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Open AccessArticle

Influence of Various Climatic Conditions on the Structural Changes of Semicrystalline PLA Spun-Bonded Mulching Nonwovens during Outdoor Composting

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Centre of Advanced Technologies of Human-Friendly Textiles “Pro Humano Tex”, Department of Material and Commodity Sciences and Textile Metrology, Faculty of Material Technologies and Textile Design, Lodz University of Technology, ul. Zeromskiego 116, 90-924 Lodz, Poland
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University of Agriculture in Krakow, al. Mickiewicza 21, 31-120 Krakow, Poland
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Agricultural University—Plovdiv, 12 Mendeleev Blvd, 4000 Plovdiv, Bulgaria
*
Author to whom correspondence should be addressed.
Polymers 2019, 11(3), 559; https://doi.org/10.3390/polym11030559
Received: 23 February 2019 / Revised: 20 March 2019 / Accepted: 22 March 2019 / Published: 25 March 2019
This study analyzed the structural changes of semicrystalline polylactide (PLA) in the form of spun-bonded mulching nonwovens, during outdoor composting. The investigation was carried out at the microstructural, supramolecular and molecular levels using scanning electron microscopy (SEM), wide-angle X-ray diffraction (WAXD) and the viscosity method, respectively. The obtained experimental results revealed how the popular outdoor composting method, realized under two different European climatic conditions (in Poland and in Bulgaria), affects the degradation of PLA nonwoven, designed for agriculture use. The results showed the insignificant influence of the climatic conditions and prepared compost mixtures on the molecular and micromorphological structure of PLA spun-bonded mulching nonwovens, with a visible increase in crystallinity after the first year of composting. Significant changes were observed only after the second year of composting, which indicates the resistance of semicrystalline PLA to degradation in outdoor composting conditions. View Full-Text
Keywords: biopolymers and renewable polymers; polylactide (PLA); degradation; composting; nonwovens; crystallization; crystal form; microstructure evolution biopolymers and renewable polymers; polylactide (PLA); degradation; composting; nonwovens; crystallization; crystal form; microstructure evolution
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Puchalski, M.; Siwek, P.; Panayotov, N.; Berova, M.; Kowalska, S.; Krucińska, I. Influence of Various Climatic Conditions on the Structural Changes of Semicrystalline PLA Spun-Bonded Mulching Nonwovens during Outdoor Composting. Polymers 2019, 11, 559.

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