Synthesis, Structure, and Photophysical Properties of Yellow-Green and Blue Photoluminescent Dinuclear and Octanuclear Copper(I) Iodide Complexes with a Disilanylene-Bridged Bispyridine Ligand
Abstract
:1. Introduction
2. Results and Discussion
2.1. Synthesis and Crystal Structure of Cu Complexes 2 and 3
2.2. Photophysical Properties
2.3. Theoretical Consideration
3. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Sample Availability
References
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Complex | 2 | 3 |
---|---|---|
λem/nm | 519 | 478 |
/eV [a] | 0.46 | 0.43 |
Φ[b] | 0.60 | 0.04 |
τ/µs | 11 | 2.6 |
kr /s−1 [c] | 5.5 × 104 | 1.5 × 104 |
knr /s−1 [d] | 3.6 × 104 | 3.7 × 105 |
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Nakae, T.; Miyabe, H.; Nishio, M.; Yamada, T.; Yamanoi, Y. Synthesis, Structure, and Photophysical Properties of Yellow-Green and Blue Photoluminescent Dinuclear and Octanuclear Copper(I) Iodide Complexes with a Disilanylene-Bridged Bispyridine Ligand. Molecules 2021, 26, 6852. https://doi.org/10.3390/molecules26226852
Nakae T, Miyabe H, Nishio M, Yamada T, Yamanoi Y. Synthesis, Structure, and Photophysical Properties of Yellow-Green and Blue Photoluminescent Dinuclear and Octanuclear Copper(I) Iodide Complexes with a Disilanylene-Bridged Bispyridine Ligand. Molecules. 2021; 26(22):6852. https://doi.org/10.3390/molecules26226852
Chicago/Turabian StyleNakae, Toyotaka, Hiroto Miyabe, Masaki Nishio, Teppei Yamada, and Yoshinori Yamanoi. 2021. "Synthesis, Structure, and Photophysical Properties of Yellow-Green and Blue Photoluminescent Dinuclear and Octanuclear Copper(I) Iodide Complexes with a Disilanylene-Bridged Bispyridine Ligand" Molecules 26, no. 22: 6852. https://doi.org/10.3390/molecules26226852