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Magnetochemistry, Volume 11, Issue 3

2025 March - 4 articles

Cover Story: The copper/2,2′-bipyrimidine/iodide system was explored in water and at room temperature, with the intent of combining the reducing properties of the iodide ion towards Cu(II) with the protective effect of ligand coordination. The approach afforded, systematically, both the fully reduced Cu(I) chain of {[CuI2(μ-I)2(bpm)]}n, which is of broad interest for its well established optical and photocatalytic properties, and a structurally unprecedented regular alternating mixed-valent Cu(II)-Cu(I) chain of {[CuI(I3)CuII(I)(bpm)2](I3)}n, whose chemical nature was undoubtably validated through magneto-structural correlation analysis. Numerous I···I contacts between iodide and tri-iodide anions in the latter complex reasonably account for its excellent stability and striking synthetic reproducibility. View this paper
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Articles (4)

  • Communication
  • Open Access
1,170 Views
7 Pages
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Design of Fe7S8@Lip Composite for the pH-Selective and Magnetically Targeted Programmed Release of H2S

  • Shenghua Wang,
  • Hanlin Wei,
  • Jialian Li,
  • Ning Liu,
  • Zhiming Deng and
  • Junqing Huang
Magnetochemistry2025, 11(3), 22;https://doi.org/10.3390/magnetochemistry11030022

14 March 2025

The significance of hydrogen sulfide (H2S) release in vivo is multifaceted. It functions as a crucial gaseous signaling molecule with extensive physiological and pathological impacts within organisms. To create novel H2S-releasing materials, we synth...

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  • Article
  • Open Access
1,112 Views
14 Pages
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Fast Calculations for the Magnetohydrodynamic Flow and Heat Transfer of Bingham Fluids with the Hall Effect

  • Ye Tian and
  • Yi Liu
Magnetochemistry2025, 11(3), 21;https://doi.org/10.3390/magnetochemistry11030021

12 March 2025

This study examines a mathematical model to represent the magnetohydrodynamic flow and heat transfer of Bingham fluids. The model is subject to a magnetic field’s influence and incorporates the modified energy equation derived from Fourier&rsqu...

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  • Article
  • Open Access
1 Citations
1,646 Views
16 Pages
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Chemical and Structural Versatility in the Copper/2,2′-Bipyrimidine/Iodide System: A Regular Alternating Mixed-Valent Cu(II)-Cu(I) Chain Showing Unusually Similar Metal Coordination Environments

  • Nadia Marino,
  • Francesc Lloret,
  • Miguel Julve and
  • Giovanni De Munno
Magnetochemistry2025, 11(3), 20;https://doi.org/10.3390/magnetochemistry11030020

5 March 2025

The reaction in reagent grade acetone of copper(II) nitrate hexahydrate, 2,2′-bipyrimidine (bpm) and potassium iodide in a 1:2:2 molar ratio afforded three different products: an unreduced Cu(II) species, a fully reduced Cu(I) species and a mix...

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  • Article
  • Open Access
1 Citations
1,178 Views
19 Pages
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Study on the Influence of Hall Effect on the Performance of Disk Generation Channel

  • Linyong Li,
  • Guang Wang,
  • Yingke Liao,
  • Qing Wu and
  • Peijie Ning
Magnetochemistry2025, 11(3), 19;https://doi.org/10.3390/magnetochemistry11030019

4 March 2025

Compared to the Faraday-type power generation channel structure, the disk-type power generation channel offers several advantages, including a simpler structure, higher enthalpy extraction efficiency, and greater power density. These features effecti...

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Magnetochemistry - ISSN 2312-7481
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