Nanotechnology and Functional Nanomaterials

A special issue of Applied Sciences (ISSN 2076-3417). This special issue belongs to the section "Nanotechnology and Applied Nanosciences".

Deadline for manuscript submissions: closed (30 June 2023) | Viewed by 3970

Special Issue Editors


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Guest Editor
Center for Photonics and 2D Materials, Moscow Institute of Physics and Technology, National Research University, 9 Institutskiy per., Dolgoprudny, Moscow 141701, Russia
Interests: nanotechnology; nanoscience; nanomaterials; nanoparticles; nanostructures; synthesis
Special Issues, Collections and Topics in MDPI journals

E-Mail Website
Guest Editor
Center for Photonics and 2D Materials, Moscow Institute of Physics and Technology, National Research University, 9 Institutskiy per., Dolgoprudny, Moscow 141701, Russia
Interests: nanotechnology; nanoscience; nanomaterials; nanoparticles; nanostructures; synthesis; Raman spectroscopy; nonlinear optics
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Nanotechnology now plays a role in the daily life of every person, whether they are aware of it or not. Functional nanomaterials are created annually in various fields of science and technology, and their properties largely depend on the technology of their production.

The purpose of modern methods for obtaining functional nanomaterials is to modify both the methods and parameters of synthesis, as well as the composition of nanostructures to obtain a nanomaterial with widely known properties, as well as extremely unique properties for the application of the obtained nanomaterials in highly specialized fields of science and technology.

This Special Issue will focus on new perspectives on the chemical and functional properties of nanomaterials.

The topics that will be discussed in this Special Issue will focus not only on modern methods, technologies, and further processing of nanomaterials to improve their functional properties, but also on testing their properties in specific applications. 

Dr. Alexander V. Syuy
Dr. Gleb I. Tselikov
Guest Editors

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Keywords

  • nanotechnology
  • nanoscience
  • nanomaterials
  • nanoparticles
  • nanostructures
  • synthesis

Published Papers (3 papers)

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Research

10 pages, 1672 KiB  
Article
Gadolinium-Doped Carbon Nanoparticles with Red Fluorescence and Enhanced Proton Relaxivity as Bimodal Nanoprobes for Bioimaging Applications
by Dariia U. Musaeva, Alexey N. Kopylov, Alexander V. Syuy, Valentyn S. Volkov, Nikita D. Mitiushev, Olga S. Pavlova, Yury A. Pirogov, Andrey N. Baranov and Victor Yu. Timoshenko
Appl. Sci. 2023, 13(16), 9322; https://doi.org/10.3390/app13169322 - 16 Aug 2023
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Abstract
Carbon-based nanoparticles (CNPs) have demonstrated great potential in biomedical applications because of their unique physical and chemical properties, and excellent biocompatibility. Herein, we have studied two types of CNPs with gadolinium (Gd) impurities (Gd-CNPs), which were prepared by microwave synthesis (MWS) and hydrothermal [...] Read more.
Carbon-based nanoparticles (CNPs) have demonstrated great potential in biomedical applications because of their unique physical and chemical properties, and excellent biocompatibility. Herein, we have studied two types of CNPs with gadolinium (Gd) impurities (Gd-CNPs), which were prepared by microwave synthesis (MWS) and hydrothermal synthesis (HTS), for potential applications as photoluminescent (PL) labels and contrast agents in magnetic resonance imaging (MRI). The prepared Gd-CNPs were investigated by means of transmission electron microscopy (TEM), Fourier-transform infrared spectroscopy, UV–visible absorption spectroscopy, and magnetic-resonance relaxometry, which allowed us to reveal specific features and functional properties of the prepared samples. While the TEM data showed similar size distributions of both types of Gd-CNPs with mean sizes of 4–5 nm, the optical absorption spectroscopy showed higher absorption in the visible spectral region and stronger PL in the red and near-infrared (NIR) spectral regions for the MWS samples in comparison with those prepared by HTS. Under green light excitation the former samples exhibited the bright red-NIR PL with quantum efficiency of the order of 10%. The proton relaxometry measurements demonstrated that the HTS samples possessed longitudinal and transverse relaxivities of about 42 and 70 mM−1s−1, whereas the corresponding values for the MWS samples were about 8 and 13 mM−1s−1, respectively. The obtained results can be useful for the selection of appropriate synthesis conditions for carbon-based nanoparticles for bimodal bioimaging applications. Full article
(This article belongs to the Special Issue Nanotechnology and Functional Nanomaterials)
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19 pages, 5286 KiB  
Article
Triangular Silver Nanoparticles Synthesis: Investigating Potential Application in Materials and Biosensing
by Laura G. Rodriguez Barroso, Eduardo Lanzagorta Garcia, Marija Mojicevic, Miriam Huerta, Robert Pogue, Declan M. Devine and Margaret Brennan-Fournet
Appl. Sci. 2023, 13(14), 8100; https://doi.org/10.3390/app13148100 - 11 Jul 2023
Cited by 1 | Viewed by 1314
Abstract
Triangular silver nanoplates (TSNPs) exhibit unique optical and antimicrobial properties due to their shape, sharp edges, and vertices. In this study, TSNPs were incorporated into biopolymer blends (bacterial cellulose (BC) with polylactic acid (PLA), polycaprolactone (PCL), and polyhydroxybutyrate (PHB)). Antimicrobial activity of materials [...] Read more.
Triangular silver nanoplates (TSNPs) exhibit unique optical and antimicrobial properties due to their shape, sharp edges, and vertices. In this study, TSNPs were incorporated into biopolymer blends (bacterial cellulose (BC) with polylactic acid (PLA), polycaprolactone (PCL), and polyhydroxybutyrate (PHB)). Antimicrobial activity of materials was tested against Escherichia coli ATCC 95922 and Staphylococcus aureus ATCC 25923 (106 CFU/mL). After incubation (24 h at 37 °C, 100 rpm), optical density was measured at 630 nm. In order to assess biosensing applications, specifically fibronectin (Fn) behavior, TSNPs were protected with gold (AuTSNP) and analyzed via sucrose sensitivity test and monitored by localized surface plasmon resonance (LSPR). Additionally, AuTSNPs were coated with polyethylene glycol (PEGAuTSNP). Fibronectin functionalization of PEGAuTSNPs and pH-conformation was monitored (FnPEGAuTSNP). Eventually, adequate Fn and anti-Fn antibody concentrations were determined. BC/PHB/TSNPs showed antimicrobial activity against E. coli and S. aureus with 80 and 95% of growth inhibition, respectively. The sucrose sensitivity test indicated that the LSPRλmax of the spectra is directly proportional to the sucrose concentration. LSPRλmax of Fn-PEGAuTSNPs at pH 7 and pH 4 were measured at 633 and 643 nm, respectively. A total of 5 µg of Fn was determined to be adequate concentration, while 0.212 mg/mL of anti-Fn antibody indicatied system saturation. Full article
(This article belongs to the Special Issue Nanotechnology and Functional Nanomaterials)
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15 pages, 1872 KiB  
Article
Investigation of the Structural Perfection of a LiNbO3:Gd3+(0.003):Mg2+(0.65 wt.%) Double-Doped Single Crystal Using the Raman Spectra Excited by Laser Lines in the Visible (532 nm) and Near-IR (785 nm) Regions
by Nikolay Sidorov, Mikhail Palatnikov, Alexander Pyatyshev and Alexander Skrabatun
Appl. Sci. 2023, 13(4), 2348; https://doi.org/10.3390/app13042348 - 11 Feb 2023
Cited by 2 | Viewed by 1187
Abstract
A compositionally homogeneous nonlinear optical single crystal of double-doped LiNbO3:Gd3+(0.003):Mg2+(0.65 wt.%) was obtained. Fine features of the LiNbO3:Gd3+(0.003):Mg2+(0.65 wt.%) crystal structure were studied from the Raman spectra of the first and [...] Read more.
A compositionally homogeneous nonlinear optical single crystal of double-doped LiNbO3:Gd3+(0.003):Mg2+(0.65 wt.%) was obtained. Fine features of the LiNbO3:Gd3+(0.003):Mg2+(0.65 wt.%) crystal structure were studied from the Raman spectra of the first and second orders upon excitation by laser lines in the visible (532 nm) and near-IR (785 nm) regions. When the Raman spectrum was excited by a 785 nm laser line in the frequency range of 1000–2000 cm−1 for the first time, a number of low-intensity lines in the range of 900–2000 cm−1, corresponding to the second-order Raman spectrum, were discovered. The same lines also appear in the spectrum upon excitation by a laser line with a wavelength of 532 nm, but their intensities are significantly (by an order of magnitude or more) lower. It is shown that in the structure of the double-doped LiNbO3:Gd3+(0.003):Mg2+(0.65 wt.%), the crystal oxygen-octahedral clusters MeO6 (Me–Li, Nb, Gd, Mg) are slightly distorted, and in addition, the value R = [Li]/[Nb] ≈ 1 is close to that for a nominally pure stoichiometric crystal. Full article
(This article belongs to the Special Issue Nanotechnology and Functional Nanomaterials)
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