Search Results (40,719)

In order to create a safe and healthy working environment in mines, an issue that urgently needs to be addressed is the rapid discharge of high concentrations of toxic and harmful pollutants after blasting. This paper proposes a deep well rapid purification system based on the combination of nanobubble water spray and water bath/wire mesh carbon, and conducts single-variable optimization tests on the parameters of micro-nano bubble water and the atomizing nozzle. The wet spray fiber grid and carbon adsorption network form in sequence and verify the purification experiment under the clear optimal parameters. The results show that the micro-nano bubble water is used as the spray medium, and a high-pressure nozzle with a diameter of 0.4 mm is also used. The water supply pressure of the nozzle is 3.0 MPa, the wet spray fiber grid uses a double-layer 10-mesh metal wire, and the carbon adsorption network uses 5 mm activated carbon fiber cotton as the optimal parameter for the deep well rapid purification system. Under these conditions, the efficiency of total dust and exhalation dust reduction is 72.90% and 79.17%, respectively, and the purification efficiency of CO, H₂S, and SO₂ reaches 84.39%, 78.75%, and 55.54%, respectively. This study provides reference data for efficient pollution reduction in mines and has high practical value. Full article

This article examines how everyday architecture can advance spatial justice in post-active conflict cities through ethnographic and participatory design. Drawing on a decade of work by the StreetSpace studio in Belfast (2015–2025), the paper explores how architecture students and community participants co-design spatial strategies that enhance mixed-use mid-density living, inclusive mobility, and street-level accessibility. In a context where car dominance, segregation, and privatisation of public space continue to fragment urban life, the everyday street becomes a testbed for envisioning an equitable and community-centred city. The studio’s methodology is grounded in ethnographic engagement, informed by an embedded anthropologist, and includes stakeholder mapping, walking workshops, and collaborative drawing. These practices reveal lived experiences and shape community-driven briefs for housing, schools, public spaces, and multifunctional infrastructure. Anchored in spatial justice discourse and feminist theory (Jane Jacobs, David Harvey, Roberto Rocco, Phil Hubbard, Leslie Kern, and Caroline Criado Perez), the work positions the everyday as a site of architectural agency and proposes a contemporary vernacular that is socially embedded and climate-resilient. This work unfolds through complex and often contested processes that require sustained, iterative engagement with people and places. Meaningful collaboration is neither linear nor inherently caring; it frequently involves conflict, disagreement, and competing priorities that must be navigated over time. Through long-term relationships with government departments, local authorities, and NGOs, StreetSpace demonstrates how architectural pedagogy can nonetheless contribute to policy formation and more inclusive urban redevelopment by engaging in compromise, critical negotiation, and moments of care alongside friction and resistance. Through a series of collaborations and public events the project has contributed to the transformation of Botanic Avenue, informed studies of the East Belfast Greenways through contributions to Groundswell and participated in embedded public processes in collaboration with PPR, culminating in an exhibition at the MAC in Belfast in 2025. Full article

Primula vulgaris Huds., one of the 33 Primula L. species native to Europe, occurs across diverse habitats, including the biodiversity hotspot of the Prespa Lake region (NW Greece). Building on previous phytochemical studies, the present work provides the first detailed characterization of flavonoids from the aerial parts of the species growing wild in the area. Using classical chromatographic separation methods combined with spectrometric techniques, seven metabolites were isolated and structurally elucidated from the dichloromethane and methanol extracts. These included flavone (1), 2′-methoxyflavone (2), 3′-methoxyflavone (3), 3′-hydroxy-4′,5′-dimethoxyflavone (4), kaempferol-3-O-β-glucopyranosyl-(1→2)-β-glucopyranosyl-(1→6)-β-glucopyranoside (6), 3′-hydroxyflavone-4′-O-β-glucopyranoside (7) and 5,6,2′,3′,6′-pentamethoxyflavone (5), which was reported for the first time in this species. Additionally, the total phenolic content (TPC) of the methanol extract was determined using the Folin–Ciocalteu method, demonstrating 46.46 ± 2.48 mg GAE/g extract, while through the DPPH radical scavenging assay, it expressed moderate activity. Overall, these results provide novel insights into the flavonoid composition of Greek P. vulgaris and support its potential for further pharmacological investigations and herbal applications. Full article

Superabsorbent polymers (SAPs) are materials that can absorb and retain water solutions with a mass of several hundred times greater than their own. This work aimed to synthesise and evaluate the effects of highly absorbent starch phosphate-g-poly(acrylic acid) copolymers on the microbiological activity of soils previously used for agriculture. The biopolymers studied were obtained by thermal and chemical oxidation of starch phosphates and copolymerized with potassium salts of acrylic acid. Basic physicochemical parameters were determined in the applied soil. Following SAP application, the basal respiration rate was measured at 22 °C with a constant soil moisture content of 60% WHC. The incubation time in constant temperature and moisture conditions was 78 days. After this period, their microbiological activity (microbial and organic phosphorus fractions) was assessed, thereby enabling the determination of the direction of change in the soil environment. The addition of SAP increases the soil’s water-holding capacity and respiration. The SP-g-PAA polymers serve as slow-release sources of potassium and phosphorus ions. These elements were bound to the polymer network by ionic and covalent bonds. Analysis of the results shows that within two weeks, 47–80% of the starch hydrogel undergoes microbial degradation. No differences were found in the content of labile forms of phosphorus in soils with SAP additions compared to soils without polymer additions. The use of modified starch reduces the consumption of vinyl monomers, while the resulting product is characterised by high absorbency and low water content, which reduces the amount of energy needed to obtain the finished product, thus contributing to sustainable development. Full article

Therapeutic approaches using virtual reality (VR) have been effective in recovering function against various physical and cognitive disorders. Given its programmability and precise activity tracking, VR is a powerful tool for therapists to personalize treatments and monitor their patients more effectively. Due to the growing prevalence of VR systems for personal and work uses, and the high reliability of broadband telecommunication, the opportunity to standardize remote delivery of VR therapies is apparent. VR-based rehabilitation has high potential to be a cornerstone approach for remote therapies given critical features: (1) accessibility for home users, (2) patient–therapist engagement, (3) capacity for personalization, and (4) capabilities for precision monitoring. Unlike prior reviews that summarize established measures of efficacy of VR-based rehabilitation for various clinical populations, this perspective highlights the potency of applying VR rehabilitation methods remotely and ways to expand and optimize that usage such as its integration with wearables for monitoring and AI. Moreover, this paper restricts its focus to VR as opposed to augmented (AR) or mixed-mode (MR) reality platforms that are also increasing their prevalence in clinical settings. This perspective article broadly overviews VR-based therapies for rehabilitating physical and cognitive function for various disorder cases before postulating their potential as an effective platform for delivering remote treatment. This article concludes with essential considerations for advancing VR-based remote therapy in the future. Full article

Li/fluorinated carbon (CF_x) batteries have attracted considerable attention in the field of energy storage owing to their excellent energy density and long storage life. However, the development of CF_x cathodes is restricted by their poor conductivity at high degrees of fluorination. Herein, ZIF-8-based fluorinated carbon with a well-developed network structure was fabricated via gas-phase fluorination and acid treatment. Moreover, treatment at a low fluorination temperature of 180 °C for 4 h and acid washing endowed the obtained fluorinated carbon (HFG@ZIF-8) with a high F/C (1.62), favorable specific surface area (207 m² g⁻¹), unique porous channels, and highly electrochemically active C–F bonds, resulting in a maximum specific capacity (1143.4 mAh g⁻¹) and energy density (2614.8 Wh kg⁻¹) at 0.02 C. The superior Li⁺ transport efficiency, with diffusion coefficients ranging from 1.47 × 10⁻¹¹ to 1.93 × 10⁻¹⁷ cm² s⁻¹, enables HFG@ZIF-8 to deliver 453.4 mAh g⁻¹ at 5 C with no voltage delay. Therefore, this work provides an innovative strategy for the preparation of high-performance CF_x cathodes. Full article

The efficient conversion of CO₂ into valuable chemicals using highly efficient, environmentally friendly, and renewable heterogeneous catalysts is paramount for the progression of a carbon circular economy. In pursuit of this goal, this study introduces a metal-free, scalable melamine-based organic polymer catalyst designed to integrate CO₂ adsorption with customizable functional properties. Employing both solid-state thermal synthesis (SST) and hydrothermal methods, we synthesized three amine-based hydrogen bond donor catalysts, thereby balancing environmentally conscious practices with scalable synthesis: MCA, a high-nitrogen-content polymer derived from trichlorocyanuric acid; MCA-SST; and MTAB, a triazine-trichlorocyanuric acid polymer. Under mild conditions (100 °C, 0.1 MPa, 24 h), MCA demonstrated superior catalytic performance in the CO₂ cycloaddition of epichlorohydrin, achieving a 99% conversion rate, significantly surpassing MCA-SST (60%) and MTAB (78%). MCA’s high specific surface area and structural integrity facilitate efficient catalysis under mild conditions, and it retains 79% of its initial activity after five cycles, indicating exceptional stability. These results suggest that while the incorporation of secondary amines and increased nitrogen content generally promote the reaction, densely packed adjacent secondary amine linkages can induce repulsion between nitrogen atoms, thereby weakening active sites and reducing catalytic activity. Consequently, this study not only presents MCA as a novel metal-free catalyst exhibiting remarkable performance in catalyzing CO₂ cycloaddition under ambient pressure and mild conditions, but also elucidates the structure–activity relationship between secondary amine density and catalytic activity. This work provides a deeper mechanistic understanding and offers a theoretical foundation for future rational catalyst design. Full article

Background/Objectives: Although cyberbullying among adolescents has been widely studied, relatively little attention has been paid to the overlapping roles through which cyberbullying is experienced. This study reconceptualizes cyberbullying involvement by classifying perpetration, victimization, and witnessing into eight mutually exclusive involvement types, enabling systematic and non-overlapping comparison of adolescents’ experiences. The study further examines how engagement in individual-level cyber-risk indicators is associated with different patterns of cyberbullying involvement. Methods: The study analyzed nationally representative data from the 2022 Cyberbullying Survey conducted by the Korea National Information Society Agency, including 9693 students from elementary, middle, and high schools across South Korea. Individual-level cyber-risk indicators were assessed through multiple dimensions, including risky online behaviors, intensity of digital activity, peer environments, and awareness of harmful online behaviors. Multinomial logistic regression analyses were conducted to examine associations between individual-level cyber-risk indicators and the eight types of cyberbullying involvement. Results: Engagement in individual-level cyber-risk indicators was associated with increased odds of involvement in at least one cyberbullying type. Risky online behaviors and exposure to peers engaging in cyberbullying were linked to higher likelihood of both single and overlapping involvement patterns, whereas greater acceptance of harmful online behaviors was consistently associated with lower odds of victimization. Conclusions: These findings underscore cyberbullying as a relational and context-dependent phenomenon shaped by everyday digital practices and peer norms rather than isolated individual behavior. From a school social work perspective, the results support preventive, environment-focused interventions, including school-based media literacy education and institutionalized cyberbullying response systems, as promising strategies for reducing cyberbullying involvement among adolescents. Full article

Intracellular transport is essential for cellular organization and function. This process is driven by molecular motors that ferry cargo along microtubules, but is characterized by intermittent motility, where cargoes switch between directed runs and prolonged pauses. The fundamental nature of these pauses has remained a mystery, specifically whether they are periods of motor detachment and passive drifting or states of active motor engagement. By combining single-particle tracking with large-scale motion analysis, we discovered that pauses are not passive. Instead, they are active, motor-driven states. We uncovered a unifying quantitative law: the diffusivity of a vesicle during a pause scales with the square of its velocity during a run. This parabolic relationship, D_eff ∝ v², holds true for both kinesin and dynein motors, different cargo types, and a variety of cellular perturbations. We show that this coupling arises because the number of engaged motors governs motility in both states. When we reduce motor engagement, vesicles move more slowly and become trapped in longer, less mobile pauses, collectively causing them to fail to reach their destination. Our work redefines transport pauses as an essential, motor-driven part of microtubule-based cargo delivery, revealing a quantitative principle that contributes to robust cargo transport through the crowded cellular environment. Full article

In this work, four different magnetic Fe₃O₄ nanoparticles are prepared via solvothermal method. According to the morphology, the products can be divided into flower-like Fe₃O₄ (F-Fe₃O₄), solid spherical Fe₃O₄ (S-Fe₃O₄), hollow spherical Fe₃O₄ (HO-Fe₃O₄), and hexahedral Fe₃O₄ (HE-Fe₃O₄). A set of measurements is performed to confirm the structure, composition, and pore properties of the obtained materials. The catalytic activities of the prepared materials are examined and compared. The results prove that the four materials have an intrinsic catalytic property. HO-Fe₃O₄ ranks first in the catalytic activity mainly due to its large surface area and reasonable element composition. The maximum specific saturation magnetization and specific surface area of HO-Fe₃O₄ are 72.94 emu/g and 42.60 m²/g. Fe²⁺/Fe³⁺ in HO-Fe₃O₄ is 51.5%. It is found that HO-Fe₃O₄ possesses fantastic stability and perfect reproducibility as it is used as a catalyst several times without significant loss in its activity. Full article

CO₂ flooding is an effective technique for enhancing oil recovery in low-permeability reservoirs. However, it is often hindered by severe CO₂ channeling. This challenge is particularly pronounced in near-wellbore regions with large pressure differentials and in fractured reservoirs, where high CO₂ injection rates and rapid breakthrough require channel blocking systems with high mechanical strength and excellent CO₂-resistant performance. In this work, a smart responsive polymer was synthesized and subsequently crosslinked with a highly active phenolic resin crosslinking agent to develop a smart responsive polymer gel channel blocking system. The resulting gel exhibits CO₂-responsive strength enhancement and excellent CO₂-resistant performance. The static and dynamic gelation behaviors, nonlinear rheological properties, CO₂-resistant performance, channel blocking, and enhanced oil recovery performance of the smart responsive polymer gel were systematically investigated. The results demonstrate that the polymer gel maintains good structural stability during dynamic transport in the reservoir and does not undergo significant strength degradation under shear conditions. Moreover, the smart responsive polymer gel exhibits excellent CO₂-resistant performance within a temperature range of 80–110 °C, salinity up to 10 × 10⁴ mg/L, and pressure up to 20 MPa. Moreover, the system shows a significant enhancement in channel blocking and enhanced oil recovery performance, highlighting its promising potential for effective CO₂ flooding channel blocking in low-permeability reservoirs. Full article

Greenhouse gases (GHG), accumulated in the atmosphere, are the main cause of climate change. In 2017, the increase in average temperature was about 1 °C (between 0.8 °C–1.2 °C) above pre-industrial levels. Global warming refers to the increase in air surface, sea surface, and soil surface temperature and according to IPCC (Intergovernmental Panel Climate Change), since the industrial revolution, C emissions are due to land use changes like deforestation, biomass burning, conversion of natural lands, drainage of wetlands, soil cultivation, and tillage. As the world population has increased, world food production has risen too with a subsequent increase in GHG emissions and agricultural production, which is worsened by climate change. Negative consequences are well known such as the loss in water availability and in soil fertility, and pest infestations which are climate change’s effects on agriculture activity. Climate change’s main aftermath is the frequency of extreme weather events influencing crop yields. As climate change exacerbates degradation processes, land management can mitigate its impact and aid adaptation strategies for climate change. About 21–37% of GHGs have been caused by the agriculture activity, so the application of Nature-based Solutions (NbS) like sustainable agriculture could be a way to reduce GHGs worldwide. The aim of this article is to review how NbS may mitigate GHG emissions from soil, with solutions defined as an integrated approach to tackle climate change and to sustainably restore and manage ecosystems, delivering multiple benefits. NbS is a low-cost tool working within and with nature, which holds many benefits for people and the environment. Full article

This study investigates the effects of polypropylene microplastics (PP-MPs) and copper (Cu), applied individually and in combination, on the growth (root and shoot length, fresh and dry biomass), peroxidase (POD) activity, and Cu accumulation of rice seedlings. A hydroponic experiment was conducted with four treatments: control (CK), PP, Cu, and PP+Cu. Exposure to PP-MPs slightly promoted seedling growth, whereas Cu markedly inhibited growth and induced chlorosis. Compared with Cu alone, co-exposure to PP-MPs and Cu (PP+Cu) partially improved shoot growth and alleviated Cu-induced suppression of shoot POD activity. In contrast, root POD activity showed the strongest reduction under PP+Cu (91.7% decrease), revealing a pronounced root–shoot divergence in antioxidant responses. Moreover, total Cu accumulation in seedlings increased by 12.3% in PP+Cu relative to Cu alone, implying that PP-MPs may influence Cu bioavailability and/or internal partitioning. However, Cu speciation and subcellular distribution were not quantified in this study and should be examined in future work. Overall, PP-MPs may simultaneously enhance Cu uptake while partially mitigating shoot-level toxicity, underscoring the complexity of microplastic–metal co-contamination in rice seedling systems. Full article

This review focuses on chemesthetic perception (i.e., pungency, tingling, and astringency) in extra virgin olive oil (EVOO), with particular attention to the sensory mechanisms underlying trigeminal stimulation elicited by phenolic secoiridoids, considering olive-fruit ripening as a key modulating factor. The chemesthetic profile represents one of the most distinctive sensory features of EVOO and is primarily associated with phenolic secoiridoids derivatives, formed through enzymatic transformations of ligstroside and oleuropein. Generally, a progressive decrease in chemesthetic potential is observed during ripening, due to the reductions in total phenols, o-diphenols, and secoiridoids. Among these compounds, secoiridoid derivatives, most notably oleocanthal and oleacin, elicit chemesthetic sensations and represent some of the most biologically active EVOO phenolic constituents. In this context, chemesthetic perception may work as a sensory marker of phenolic richness and nutraceutical value, linking sensory science with olive ripening and informed consumer choice. Moreover, integrating chemesthetic mechanisms with phenolic chemistry, olive ripening physiology, and sensory methodology allows for a more comprehensive interpretation of EVOO quality beyond commercial classifications. Future studies combining chemical profiling, dynamic sensory methods, and consumer-focused research will be essential to refine quality-assessment tools and promote a deeper appreciation of the sensory diversity and functional value of high-quality EVOOs. Full article

The presence of emerging organic contaminants in water and effluents, including antibiotics, poses significant environmental and health risks. Moreover, while photocatalysis is a promising approach for their removal, the inefficient utilization of natural sunlight by common photocatalysts limits its large-scale use. This work demonstrates the enhanced sunlight-driven photodegradation of the antibiotic Ciprofloxacin (CIP) using a nanocomposite composed of carbon dots (CDs) and TiO₂ (NC_50:50). The CDs were obtained from corn stover, a major agricultural waste product. Initial testing was performed under artificial solar radiation: CIP was virtually fully degraded within 20 min, with a rate constant of 0.2372 min⁻¹ and a 217% enhancement of catalytic activity over commercial TiO₂. Validation under real-world irradiation conditions was subsequently made by performing photocatalytic assays under natural sunlight on different days under diverse meteorological conditions. The performance of NC_50:50 was retained, degrading CIP within 30 min under natural conditions. Notably, while degradation by-products were identified under both artificial and natural sunlight, they were subsequently photodegraded by the nanocomposite under these conditions. This enhanced performance was attributed to a combination of effects resulting from CDs’ incorporation, namely, improved absorption of visible light, enhanced charge separation, and increased specific surface area. Furthermore, the addition of CDs resulted in changes in the reactive species generation profile, which can alter the available degradation pathways. Thus, this study provides insight that can be useful for strategies aimed at the rational design of sunlight-active TiO₂-based photocatalysts with tunable surface reactivity. Full article