Complete Benzene Oxidation over Mono and Bimetallic Pd—Au Catalysts on Alumina-Supported Y-Doped Ceria
Abstract
:Featured Application
Abstract
1. Introduction
2. Materials and Methods
2.1. Catalyst Synthesis
2.2. Catalyst Characterization
2.3. Catalytic Measurements
3. Results
3.1. Catalytic Activity Measurements
3.1.1. Effect of Preparation Method of CeO2/Al2O3 and Y-CeO2/Al2O3 on CBO Activity of Gold-Based Catalysts
3.1.2. Role of the Type of Noble Metal on CBO
3.1.3. Role of the Nature of Support
3.2. Catalyst Characterization
3.2.1. Textural Properties
3.2.2. PXRD measurements
3.2.3. XPS Measurements
3.2.4. TPR
3.2.5. EPR Investigation
4. Discussion
5. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample | SBET (m2·g−1) | Vpore (cm3·g−1) | Dpore (nm) | Dceria (nm) | αceria (nm) |
---|---|---|---|---|---|
γ-Al2O3 | 200 | 0.53 | 10.6 | - | - |
Au/Al | 204 | 0.51 | 10.0 | - | - |
Pd/Al | 195.8 | 0.52 | 9.7 | - | - |
Pd-Au/Al | 193.7 | 0.52 | 9.6 | - | - |
CeO2 | 63.0 | 0.29 | 20.3 | - | - |
Au/Ce | 65.0 | 0.28 | 17.1 | 4.9 | 0.5418(7) |
Pd/Ce | 67.6 | 0.28 | 16.5 | 6.2 | 0.5424(4) |
Pd-Au/Ce | 62.5 | 0.29 | 22.5 | 5.1 | 0.5421(7) |
CeAl | 165.0 | 0.39 | 9.5 | - | - |
Au/CeAl | 147.9 | 0.39 | 9.8 | 6.2 | 0.5426(1) |
Pd/CeAl | 161.2 | 0.45 | 9.5 | 5.8 | 0.5424(1) |
Pd-Au/CeAl | 151.6 | 0.37 | 9.6 | 5.6 | 0.5425(1) |
YCeAl | 168.0 | 0.43 | 10.0 | - | - |
Au/YCeAl | 160.0 | 0.39 | 9.7 | 6.2 | 0.5428(1) |
Pd/YCeAl | 166.4 | 0.40 | 9.6 | 5.8 | 0.5420(1) |
Pd-Au/YCeAl | 157.9 | 0.38 | 9.6 | 5.8 | 0.5425(1) |
Au/CeAl IM | 127.0 (142 *) | 0.27 | 8.6 | 16.8 | 0.5398(1) |
Au/YCeAl IM | 125.0 (135 *) | 0.27 | 8.7 | 12.6 | 0.5402(7) |
Catalyst | Ce 3d5/2 (eV) | Au 4f7/2 (eV) | Pd 3d5/2 (eV) | Y 3d5/2 (eV) | Au/Pd (1.1) * | Y/Pd (0.28) * | Y/Au (0.25) * | Ce3+/(Ce3++Ce4+) |
---|---|---|---|---|---|---|---|---|
Au/Ce | 882.1 | 84.5 | - | - | - | - | - | 0.30 |
Au/CeAl | 881.9 | 84.3 | - | - | - | - | - | 0.22 |
Au/YCeAl | 881.7 | 84.5 | - | 157.8 | - | - | 1.1 | 0.31 |
Pd/Al | - | - | 336.7 | - | - | - | - | - |
Pd/Ce | 881.7 | - | 337.1 | - | - | - | - | 0.35 |
Pd/CeAl | 881.8 | - | 336.6 | - | - | - | - | 0.25 |
Pd/YCeAl | 881.8 | - | 336.7 | 157.8 | - | 0.21 | - | 0.38 |
Pd-Au/Al | - | 84.4 | 336.5 | - | 0.21 | - | - | - |
Pd-Au/Ce | 881.7 | 84.2 | 337.0 | - | 0.46 | - | - | 0.41 |
Pd-Au/CeAl | 881.9 | 84.2 | 336.7 | - | 0.20 | - | - | 0.29 |
Pd-Au/YCeAl | 881.7 | 84.3 | 336.7 | 158.2 | 0.18 | 0.23 | 1.2 | 0.33 |
Catalyst | HC (mmol·g−1) |
---|---|
Au/Ce | 0.54 |
Au/CeAl | 0.26 |
Au/YCeAl | 0.32 |
Pd/Ce | 0.43 |
Pd/CeAl | 0.23 |
Pd/YCeAl | 0.29 |
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Tabakova, T.; Ilieva, L.; Petrova, P.; Venezia, A.M.; Karakirova, Y.; Liotta, L.F.; Avdeev, G. Complete Benzene Oxidation over Mono and Bimetallic Pd—Au Catalysts on Alumina-Supported Y-Doped Ceria. Appl. Sci. 2020, 10, 1088. https://doi.org/10.3390/app10031088
Tabakova T, Ilieva L, Petrova P, Venezia AM, Karakirova Y, Liotta LF, Avdeev G. Complete Benzene Oxidation over Mono and Bimetallic Pd—Au Catalysts on Alumina-Supported Y-Doped Ceria. Applied Sciences. 2020; 10(3):1088. https://doi.org/10.3390/app10031088
Chicago/Turabian StyleTabakova, Tatyana, Lyuba Ilieva, Petya Petrova, Anna Maria Venezia, Yordanka Karakirova, Leonarda Francesca Liotta, and Georgi Avdeev. 2020. "Complete Benzene Oxidation over Mono and Bimetallic Pd—Au Catalysts on Alumina-Supported Y-Doped Ceria" Applied Sciences 10, no. 3: 1088. https://doi.org/10.3390/app10031088