Au Clusters Supported on Defect-Rich Ni-Ti Oxides Derived from Ultrafine Layered Double Hydroxides (LDHs) for CO Oxidation at Ambient Temperature
Abstract
:1. Introduction
2. Results and Discussion
2.1. Characterization of Ni-Ti LDH/SiO2
2.2. Characterization of Ni-Ti MMO/SiO2
2.3. Characterization of Au/Ni-Ti MMO/SiO2
2.4. Catalytic Activity for CO Oxidation
2.5. Evaluation of Oxygen Vacancies on Ni-Ti MMO/SiO2
2.6. Temperature-Programmed Reaction of CO
2.7. CO Oxidation in Humid Air
3. Materials and Methods
3.1. Catalyst Preparation
3.1.1. Materials
3.1.2. Ni-Ti LDH/SiO2
3.1.3. Au/Ni-Ti MMO/SiO2 (LDH-DP and MMO-DP)
3.1.4. Au/Ni-Ti MMO/SiO2 (LDH-DPU and MMO-DPU)
3.1.5. Au/bulk Ni-Ti MMO
3.2. Characterization
3.3. CO Oxidation
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Entry | Catalyst | Loading/wt% 1 | Au Size 2/nm | T1/23/°C | ||
---|---|---|---|---|---|---|
Au | Ni | Ti | ||||
1 | LDH-DP | 0.24 | 15 | 2.0 | 4.0 ± 1.5 | 115 |
2 | LDH-DPU | 0.28 | 15 | 2.6 | 2.3 ± 2.0 | 10 |
3 | MMO-DP | 0.15 | 15 | 2.9 | 1.7 ± 0.5 | 38 |
4 | MMO-DPU | 0.3 | 15 | 2.0 | 3.5 ± 1.8 | 191 |
5 | Au/Ni-Ti LDH/SiO2 | 0.28 | 15 | 2.6 | 3.5 ± 1.2 | 182 |
6 | LDH-DPU-300 | 0.28 | 15 | 2.6 | – | 87 |
7 | LDH-DPU-400 | 0.28 | 15 | 2.6 | – | 11 |
8 | Au/Ni-Ti MMO/SiO2 (Ni/Ti = 2/1) | 0.25 | 32 | 2.0 | 6.0 ± 2.1 4 | 65 |
9 | Au/bulk Ni-Ti MMO | 0.23 | – | – | 3.2 ± 1.3 | 24 |
10 | Au/TiO2 | 0.96 | – | – | 4.1 ± 2.2 | 10–20 |
11 | Au/NiO | 0.93 | – | – | – 5 | 57 |
12 | Au/SiO2 | 1.00 | – | – | 6.6 ± 2.7 | >300 |
13 | Au/Fe2O3 | 0.81 | – | – | 1.8 ± 0.7 | 36 |
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Takahashi, A.; Nakayama, A.; Murayama, T.; Sakaguchi, N.; Shimada, T.; Takagi, S.; Ishida, T. Au Clusters Supported on Defect-Rich Ni-Ti Oxides Derived from Ultrafine Layered Double Hydroxides (LDHs) for CO Oxidation at Ambient Temperature. Catalysts 2023, 13, 1155. https://doi.org/10.3390/catal13081155
Takahashi A, Nakayama A, Murayama T, Sakaguchi N, Shimada T, Takagi S, Ishida T. Au Clusters Supported on Defect-Rich Ni-Ti Oxides Derived from Ultrafine Layered Double Hydroxides (LDHs) for CO Oxidation at Ambient Temperature. Catalysts. 2023; 13(8):1155. https://doi.org/10.3390/catal13081155
Chicago/Turabian StyleTakahashi, Ayu, Akihiro Nakayama, Toru Murayama, Norihito Sakaguchi, Tetsuya Shimada, Shinsuke Takagi, and Tamao Ishida. 2023. "Au Clusters Supported on Defect-Rich Ni-Ti Oxides Derived from Ultrafine Layered Double Hydroxides (LDHs) for CO Oxidation at Ambient Temperature" Catalysts 13, no. 8: 1155. https://doi.org/10.3390/catal13081155