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Catalysts 2019, 9(3), 240;

Ball Milling-Assisted Synthesis of Ultrasmall Ruthenium Phosphide for Efficient Hydrogen Evolution Reaction

Key Laboratory for Advanced Materials and Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China
Department of Applied Chemistry, School of Science, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter (Xi’an Jiaotong University), Xi’an Key Laboratory of Sustainable Energy Materials Chemistry and State Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University, Xi’an 710049, China
Authors to whom correspondence should be addressed.
Received: 16 February 2019 / Revised: 1 March 2019 / Accepted: 1 March 2019 / Published: 5 March 2019
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The development of scalable hydrogen production technology to produce hydrogen economically and in an environmentally friendly way is particularly important. The hydrogen evolution reaction (HER) is a clean, renewable, and potentially cost-effective pathway to produce hydrogen, but it requires the use of a favorable electrocatalyst which can generate hydrogen with minimal overpotential for practical applications. Up to now, ruthenium phosphide Ru2P has been considered as a high-performance electrocatalyst for the HER. However, a tedious post-treatment method as well as large consumption of solvents in conventional solution-based synthesis still limits the scalable production of Ru2P electrocatalysts in practical applications. In this study, we report a facile and cost-effective strategy to controllably synthesize uniform ultrasmall Ru2P nanoparticles embedded in carbon for highly efficient HER. The key to our success lies in the use of a solid-state ball milling-assisted technique, which overcomes the drawbacks of the complicated post-treatment procedure and large solvent consumption compared with solution-based synthesis. The obtained electrocatalyst exhibits excellent Pt-like HER performance with a small overpotential of 36 mV at current density of 10 mA cm−2 in 1 M KOH, providing new opportunities for the fabrication of highly efficient HER electrocatalysts in real-world applications. View Full-Text
Keywords: mechanochemistry; hydrogen evolution; electrocatalysts; ruthenium phosphide mechanochemistry; hydrogen evolution; electrocatalysts; ruthenium phosphide

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Liu, X.; Guo, Y.; Zhan, W.; Jin, T.L. Ball Milling-Assisted Synthesis of Ultrasmall Ruthenium Phosphide for Efficient Hydrogen Evolution Reaction. Catalysts 2019, 9, 240.

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