Search Results (209)

Monitoring ultraviolet (UV) radiation dose distribution is crucial in many fields, like medicine and materials science, but traditional point-of-care methods limit the ability to fully assess the spatial extent of the irradiated surface. This paper presents the characterisation of a two-dimensional (2D) dosimetry system based on Pluronic F-127 hydrogel matrix doped with 2,3,5-triphenyltetrazolium chloride (TTC) with respect to exposition to UVA radiation. The hydrogel matrix (25% w/w) provides both high transparency and mechanical stability, while TTC (0.1% w/w) functions as a colour precursor that undergoes irreversible reduction to form water-insoluble red formazan upon UVA exposure. The insolubility of TTC formazan ensures that the resulting colour changes remain spatially stable within the dosimeter. The study included sample preparation in flat PMMA containers and analysis of the effect of radiation field uniformity in a UVP CL-1000 exposure chamber. It was supported by application of Kodak X-Omat 100 NIF UV Film dosimetry. The actual dose distribution in the chamber was shown to be significantly heterogeneous (CV coefficient of variation of approximately 18%), which emphasises the need for 2D dosimeters for precise validation of irradiation devices. The use of flatbed scanning and dedicated image analysis software allowed obtaining precise 2D dose distribution maps. The dosimeter was characterised in the dose range of 0–5000 mJ/cm², showing a reproducible response (R² = 0.9967). A resolution test was conducted to assess the precision of geometric representation. In the final stage of the study, the suitability of the developed dosimetry system was verified under conditions simulating heterogeneous UV radiation dose distribution using patterns printed with Computer-to-Film (CtF) technology. The results showed that optical effects in printed films significantly affect UV transmission, limiting accurate dose recording for black coverage above approximately 40–50%. The results obtained confirm that the TTC-Pluronic F-127 system is an effective, simple and low-cost tool for 2D monitoring of UVA radiation, with potential applications in cosmetology, dermatology, and material ageing tests. Full article

The spectral selectivity of underwater multiwavelength single-photon LiDAR offers a promising pathway to discriminate target materials beyond conventional geometric imaging. However, the complex interactions among wavelength-dependent water attenuation, target reflectance, and scattering-induced waveform distortion remain poorly quantified. This study establishes a comprehensive theoretical and experimental framework linking these factors, validated through controlled experiments across two water turbidity levels (attenuation coefficients of 0.1 m⁻¹ and 2.0 m⁻¹), six wavelengths (490–570 nm), and diverse target types. We demonstrate that target ranging bias exhibits a wavelength-dependent linear trend (8.3 ps/nm) in turbid waters. This phenomenon is fundamentally attributable to forward-scattering-induced centroid shifts rather than true spatial displacements, a mechanism we quantify through comparative peak-detection and Gaussian fitting analyses. Contrary to intuitive expectations, we reveal that spectral discrimination efficacy decouples from received photon counts. Principal component analysis confirms that a multidimensional spectral feature space enables accurate target clustering independent of absolute intensity, with specific bands (e.g., 510 nm and 550 nm) exhibiting heightened sensitivity to material signatures. These findings establish that underwater target recognition is primarily influenced by the spectral contrast between target reflectance and water transmission windows, rather than solely depending on received photon counts, providing a robust physical basis for next-generation underwater LiDAR optimization. Full article

In this study, zinc-modified biochar (ZBC) was prepared from rose willow, and NiCoMn-LDHs@ZBC composites were synthesized using a hydrothermal method. The composites were characterized by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) surface area analysis, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). The adsorption mechanism of As(V) from aqueous solution onto NiCoMn-LDHs@ZBC was investigated through a series of arsenic adsorption experiments. The effects of various experimental parameters (including adsorbent composition and ratio, adsorbent dosage, solution pH, contact time, temperature, and coexisting ions) on the adsorption capacity were evaluated. Additionally, adsorption model fitting and kinetic analysis were conducted. The results indicate that the adsorption process follows the pseudo-second-order kinetic model (linear correlation coefficient R² = 0.99), while the isothermal adsorption process adheres to the Langmuir model, with a maximum adsorption capacity of 159.780 mg/g. The adsorption process is primarily dominated by chemisorption and involves three pathways: first, electrostatic attraction between the material surface and arsenic-containing ions; second, ion exchange between arsenic-containing ions and interlayer carbonate ions; and third, coordination reactions between the surface hydroxyl groups (-OH) of NiCoMn-LDHs@ZBC and As, forming As-O-M inner-sphere complexes as adsorption proceeds. Furthermore, the NiCoMn-LDHs@ZBC composite exhibits relatively stable reusability, demonstrating significant potential for the treatment of arsenic pollution in water bodies. Full article

Determining how flow rate and silica nanoparticle addition affect the heat transfer coefficient is the goal of this study. SEM-EDX testing was carried out to obtain the morphologcal structure of nanosilica and the chemical content of nanosilica. Dispersion of silica nanoparticles (SiO₂) with concentrations of 0.1%, 0.2%, and 0.3% in the base fluid of radiator water was carried out using a magnetic stirrer for 1 h. Next, PSA testing was carried out on the silica–water radiator nanofluid to determine the size of the nanosilica particles. Tests were carried out with discharge variations of 2.4, 6 lpm and concentration variations of 0%, 0.1%, 0.2%, and 0.3%. The findings indicate that the fluids without the addition of nanoparticles at a discharge of 2 lpm have the lowest heat transfer coefficient at 7.03 W/m²·°C, and the fluids with a 0.3% silica concentration at a discharge of 6 lpm have the highest heat transfer coefficient at 15.61 W/m²·°C. The coefficient of heat transmission increased by 122%. Full article

The functional performance and structural integrity of natural rock materials under fluctuating environmental stressors are pivotal for their advanced applications. As a non-ionizing and radiation-free technology, terahertz (THz) spectroscopy offers a safe and promising alternative for non-destructive testing (NDT), uniquely capable of being deployed in open and unshielded environments. However, limited penetration depth, exacerbated by both the dense geological matrix and the extreme sensitivity of THz waves to moisture states, has long hindered its widespread application in rock characterization. This study establishes a quantitative Terahertz Time-Domain Spectroscopy (THz-TDS) framework to characterize four lithologies under drying–wetting cycles. Exponential signal attenuation across thicknesses was quantified based on the Beer–Lambert law, with attenuation coefficients ranging from 0.15 to 0.74 per millimeter. Planar transmission imaging successfully visualizes lithologic and moisture-dependent heterogeneity: limestone exhibits a dense, homogeneous structure with stable amplitude distribution; sandstone and purple sandstone show parallel statistical trends, reflecting uniform pore networks; and granite demonstrates the most pronounced imaging contrast under varying moisture states, driven by complex grain-boundary scattering. The findings reveal that THz transmission is dictated by the synergistic effects of mineral compositions and pore structures: scattering at grain boundaries and fractures leads to significant energy dissipation, whereas clay-rich lithologies exhibit the highest sensitivity to moisture variations due to water adsorption and interfacial polarization effects. As an exploration of THz technology in the non-destructive evaluation of rock materials, these findings establish an analytical framework for the quantitative assessment of microstructure evolution. Full article

Nine sets of fin parameter combinations, including a plain tube control group, were modeled. Simulations were performed under steady-state conditions using the EWT Realizable k-ε turbulence model, with benzene and water as working fluids, while accounting for temperature-dependent thermophysical properties. Flow field distribution, temperature profile, Nusselt number, and pressure drop in the shell side of the heat exchanger were analyzed. Response surface methodology was employed to systematically evaluate the coupled effects of fin height and fin spacing on thermal performance. The results indicate that annular fins significantly enhance heat transfer by inducing secondary flow and disrupting the thermal boundary layer. Compared to the smooth tube, the finned tubes increased the Nusselt number (Nu) by up to 28.6% and the total heat transfer rate by 13.55%, while the pressure drop (ΔP) increased by approximately 9.81% to 16.5%. The analysis revealed that fin height is the dominant factor affecting performance, whereas fin spacing plays a regulatory role. As the fins became taller or denser, the temperature field evolved from stable stratification to intense mixing and eventually to local disorder. The study identified an optimal parameter range for engineering applications. A fin height of 2–3 mm combined with a spacing of 10–15 mm achieves the best balance between heat transfer enhancement and flow resistance. Specifically, the combination of h = 3 mm and s = 10 mm yielded the highest Energy Efficiency Coefficient (EEC) of 1.567. This configuration is recommended for large-flow, pressure-drop-sensitive systems, such as those found in petrochemical plants or long-distance heat transmission applications. Full article

In Hungary, a fast-growing Empress tree hybrid (×Paulownia Clone in vitro 112) also known as Smaragdfa^® has been developed as a low-density plantation species seeking industrial utilization. Many potential industrial applications presuppose its bonding. The presence of adhesives in bonded layered assemblies, with differing climatic conditions on the internal and outer side, may induce undesired internal strains due to restricted water vapor diffusion, especially in the case of Smaragdfa as a low-density wood species. For decades, lasures have been specifically formulated with a molecular structure that allows partial vapor transmission while hindering water diffusion. Lasure-coated samples were used as control samples to identify, among the different custom-made MW adhesives, the one with diffusion properties closest to those of the lasure. Uncoated Smaragdfa wood samples were used as the baseline reference to evaluate the effect of different adhesive and coating systems on water vapor diffusion. Smaragdfa samples were prepared both uncoated and coated with different adhesive and lasure layers. Experiments were conducted following ISO 12572 and ASTM E96 standards using the cup method, with all specimens pre-conditioned to 12% moisture content. Results showed that the uncoated Smaragdfa exhibited the highest diffusion coefficient (δ = 7.02 × 10⁻¹³ kg/(m·s·Pa)) and flow rate (G = 0.055763 g/h), while the commercial adhesive-coated sample displayed an 84% reduction in diffusion capacity (δ = 1.15 × 10⁻¹³ kg/(m·s·Pa)), indicating a strong vapor-blocking effect. The lasure coating allowed partial vapor transmission, confirming its semi-permeable nature. Adhesives formulated with varying polyol molecular weights (Series 1–5) revealed a clear molecular-weight-dependent diffusion behavior: low-MW systems (S1) acted as strong diffusion barriers comparable to lasure-coated samples (SMW_L), in the same time high-MW systems (S4, S5) permitted excessive diffusion but induced microcracking, while intermediate formulations (S2, S3) achieved the most balanced performance, combining moderate diffusion with structural stability. Overall, the findings confirm that adhesive layers significantly influence water vapor transmission through Smaragdfa wood, with the degree of hindrance closely related to the molecular weight of the polyol matrix. The optimized formulations (S2, S3) demonstrate promising potential for use in bonded assemblies and engineered wood products where controlled vapor diffusion and mechanical reliability are critical in order to support reduced strains caused by water vapor. Full article

Resonant Wave Energy Converter 1 (REWEC1) is a submerged caisson breakwater integrating a device designed to absorb incoming wave energy. Although the wave energy-extraction performance of this system and its hydraulic characteristics have been extensively investigated, its potential role in reducing coastal inundation, as an alternative to traditional rubble-mound breakwaters, has not yet been examined. In this context, the present study analyzes the mitigation effects on coastal flooding induced by the installation of REWEC1 barriers. The analysis focuses on the coast of Cetraro, located along the Tyrrhenian Sea in the province of Cosenza (Calabria, Southern Italy). The effectiveness of REWEC1 farms in reducing coastal flooding was assessed by considering fixed-air and no-air operation modes, as well as different spatial configurations. The input wave conditions were propagated in the nearshore using the SWAN model to simulate wave–structure interactions, while the XBeach model was employed to investigate coastal inundation processes based on the wave field behind the caissons, also accounting for Sea Level Rise (SLR). The results were evaluated in terms of maximum flooded areas and water penetration lengths along the emerged coast, as well as wave run-up and set-up along selected transects. To assess the robustness of the results, a sensitivity analysis was carried out by varying the transmission coefficients of the REWEC1 units within a plausible uncertainty range, and the corresponding variability in flooding indicators was quantified. The numerical results indicate a progressive reduction in these hydrodynamic response indicators as the spacing between adjacent REWEC1 devices decreases, and show that the relative mitigation performance of REWEC1 remains consistent when accounting for uncertainties in wave–structure interaction parameters. Further analyses were conducted to compare the effectiveness of REWEC1 farms with that of conventional rubble-mound breakwaters in reducing coastal flooding. Full article

This work presents microwave sensing of ethanol concentration in ethanol–water mixtures using a low-cost 3D-printed cavity resonator. The objective is to realize a customizable liquid sensor that combines high measurement accuracy with inexpensive, in-house fabrication. The cylindrical cavity is fabricated from polylactic acid using fused deposition modeling and metallized on its inner surface with copper tape. The resonator operates in the TM₀₁₀ mode with a resonant frequency of 3 GHz. A standard 1.5 mL centrifuge tube is used as a modular sample holder and inserted through a circular opening in the top endcap of the cavity. The quality factor of the air-filled cavity is 200, which decreases to 37.3 when the cavity is loaded with deionized water. As an application example, ethanol concentrations in ethanol–water mixtures are determined using both the resonant frequency and the peak magnitude of the transmission coefficient (|S₂₁|). For ethanol concentrations between 20% and 100%, the concentration can be accurately extracted from the resonant frequency alone: a quartic calibration curve yields a coefficient of determination $R^2=0.9992$, an average sensitivity of approximately 8.4 MHz/% ethanol, and a mean absolute error of about 0.58% on the calibration set. In addition, a cubic calibration based on the peak $\mid S_{21}\mid$ over the 0–90% concentration range achieves a mean absolute error of approximately 0.52% on the calibration set and about 0.55% on an independent validation set covering 5–85% ethanol. Comparison with conventionally machined metal cavities shows that the proposed 3D-printed cavity achieves a high Q-factor at significantly lower cost and can be fabricated in-house using a standard 3D printer. These results demonstrate metrologically relevant performance in terms of low error and high sensitivity using a low-cost and easily replicable platform for microwave liquid sensing in biomedical and chemical engineering applications. Full article

Currently, wireless sensor networks (WSNs) have been mutually applied to environmental monitoring and industrial control due to their low-cost and low-energy sensor nodes. However, WSNs are composed of a large number of energy-limited sensor nodes, which requires balancing the relationship among energy consumption, transmission delay, and network lifetime simultaneously to avoid the formation of energy holes. In nature, gregarious herbivores, such as the white-bearded wildebeest on the African savanna, employ a “fast-transit and selective-dwell” strategy when searching for water; they cross low-value regions quickly and prolong their stay in nutrient-rich pastures, thereby minimizing energy cost while maximizing nutrient gain. Ants, meanwhile, dynamically evaluate the “energy-to-reward” ratio of a path through pheromone concentration and its evaporation rate, achieving globally optimal foraging. Inspired by these two complementary biological mechanisms, our study proposes a novel ACO-conceptualized optimization model formulated via mixedinteger linear programming (MILP). By mapping the pheromone intensity and evaporation rate into the MILP energy constraints and cost functions, the model integrates discrete decision-making (path selection) and continuous variables (dwell time) by dynamic path planning and energy optimization of mobile sink, constituting multi-objective optimization. Firstly, we can achieve flexible trade-offs between multiple objectives such as data transmission delay and energy consumption balance through adjustable weight coefficients of the MILP model. Secondly, the method transforms complex path planning and scheduling problems into deterministic optimization models with theoretical global optimality guarantees. Finally, experimental results show that the model can effectively optimize network performance, significantly improve energy efficiency, while ensuring real-time performance and extended network lifetime. Full article

Controlling the rheological properties of liquids allows for the regulation of effective movement, transport of substances, and processes in biological systems. This work presents an experimental investigation into the influence of the proton-exchange polymer membrane Nafion on the surface tension coefficient (STC) of distilled water, aqueous solutions of two methylene blue (MB) forms, and ascorbic acid (AA). Immediately upon membrane immersion in the solutions, a sharp decrease in the surface tension of distilled water, as well as of the oxidized and reduced forms of MB, occurs. The observed narrow time interval is associated with the formation of an exclusion zone near the membrane–solution interface, containing dissociated sulfonate groups $\left(\mathrm{S}{\mathrm{O}}_3^{-}\right)$. The value of the time interval depends on the type of aqueous solution. At long soaking of the membrane in solutions, we obtained: for the aqueous solution of Mb⁺ (blue-coloured solution) the STC value eventually increases by about 5%, and for the reduced form of methylene blue MbH⁰-colourless solution, the STC value decreases by 4%. The STC value of the solutions formed during diffusion into the membrane has a significantly lower value compared to the STC of distilled water by 20% for the Mb⁺ form and by 24% for the MbH⁰ form of MB. The presence of the membrane in the aqueous AA solution causes only an increase in the STC value of the solution. Ultimately, for the solution with a concentration of 5 g/L, this increase reached 15% relative to the STC value of the original AA solution. The change in surface tension of the investigated solutions in the presence of the membrane is due to their adsorption onto the membrane surface. Fourier-transform infrared (FTIR) spectroscopy investigation of distilled water, MB, and AA solution diffusion into the membrane across the range (370–7800) cm⁻¹ confirms the process nonlinearity and enables identification of distinct time intervals corresponding to membrane swelling stages. The positions of IR transmission minima for membranes containing water and solution components remain unchanged; only the numerical values of the transmission coefficients vary. Using spectrophotometry, absorption lines of the membrane with adsorbed components of MB and AA solutions were identified in the range of (190–900) nm. The absorption spectra of dried membranes with adsorbed Mb⁺ and AA solutions show a redshift to the IR region for the Nafion with Mb⁺ and a shift to the UV region for the Nafion soaked in an aqueous ascorbic acid solution. A surface tension gradient at the membrane–solution interface can induce concentration-capillary convection in the liquid. Full article

In the present study, thin-layered core–shell Gd₂O₃@SiO_1.5R (R is C₃H₆NH₂) structures were synthesized by gas-phase surface modification of a Gd₂O₃ core with a 3-aminopropyltriethoxysilane (APTES) shell for the first time. The proposed method consists of two consecutive steps carried out in a fixed-bed reactor. The first step involves APTES adsorption on the Gd₂O₃ surface, followed by APTES hydrolysis by water vapor. The organosyloxane shell formation was confirmed by transmission and scanning electron microscopy, IR spectroscopy, and thermogravimetric data. X-ray attenuation coefficients of Gd₂O₃ and Gd₂O₃@SiO_1.5R samples were determined by photon-counting computed tomography in a phantom study. The SiO_1.5R shells in the synthesized Gd₂O₃@SiO_1.5R samples had minimal thickness and did not affect the attenuation coefficients of Gd₂O₃. Full article

Diagnosing water-phase damage remains challenging because routine petrophysical parameters do not capture capillary hysteresis and pressure-transmission effects. In this study, a standardized, auditable workflow was established to link laboratory descriptors to field-relevant cleanup. Full-curve mercury injection capillary pressure data were acquired and converted using consistent Washburn parameters, from which withdrawal efficiency was computed on the withdrawal branch. A pressure-transmission coefficient was evaluated under unified boundary conditions to complement permeability and porosity. After preprocessing and partial least-squares regression (PLSR) screening, MICP descriptors were clustered by k-means (k = 5) to obtain reservoir Types I–V. Regressions relating WE to permeability and flowback behavior were then used to assess engineering relevance. The results indicate that WE capture hysteretic trapping/back-pressure not contained in permeability or porosity and, when interpreted jointly with PTC, differentiates reservoir types by cleanup propensity. This framework provides a reproducible bridge from laboratory MICP hysteresis to field-scale flowback interpretation. Practical implications include prioritization of gas–wet wettability modification, low-surface-tension systems, and minimized early liquid loading for clusters exhibiting higher WE and lower PTC. Full article

This study looks into the parameters that affect the heat transfer coefficient (h₂) on the wet surfaces of vertical tube indirect evaporative coolers (VTIEC). An experimental platform was used to investigate the impact of secondary-to-primary airflow ratios (AFR) and spray water density on the HTC. The findings show that raising the primary air temperature drop, expanding the outside dry-bulb and wet-bulb temperature differences, and decreasing the air-to-water ratio improve heat transmission. The HTC of the wet sides ranged from 34.79 to 924.5 W/(m²·°C) throughout testing. To achieve optimal performance, aim for a spray water density of 2.07 to 3.46 m³/(m²·h), an AFR of 0.5 to 0.6, and a primary air temperature drop of at least 6 °C. These factors help keep the h₂ above 350 W/(m²·°C). Full article

This study numerically investigates wave transformation and setup processes across fringing reefs, focusing on artificial reef configuration effects under varying tidal conditions and incident wave parameters. The OpenFOAM-based waves2Foam model simulates hydrodynamic processes along reef profiles containing a fore-reef slope and reef flat. Following validation against laboratory data, the model simulates cross-shore wave height attenuation and setup within fringing reef systems. The results demonstrate that reef flat water depth substantially modulates wave dynamics: during low tide, intensified wave breaking elevates the maximum wave height and setup by up to 45.7% and 78.5%, respectively, compared to high-tide conditions. Furthermore, this water depth critically governs the reef configuration’s influence on wave energy dissipation efficiency. Under high tide, additional reef rows increase the peak wave height by 5.2% while reducing wave setup by 10.5%. In contrast, expanded reef spacing reduces the peak wave height by 2.1% and decreases the peak wave setup by 2.4%. The temporal evolution of wave reflection ($K_R$) and transmission ($K_T$) coefficients reveals that shallow-water conditions amplify wave reflection while diminishing transmission capacity, as tidal variations directly regulate wave propagation mechanisms through water depth modulation. At the outer reef flat boundary, $K_R$ and $K_T$ values for existing artificial reefs exhibit variations below 5% across all tidal phases, row configurations, and spacing combinations. Consequently, current reef structures provide limited control over wave transmission in fringing reef terrains, indicating that structural modifications such as increasing reef elevation or deploying reefs on the fore-reef slope could enhance attenuation performance. Full article