Abstract
We present a detailed derivation of the quantum and quantum–thermal effective action for non-relativistic systems, starting from the single-particle case and extending to the Gross–Pitaevskii (GP) field theory for weakly interacting bosons. In the single-particle framework, we introduce the one-particle-irreducible (1PI) effective action formalism, taking explicitly into account the choice of the initial quantum state, its saddle-point plus Gaussian-fluctuation approximation, and its finite-temperature extension via Matsubara summation, yielding a clear physical interpretation in terms of zero-point and thermal contributions to the Helmholtz free energy. The formalism is then applied to the GP action, producing the 1PI effective potential at zero and finite temperature, including beyond-mean-field Lee–Huang–Yang and thermal corrections. We discuss the gapless and gapped Bogoliubov spectra, their relevance to equilibrium and non-equilibrium regimes, and the role of regularization. Applications include the inclusion of an external potential within the local density approximation, the derivation of finite-temperature Josephson equations, and the extension to D-dimensional systems, with particular attention to the zero-dimensional limit. This unified approach provides a transparent connection between microscopic quantum fluctuations and effective macroscopic equations of motion for Bose–Einstein condensates.
1. Introduction
Quantum and thermal fluctuations play a crucial role in determining the properties of many-body systems, particularly in the realm of ultracold atomic gases and Bose–Einstein condensates (BECs). Since the first theoretical descriptions of spontaneous symmetry breaking and effective potentials by Goldstone and Weinberg [1], and the seminal works by Jona-Lasinio on effective action methods [2,3], the field-theoretic approach has become a foundational tool to bridge microscopic quantum dynamics and emergent macroscopic phenomena. Coleman and Weinberg’s pioneering analysis of radiative corrections in effective potentials [4] further enriched the understanding of fluctuation effects beyond classical approximations [5,6,7]. For non-relativistic and non-interacting bosons in the presence of an external potential, an effective action approach was developed by Toms and Kirsten [8,9]. For interacting bosons the Gross–Pitaevskii (GP) equation [10,11] provides a mean-field description of the condensate wavefunction. However, capturing corrections beyond mean-field theory, such as the Lee–Huang–Yang quantum fluctuations [12,13,14] and thermal effects [15,16,17], requires a more comprehensive framework. The quantum effective action formalism, especially within the one-particle-irreducible (1PI) scheme [5,6,7], offers a systematic pathway to incorporate these fluctuations by deriving effective potentials and excitation spectra that reflect both quantum and thermal contributions. Recent experimental advances in ultracold gases have highlighted the importance of precise theoretical tools for describing weakly interacting bosons under various conditions, including finite temperature, external trapping potentials, and low-dimensional regimes [15,18,19]. Moreover, the interplay between gapless and gapped Bogoliubov modes has implications for equilibrium properties and non-equilibrium dynamics, such as Josephson oscillations [20,21], which require refined effective descriptions [22].
Building on these developments, this work presents a detailed derivation of the quantum and quantum–thermal effective action for non-relativistic systems. Starting from the fundamental single-particle case, we clarify the construction of the 1PI effective action and its approximation at the Gaussian (one-loop) level. This formalism is then extended to the GP field theory for weakly interacting bosons, capturing beyond-mean-field Lee–Huang–Yang corrections and finite-temperature generalizations. We also discuss the inclusion of external potentials within local density approximations and the dimensional crossover to analytically tractable limits, including the zero-dimensional case. By providing a transparent and unified framework that connects microscopic quantum fluctuations to macroscopic condensate dynamics, our approach complements and extends previous theoretical efforts [17,22] and lays the groundwork for future studies involving dissipative effects, stronger interactions, and non-equilibrium phenomena.
2. Single-Particle Non-Relativistic Quantum Mechanics
2.1. Quantum Effective Action
Let us consider a particle of mass m and coordinate described by the action functional
It is well known that the classical trajectory is the one that extremizes this action, namely
We now introduce the following decomposition
where
is the average of with respect some pure or mixed quantum state. For instance, in the case of a pure quantum state , such that is its wavefunction (normalized to one) in the coordinate representation at time t, we have
by using the Feynman path integral representation of the quantum propagator
that gives the conditional probability amplitude of finding the particle in the position q at time t having it in the position at time , and consequently
From Equation (5) one explicitly shows that crucially depends on the choice of the wavefunction of the pure quantum state at the initial time . Notice that is sometimes called the background dynamical variable and, in general, . Thus, usually
The main issue of this paper is to find the functional of whose Euler-Lagrange equation gives the exact equation of motion of . This functional is usually called the quantum (one-particle irreducible, 1PI) effective action . It is important to stress that, in general, cannot explicitly be calculated without doing some approximation or some perturbative expansion. Usually is obtained by introducing a source term and performing a Legendre transformation [4,5]. Here, we will derive the 1PI quantum effective action of the system without the use of source terms or Legendre transformations. In our approach, is simply given by
provided that Equation (9) holds. In the absence of the condition (9), the action of Equation (10) is called the background effective action.
The stationary phase approximation (saddle-point plus Gaussian fluctuations) of this functional integral around gives
where
is the contribution due to Gaussian fluctuations. Quite remarkably, although expanding produces a linear term in whenever is not equal to the classical trajectory , this contribution does not appear in the effective action . The reason is that quantum corrections from higher-order fluctuation terms (tadpoles) exactly compensate the bare linear term, leaving free of such contributions by construction. One can prove [6,7] that this compensation is ensured by the condition (9), or equivalently by the definition of the background field (4). This guarantees that the linear term in the fluctuation expansion cancels between the bare action and the quantum tadpole contributions.
To conclude the discussion, we notice that can be exponentiated:
This means that we can write
Thus, at the Gaussian level, the quantum effective action is the classical action plus the one-loop quantum correction .
The exact analytical calculation of can be performed only in the very simple case where in is time independent. If is time dependent, the standard trick (lowest-order derivative expansion, aka adiabatic approximation, aka local field approximation) is to calculate assuming that is time independent and restoring the time dependence only at the end of the calculation. Under this assumption we have
In this way we identify the effective (one-loop) potential of the system
After integration, and discarding spurious divergent terms, we obtain
and the corresponding one-loop 1PI action functional
The quantum effective action method is rather complicated but the final result is quite simple: the quantum effective action it is nothing else than the one derived from the stationary phase approximation (saddle point plus Gaussian fluctuations) of the path integral. The only caveat is that the saddle point classical (mean field) solution , which extremizes the classical action , must be re-interpreted as the quantum average of the dynamical variable of the problem. Moreover, the Gaussian beyond-mean-field correction can be interpreted as the zero-point energy of the harmonic oscillator of quantum fluctuations with effective frequency
In conclusion, we observe that it is possible to extend this effective action approach to the case of a mass m (see Equation (1)) that depends on the dynamical variable : . For details see Refs. [5,23,24].
2.2. Quantum-Thermal Effective Action
In the spirit of the adiabatic approximation, Equation (15) can be generalized to the case of finite temperature T as follows
where are the bosonic Matsubara frequencies and with the Boltzmann constant. Thus, the quantum-thermal effective potential reads
namely
This final result has a clear physical interpretation: the Gaussian beyond-mean-field quantum-thermal correction is the Helmholtz free energy of the harmonic oscillator, with effective frequency given Equation (19), of quantum-thermal fluctuations around the mean-field (classical) result. Notice that for one has . The key point is that to obtain an action functional containing both time t and temperature T it is useful to have a two times action functional and then performing a Wick rotation with respect to one of the two times. Equation (15) contains implicitly two times: explicitly t and implicitly because is the Fourier dual of .
3. Gross-Pitaevskii Quantum Field Theory
Let us now face the problem of the non-relativistic quantum field theory for the Schrödinger field with action functional
where g is the strength of the contact interaction of the identical bosonic particles of mass m with chemical potential . The action functional (24) is called Gross-Pitaevskii (GP) action. Also in this case we are looking for the quantum effective action of the average of the Schrödinger field . To maintain a connection with the discussion of the previous section, we denote by the normalized wavefunctional of the field at time t, where is the coherent state, i.e., the eigenstate, of the quantum field operator with eigenvalue , while is a many-body quantum state at the initial time. The expectation value
of the field is computed as the average of the configuration field with respect to the probability density , namely
which is a generalization of Equation (5).
Without repeating the procedure developed in the previous section, taking into account well established results for zero-temperature Gaussian fluctuations [14], we find that the quantum effective action is given by
where
In this formula appears the zero-point energy of Gaussian quantum fluctuations, characterized by the gapped Bogoliubov spectrum
which reduces to the gapless Bogoliubov spectrum
only under the very strong assumption
that is justified only at equilibrium. By the way, the Goldstone theorem (gapless spectrum) works only at equilibrium and at . The Gaussian beyond-mean-field correction can be interpreted as the zero-point energy of a set of harmonic oscillators with effective frequencies . It is important to stress that is divergent but one can extract a meaningful finite contribution performing an appropriate regularization, for details see Ref. [14]. In three spatial dimensions one obtains the so-called Lee–Huang–Yang quantum correction.
We can easily extend this result at finite temperature. On the basis of the physical interpretation of quantum fluctuations as a gas of Bogoliubov excitations, by using Equation (5) of Ref. [17] we immediately obtain
This is the 1PI effective potential of the GP action at finite temperature. Indeed, is nothing else than the grand canonical potential of Ref. [17] with the identification .
The equation of motion of is given by
where is fixed by imposing that
Our Equation (33) reduces to the stationary generalized Gross-Pitaevskii equation discussed in Refs. [18,19] setting and adopting the spectrum (29) instead of (30) in .
The standard approach is to adopt the gapless Bogoliubov spectrum in Equation (33) under the assumption of working near thermal equilibrium. Introducing the local number density
Equation (33) can be then written as
where
is the renormalized zero-temperature Lee–Huang–Yang beyond-mean-field correction, i.e., a sort of additional bulk chemical potential with the s-wave scattering length such that , while
is the quantum-thermal correction, where
plays the role of the density of a thermal bath, such that
with and
with . We stress that Equation (36) can also be seen as the time-dependent extension of the stationary Gross-Pitaevskii equation for the Bose–Einstein condensate which appears in the Zaremba-Nikuni-Griffin (ZNG) formalism [15]. By adopting the ZNG formalism we recover our thermal density from a Boltzmann equation of non-condensed bosons. At equilibrium and zero temperature the Lee–Huang–Yang term of Equation (36) is consistent with the modified Gross–Pitaevskii equation of Ref. [13].
3.1. Including an External Potential
In the spirit of the local density approximation (LDA) we can also consider the inclusion of an external potential in Equation (36), namely
Remember that here, and in Equation (36), the chemical potential can be formally removed with an appropriate redefinition of the phase of time-dependent field .
A drawback of Equation (42) is that, for the thermal density becomes uniform despite the presence of . To cure this drawback it is sufficient to make the substitution in Equation (39). However, just to simplify a bit the problem one usually considers the following Hartree approximation of the Bogoliubov spectrum in the single-particle phase space [16]
that is reliable for large k. In this way we have
with
3.2. Josephson Equations at Finite Temperature
Under the assumption of an external potential which separates our three-dimensional () system in two weakly linked regions and that of Equation (42) truly describes Bose-condensed particles at finite temperature T, a straightforward generalization of the Josephson equations [20,21] at finite temperature reads
where is the population imbalance of the Bose–Einstein condensate, is the relative phase of the Bose condensate, J is the tunneling energy of condensed bosons, is the space-time independent average number density of condensed bosons in the two regions, and
Working with a fixed total average number density of bosons, the average number density of condensed bosons can be extracted from the finite-temperature Bogoliubov formula
with given by
A detailed derivation of Equation (49) with Equation (50) is discussed in Ref. [17]. The main idea is to write the thermodynamic grand potential of the system at equilibrium as a function of both the chemical potential and the condensate density by using the gapped Bogoliubov spectrum (29). The number density is then obtained as . Finally, setting one finds as a function of and T.
3.3. 1PI GP Effective Potential in D Dimensions
As previously discussed, for , we can safely use the gapless spectrum instead of the gapped spectrum in this effective potential. However, this substitution cannot be performed for , where only the mode survives, because it will imply , see Equation (30).
In the zero-dimensional case () one must use the gapped spectrum of Equation (29) with , namely
Thus, the 1PI GP effective potential for reads
Actually, a better treatment at is obtained considering the gapless Bogoliubov spectrum with a finite and dimensional regularization around [25]. At finite temperature one instead uses the gapped . At the end, we obtain
Quite remarkably, the term gives for the exact internal energy at equilibrium with .
4. Conclusions
We have reviewed and extended the quantum effective action formalism for non-relativistic systems, with emphasis on its Gaussian (one-loop) implementation and finite-temperature generalization. Starting from the single-particle case, we showed how the 1PI effective action can be systematically derived and how the saddle-point plus Gaussian-fluctuation approximation leads to simple yet physically transparent expressions for the effective potential. The finite-temperature extension, obtained through Matsubara summation, yields quantum–thermal corrections with a clear interpretation as the Helmholtz free energy of harmonic modes with effective Bogoliubov frequencies. Applied to the Gross–Pitaevskii field theory, this approach naturally incorporates beyond-mean-field effects, including the Lee–Huang–Yang correction and its finite-temperature counterpart, and accommodates both gapped and gapless excitation spectra. The formalism is flexible enough to handle external potentials within the local density or Hartree approximations, to describe Josephson dynamics at finite temperature, and to generalize to arbitrary spatial dimensions, including the analytically interesting zero-dimensional limit. Overall, the quantum–thermal effective action framework offers a unified and physically intuitive route from microscopic fluctuations to macroscopic dynamical equations for Bose–Einstein condensates. It connects field-theoretic principles with experimentally relevant phenomena, providing a solid base for further developments, such as the inclusion of dissipative effects, stronger interaction regimes, or non-equilibrium dynamics. Regarding the connection with experiments, it is important to stress that, in the context of superconducting Josephson junctions, the zero-point correction of Equation (17) explains the shift of the quantized energy levels of qubits [26]. Instead, in the context of ultracold bosonic atoms, the beyond-mean-field Gaussian quantum corrections described here have been found in several experiments (see, for instance, Refs. [27,28,29]). In this review we have not considered open quantum systems and the impact of external environments. This is a hot topic of research where, however, a clear connection between the formalism of master equations [30,31,32] and the quantum effective action approach is still lacking.
Funding
PRIN 2022 Project of MUR “Quantum Atomic Mixtures: Droplets, Topological Structures, and Vortices” (2023–2024); Dipartimenti di Eccellenza Project of MUR “Frontiere Quantistiche”; Iniziativa Specifica “Quantum” of INFN.
Data Availability Statement
No new data were created or analyzed in this study. Data sharing is not applicable to this article.
Acknowledgments
The author thanks Francesco Ancilotto, Alessandro Pennacchio, Sofia Salvatore, and Cesare Vianello for useful discussions and suggestions.
Conflicts of Interest
The author declares no conflicts of interest.
References
- Weinberg, S.; Goldstone, J. Broken Symmetries. Phys. Rev. 1962, 127, 965. [Google Scholar]
- Jona-Lasinio, G. Relativistic field theories with symmetry-breaking solutions. Nuovo Cimento 1964, 34, 1790. [Google Scholar] [CrossRef]
- Cametti, F.; Jona-Lasinio, G.; Presilla, C.; Toninelli, F. Comparison between quantum and classical dynamics in the effective action formalism. In Proceedings of the International School of Physics “Enrico Fermi” Course CXLIII, Varenna, Italy, 20–30 July 1999; Casati, G., Guarnieri, I., Smilansky, U., Eds.; IOS Press: Amsterdam, The Netherlands, 2000; pp. 431–448. [Google Scholar]
- Coleman, S.; Weinberg, E. Radiative Corrections as the Origin of Spontaneous Symmetry Breaking. Phys. Rev. D 1973, 7, 1888. [Google Scholar] [CrossRef]
- Kleinert, H. Path Integrals in Quantum Mechanics, Statistics, Polymer Physics, and Financial Market; Section 10.13; World Scientific: Singapore, 2009. [Google Scholar]
- Jackiw, R. Functional evaluation of the effective potential. Phys. Rev. D 1974, 9, 1686. [Google Scholar] [CrossRef]
- Abbott, L.F. Introduction to the background field method. Acta Phys. Pol. B 1982, 13, 33. [Google Scholar]
- Toms, D.J. Effective action approach to Bose-Einstein condensation and superconductivity of charged ideal nonrelativistic Bose gas. Phys. Rev. B 1994, 50, 3120. [Google Scholar] [CrossRef] [PubMed]
- Kirsten, K.; Toms, D.J. Effective Action Approach to Bose-Einstein Condensation of Ideal Gases. J. Res. NIST 1996, 101, 471. [Google Scholar] [CrossRef] [PubMed]
- Gross, E.P. Structure of a quantized vortex in boson systems. Nuovo Cimento 1961, 20, 454. [Google Scholar] [CrossRef]
- Pitaevskii, L.P. Vortex Lines in an Imperfect Bose Gas. Sov. Phys. JETP 1961, 13, 451. [Google Scholar]
- Lee, T.D.; Huang, K.; Yang, C.N. Eigenvalues and Eigenfunctions of a Bose System of Hard Spheres and Its Low-Temperature Properties. Phys. Rev. 1957, 106, 1135. [Google Scholar] [CrossRef]
- Salasnich, L. Self-Consistent Derivation of the Modified Gross–Pitaevskii Equation with Lee–Huang–Yang Correction. Appl. Sci. 2018, 8, 1998. [Google Scholar] [CrossRef]
- Stoof, H.T.C.; Gubbels, K.B.; Dickerscheid, D.B.M. Ultracold Quantum Fields; Springer: Berlin/Heidelberg, Germany, 2009. [Google Scholar]
- Zaremba, E.; Nikuni, T.; Griffin, A. Dynamics of trapped Bose gases at finite temperatures. J. Low Temp. Phys. 1999, 116, 277. [Google Scholar] [CrossRef]
- Giorgini, S.; Pitaevskii, L.P.; Stringari, S. Thermodynamics of a Trapped Bose-Condensed Gas. J. Low Temp. Phys. 1997, 109, 309. [Google Scholar] [CrossRef]
- Vianello, C.; Salasnich, L. Condensate and superfluid fraction of homogeneous Bose gases in a self-consistent Popov approximation. Sci. Rep. 2024, 14, 15034. [Google Scholar] [CrossRef]
- Aybar, E.; Oktel, M.O. Temperature-dependent density profiles of dipolar droplets. Phys. Rev. A 2019, 99, 013620. [Google Scholar] [CrossRef]
- Sanchez-Baena, J.; Politi, C.; Maucher, F.; Ferlaino, F.; Pohl, T. Heating a dipolar quantum fluid into a solid. Nature Commun. 2023, 14, 1868. [Google Scholar] [CrossRef] [PubMed]
- Josephson, B.D. Possible new effects in superconductive tunnelling. Phys. Lett. 1962, 1, 251. [Google Scholar]
- Smerzi, A.; Fantoni, S.; Giovanazzi, S.; Shenoy, S.R. Quantum Coherent Atomic Tunneling between Two Trapped Bose-Einstein Condensates. Phys. Rev. Lett. 1997, 79, 4950. [Google Scholar] [CrossRef]
- Furutani, K.; Tempere, J.; Salasnich, L. Quantum effective action for the bosonic Josephson junction. Phys. Rev. B 2022, 105, 134510. [Google Scholar] [CrossRef]
- Salvatore, S. Quantum Fluctuations in Josephson Junctions: A Path Integral Approach. Master’s Thesis, University of Padova, Padova, Italy, 2025. [Google Scholar]
- Vianello, C.; Salvatore, S.; Salasnich, L. Quantum action of the Josephson dynamics. Int. J. Theor. Phys. 2025, 64, 315. [Google Scholar] [CrossRef]
- Bardin, A. (University of Padova, Padova, Italy). Personal communication, 2024.
- Clarke, J.; Cleland, A.N.; Devoret, M.H.; Esteve, D.; Martinis, J.M. Quantum Mechanics of a Macroscopic Variable: The Phase Difference of a Josephson Junction. Science 1988, 239, 992. [Google Scholar] [CrossRef]
- Wild, R.; Papp, S.; Pino, J.; Ronen, S.; Bohn, J.; Jin, D.; Wieman, C.; Cornell, E. Bragg Spectroscopy of a Strongly Interacting 85Rb Bose-Einstein condensate. Phys. Rev. Lett. 2008, 101, 135301. [Google Scholar]
- Wild, R.J.; Makotyn, P.; Pino, J.M.; Cornell, E.A.; Jin, D.S. Measurements of Tan’s contact in an atomic Bose-Einstein condensate. Phys. Rev. Lett. 2012, 108, 145305. [Google Scholar] [CrossRef]
- Cabrera, C.R.; Tanzi, L.; Sanz, J.; Naylor, B.; Thomas, P.; Cheiney, P.; Tarruell, L. Quantum liquid droplets in a mixture of Bose-Einstein condensates. Science 2018, 359, 6373. [Google Scholar] [CrossRef] [PubMed]
- Breuer, H.-P.; Laine, E.-M.; Piilo, J. Exact master equations for the non-Markovian decay of a qubit. Phys. Rev. Lett. 2009, 103, 210401. [Google Scholar] [CrossRef]
- Vacchini, B.; Breuer, H.-P. Exact master equations for the non-Markovian decay of a qubit. Phys. Rev. A 2010, 81, 042103. [Google Scholar] [CrossRef]
- Shen, H.Z.; Shang, C.; Zhou, Y.H.; Yi, X.X. Unconventional single-photon blockade in non-Markovian systems. Phys. Rev. A 2018, 98, 023856. [Google Scholar] [CrossRef]
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