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Article

Rhodium-Catalyzed Aqueous Biphasic Olefin Hydroformylation Promoted by Amphiphilic Cyclodextrins

1
Univ. Artois, CNRS, Centrale Lille, ENSCL, Univ. Lille, Unité de Catalyse et Chimie du Solide (UCCS), UMR 8181, rue Jean Souvraz, F-62307 Lens, France
2
Laboratoire de Glycochimie des Antimicrobiens et des Agroressources, LG2A UMR 7378 CNRS, Université de Picardie Jules Verne, 33 rue Saint-Leu, 80039 Amiens, France
*
Author to whom correspondence should be addressed.
Catalysts 2020, 10(1), 56; https://doi.org/10.3390/catal10010056
Received: 5 December 2019 / Revised: 18 December 2019 / Accepted: 20 December 2019 / Published: 1 January 2020
(This article belongs to the Special Issue Supramolecules for Catalysis)
Hydroformylation is an industrial process that allows for the production of aldehydes from alkenes using transition metals. The reaction can be carried out in water, and the catalyst may be recycled at the end of the reaction. The industrial application of rhodium-catalyzed aqueous hydroformylation has been demonstrated for smaller olefins (propene and butene). Unfortunately, larger olefins are weakly soluble in water, which results in very low catalytic activity. In an attempt to counteract this, we investigated the use of amphiphilic oleic succinyl-cyclodextrins (OS-CDs) synthesized from oleic acid derivatives and maleic anhydride. OS-CDs were found to increase the catalytic activity of rhodium during the hydroformylation of water-insoluble olefins, such as 1-decene and 1-hexadecene, by promoting mass transfer. Recyclability of the catalytic system was also evaluated in the presence of these cyclodextrins. View Full-Text
Keywords: cyclodextrin; hydroformylation; water cyclodextrin; hydroformylation; water
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MDPI and ACS Style

Cocq, A.; Bricout, H.; Djedaïni-Pilard, F.; Tilloy, S.; Monflier, E. Rhodium-Catalyzed Aqueous Biphasic Olefin Hydroformylation Promoted by Amphiphilic Cyclodextrins. Catalysts 2020, 10, 56. https://doi.org/10.3390/catal10010056

AMA Style

Cocq A, Bricout H, Djedaïni-Pilard F, Tilloy S, Monflier E. Rhodium-Catalyzed Aqueous Biphasic Olefin Hydroformylation Promoted by Amphiphilic Cyclodextrins. Catalysts. 2020; 10(1):56. https://doi.org/10.3390/catal10010056

Chicago/Turabian Style

Cocq, Aurélien, Hervé Bricout, Florence Djedaïni-Pilard, Sébastien Tilloy, and Eric Monflier. 2020. "Rhodium-Catalyzed Aqueous Biphasic Olefin Hydroformylation Promoted by Amphiphilic Cyclodextrins" Catalysts 10, no. 1: 56. https://doi.org/10.3390/catal10010056

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