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N,N-bis(2-quinolinylmethyl)benzylamine

School of Chemistry and Physics, University of KwaZulu-Natal, Private Bag X01, Scottsville, Pietermaritzburg 3209, South Africa
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Academic Editor: Rodrigo Abonia
Molbank 2021, 2021(2), M1208; https://doi.org/10.3390/M1208
Received: 23 March 2021 / Revised: 14 April 2021 / Accepted: 15 April 2021 / Published: 2 May 2021
(This article belongs to the Section Structure Determination)
N,N-bis(2-quinolinylmethyl)benzylamine (1) was synthesized under basic conditions from a pseudo-three-component reaction between benzylamine and two molecules of 2-(quinolinylmethyl)chloride, resulting in the formation of two N–C bonds in a single step. Compound (1) crystallizes in the triclinic system of the P-1 space group. The unit cell comprises a dimer of 1, in which the monomers are linked by two complementary hydrogen bonds between N1 and H′1–C′1 of another molecule. The dimers form chains along the a-axis through intermolecular interactions between the N′2 acceptor atoms and C″17 donors from molecules in the nearest neighboring dimer. These interactions form extended sheets of the dimers of 1, along the ab plane. The quinolinylmeth-2-yl groups of 1 lie in almost orthogonal planes and their N1/2(q) donor atoms are away from the apical amino N3 atom. View Full-Text
Keywords: bis(2-quinolinylmethyl)benzylamine; crystal structure; hydrogen bonds; van der Waal bis(2-quinolinylmethyl)benzylamine; crystal structure; hydrogen bonds; van der Waal
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MDPI and ACS Style

Hunter, L.A.; Naidoo, S.; Mambanda, A. N,N-bis(2-quinolinylmethyl)benzylamine. Molbank 2021, 2021, M1208. https://doi.org/10.3390/M1208

AMA Style

Hunter LA, Naidoo S, Mambanda A. N,N-bis(2-quinolinylmethyl)benzylamine. Molbank. 2021; 2021(2):M1208. https://doi.org/10.3390/M1208

Chicago/Turabian Style

Hunter, Leigh A.; Naidoo, Shivani; Mambanda, Allen. 2021. "N,N-bis(2-quinolinylmethyl)benzylamine" Molbank 2021, no. 2: M1208. https://doi.org/10.3390/M1208

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