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A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine)

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School of Physical Sciences, University of Kent, Canterbury, Kent CT2 7NH, UK
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Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK
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School of Chemistry, University of Leeds, Woodhouse Lane, Leeds LS2 9JT, UK
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Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA
*
Author to whom correspondence should be addressed.
Academic Editor: Guillem Aromí
Magnetochemistry 2016, 2(1), 9; https://doi.org/10.3390/magnetochemistry2010009
Received: 11 January 2016 / Revised: 31 January 2016 / Accepted: 2 February 2016 / Published: 17 February 2016
(This article belongs to the Special Issue Spin Crossover (SCO) Research)
A high pressure single crystal X-ray diffraction and Raman spectroscopy study has revealed a similar mechanism for both thermal and pressure-induced spin crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine) and the concomitant anion order-disorder transition. View Full-Text
Keywords: spin-crossover; molecular materials; high pressure; order-disorder phenomena spin-crossover; molecular materials; high pressure; order-disorder phenomena
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Shepherd, H.J.; Tonge, G.; Hatcher, L.E.; Bryant, M.J.; Knichal, J.V.; Raithby, P.R.; Halcrow, M.A.; Kulmaczewski, R.; Gagnon, K.J.; Teat, S.J. A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine). Magnetochemistry 2016, 2, 9.

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