Effect of Support on Oxidative Esterification of 2,5-Furandiformaldehyde to Dimethyl Furan-2,5-dicarboxylate
Abstract
:1. Introduction
2. Results and Discussion
2.1. Catalysts Characterization
2.2. Effect of the Calcination Temperature of the Catalyst
2.3. Effect of Reaction Temperature
2.4. Catalytic Performance of Au/Mg3Al-HT on Different Substrates
2.5. Stability of Au/Mg3Al-HT Catalyst
3. Materials and Methods
3.1. Materials
3.2. Preparation of the Catalyst
3.3. Catalytic Evaluation
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Entry | Substrate | Solvent | Conv. | (di)Ester | Monoester | Monoacetal | Monoester-Monoacetal | (di)Acetal |
---|---|---|---|---|---|---|---|---|
entry 1 | FF 1 | methanol | 100.00 | 97.23 | / | / | / | 2.77 |
entry 2 | BzH 2 | methanol | 100.00 | 99.01 | / | / | / | 0.99 |
entry 3 | DFF | methanol | 100.00 | 97.78 | / | / | / | 2.22 |
entry 4 | DFF | ethanol | 100.00 | 54.61 | 12.89 | 6.47 | 24.45 | 1.57 |
entry 5 | DFF | n-butanol | 94.02 | 6.65 | 3.76 | 82.59 | 6.99 | / |
entry 6 | DFF | 1-pentanol | 59.24 | / | 2.60 | 34.56 | 62.84 | / |
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Ge, T.; Liu, X.; Tang, J.; Liu, C.; Huang, J. Effect of Support on Oxidative Esterification of 2,5-Furandiformaldehyde to Dimethyl Furan-2,5-dicarboxylate. Catalysts 2023, 13, 1430. https://doi.org/10.3390/catal13111430
Ge T, Liu X, Tang J, Liu C, Huang J. Effect of Support on Oxidative Esterification of 2,5-Furandiformaldehyde to Dimethyl Furan-2,5-dicarboxylate. Catalysts. 2023; 13(11):1430. https://doi.org/10.3390/catal13111430
Chicago/Turabian StyleGe, Tingting, Xiaorui Liu, Jie Tang, Chao Liu, and Jiahui Huang. 2023. "Effect of Support on Oxidative Esterification of 2,5-Furandiformaldehyde to Dimethyl Furan-2,5-dicarboxylate" Catalysts 13, no. 11: 1430. https://doi.org/10.3390/catal13111430