Search Results (137)

Fire-resistant coatings have emerged as crucial materials for reducing fire hazards in various industries, including construction, textiles, electronics, and aerospace. This review provides a comprehensive account of recent advances in fire-resistant coatings, emphasizing environmentally friendly and high-performance systems. Beginning with a classification of traditional halogenated and non-halogenated flame retardants (FRs), this article progresses to cover nitrogen-, phosphorus-, and hybrid-based systems. The synthesis methods, structure–property relationships, and fire suppression mechanisms are critically discussed. A particular focus is placed on bio-based and waterborne formulations that align with green chemistry principles, such as tannic acid (TA), phytic acid (PA), lignin, and deep eutectic solvents (DESs). Furthermore, the integration of nanomaterials and smart functionalities into fire-resistant coatings has demonstrated promising improvements in thermal stability, char formation, and smoke suppression. Applications in real-world contexts, ranging from wood and textiles to electronics and automotive interiors, highlight the commercial relevance of these developments. This review also addresses current challenges such as long-term durability, environmental impacts, and the standardization of performance testing. Ultimately, this article offers a roadmap for developing safer, sustainable, and multifunctional fire-resistant coatings for future materials engineering. Full article

Dou-Gong brackets, the distinctive structural element in ancient Chinese architecture, fulfill critical roles in load transfer, span reduction, and decoration, making its preservation vital for safeguarding wooden heritage buildings. This study investigates the combustion performance and residual load-bearing capacity of key Dou-Gong bracket components—Zuo-dou, Zheng-xin-gua-gong, and Qiao—exposed to varying fire conditions. The results reveal that an increasing fire load elevates heating rates and peak temperatures of wood substrates, resulting in a significant degradation of structural integrity. At a fire load of 55 kW, the peak temperatures at the bottom, joint edge, and top of the Dou-Gong brackets reach 755.3 °C, 489.9 °C, and 620.7 °C, respectively, representing increases of 2%, 65%, and 38%, respectively, compared to those observed at a fire load of 20 kW. Moreover, the charring rate of Dou-Gong bracket increases from 0.22–0.26 mm/min at a fire load of 20 kW to 0.50–0.56 mm/min at a fire load of 55 kW, accompanied by an increase in mass loss rate from 28.5% to 36.9%. These findings highlight the significant impact of fire conditions on the fire characteristic and structural integrity of Dou-Gong brackets, providing the first quantitative evidence of their degradation under fire exposure. By addressing this vulnerability, the study contributes to the scientific preservation of ancient wooden architecture under contemporary fire risk scenarios. Full article

The pyrolysis of non-recyclable construction, renovation, and demolition (CRD) wood waste is a complex thermochemical process involving devolatilization, diffusion, phase transitions, and char formation. CRD wood, a low-ash biomass containing 24–32% lignin, includes both hardwood and softwood components, making it a viable heterogeneous feedstock for bioenergy production. Thermogravimetric analysis (TGA) of CRD wood residues was conducted at heating rates of 10, 20, 30, and 40 °C/min up to 900 °C, employing model-fitting (Coats–Redfern (CR)) and model-free (Ozawa–Flynn–Wall (OFW), Kissinger–Akahira–Sunose (KAS), and Friedman (FM)) approaches to determine kinetic and thermodynamic parameters. The degradation process exhibited three stages, with peak weight loss occurring at 350–400 °C. The Coats–Redfern method identified diffusion and phase interfacial models as highly correlated (R² > 0.99), with peak activation energy (E_a) at 30 °C/min reaching 114.96 kJ/mol. Model-free methods yielded E_a values between 172 and 196 kJ/mol across conversion rates (α) of 0.2–0.8. Thermodynamic parameters showed enthalpy (ΔH) of 179–192 kJ/mol, Gibbs free energy (ΔG) of 215–275 kJ/mol, and entropy (ΔS) between −60 and −130 J/mol·K, indicating an endothermic, non-spontaneous process. These results support CRD wood’s potential for biochar production through controlled pyrolysis. Full article

Recent research has focused on developing environmentally friendly flame-retardant coatings to improve the fire resistance of wood. In this study, phytic acid–guanazole (PG), a dual-functional compound synthesized through an ionic reaction between phytic acid and guanazole, was added to KH550-modified urea–formaldehyde resin (KUF) as both a curing agent and flame retardant. The $-{\mathrm{PO}}_4^{3-}$ groups from phytic acid act as an acid source to accelerate char formation during combustion, while the −NH₂ groups introduced by guanazole release non-combustible gases to dilute oxygen in the air, synergistically enhancing flame retardancy. Additionally, the hygroscopic $-{\mathrm{PO}}_4^{3-}$ groups absorb free water in the resin, reducing the curing temperature and accelerating coating solidification. The KH550 coupling agent improves compatibility between KUF and PG while introducing silicon, which forms SiO₂ during combustion to strengthen the char layer and further enhance flame resistance. Evaluations showed that PG outperforms conventional tannic acid (TA) in curing efficiency and fire resistance. Comprehensive analyses, including Differential Scanning Calorimetry (DSC), Limiting Oxygen Index (LOI), vertical flame tests, and cone calorimetry, confirmed PG’s dual functionality. Scanning Electron Microscope (SEM) and Raman spectroscopy revealed that PG-modified coatings form denser post-combustion char layers, directly linked to improved fire resistance. As a multifunctional additive, PG eliminates the need for separate curing agents and utilizes bio-based phytic acid, offering cost-effective and sustainable advantages for industrial applications. Full article

In this study we present an application of wood biomass—alder wood char—as the carbon precursor for the synthesis of novel and sustainable nitrogen-doped activated-carbon-supported nickel nanoparticle catalyst (AWC-Ni-N) for hydrazine oxidation. For comparison, the wood-based carbon material doped with nitrogen only (AWC-N) was also synthesized. Extensive characterization, including SEM, Raman spectroscopy, XPS, and XRD revealed the catalysts’ microstructure and properties. Electrochemical testing demonstrated that the AWC-Ni-N catalyst significantly enhanced the efficiency of the hydrazine oxidation reaction. In addition, direct N₂H₄-H₂O₂ single-fuel-cell tests were conducted using the prepared AWC-N and AWC-Ni-N catalysts as the anodes and cathodes. Peak power densities of up to 10.8 mW cm⁻² were achieved at 25 °C, corresponding to a current density of 27 mA cm⁻² and a cell voltage of 0.4 V when the AWC-Ni-N catalyst was used as both the anode and cathode. Furthermore, the peak power density increased by approximately 1.6 and 2.9 times, respectively, when the operating temperature was raised from 25 °C to 55 °C for the AWC-N and AWC-Ni-N catalysts. Overall, the AWC-N and AWC-Ni-N catalysts demonstrated significant potential as anode and cathode materials in direct N₂H₄-H₂O₂ fuel cells. Full article

This study presents a comprehensive assessment of the morphology and porosity of microstructured charcoal using a combination of scanning electron microscopy (SEM), computed tomography (CT), and mercury intrusion porosimetry (MIP) methods. SEM analysis revealed a parallel arrangement of tube-like structures interspersed with smaller pores, confirming the presence of fibrous formations. MIP evaluation was conducted in two research series. MIP results identified macropores as the primary contributors to mercury intrusion; however, a minor volume of mercury also intrudes to the mesopores. The total pore area was determined to range between 70.7 and 88.5 m²·g⁻¹, with porosity values of approximately 58.0–62.4% across different experimental series. These variations highlight the heterogeneous nature of the sample. Additionally, the uniformity of the charring process during dry wood distillation was indicated by wall thickness measurements, which ranged narrowly from 5.7 to 25 µm. Full article

Extended producer responsibility (EPR) and the circular economy can address the growing challenge of managing wood-based waste in the context of sustainability. This research explores pyrolysis as an effective method for converting wood-based waste, i.e., bamboo flooring (BF) and high-density fiberboard floor panels (HDF), into valuable products, particularly char. Char samples were activated through two distinct methods: (1) thermal activation at 700 and 850 °C and (2) chemical activation with KOH. Analytical techniques, including elemental and heavy metals analysis, FTIR, Raman spectroscopy, SEM, and TEM were used to assess the chemical composition and surface characteristics of the produced chars. Elemental analysis showed a notable rise in the amount of carbon to 81% and 75% in BF and HDF, respectively. The nitrogen content was relatively high in HDF at 5.12%. Heavy metals analysis revealed total metal contents ranging from 3632 to 9494 ppm in BF chars and 1717 to 7426 ppm in HDF chars. Raman spectra exhibited characteristic D and G bands, with I_D/I_G ratios of 0.83 for BF and 0.85 for HDF after activation. SEM and TEM analyses revealed heterogeneous porous structures with dominant carbon elements. The high carbon content, low toxicity, and advantageous elemental composition of the chars make them suitable for environmental applications. Full article

This study investigates innovative surface coatings’ effectiveness in enhancing spruce wood’s fire resistance (Picea abies spp.). Spruce wood samples were treated with various agents, including oils, waxes, boric acid, commercial coatings, and fire-retardant agents. The evaluation was conducted using the small flame method (EN ISO 11925-2:2020), surface roughness analysis, hyperspectral imaging (HSI), and contact angle measurements. The results demonstrated significant improvements in fire resistance for samples treated with specific coatings, particularly the Burn Block spray and Caparol coating, which effectively prevented flame spread. The analysis revealed that the Burn Block spray reduced the average flame height to 6.57 cm, while the Caparol coating achieved a similar effect with an average flame height of 6.95 cm. In contrast, untreated samples exhibited a flame height of 9.34 cm, with boric acid-treated samples reaching up to 12.18 cm. Char depth measurements and the surface roughness analysis revealed a clear correlation between the type of treatment and the thermal stability of the wood. Hyperspectral imaging enabled a detailed visualisation of surface degradation, while contact angle measurements highlighted the impact of hydrophobicity on flammability. This research provides in-depth insights into the fire-retardant mechanisms of spruce wood and offers practical guidelines for developing safer and more sustainable wood materials for the construction industry. Full article

Scots pine (Pinus sylvestris L.) sapwood was modified using maleic anhydride (MA) and sodium hypophosphite (SHP) to improve its durability against wood-deteriorating fungi, mechanical strength, and fire retardancy (thermal stability). The modification significantly reduced mass loss caused by wood-decaying fungi (Trametes versicolor, Rhodonia placenta, and soft rot fungi) due to the formation of cross-links between wood, MA, and SHP, which limited the moisture uptake and altered the chemical structure of wood. On the other hand, the modification did not provide improved resistance to fungi growth on the wood surface, which indicated that the modification had little impact on the accessibility of nutrients on the surface. A bending test showed that the modulus of elasticity (MOE) was not affected by the treatment, whilst the modulus of rupture (MOR) decreased to half the value of untreated wood. Thermal resistance was improved, as demonstrated by micro-scale combustion calorimeter testing, where the total heat release was halved, and the residue percentage nearly doubled. These results indicate that phosphonate protects the modified wood via the formation of a protective char layer on the surface and the formation of radical moieties. Based on the results, wood modified with MA and SHP shows potential for possible use in outdoor, non-loadbearing structures. Full article

Wood, in the form of cladding or furniture, is often placed in close proximity to heat radiant sources. This research focused on samples, which are Norway spruce (Picea abies L.), Red spruce (Picea rubens Sarg.), cherry (Prunus avium), and oak (Quercus spp.). The aim of this paper was to observe the effect of the distance of the selected wood samples from the radiant heat source on the process of thermal degradation of wood. Additionally, this research aimed to identify significant effects of wood species and sample distance on this process. A hot-plate device, an electric plate heated according to a temperature–time curve, was used as the initiating source. Samples were placed directly on the plate, as well as at two different distances from the plate (12 and 32 mm). During the experiment, the temperature history on the heat-exposed side of the sample, its mass loss, and the formation of a charred layer were monitored. Additionally, the progression of thermal degradation and related effects (smell, smoldering, and charring layer) were visually observed. The highest level of degradation was observed in the spruce sample placed directly on the plate, which started to smolder after 540 s of exposure to radiant heat at 291.2 °C. Full article

This study evaluates selected flame retardants on the basis of their influence on the change of fire-technical parameters of soft and hard woods (spruce and oak) during exposure to a flame heat source. The parameters evaluated were mass loss, mass loss rate and depth of the charred layer. The experiments were carried out on simple test equipment on which the samples were exposed to direct flame while their mass was monitored. The measured data and their statistical evaluation showed a significant dependence of the mass loss on the type of retardant used (inorganic salt-based flame retardant—IS and intumescent flame retardant—IFR) and on the type of wood species. In spite of the same reaction to fire class specified by the manufacturers for both types of retardants studied, significant differences were observed in the parameters monitored. The mass loss, mass loss rate and charred layer reached much lower values when using IFR retardant, whose efficiency was higher in the order of tens of percent compared to the use of IS retardant. The use of IFR flame retardant reduced the depth of the charred layer on oak samples by up to 84% compared to untreated samples, indicating its high effectiveness and potential to increase the fire resistance of wooden structures. These results show that IFRs are more effective in the parameters studied compared to ISs despite their equal class of reaction to fire, which may have wider implications for the construction industry and highlight the need for a thorough evaluation of flame retardants based on their performance under real-world conditions. Full article

Although the application of biochar to soils has been proposed as a method of carbon sequestration for climate mitigation while improving crop yields, losses of biochar carbon (BC) through mineralization may reduce these benefits. However, few field studies have been conducted that control for biochar migration so that the rates and processes of BC remineralization from soils, as well as the effects of biochar on native soil organic carbon, can be accurately determined. Here, biochar made from different biomass types (oak, pine wood, and grass) and temperatures (lightly charred at 250 °C and pyrolyzed at 400 and 650 °C) were added to fine sandy Entisol in an open agricultural field and Spodosol in a shaded forested site in North Central Florida. After 15 months, BC losses, determined by the Kurth–Mackenzie–Deluca chemical–thermal oxidation method, ranged from 17.5 to 93.3% y⁻¹ (14.0–51.5% y⁻¹ for the 650 °C biochar). These losses were correlated with but much greater than the 0.4–3% y⁻¹ BC losses recorded in a one-year laboratory study using the same biochars and those of several previous field studies (1–14% y⁻¹). The losses of non-BC native carbon stocks (i.e., positive priming) also varied with biochar and soil type and ranged from 1.5 to 15.8% y⁻¹. The high BC losses observed in this study may be attributed to the subtropical and temporally variable climate conditions at the study site. Greater efforts should be made to base BC long-term stability estimates on field studies that monitor or control for biochar migration rather than reliance only upon laboratory incubations. Full article

Carbon emissions accelerate global warming and climate change, prompting the global development of strategies for carbon reduction. Wood, with its excellent carbon storage capacity, is a sustainable and environmentally friendly material. One cubic meter of timber can absorb 1 t of carbon dioxide and store 250 kg of carbon. This study aimed to conduct fire resistance tests on structural glue-laminated timber beams made from Korean larch (Larix kaempferi) and analyze their char properties. The specimens were fabricated with different cross-sectional shapes and areas and underwent load-bearing fire resistance tests. The results were analyzed in terms of char depth, char rate, and changes in char thickness based on the aspect ratio of the beams. In the smaller specimens, the char properties were influenced more by the width than by the length of the beam. Additionally, at a constant cross-sectional area, charring was deeper when the width was shorter than the height. The specimens did not exhibit significant differences in displacement behavior, with all specimens displaying displacements below the maximum permissible value, indicating suitable fire resistance. The findings of this study provide a foundation for research and development of fire resistance design standards for wooden structures utilizing Korean timber. Full article

The growing demand for eco-friendly activated carbon necessitates sustainable production methods. This study investigates the conversion of waste wood into activated carbon using goethite iron ore as an activating agent. A high-temperature rotary furnace was used to activate the carbon at 1373 K. The oxygen released from the iron oxide during the heat treatment reacted with the carbon in the wood, resulting in 49% of activated carbon with BET surface areas between 684 m²/g and 770 m²/g. The activated carbon and char showed type I isotherms with micropore areas between 600 m²/g and 668 m²/g, respectively. Additionally, 92% of the iron in the ore was reduced from ferric to ferrous. The findings demonstrate that goethite iron ore is an effective activating agent for producing wood-based activated carbon while also generating metallic iron as a byproduct. This alternative activation method enhances the sustainability and efficiency of activated carbon production. Full article

As the carbon storage capacity of timber is recognized, there is growing interest in timber and wooden structures as a solution to various environmental problems. The use of Korean timber with substantial carbon storage capacity is required to reduce Korean carbon emissions and circulate timber resources. In this study, fire tests were conducted to investigate the charring properties of glued laminated timber columns made of Korean larch. The fire tests were conducted under both load-bearing and non-load-bearing conditions. The fire test results showed that the charring depth was affected by the corners of the section and that the load ratio had an insignificant influence on the charring depth when the load ratio was 0.9 or less. This study provides data that can be used to compare the charring properties of laminated wood produced using South Korean larch with the charring properties of foreign standards. This research provides reference data for developing fire-resistant design standards for timber structures made from South Korean timber. Full article