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Functional Energy Accumulation, Photo- and Magnetosensitive Hybridity in the GaSe-Based Hierarchical Structures

1
Faculty of Electrical Engineering, Czestochowa University of Technology, Al. Armii Krajowej 17, 42-200 Częstochowa, Poland
2
Institute of Applied Mathematics and Fundamental Sciences, Lviv Polytechnic National University, Bandera Str. 12, 79013 Lviv, Ukraine
3
Theoretical Physics Department, Ivan Franko Lviv National University, 8 street Cyril and Methodius, 79005 Lviv, Ukraine
*
Author to whom correspondence should be addressed.
Energies 2020, 13(17), 4321; https://doi.org/10.3390/en13174321
Received: 23 June 2020 / Revised: 9 August 2020 / Accepted: 13 August 2020 / Published: 20 August 2020
(This article belongs to the Section Energy Storage and Application)
We report on the complex GaSe-based hierarchical structures GaSe(CS(NH2)2), GaSe(SmCl3) and GaSe(CS(NH2)2(SmCl3)) synthesized by an intercalation method. The conductive properties of synthesized clathrates and their relation to hierarchical structural complexity were explored by an impedance spectroscopy technique. The impedance response, thermostimulated discharge spectra, and photo- and magnetoresistive effects are reported. Based on the obtained results, the impurity energy spectra were calculated. A strong low-frequency inductive response, observable in the GaSe(SmCl3) clathrate, makes this material promising for the development of gyrator-free nanodelay lines potentially applicable in nanoelectronics. Hierarchical GaSe(CS(NH2)2(SmCl3)) clathrate, on the other hand, reveals hysteresis of the current–voltage characteristics, apparently confirming an accumulation of electric energy at interphase boundaries. A relevant spin battery effect, observable experimentally in stationary magnetic fields, demonstrates a principal possibility of the electric energy accumulation at a quantum level. View Full-Text
Keywords: hierarchical architecture; supramolecular ensemble; impedance spectroscopy; photoresistivity; magnetoresistivity; spin battery effect hierarchical architecture; supramolecular ensemble; impedance spectroscopy; photoresistivity; magnetoresistivity; spin battery effect
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MDPI and ACS Style

Chabecki, P.; Całus, D.; Ivashchyshyn, F.; Pidluzhna, A.; Hryhorchak, O.; Bordun, I.; Makarchuk, O.; Kityk, A.V. Functional Energy Accumulation, Photo- and Magnetosensitive Hybridity in the GaSe-Based Hierarchical Structures. Energies 2020, 13, 4321. https://doi.org/10.3390/en13174321

AMA Style

Chabecki P, Całus D, Ivashchyshyn F, Pidluzhna A, Hryhorchak O, Bordun I, Makarchuk O, Kityk AV. Functional Energy Accumulation, Photo- and Magnetosensitive Hybridity in the GaSe-Based Hierarchical Structures. Energies. 2020; 13(17):4321. https://doi.org/10.3390/en13174321

Chicago/Turabian Style

Chabecki, Piotr, Dariusz Całus, Fedir Ivashchyshyn, Anna Pidluzhna, Orest Hryhorchak, Ihor Bordun, Oleksandr Makarchuk, and Andriy V. Kityk 2020. "Functional Energy Accumulation, Photo- and Magnetosensitive Hybridity in the GaSe-Based Hierarchical Structures" Energies 13, no. 17: 4321. https://doi.org/10.3390/en13174321

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