Search Results (183)

Rapid socio-economic development and the impact of human activities have exerted tremendous pressure on the groundwater system of the Dawen River Basin (DRB), the largest tributary in the middle and lower reaches of the Yellow River. Hydrochemical studies on the DRB have largely centered on the upstream Muwen River catchment and downstream Dongping Lake, with some focusing solely on karst groundwater. Basin-wide evaluations suggest good overall groundwater quality, but moderate to severe contamination is confined to the lower Dongping Lake area. The hydrogeologically complex mid-reach, where the Muwen and Chaiwen rivers merge, warrants specific focus. This region, adjacent to populous areas and industrial/agricultural zones, features diverse aquifer systems, necessitating a thorough analysis of its hydrochemistry and origins. This study presents an integrated hydrochemical, isotopic investigation and EWQI evaluation of groundwater quality and formation mechanisms within the multiple groundwater types of the central DRB. Central DRB groundwater has a pH of 7.5–8.2 (avg. 7.8) and TDSs at 450–2420 mg/L (avg. 1075.4 mg/L) and is mainly brackish, with Ca²⁺ as the primary cation (68.3% of total cations) and SO₄²⁻ (33.6%) and NO₃⁻ (28.4%) as key anions. The Piper diagram reveals complex hydrochemical types, primarily HCO₃·SO₄-Ca and SO₄·Cl-Ca. Isotopic analysis (δ²H, δ¹⁸O) confirms atmospheric precipitation as the principal recharge source, with pore water showing evaporative enrichment due to shallow depths. The Gibbs diagram and ion ratios demonstrate that hydrochemistry is primarily controlled by silicate and carbonate weathering (especially calcite dissolution), active cation exchange, and anthropogenic influences. EWQI assessment (avg. 156.2) indicates generally “good” overall quality but significant spatial variability. Pore water exhibits the highest exceedance rates (50% > Class III), driven by nitrate pollution from intensive vegetable cultivation in eastern areas (Xiyangzhuang–Liangzhuang) and sulfate contamination from gypsum mining (Guojialou–Nanxiyao). Karst water (26.7% > Class III) shows localized pollution belts (Huafeng–Dongzhuang) linked to coal mining and industrial discharges. Compared to basin-wide studies suggesting good quality in mid-upper reaches, this intensive mid-reach sampling identifies critical localized pollution zones within an overall low-EWQI background. The findings highlight the necessity for aquifer-specific and land-use-targeted groundwater protection strategies in this hydrogeologically complex region. Full article

Honey processing is closely linked to water pollution due to the lack of a specific wastewater treatment. This study proposes a sustainable and innovative solution based on two sequential bioprocesses using a real effluent from an Argentine honey-exporting facility. In the initial stage, the honey wastewater was enriched with a non-Saccharomyces yeast (Candida ethanolica), isolated from the same effluent. Treatment with this yeast in a bioreactor nearly doubled the total sugar removal efficiency compared to the control (native flora). Subsequent clarification with diatomaceous earth reduced the optical density (91.6%) and COD (30.9%). In the second stage, secondary sewage effluent was added to the clarified effluent and inoculated with Chlorella vulgaris under different culture conditions. The best microalgae performance was observed under high light intensity and high inoculum concentration, achieving a fivefold increase in cell density, a specific growth rate of 0.752 d⁻¹, and a doubling time of 0.921 d. Although total sugar removal in this stage remained below 28%, cumulative COD removal reached 90% after nine days under both lighting conditions. This study presents the first integrated treatment approach for honey industry effluents using a native yeast–microalgae system, incorporating in situ effluent recycling and the potential for dual waste valorization. Full article

Catalysts are ubiquitous in manufacturing industries and gas phase pollutant abatement but are not widely used in wastewater treatment, as high temperatures and concentrated waste streams are needed to achieve the reaction degradation rates required. Heating water is energy intensive, and alternative, low temperature solutions have been investigated, collectively known as advanced oxidation processes. However, many of these advanced oxidation processes use expensive oxidants such as perchlorate, hydroxy radicals or ozone to react with contaminants, and therefore have high running costs. This study has investigated microwave catalysis as a low-energy, low-cost technology for water treatment using NiO catalysts that can be heated in the microwave field to drive the decomposition of azo-dye contaminants. Using this methodology for the microwave-assisted degradation of two azo dyes (azorubine and methyl orange), conversions of >95% were achieved in only 10 s with 100 W microwave power. Full article

Sulfate as a potential pollution source in the water environment of the basin, identifying sulfate sources and migration mechanisms is essential for protecting the water environment and ensuring sustainable water management. Liuyang River is a primary tributary of the Xiangjiang River. It has experienced progressively intensifying anthropogenic influences in recent decades, manifested by sustained sulfate concentration increases. However, the sulfate sources and their contributions were not clear. This study used hydrochemistry and multi-isotopes methods combined with Simmr model to study the hydrochemical characteristics, sulfate sources, and migration–transformation processes of surface water and groundwater. The results showed that the hydrochemical types of surface water were HCO₃-Ca and HCO₃·SO₄-Ca·Mg, and groundwater were HCO₃-Ca, HCO₃-Ca·Mg, and HCO₃·SO₄-Ca. Ions in the water primarily originated from carbonate and silicate rocks dissolution and sulfide oxidation, augmented by mining operations, sewage discharge, and chemical production. The analyses of hydrochemistry, isotopes, and Simmr model revealed that surface water sulfate originated from soil sulfate (35.70%), sulfide oxidation (26.56%), sewage (16.58%), and atmospheric precipitation (12.45%). Groundwater sulfate was derived predominantly from sewage (34.96%), followed by soil sulfate (28.09%), atmospheric precipitation (17.35%), and sulfide oxidation (12.25%). Sulfate migration and transformation were controlled by the natural environment and anthropogenic impacts. When unaffected by human activities, sulfate mainly originated from soil and atmospheric precipitation, relating to topography, geological conditions, agricultural activities, and precipitation intensity. However, in regions with intense human activities, contributions from sewage and sulfide oxidation significantly increased due to the influences of mining and industrial activities. Full article

This study presents a biomonitoring study of surface waters in the Krynka River basin, encompassing three major regional reservoirs: Khanzhenkovskoe, Olkhovskoe, and Zuyevskoe. These water bodies face significant anthropogenic pressure from mining effluents, industrial discharges, and domestic wastewater. Key pollutants identified are surfactants (SAAs), sulfates, phenols, chlorides, and manganese, with chemical oxygen demand (COD) exceeding regulatory limits. The research was conducted in September 2024. Based on the Specific Combinatorial Water Pollution Index, surface waters in the studied objects can be characterized as slightly polluted. To assess the negative impact of the identified pollutants on hydrobionts, the species composition of phytoplankton of the studied water bodies was analyzed. In the Olkhovskoe Reservoir and Olkhovaya River, cyanobacterial blooms (Oscillatoria agardhii G.) were observed, altering biodiversity in the Krynka River and Zuyevskoe Reservoir. Phytoplankton genera Synedra, Amphiprora, and Navicula—established bioindicators of aquatic ecosystem health—were dominant in Khanzhenkovskoe Reservoir, signaling nutrient enrichment and organic pollution. Changes in the species composition and structure of phytoplankton in the Krynka River, its tributaries and reservoirs, indicate a change in the level of saprobic water bodies from β to α-mesosaprobic, which indicates both the general level of surface water pollution and the accumulation of pollutants along the course of the river. The paper presents the results of fluorimetric analysis of photosynthetic activity of natural phytoplankton cells and demonstrates the possibility of using fluorescence induction curves for regular monitoring measurements. Fluorescence parameters indicate a general deterioration of photosynthetic activity of natural phytoplankton. The growth of Oscillatoria agardhii in the waters of the Olkhovskoe Reservoir and of green microalgae in the Zuevskoe Reservoir led to an increase in the fluorescence quantum yield (F_v/F_m) and the total photosynthetic activity index (PI), which makes it possible to use these parameters as indicator parameters reflecting the intensity of “blooming” of various phytoplankton species. Full article

High levels of pesticide use are associated with intensive crop production. Pesticides are increasingly prevalent in surface and groundwater, which is a major environmental concern. Various methods have been proposed to improve the retention and/or degradation of pesticides in soils. These methods are mainly based on soil adaptation with organic wastes to mitigate soil and water pollution. In addition, there has recently been increased interest in assessing the influence of organic waste additions on pesticide movement in soils with low contents of organic matter. Agriculture and related industries generate large amounts of waste each year. Because of their components, they have the great ability to produce high-value products for environmental restoration. This study reports on the influence of four different agro-industrial wastes (orange peel, beer bagasse, grape pomace, and gazpacho waste) used as organic amendments on the leaching of metobromuron and chlorbromuron (phenylurea herbicides) on a silty clay loam soil (gypsic–calcaric regosol) with low organic matter contents from a semiarid area (southeastern Spain). The adsorption, leaching, and dissipation processes of these herbicides were evaluated on a laboratory scale in amended and unamended soils. In addition, the main leaching indices (GUS, LIX, LEACH, M LEACH, LIN, GLI, HI, and ELI) commonly used to assess groundwater protection against pesticide pollution were evaluated. The sorption coefficients (K_OC) increased in the amended soils. Metobromuron was found in leachates in all cases, although a marked reduction was observed in amended soils, while chlorbromuron was mainly retained in soils, especially in the top layer. The disappearance time (DT₅₀) for metobromuron and chlorbromuron in soil ranged from 11 to 56 d and 18 to 95 d, respectively. All indices except GLI categorize metobromuron as mobile or very mobile in unamended soil. For chlorbromuron, GUS, LIX, LEACH, MLEACH, and Hornsby classify this compound as a medium-to-high leache, while GLI and ELI classify it as having low mobility. In amended soils, most indices classify metobromuron as transitioning to mobile, while most indices catalog chlorbromuron as immobile/transition. Full article

Nowadays, nitrate ions and azo dyes are a significant source of water pollution due to their high toxicity, persistence, and potential to be carcinogenic. Both contaminants are the result of anthropogenic sources, such as sewage or industrial wastewater discharge; the first one results also as a consequence of the intensive use of fertilizers. In this work we report the use of a new quaternized pentablock copolymer (PTBr) for the removal of nitrate ions and methyl orange (MO) dye from water by adsorption processes. Morphological, chemical, and thermal properties of the pentablock copolymer were investigated, respectively, by scanning electron microscopy (SEM), Attenuated Total Reflectance Infrared Spectroscopy (ATR-FTIR) (FT-IR), and X-ray photoelectron spectroscopy (XPS), thermal gravimetric analysis (TGA), and differential scanning calorimetry (DSC) analyses. Anionic removal ability and adsorption rate in water solutions containing either a single contaminant species or a mix of the two contaminants were studied by UV–VIS absorbance spectroscopy as a function of time and initial concentration. The presence of imidazole groups confers on PTBr a positive charge and a hydrophilic character that are responsible for an effective removal of anions from water. PTBr film reports an adsorption efficiency of 10.15 mg/g for nitrate removal and this value is in line with others reported in the literature. In the case of the simultaneous presence of nitrate and MO, it is found that nitrate ions removal is slightly affected by the presence of the dye, since both contaminants compete for electrostatic interaction with imidazole groups. On the contrary, the dye removal does not show significant change with or without the presence of nitrate ions, probably due to other kinds of interaction that it can establish with the polymer surface (π-π interaction). The adsorption process and the related mechanisms are described using kinetic and isothermal models. Despite a certain reduction in the adsorption efficiency for one of the investigated contaminants, the results confirm the possibility of using the quaternized pentablock copolymer for the co-adsorption of both inorganic and organic anions. Full article

The Andean river basins of central–southern Chile face multiple anthropogenic disturbances, including water extraction, hydropower, mining, and industrial discharges, which affect their ability to adapt to new disturbances. Disturbance intensity forms a gradient from high (Maipo, Rapel, Biobío, Maule) through medium (Mataquito, Itata) to low (Imperial, Toltén). This study evaluated resilience in these eight river basins based on fish assemblages, using taxonomic and functional trait indices within the framework of the three Rs of resilience: resources, recruitment, and refugia. Taxonomic indices captured changes in species richness, abundance, diversity, evenness, and beta diversity, while functional traits reflected the fish species characteristics promoting resilience. Statistical tests revealed significant differences in resilience indices among basins. Recruitment was the most impacted resilience mechanism, with beta diversity revealing effects from river fragmentation in the Maipo, Rapel, and Biobío basins. The resources mechanism was also affected, primarily by land-use changes and water pollution, leading to low species richness in the Maipo, Rapel, Mataquito, and Maule river basins. Interestingly, basins with medium disturbance levels showed high resilience, indicating adaptive responses to moderate impacts. This study emphasizes the importance of multiple indicators to assess ecosystem resilience and calls for integrated strategies to address the complex challenges impacting freshwater biodiversity. Full article

This research aims to address the environmental and economic challenges associated with conventional concrete by partially replacing cement—the most polluting, expensive, and energy-intensive ingredient—with industrial paint sludge ash (PSA), a highly contaminated industrial waste that is typically landfilled. Mortar mixtures were prepared with PSA replacement levels ranging from 0% to 20% in 5% increments while maintaining a constant water-to-binder ratio of 0.48. This study comprehensively evaluated the fresh, mechanical, durability, and microstructural properties of the PSA-modified mortar to assess its potential as an ecofriendly construction material. Results showed that as PSA content increased, the fresh properties, such as workability/slump flow and setting time, decreased, while the water demand for attaining normal consistency increased. Soundness tests indicated expansion up to 15% PSA replacement, beyond which expansion became more pronounced. Compressive strength improved significantly with PSA replacements of 5% to 15% compared to the control sample, with a slight decline at 15% relative to 5% and 10%. This trend was consistent with bulk density and ultrasonic pulse velocity measurements. Furthermore, the incorporation of PSA enhanced key durability properties, including water absorption, sulfate resistance, and porosity reduction, up to 15% PSA replacement. Microstructural analysis using SEM, XRD, TGA/DTA, and FTIR confirmed that PSA inclusion led to increased mortar densification, with the 10% PSA mix exhibiting thermal stability and minimal mass loss at elevated temperatures. FTIR spectra further indicated improved composition with higher PSA content. Overall, PSA proved to be a viable partial cement replacement, offering enhanced mortar properties without compromising performance. Its use contributes to sustainability by reducing reliance on cement, lowering construction costs, and eliminating the environmental and logistical burdens of paint sludge disposal. Full article

The semiconductor industry is essential to information technology and the ongoing artificial intelligence transformation but also poses significant environmental challenges, including greenhouse gas emissions, air pollution, solid waste, and high water and energy consumption. This review identifies key emission sources in semiconductor manufacturing, focusing on the release of fluorinated gases from chemical-intensive processes and the sector’s substantial energy demands. We evaluate the effectiveness and limitations of current mitigation strategies, such as process optimization, clean energy adoption, and material substitution. We also examine supply chain interventions, including green procurement, logistics optimization, and intelligent management systems. While technological innovation is crucial for the sustainable transition of the global semiconductor industry, the high cost of upgrading to greener production processes remains a major obstacle. Despite progress in clean energy integration and material alternatives, significant challenges persist in reducing emissions across the entire value chain. This review underscores an urgent need for collaborative, integrated approaches to drive the sustainable transition of the semiconductor sector and its upstream supply chain. Full article

The textile industry ranks among the highest water-consuming sectors globally, with annual usage reaching billions of cubic meters. In manufacturing, wet processing, including dyeing, printing, and finishing, accounts for 72% of this water demand. These stages not only require vast water volumes but also produce wastewater containing hazardous chemicals, polluting ecosystems and reducing soil fertility. Furthermore, the energy-intensive nature of these processes, combined with a heavy reliance on fossil fuels, contributes significantly to greenhouse gas emissions. In response to these environmental challenges, innovative technologies have emerged, such as waterless dyeing using supercritical carbon dioxide, digital printing, ultrasonic-assisted processing, foam dyeing, laser-based denim finishing, and dope dyeing for man-made fibers. These methods drastically reduce water consumption, lower energy use, and minimize emissions while maintaining textile quality. However, the widespread adoption of these alternatives faces challenges, including high implementation costs, process scalability, and compatibility with existing infrastructure. This review critically explores current advancements in sustainable textile wet processing, analyzing their effectiveness, limitations, and industrial viability. By addressing these challenges, the textile industry can transition toward environmentally friendly and resource-efficient manufacturing processes. Full article

This research quantifies mercury use and models its transport in artisanal and small-scale gold mining (ASGM) in the Lom River during two key periods of intense mining activities and high water flow. Mercury concentrations from mining surfaces were estimated using a soil input function approach. Industrial mercury releases were assessed with a ratio-based approach using official gold production data and the mercury-to-gold ratio. The PEGASE model was applied to simulate mercury transport and pollution in the Lom River and to analyze the pressure–impact relationships of ASGM activities on surface water. Field measurements of the mercury concentrations in the Lom River during the dry and rainy seasons of 2021 were used to validate modeling results. The results indicate that volatilization has a more significant impact on the predicted mercury concentrations than photodissociation. Three scenarios were modeled for mercury use: whole ore amalgamation (WOA), combined whole and concentrate ore amalgamation (WOA + COA), and concentrate ore amalgamation (COA). Mercury use estimates ranged from 2250–7500 kg during intense activity to 1260–4200 kg during high water for the gold production of 750 and 525 kg, respectively. Industrial discharges dominated mercury pollution during the dry season while leaching from mining surfaces was the primary contributor during the rainy season. Full article

The increasing presence of persistent pollutants in industrial wastewater underscores the shortcomings of conventional treatment methods, prompting the adoption of advanced oxidation processes (AOPs) for sustainable water remediation. This review examines the development of AOPs, focusing on their ability to produce hydroxyl radicals and reactive oxygen species (ROS) to mineralize complex pollutants. Homogeneous systems such as Fenton’s reagent show high degradation efficiency. However, challenges like pH sensitivity, catalyst recovery issues, sludge generation, and energy-intensive operations limit their scalability. Heterogeneous catalysts, such as TiO₂-based photocatalysts and Fe₃O₄ composites, offer improved pH adaptability, visible-light activation, and recyclability. Emerging innovations like ultraviolet light emitting diode (UV-LED)-driven systems, plasma-assisted oxidation, and artificial intelligence (AI)-enhanced hybrid reactors demonstrate progress in energy efficiency and process optimization. Nevertheless, key challenges remain, including secondary byproduct formation, mass transfer constraints, and economic feasibility for large-scale applications. Integrating AOPs with membrane filtration or biological treatments enhances treatment synergy, while advances in materials science and computational modeling refine catalyst design and reaction mechanisms. Addressing barriers in energy use, catalyst durability, and practical adaptability requires multidisciplinary collaboration. This review highlights AOPs as pivotal solutions for water security amid growing environmental pollution, urging targeted research to bridge gaps between laboratory success and real-world implementation. Full article

Heavy metals represent a class of pollutants detected at concentrations lower than 10 ppm in different matrices that are intensively monitored due to having a major impact on human health. Industrial activities including mining, agriculture, and transport, determine their presence in different environments. Corrosion phenomena of various installations, volcanic eruptions, or atmospheric deposition on the soil surface and in water can contaminate the respective environments. Atmospheric pollutants in the form of suspended dust particles with diameters below 10 microns are predominantly composed of different metallic species from Cd, Cr, Cu, Ni, etc. This paper presents a review of the main sources and types of heavy metals present in the atmosphere in the composition of particulate matter (PM), highlighting the main mechanisms of occurrence and detection techniques, including the impact on bio-geo-chemical processes in the soil and food chain, in close correlation with their impact on environment and human health. The purpose of this review is to highlight the current level of knowledge regarding the global situation of heavy metals in PM and to identify gaps as targets for future research. Full article

Dyeing is a major contributor to pollution, with high concentrations of hydrolyzed dyes and electrolytes in its effluents. Recent studies suggest the possibility of dyeing cotton substrates with reactive dyes in an oil medium, reducing the need for electrolytes. This study evaluated the dyeing of cotton yarns with reactive Red 195 dye in an oil medium using crude and refined soybean oil. The method employed 75% oil and 25% water, with the oil recovered for reuse, significantly reducing water consumption and effluent generation. Dyeing with crude soybean oil showed higher color intensity than the conventional method and the use of refined soybean oil. Additionally, reducing electrolyte concentration from 75 to 18.75 g/L did not affect color intensity, yielding similar results to conventional aqueous dyeing. The dyed substrates were tested for washing, rubbing, and lightfastness, showing comparable performance to conventional methods. The dyeing followed pseudo-second-order kinetics, and the Freundlich isotherm model better fit the oil medium process. FTIR analysis revealed no changes in the functional groups on the yarn surface, and tensile strength tests showed similar results across methods. These findings indicate that oil medium dyeing can reduce electrolyte use, conserve water, and allow for oil reuse, demonstrating potential for industrial-scale application. Full article