Design and Synthesis Strategy of MXenes-Based Anode Materials for Sodium-Ion Batteries and Progress of First-Principles Research
Abstract
:1. Introduction
2. Design and Synthesis Strategy of Anode Materials for MXenes-Based Sodium-Ion Batteries
2.1. Design and Synthesis of Elementally-Doped MXenes-Based Materials
2.2. Design of MXenes-Based Binary Composite Synthesis
2.2.1. Hydrothermal Methods
2.2.2. Electrostatic Assembly Method
2.2.3. In Situ Synthesis Method
2.2.4. Other Synthesis Strategies
2.3. Design and Synthesis of MXene-Based Ternary Composites
Serial Number | Material Composition | Preparation Method | First Charge (mAh g−1) | First Discharge (mAh g−1) | Cycling Performance | Rate Capability | References |
---|---|---|---|---|---|---|---|
1 | S-doped Ti3C2Tx | Vacuum freeze drying | 821.7 | 970 | 577 mAh g−1 after 500 cycles | [17] | |
2 | S-doped Ti3C2Tx | Electrostatic self-assembly | 325 | 135 mAh g−1 after 1000 cycles at 2.0 A g−1 | 136.6 mAh g−1 at 5 A g−1 | [18] | |
3 | S-doped mesoporous Ti3C2Tx film | Electrostatic self-assembly | 354.6 | 345.6 mAh cm−3 after 5000 cycles at 1 A g−1 | 129.2 m Ah g−1 at 1 A g−1 | [20] | |
4 | N-doped Ti3C2Tx | Electrostatic self-assembly | 132.6 | 338.5 | 123.4 mAh g−1 after 5000 cycles at 1 A g−1 | 120 mAh g−1 at 1 A g−1 | [24] |
5 | N-doped Ti3C2Tx | Electrostatic self-assembly | 1844.7 | 284.2 mAh g−1 after 1000 cycles at 5.0 C | 180.5 mAh g−1at 25 C | [25] | |
6 | VO2/MXenes | Hydrothermal method | 229.2 | 280.9 mAh g−1 after 200 cycles at 0.1 A g−1 | 206 mAh g−1 at 1.6 A g−1 | [29] | |
7 | NaTi8O13/NaTiO2 | Two-step hydrothermal method | 125 | 162 | 82 mAh g−1 after 1900 cycles at 2.0 A g−1 | 143 mAh g−1 at 0.1 A g−1 | [30] |
8 | MoSe2/MXene | Hydrothermal method combined with thermal annealing process | 578 | 826 | 384 mAh g−1 after 400 cycles at 2.0A g−1 | 490 mAh g−1 at 1.0A g−1 | [31] |
9 | SnS/Ti3C2Tx | Hydrothermal method combined with thermal annealing process | 348.4 | 495.0 | 320 mAg−1 after 50 cycles at 500 mAg−1 | 255.9 mAh g−1 at 1000 mA g−1 | [32] |
10 | CoNiO2/MXene | Hydrothermal method combined with thermal annealing process | 463 | 223 mAh g−1 after 140 cycles at 0.1 A g−1 | 188 mAh g−1 at 0.3 A g−1 | [33] | |
11 | VO2-NTs/Ti3C2 | Electrostatic self-assembly | 1164 | 2132 | 516 mAh g−1 after 2000 cycles at 5.0 A g−1 | 703 mAh g−1 at 10.0 A g−1 | [35] |
12 | Ti3C2Tx/CNT | Electrostatic self-assembly | 179 | 501 | 120 mAh g−1 after 500 cycles at 0.1 A g−1 | [36] | |
13 | PDDA-BP/Ti3C2 | Electrostatic self-assembly | 1780 | 2588 | 1112 mAh g−1 after 500 cycles at 0.1 A g−1 | 560 mAh g−1 at 1 A g−1 | [37] |
14 | TiO2@Ti3C2Tx | Electrostatic self-assembly | 233.9 | 497.1 | 116 mAh g−1 after 5000 cycles at 0.96 A g−1 | 177 mAh g−1 at 0.12 A g−1 | [40] |
15 | M-SnP-In | In situ synthesis | 438.2 | 436.6 mAhg−1 after 1500 cycles at 2 Ag−1 | 438.2 mAhg−1 at 15 A g−1 | [41] | |
16 | T-MXene@C | In situ synthesis | 580.6 | 499.4 mAh g−1 after 200 cycles at 0.2 C | 478 mAh g−1 at 0.2 C (1 C = 320 mA g−1) | [44] | |
17 | a-VOx/V2C | In situ synthesis | 161 | 54 mAh g−1 after 1800 cycles at 2000 mA g−1 | 96 mAh g−1 at 2 Ah g−1 | [48] | |
18 | Cu1.75Se—MXene—CNRib | Microbial electrostatic assembly | 744.2 | 1353.1 | 305.6 mAh g−1 after 400 cycles at 1.0 A g−1 | 435.3, 356.2, 315.7, 274.3, 232.6, and 161.3 mAh g−1 at 0.1 to 5.0 A g−1 | [49] |
19 | Nb2CTx/MoS2/CS | Electrostatic self-assembly method + template method | 1270 | 526 mAh g−1 after 100 cycles at 0.1 A g−1 394 mAh g−1 after 900 cycles at 1 A g−1 | 196 mAh g−1 at 20 A g−1 | [50] | |
20 | MXene@CoS2/NC | In situ growth method + template method | 660 | 885 | 620 mAhg−1 after 200 cycles at 0.2 A g−1 | 708, 614, 551, 438, and 394 mAh g−1 at 0.2, 0.5, 1, 2, and 5 A g−1 | [51] |
3. First-Principles Study of Anode Materials for MXenes-Based Sodium-Ion Batteries
3.1. MXenes Theoretical Computational Study of the Electronic Structure of the Material
3.2. Theoretical Computational Study of Elementally Doped MXenes Materials
3.3. Theoretical Computational Study of MXenes Matrix Composites
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
Sample Availability
References
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Su, D.; Zhang, H.; Zhang, J.; Zhao, Y. Design and Synthesis Strategy of MXenes-Based Anode Materials for Sodium-Ion Batteries and Progress of First-Principles Research. Molecules 2023, 28, 6292. https://doi.org/10.3390/molecules28176292
Su D, Zhang H, Zhang J, Zhao Y. Design and Synthesis Strategy of MXenes-Based Anode Materials for Sodium-Ion Batteries and Progress of First-Principles Research. Molecules. 2023; 28(17):6292. https://doi.org/10.3390/molecules28176292
Chicago/Turabian StyleSu, Dan, Hao Zhang, Jiawei Zhang, and Yingna Zhao. 2023. "Design and Synthesis Strategy of MXenes-Based Anode Materials for Sodium-Ion Batteries and Progress of First-Principles Research" Molecules 28, no. 17: 6292. https://doi.org/10.3390/molecules28176292