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Spin-Crossover Behavior of Hofmann-Type-Like Complex Fe(4,4’-bipyridine)Ni(CN)4·nH2O Depending on Guest Species

1
Department of Basic Science, Graduate School of Arts and Sciences, the University of Tokyo, 3-8-1, Komaba, Meguro-ku, Tokyo 153-8902, Japan
2
Department of Chemistry, Faculty of Science, Toho University, 2-2-1 Miyama, Funabashi, Chiba 274-8510, Japan
3
Research Centre for Materials with Integrated Properties, Toho University, 2-2-1 Miyama, Funabashi, Chiba 274-8510, Japan
*
Author to whom correspondence should be addressed.
These authors contributed equally to this work.
Academic Editors: Guillem Aromí and José Antonio Real
Magnetochemistry 2016, 2(1), 8; https://doi.org/10.3390/magnetochemistry2010008
Received: 7 January 2016 / Revised: 26 January 2016 / Accepted: 1 February 2016 / Published: 16 February 2016
(This article belongs to the Special Issue Spin Crossover (SCO) Research)
A newly prepared metal complex Fe(4,4’-bipyridine)Ni(CN)4·nH2O, which was estimated to have a structure similar to the Hofmann-type clathrate host, changed its color from orange to deep orange and yellow on exposure to ethanol and acetone vapor, respectively, and the respective samples showed thermally induced two-step and one-step spin transitions. View Full-Text
Keywords: spin-crossover; vapochromism; guest inclusion; isotope effect spin-crossover; vapochromism; guest inclusion; isotope effect
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Hosoya, K.; Nishikiori, S.-I.; Takahashi, M.; Kitazawa, T. Spin-Crossover Behavior of Hofmann-Type-Like Complex Fe(4,4’-bipyridine)Ni(CN)4·nH2O Depending on Guest Species. Magnetochemistry 2016, 2, 8.

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