources has led to pollution and environmental concerns. Thus, a shift towards efficient, cost-effective, electrochemical energy technologies is crucial for achieving a carbon-neutral future.

This issue focuses on the design and optimization of advanced electrocatalysts for key reactions like fuel cells, batteries, water splitting, CO2 reduction, and others. Additionally, it highlights recent progress in synthesizing novel catalysts, enhancing performance, and building efficient devices. In addition, advanced characterization techniques—such as ex-situ, in-situ, and operando methods—are utilized to provide insights into the mechanisms, supported by theoretical and computational modeling. In particular, the development of these technologies requires a multidisciplinary approach, bridging materials science, chemistry, physics, and computational fields. Thus, this issue aims to inspiring publications towards sustainable energy storage and conversion solutions.

Dr. Junshan Li
Guest Editor

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Keywords

  • electrocatalysis
  • batteries
  • water splitting
  • energy storage
  • sustainable technology
  • electrooxidation
  • electrocatalytic transformation
  • carbon dioxide

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Published Papers (2 papers)

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Research

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13 pages, 5100 KiB  
Article
Solid-State Reaction Synthesis of CoSb2O6-Based Electrodes Towards Oxygen Evolution Reaction in Acidic Electrolytes: Effects of Calcination Time and Temperature
by Francesco Vanzetti, Hilmar Guzmán and Simelys Hernández
Catalysts 2025, 15(1), 68; https://doi.org/10.3390/catal15010068 - 13 Jan 2025
Viewed by 875
Abstract
Mitigating global warming necessitates transitioning from fossil fuels to alternative energy carriers like hydrogen. Efficient hydrogen production via electrocatalysis requires high-performance, stable anode materials for the oxygen evolution reaction (OER) to support the hydrogen evolution reaction (HER) at the cathode. Developing noble metal-free [...] Read more.
Mitigating global warming necessitates transitioning from fossil fuels to alternative energy carriers like hydrogen. Efficient hydrogen production via electrocatalysis requires high-performance, stable anode materials for the oxygen evolution reaction (OER) to support the hydrogen evolution reaction (HER) at the cathode. Developing noble metal-free electrocatalysts is therefore crucial, particularly for acidic electrolytes, to avoid reliance on scarce and expensive metals such as Ir and Ru. This study investigates a low-cost, solvent-free solid-state synthesis of CoSb2O6, focusing on the influence of calcination time and temperature. Six samples were prepared and characterized using powder X-ray diffraction (PXRD), energy-dispersive X-ray spectroscopy (EDX), Brunauer–Emmett–Teller (BET) analysis, field-emission scanning electron microscopy (FESEM), and electrochemical techniques. A non-pure CoSb2O6 phase was observed across all samples. Electrochemical testing revealed good short-term stability; however, all samples exhibited Tafel slopes exceeding 200 mV dec−1 and overpotentials greater than 1 V. The sample calcined at 600 °C for 6 h showed the best performance, with the lowest Tafel slope and overpotential, attributed to its high CoSb2O6 content and maximized {110} facet exposure. This work highlights the role of calcination protocols in developing Co-based OER catalysts and offers insights for enhancing their electrocatalytic properties. Full article
(This article belongs to the Special Issue Catalysis for Energy Storage and Batteries)
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Review

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19 pages, 2845 KiB  
Review
Nickel Selenides in Electrocatalysis: Coupled Formate and Hydrogen Production Through Methanol Oxidation Reaction
by Hong Tu, Yan Zhong, Zhihao Yang, Caihong Zhang, Yi Ma, Yong Zhang, Ning Jian, Huan Ge and Junshan Li
Catalysts 2025, 15(6), 516; https://doi.org/10.3390/catal15060516 - 23 May 2025
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Abstract
The hydrogen economy, associated with electrochemical water splitting, represents a promising pathway to mitigate reliance on fossil fuels. However, the efficiency of this process is constrained by the sluggish oxygen evolution reaction (OER) at the anode, with low commercial interests of the produced [...] Read more.
The hydrogen economy, associated with electrochemical water splitting, represents a promising pathway to mitigate reliance on fossil fuels. However, the efficiency of this process is constrained by the sluggish oxygen evolution reaction (OER) at the anode, with low commercial interests of the produced oxygen. As a promising solution, OER can be replaced with the methanol oxidation reaction (MOR), which not only accelerates the hydrogen evolution reaction (HER) but also yields valuable formate as a product, depending on the nature of the anode electrocatalysts. In this context, nickel selenides have emerged as highly efficient and cost-effective electrocatalysts due to their rich compositional diversity, tunable electronic structures, and superior conductivity. Additionally, nickel selenides exist in multiple stoichiometric and nonstoichiometric phases, and also in the engineering versatility for optimizing catalytic MOR performance. This review comprehensively presents the design principles of electrocatalysts, provides a strategy for the optimization of performance, and discusses the mechanistic understanding of nickel selenide-based electrocatalysts for coupled HER and MOR systems, particularly focusing on the MOR. By bridging fundamental insights with practical applications, it additionally highlights the latest advancements in their catalytic MOR performance, offering insights into their potential for future energy and chemical applications. Full article
(This article belongs to the Special Issue Catalysis for Energy Storage and Batteries)
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