Next Article in Journal
Nanomaterials in Plants: A Review of Hazard and Applications in the Agri-Food Sector
Previous Article in Journal
Nanophosphor-Based Contrast Agents for Spectral X-ray Imaging
Article Menu

Export Article

Open AccessArticle

Natural Born Laser Dyes: Excited-State Intramolecular Proton Transfer (ESIPT) Emitters and Their Use in Random Lasing Studies

1
Institut de Chimie et Procédés pour l’Energie, l’Environnement et la Santé (ICPEES), UMR CNRS 7515, Ecole Européenne de Chimie, Polymères et Matériaux (ECPM), 25 Rue Becquerel, CEDEX 02, 67087 Strasbourg, France
2
CEISAM, UMR CNRS 6230, BP 92208, 2 rue de la Houssinière, CEDEX 03, 44322 Nantes, France
3
Advanced Materials Engineering and Modeling Group, Wroclaw University of Science and Technology, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw, Poland
*
Authors to whom correspondence should be addressed.
Nanomaterials 2019, 9(8), 1093; https://doi.org/10.3390/nano9081093
Received: 27 June 2019 / Revised: 21 July 2019 / Accepted: 25 July 2019 / Published: 30 July 2019
  |  
PDF [7151 KB, uploaded 30 July 2019]
  |  

Abstract

A series of five excited-state intramolecular proton transfer (ESIPT) emitters based on a 2-(2′-hydroxyphenyl) benzoxazole (HBO) scaffold, functionalized with a mono-or bis-(trialkylsilyl) acetylene extended spacer are presented. Investigation of their photophysical properties in solution and in the solid-state in different matrix, along with ab initio calculations gave useful insights into their optical behavior. Random lasing studies were conducted on a series of PMMA doped thin films, showing the presence of stimulated emission above the threshold of pumping energy density (ρth ≈ 0.5–2.6 mJ cm−2). In this work, the similarity of four level laser systems is discussed in light of the ESIPT photocycle. View Full-Text
Keywords: ESIPT; random lasing; fluorescence; ab initio calculations; excited states ESIPT; random lasing; fluorescence; ab initio calculations; excited states
Figures

Figure 1

This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

Supplementary material

SciFeed

Share & Cite This Article

MDPI and ACS Style

Massue, J.; Pariat, T.; M. Vérité, P.; Jacquemin, D.; Durko, M.; Chtouki, T.; Sznitko, L.; Mysliwiec, J.; Ulrich, G. Natural Born Laser Dyes: Excited-State Intramolecular Proton Transfer (ESIPT) Emitters and Their Use in Random Lasing Studies. Nanomaterials 2019, 9, 1093.

Show more citation formats Show less citations formats

Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Nanomaterials EISSN 2079-4991 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top