Search Results (524)

Ecotribology focuses on both saving energy resources and reducing environmental pollution. Considering environmental concerns, water-based nanolubricants have gained significant attention over conventional oil-based ones. Non-ecotoxic and highly environmentally friendly nanoadditives were chosen for nanolubricant synthesis, especially considering their use at elevated temperatures. In this study, hexagonal boron nitride nanosheets (hBNNSs) and titanium dioxide nanoparticles (TiO₂ NPs) were used to prepare water-based lubricants with glycerol and surfactant sodium dodecyl benzene sulfonate (SDBS) in water under ultrasonication. An Rtec ball-on-disk tribometer was used to investigate the tribological performance of the synthesised water-based lubricants containing different nano-hBN/TiO₂ concentrations, with dry and water conditions used as benchmarks. The results indicated that the water-based nanolubricant containing 0.5 wt% hBN and 0.5 wt% TiO₂ exhibited the best tribological performance at both ambient (25 °C) and elevated (500 °C) temperatures. This optimal concentration leads to a reduction in the coefficient of friction (COF) by 72.9% and 37.5%, wear of disk by 62.5% and 49%, and wear of ball by 74% and 69% at ambient and elevated temperatures, respectively, compared to that of distilled water. Lubrication mechanisms were attributed to the rolling, mending, tribofilm, solid layer formation, and synergistic effects of hBNNSs and TiO₂ NPs. Full article

In today’s industrial applications, cutting fluids have attained prime importance due to their all-round features, including increase of tool life by lubrication of the tool at the tool–workpiece interface. This study compares the effects of mango seed oil and pongamia oil on cutting force and surface morphology during the turning of AISI 304 steel. The design of experiments was applied using Taguchi’s method with an L9 array of experiments. During the experiment, it was discovered that mango seed and pongamia-based cutting fluid exhibited the lowest contact angles of 22.1° and 24.4°, respectively, at a 97:3 volumetric concentration of deionized water and eco-friendly oil. The use of mango seed oil as a cutting fluid with MQL (Minimum Quantity Lubrication) resulted in the lowest surface roughness of 0.809 µm, compared to 0.921 µm with pongamia-based cutting fluid. The cutting force was reduced by a maximum of 28.68% using mango seed-based cutting fluid, compared to pongamia-based cutting fluid. ANOVA analysis revealed that feed rate had the maximum influence on the optimization of output parameters for mango seed cutting fluid. For pongamia-based cutting fluid, feed rate had the maximum influence on cutting force, while the depth of cut had the strongest influence on surface roughness. Full article

Esterification is a key transformation in the production of lubricants, pharmaceuticals, and fine chemicals. Conventional processes employing homogeneous acid catalysts suffer from limitations such as corrosive byproducts, energy-intensive separation, and poor catalyst reusability. This review provides a comprehensive overview of heterogeneous catalytic systems, including ion exchange resins, zeolites, metal oxides, mesoporous materials, and others, for improved ester synthesis. Recent advances in membrane-integrated reactors, such as pervaporation and nanofiltration, which enable continuous water removal, shifting equilibrium and increasing conversion under milder conditions, are reviewed. Dual-functional membranes that combine catalytic activity with selective separation further enhance process efficiency and reduce energy consumption. Enzymatic systems using immobilized lipases present additional opportunities for mild and selective reactions. Future directions emphasize the integration of pervaporation membranes, hybrid catalyst systems combining biocatalysts and metals, and real-time optimization through artificial intelligence. Modular plug-and-play reactor designs are identified as a promising approach to flexible, scalable, and sustainable esterification. Overall, the interaction of catalyst development, membrane technology, and digital process control offers a transformative platform for next-generation ester synthesis aligned with green chemistry and industrial scalability. Full article

Silicon nitride (Si₃N₄) ceramic is widely used in the production of structural components. The surface wettability is closely related to the service life of materials. Laser surface texturing is considered an effective method for controlling surface wettability by processing specific patterns. This research focused on the laser surface texturing of a Si₃N₄ ceramic, employing rectangular patterns instead of the typical dimple designs, as these had promising applications in heat transfer and hydrodynamic lubrication. The effects of scanning speed and number of scans on the change of the morphologies and dimensions of the grooves were investigated. The results indicated that the higher scanning speed and fewer number of scans resulted in less damage to the textured surface. As the scanning speed increased, the width and depth of the grooves decreased significantly first, and then fluctuated. Conversely, increasing the number of scans led to an increase in the width and depth of the grooves, eventually stabilizing. The analysis of the elemental composition of different areas on the textured surface presented a notable increase in oxygen content at the grooves, while Si and N levels decreased. It was mainly caused by the chemical reaction between Si₃N₄ ceramic and oxygen during laser surface texturing in an air environment. This study also assessed the wettability of the textured surface, finding that the contact angle of the water droplet was significantly affected by the groove dimensions. After laser surface texturing, the contact angle increased from 35.51 ± 0.33° to 57.52 ± 1.83°. Improved wettability was associated with smaller groove volume, indicating better hydrophilicity at lower scanning speed and enhanced hydrophobicity with a fewer number of scans. Full article

Water-lubricated bearings (WLB), due to their pollution-free nature and low noise, are increasingly becoming critical components in aerospace, marine applications, high-speed railway transportation, precision machine tools, etc. However, in practice, water-lubricated bearings suffer severe friction and wear due to low-viscosity water, harsh conditions, and contaminants like sediment, which can compromise the lubricating film and shorten their lifespan. The implementation of micro-textures has been demonstrated to improve the tribological performance of water-lubricated bearings to a certain extent, leading to their widespread adoption for enhancing the frictional dynamics of sliding bearings. The shape, dimensions (including length, width, and depth), and distribution of these micro-textures have a significant influence on the frictional performance. Therefore, this study aims to explore the coupling effect of different micro-texture shapes and distributions on the frictional performance of water-lubricated sliding, using the computational fluid dynamics (CFD) analysis. The results indicate that strategically arranging textures across multiple regions can enhance the performance of the bearing. Specifically, placing linear groove textures in the outlet of the divergent zone and triangular textures in the divergent zone body maximize improvements in the load-carrying capacity and frictional performance. This specific configuration increases the load-carrying capacity by 7.3% and reduces the friction coefficient by 8.6%. Overall, this study provided critical theoretical and technical insights for the optimization of WLB, contributing to the advancement of clean energy technologies and the extension of critical bearing service life. Full article

During the construction of subgrade, the remolding water content w of lime–sand-stabilized clay usually varies in a wide range, leading to inconsistent effectiveness in strength enhancement. Until now, this aspect has not been investigated. In this study, an unconfined compression test and microscopic observation were carried out on clay and stabilized clay (adding 4% lime by mass and 50% sand by volume). The results show the following: (1) remolding water content w had a strong effect on the soil fabrics of pure clay and lime-stabilized clay. An increase in the w from the dry to wet side of optimum reduced matric suction, which diminished the aggregation effect among fine-grained particles in both clay and lime-stabilized clay. Correspondingly, fine-grained aggregate progressively disintegrated, and dispersed fine-grained particles increased. As a result, the w increment at w ≤ w_cha made the dispersed fine-grained particles successively fill the large pores between aggregates, densifying the soil fabric. In contrast, at w > w_cha, the ongoing disintegration of aggregate resulted in progressive structural weakening. Herein, w_cha was defined as the characteristic water content at which the soil fabric transitioned from structural densification to weakening. (2) The UCS of both pure clay and lime–sand-stabilized clay followed a bell-shaped pattern as the w increased, with w_cha acting as the turning point. For pure clay soils, the UCS increased with increasing w up to w_cha because of structural densification, but decreased beyond w_cha due to structural weakening. In lime–sand-stabilized clay, where a sand grain skeleton developed, the compression of lime-stabilized clay induced by the movement of sand grains during shearing activated its contribution to the overall strength. The compressive capacity of the lime-stabilized clay varied in a bell-shaped manner with w, and this trend was mirrored in the UCS of lime–sand-stabilized clay. (3) At a low w, the fact that the clay aggregate exhibited sand-like mechanical behavior reduced the effectiveness of incorporating sand and lime for enhancing the UCS. As the w increased at w ≤ w_cha, the breakdown of aggregates enlarged the distinction between pure clay and sand, resulting in a more pronounced improvement in the UCS with the addition of sand and lime. At w > w_cha, the lubrication effect occurring at the contact between sand grains diminished the interlocking between the sand grains. Consequently, the effectiveness of the UCS enhancement decreased. Full article

This article demonstrated that environmentally friendly lubricants—glycerol–water-based oil (GWB) and rapeseed oil-based oil (RSB)—would provide comparable conditions (wear of node components, friction resistance) in a friction node as a commercial semi-synthetic gear oil (REF). Wear tests were performed on a block-on-ring model friction node stand using GBZ12 (CuSn12), BA1032 (CuAl10Fe3Mn2), and BA1054 (CuAl10Ni5Fe4) bronze samples. Glycerol–water-based oil (GWB) significantly reduced the wear of the samples by several times, compared to semi-synthetic oil (REF) and rapeseed oil-based oil (RSB). The (GWB) oil also provided a stable friction coefficient value at the lowest level of 0.05–0.06. The main disadvantage of the (RSB) oil was the temporary fluctuation of the friction coefficient value (increase above 0.1), which indicated the lack of stability of the boundary layer. The results highlight the potential of (GWB) oil in reducing wear and stabilizing friction under extreme conditions, supporting the shift toward sustainable lubricants in industrial applications. Full article

The paper shows the effect of using a lubricant in the form of an ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM-PF₆), on the tribological properties of a hydrogenated diamond-like coating (DLC) doped with tungsten a-C:H:W. The coatings were deposited on 100Cr6 steel by plasma-enhanced chemical vapor deposition PECVD. Tribological tests were carried out on a TRB³ tribometer in a rotary motion in a ball–disc combination. 100Cr6 steel balls were used as a counter-sample. Friction and wear tests were carried out for discs made of 100Cr6 steel and 100Cr6 steel discs with a DLC coating. They were performed under friction conditions with and without lubrication under 10 N and 15 N loads. The ionic liquid BMIM-PF₆ was used as a lubricant. Coating thickness was observed on a scanning microscope, and the linear analysis of chemical composition on the cross-section was analyzed using the EDS analyzer. The confocal microscope with an interferometric mode was used for analysis of the geometric structure of the surface before and after the tribological tests. The contact angle of the samples for distilled water, diiodomethane and ionic liquid was tested on an optical tensiometer. The test results showed good cooperation of the DLC coating with the lubricant. It lowered the coefficient of friction in comparison to steel about 20%. This indicates the synergistic nature of the interaction: DLC coating–BMIM-PF₆ lubricant–100Cr6 steel. Full article

Both biosystems and engineering fields demand advanced friction-reducing and lubricating materials. Due to their hydrophilicity and tissue-mimicking properties, hydrogels are ideal candidates for use as lubricants in water-based environments. They are particularly well-suited for applications involving biocompatibility or interactions with intelligent devices such as soft robots. However, external environments, whether within the human body or in engineering applications, often present a wide range of dynamic conditions, including variations in shear stress, temperature, light, pH, and electric fields. Additionally, hydrogels inherently possess low mechanical strength, and their dimensional stability can be compromised by changes during hydration. This review focuses on recent advancements in using environmentally responsive hydrogels as lubricants. It explores strategies involving physical or structural modifications, as well as the incorporation of smart chemical functional groups into hydrogel polymer chains, which enable diverse responsive mechanisms. Drawing on both the existing literature and our own research, we also examine how composite friction materials where hydrogels serve as water-based lubricants offer promising solutions for demanding engineering environments, such as bearing systems in marine vessels. Full article

Understanding the mechanical behavior of frozen clay subgrade soils was essential for ensuring the safe and stable operation of transportation lines. However, the influence of remolding water content w on this behavior remained unclear. To address this gap, this study examined the effect of w through monotonic triaxial testing. Three typical remolding water contents (w = 19%, 27.5% and 35%) and three confining pressures (σ₃ = 200 kPa, 700 kPa and 1200 kPa) were considered. Results showed that the mechanical behavior of frozen clay soils displayed a clear dependence on w, which was controlled by microstructural evolution. As w increased, the shear strength q_max, resilient modulus E₀ and cohesion c increased, which resulted from the progressive development of ice bonding within the shear plane. A threshold w value was found at w_opt = 27.5%, marking a structural transition and separating the variations of q_max, E₀ and c into two regimes. When w ≤ 27.5%, the soil fabric was controlled by clay aggregates. As w increased, the growth in ice cementation was confined within these aggregates, leading to limited increase in q_max, E₀ and c. However, as w exceeded 27.5%, the soil fabric transitioned into a homogeneous matrix of dispersed clay particles. In this case, increasing w greatly promoted the development of an interconnected ice cementation network, thus significantly facilitating the increase in q_max, E₀ and c. The friction angle φ decreased with w increasing, primarily due to the lubrication effect caused by the growing ice. In addition, the enhanced lubrication effect in the clay particle-dominated fabric (w > 27.5%) resulted in a larger reduction rate of φ. Regarding Poisson’s ratio v and dilation angle ψ, the w increase led to growth in both parameters. This phenomenon could be explained by the increased involvement of solid ice into the soil structure. Full article

In pipe jacking construction, thixotropic slurry critically governs lubrication, friction reduction, and ground support. This study evaluated slurry performance through six parameters: specific gravity (SG), pH, fluid loss (FL), water separation rate (WSR), filter cake thickness (FCT), and funnel viscosity (FV). Orthogonal experiments optimizing bentonite, carboxymethyl cellulose (CMC), and sodium carbonate (Na₂CO₃) ratios established 10 wt.% bentonite, 0.3 wt.% CMC, and 0.4 wt.% Na₂CO₃ as the optimal formulation. Subsequently, to address performance limitations in challenging conditions, this study introduces hydroxyethyl cellulose (HEC) as a novel additive, with potential advantages under high-salinity and variable pH conditions. Comparative experiments demonstrated that HEC, as a non-ionic water-soluble cellulose, not only significantly increases FV and reduces FL while maintaining SG, FCT, and WSR within acceptable thresholds, but also exhibits superior pH stability compared to CMC. Based on the aforementioned results, interface friction characterization tests were conducted on representative slurry formulations with varying FVs, quantitatively demonstrating the viscosity-dependent friction-reduction performance. Complementary scanning electron microscopy (SEM) analysis of three distinct thixotropic slurry compositions systematically revealed their microstructural characteristics, with microscopic evidence confirming the excellent compatibility between HEC and thixotropic slurry matrix. These findings highlight HEC’s potential as an effective alternative in pipe jacking, particularly in demanding geological environments. Full article

Pure copper is an important metal material in the fields of integrated circuits, mold manufacturing, and aerospace. Its excellent ductility and plasticity lead to problems such as burrs and tool wear in cutting, which poses great challenges to the improvement of machining accuracy and surface quality. To achieve high-quality and efficient processing of pure copper, this paper proposes to use nanographene water-based lubricant (NGWL) to regulate its removal behavior. A single-grain diamond scribing test and a micro-milling test were carried out to systematically study the action mechanism of NGWL on removal behavior of pure copper. The results showed that, compared with dry scribing at normal forces of 100, 400, 700, and 1000 mN, the material removal efficiency induced by NGWL was increased by 54.1%, 80.7%, 44.8%, and 30.3%, respectively. Compared with dry micro-milling at feed speeds of 200, 600, 1000, and 1400 μm/s, for the 75°XT4E tool, the surface roughness Sa with NGWL-assisted micro-milling was reduced by 75.5%, 73.1%, 61.4%, and 44.2%, respectively. Similarly, for the 65°UDT4E tool, compared to dry micro-milling, the Sa with NGWL lubrication was also reduced by 28.9%, 52.2%, 54.4%, and 36.9%, respectively. The Sa of pure copper induced by NGWL could be as low as about 20 nm without scales. Overall, NGWL can regulate removal behavior of pure copper by alleviating plastic deformation and promoting ductile fracture, thereby providing a new approach to achieving high-quality and efficient processing of pure copper. Full article

Wave gliders’ power system shafts face complex conditions. To enhance their operational stability, it is crucial to study PTFE, a polymer material that could replace traditional metals. This study added carbon fiber (CF), titanium carbide (Ti-C), and both to a PTFE matrix. The impact of seawater immersion on water absorption and the mechanical properties was examined, as well as friction and wear characteristics under constant amplitude cyclic (CAC) loading and seawater lubrication. The results indicated that while Ti-C boosts PTFE matrix hardness, its poor binding with the PTFE matrix leads to high water absorption in Ti-C/PTFE (PTFE-3), causing a significant decrease in the mechanical properties post-immersion and poor friction and wear performance. In contrast, CFs and the PTFE matrix have good interfacial bonding and greatly improve the resistance of the PTFE matrix to cyclic loading and seawater immersion. Therefore, CF/PTFE (PTFE-2) shows good mechanical and tribological properties. Moreover, incorporating a certain amount of CFs into Ti-C enhances its adhesion to the PTFE matrix, reducing the occurrence three-body wear and allowing Ti-C to fully utilize its high hardness. Thus, the combination of Ti-C and CFs markedly improves PTFE’s mechanical and tribological properties under cyclic loading and in seawater. Full article

The burr removal and finishing of drilled hole walls typically require multiple post-processing steps. This experimental study introduces a novel single-step drilling approach using modified drill bits for simultaneous burr removal and surface finishing in aluminum 6061-T6. The odified-1 drill, equipped with a deburring micro-insert, achieved superior results, with a chamfer height of −2.829 mm, drilling temperature of 40.28 ◦C, and surface roughness of 0.082 µm under optimal conditions. Multi-objective optimization using the RSM and MOGA-ANN identified the optimal drilling parameters for the Modified-1 drill at 3000 rpm under water lubrication as compared to dry conditions and kerosene. Experimental validation confirmed the high prediction accuracy, with deviations under 6%. These results establish the Modified-1 twist drill bit with a deburring
 micro-insert as a highly effective tool for burr-free high-quality drilling in a single operation. This innovative drill design presents an efficient, single-step solution for burr elimination, chamfer formation, and surface finishing in drilling operations. Full article

Polycrystalline diamond (PCD), which is widely used to manufacture cutting tools due to its extreme hardness, in most cases requires grinding for machining. The cooling lubricant selected for PCD grinding largely affects the frictional conditions and the thermo-mechanical load collective between the diamond grinding wheel and the PCD. As a consequence of this, the material removal and grinding wheel wear mechanisms during grinding PCD depend on the cooling lubricant used. In this study, experimental and numerical investigations were taken into account, demonstrating that using a water-based cooling lubricant during PCD grinding predominantly leads to a mechanical load on workpiece and grinding wheel rather than thermal loads. These original findings can be used to complement existing explanatory models of the PCD grinding process valid for grinding with oil as a cooling lubricant. The aim of this work is to contribute a novel extension to the existing material removal and grinding wheel wear models to enable them for the grinding process with a water-based cooling lubricant. The knowledge obtained from this work is intended to serve as a basis for future industrial process design. Full article