A Self-Assembled Electro-Active M8L4 Cage Based on Tetrathiafulvalene Ligands
LUNAM Université, Université d'Angers, CNRS UMR 6200, Laboratoire MOLTECH-Anjou, 2 bd Lavoisier, 49045 Angers Cedex, France
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Materials 2014, 7(1), 611-622; https://doi.org/10.3390/ma7010611
Received: 29 November 2013 / Revised: 9 January 2014 / Accepted: 9 January 2014 / Published: 22 January 2014
(This article belongs to the Special Issue Supramolecular Cage Complexes)
Two self-assembled redox-active cages are presented. They are obtained by coordination-driven self-assembly of a tetra-pyridile tetrathiafulvalene ligand with cis-M(dppf)(OTf)2 (M = Pd or Pt; dppf = 1,1′-bis(diphenylphosphino)ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both species are fully characterized and are constituted of 12 electro-active subunits that can be reversibly oxidized.
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Keywords:
self-assembly; metalla-cages; metal-driven; tetrathiafulvalene; redox
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MDPI and ACS Style
Goeb, S.; Bivaud, S.; Croué, V.; Vajpayee, V.; Allain, M.; Sallé, M. A Self-Assembled Electro-Active M8L4 Cage Based on Tetrathiafulvalene Ligands. Materials 2014, 7, 611-622. https://doi.org/10.3390/ma7010611
AMA Style
Goeb S, Bivaud S, Croué V, Vajpayee V, Allain M, Sallé M. A Self-Assembled Electro-Active M8L4 Cage Based on Tetrathiafulvalene Ligands. Materials. 2014; 7(1):611-622. https://doi.org/10.3390/ma7010611
Chicago/Turabian StyleGoeb, Sébastien; Bivaud, Sébastien; Croué, Vincent; Vajpayee, Vaishali; Allain, Magali; Sallé, Marc. 2014. "A Self-Assembled Electro-Active M8L4 Cage Based on Tetrathiafulvalene Ligands" Materials 7, no. 1: 611-622. https://doi.org/10.3390/ma7010611
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