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Search Results (874)

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Keywords = water cooperation

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28 pages, 2191 KiB  
Article
An Evaluation of Food Security and Grain Production Trends in the Arid Region of Northwest China (2000–2035)
by Yifeng Hao and Yaodong Zhou
Agriculture 2025, 15(15), 1672; https://doi.org/10.3390/agriculture15151672 - 2 Aug 2025
Viewed by 205
Abstract
Food security is crucial for social stability and economic development. Ensuring food security in the arid region of Northwest China presents unique challenges due to limited water and soil resources. This study addresses these challenges by integrating a comprehensive water and soil resource [...] Read more.
Food security is crucial for social stability and economic development. Ensuring food security in the arid region of Northwest China presents unique challenges due to limited water and soil resources. This study addresses these challenges by integrating a comprehensive water and soil resource matching assessment with grain production forecasting. Based on data from 2000 to 2020, this research projects the food security status to 2035 using the GM(1,1) model, incorporating a comprehensive index of soil and water resource matching and regression analysis to inform production forecasts. Key assumptions include continued historical trends in population growth, urbanization, and dietary shifts towards an increased animal protein consumption. The findings revealed a consistent upward trend in grain production from 2000 to 2020, with an average annual growth rate of 3.5%. Corn and wheat emerged as the dominant grain crops. Certain provinces demonstrated comparative advantages for specific crops like rice and wheat. The most significant finding is that despite the projected growth in the total grain output by 2035 compared to 2020, the regional grain self-sufficiency rate is projected to range from 79.6% to 84.1%, falling below critical food security benchmarks set by the FAO and China. This projected shortfall carries significant implications, underscoring a serious challenge to regional food security and highlighting the region’s increasing vulnerability to external food supply fluctuations. The findings strongly signal that current trends are insufficient and necessitate urgent and proactive policy interventions. To address this, practical policy recommendations include promoting water-saving technologies, enhancing regional cooperation, and strategically utilizing the international grain trade to ensure regional food security. Full article
(This article belongs to the Topic Food Security and Healthy Nutrition)
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23 pages, 10936 KiB  
Article
Towards Autonomous Coordination of Two I-AUVs in Submarine Pipeline Assembly
by Salvador López-Barajas, Alejandro Solis, Raúl Marín-Prades and Pedro J. Sanz
J. Mar. Sci. Eng. 2025, 13(8), 1490; https://doi.org/10.3390/jmse13081490 - 1 Aug 2025
Viewed by 263
Abstract
Inspection, maintenance, and repair (IMR) operations on underwater infrastructure remain costly and time-intensive because fully teleoperated remote operated vehicle s(ROVs) lack the range and dexterity necessary for precise cooperative underwater manipulation, and the alternative of using professional divers is ruled out due to [...] Read more.
Inspection, maintenance, and repair (IMR) operations on underwater infrastructure remain costly and time-intensive because fully teleoperated remote operated vehicle s(ROVs) lack the range and dexterity necessary for precise cooperative underwater manipulation, and the alternative of using professional divers is ruled out due to the risk involved. This work presents and experimentally validates an autonomous, dual-I-AUV (Intervention–Autonomous Underwater Vehicle) system capable of assembling rigid pipeline segments through coordinated actions in a confined underwater workspace. The first I-AUV is a Girona 500 (4-DoF vehicle motion, pitch and roll stable) fitted with multiple payload cameras and a 6-DoF Reach Bravo 7 arm, giving the vehicle 10 total DoF. The second I-AUV is a BlueROV2 Heavy equipped with a Reach Alpha 5 arm, likewise yielding 10 DoF. The workflow comprises (i) detection and grasping of a coupler pipe section, (ii) synchronized teleoperation to an assembly start pose, and (iii) assembly using a kinematic controller that exploits the Girona 500’s full 10 DoF, while the BlueROV2 holds position and orientation to stabilize the workspace. Validation took place in a 12 m × 8 m × 5 m water tank. Results show that the paired I-AUVs can autonomously perform precision pipeline assembly in real water conditions, representing a significant step toward fully automated subsea construction and maintenance. Full article
(This article belongs to the Section Ocean Engineering)
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18 pages, 1458 KiB  
Article
Factors Influencing Willingness to Collaborate on Water Management: Insights from Grape Farming in Samarkand, Uzbekistan
by Sodikjon Avazalievich Mamasoliev, Motoi Kusadokoro, Takeshi Maru, Shavkat Hasanov and Yoshiko Kawabata
Sustainability 2025, 17(15), 6991; https://doi.org/10.3390/su17156991 - 1 Aug 2025
Viewed by 218
Abstract
Water is essential for ecological balance, environmental sustainability, and food security, particularly in arid regions where effective water management increasingly depends on farmer cooperation. The Samarkand region of Uzbekistan, known for its favorable climate and leading role in grape production, is facing rising [...] Read more.
Water is essential for ecological balance, environmental sustainability, and food security, particularly in arid regions where effective water management increasingly depends on farmer cooperation. The Samarkand region of Uzbekistan, known for its favorable climate and leading role in grape production, is facing rising drought conditions. This study explores the factors influencing grape farmers’ willingness to collaborate on water management in the districts of Ishtikhan, Payarik, and Kushrabot, which together produce 75–80% of the region’s grapes. A quantitative survey of 384 grape-producing households was conducted across 19 county citizens’ gatherings (38.7% of such gatherings), and structural equation modeling was employed to analyze a framework consisting of four dimensions: norms, environmental concerns, economic barriers, and the intention to adopt sustainable practices. The results indicate that norms and environmental concerns positively influence collaboration, suggesting a collective orientation toward sustainability. In contrast, economic barriers such as high costs and limited financial capacity significantly hinder cooperative behavior. Furthermore, a strong individual intention to adopt sustainable practices was associated with a greater likelihood of collaboration. These findings highlight the critical drivers and constraints shaping collective water use in agriculture and suggest that targeted policy measures and community-led efforts are vital for promoting sustainable water governance in drought-prone regions. Full article
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36 pages, 2676 KiB  
Review
Research Activities on Acid Mine Drainage Treatment in South Africa (1998–2025): Trends, Challenges, Bibliometric Analysis and Future Directions
by Tumelo M. Mogashane, Johannes P. Maree, Lebohang Mokoena and James Tshilongo
Water 2025, 17(15), 2286; https://doi.org/10.3390/w17152286 - 31 Jul 2025
Viewed by 262
Abstract
Acid mine drainage (AMD) remains a critical environmental challenge in South Africa due to its severe impact on water quality, ecosystems and public health. Numerous studies on AMD management, treatment and resource recovery have been conducted over the past 20 years. This study [...] Read more.
Acid mine drainage (AMD) remains a critical environmental challenge in South Africa due to its severe impact on water quality, ecosystems and public health. Numerous studies on AMD management, treatment and resource recovery have been conducted over the past 20 years. This study presents a comprehensive review of research activities on AMD in South Africa from 1998 to 2025, highlighting key trends, emerging challenges and future directions. The study reveals a significant focus on passive and active treatment methods, environmental remediation and the recovery of valuable resources, such as iron, rare earth elements (REEs) and gypsum. A bibliometric analysis was conducted to identify the most influential studies and thematic research areas over the years. Bibliometric tools (Biblioshiny and VOSviewer) were used to analyse the data that was extracted from the PubMed database. The findings indicate that research production has increased significantly over time, with substantial contributions from top academics and institutions. Advanced treatment technologies, the use of artificial intelligence and circular economy strategies for resource recovery are among the new research prospects identified in this study. Despite substantial progress, persistent challenges, such as scalability, economic viability and policy implementation, remain. Furthermore, few technologies have moved beyond pilot-scale implementation, underscoring the need for greater investment in field-scale research and technology transfer. This study recommends stronger industry–academic collaboration, the development of standardised treatment protocols and enhanced government policy support to facilitate sustainable AMD management. The study emphasises the necessity of data-driven approaches, sustainable technology and interdisciplinary cooperation to address AMD’s socioeconomic and environmental effects in the ensuing decades. Full article
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28 pages, 671 KiB  
Article
How Cooperative Are Games in River Sharing Models?
by Marcus Franz Konrad Pisch and David Müller
Water 2025, 17(15), 2252; https://doi.org/10.3390/w17152252 - 28 Jul 2025
Viewed by 230
Abstract
There is a long tradition of studying river sharing problems. A central question frequently examined and addressed is how common benefits or costs can be distributed fairly. In this context, axiomatic approaches of cooperative game theory often use contradictory principles of international water [...] Read more.
There is a long tradition of studying river sharing problems. A central question frequently examined and addressed is how common benefits or costs can be distributed fairly. In this context, axiomatic approaches of cooperative game theory often use contradictory principles of international water law, which are strictly rejected in practice. That leads to the question: Are these methods suitable for a real-world application? First, we conduct a systematic literature review based on the PRISMA approach to categorise the river sharing problems. We identified several articles describing a variety of methods and real-world applications, highlighting interdisciplinary interest. Second, we evaluate the identified axiomatic literature related to TU games with regard to their suitability for real-world applications. We exclude those “standalone” methods that exclusively follow extreme principles and/or do not describe cooperative behaviour. This is essential for a fair distribution. Third, we propose to use the traditional game-theoretical approach of airport games in the context of river protection measures to ensure a better economic interpretation and to enforce future cooperation in the joint implementation of protective measures. Full article
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17 pages, 1441 KiB  
Article
The Relaxation Behavior of Water Confined in AOT-Based Reverse Micelles Under Temperature-Induced Clustering
by Ivan V. Lunev, Alexander N. Turanov, Mariya A. Klimovitskaya, Artur A. Galiullin, Olga S. Zueva and Yuriy F. Zuev
Int. J. Mol. Sci. 2025, 26(15), 7152; https://doi.org/10.3390/ijms26157152 - 24 Jul 2025
Viewed by 258
Abstract
Relaxation behavior of water confined in reverse micelles under temperature-induced micelle clustering is undertaken using broadband dielectric spectroscopy in frequency range 1 Hz–20 GHz. All microemulsion systems with sufficiently noticeable micelle water pool (water/surfactant molar ratio W > 10) depict three relaxation processes, [...] Read more.
Relaxation behavior of water confined in reverse micelles under temperature-induced micelle clustering is undertaken using broadband dielectric spectroscopy in frequency range 1 Hz–20 GHz. All microemulsion systems with sufficiently noticeable micelle water pool (water/surfactant molar ratio W > 10) depict three relaxation processes, in low, high and microwave frequencies, anchoring with relaxation of shell (bound) water, orientation of surfactant anions at water-surfactant interface and relaxation of bulk water confined in reverse micelles. The analysis of dielectric relaxation processes in AOT-based w/o microemulsions under temperature induced clustering of reverse micelles were made according to structural information obtained in NMR and conductometry experiments. The “wait and switch” relaxation mechanism was applied for the explanation of results for water in the bound and bulk states under spatial limitation in reverse micelles. It was shown that surfactant layer predominantly influences the bound water. The properties of water close to AOT interface are determined by strong interactions between water and ionic AOT molecules, which perturb water H-bonding network. The decrease in micelle size causes a weakening of hydrogen bonds, deformation of its steric network and reduction in co-operative relaxation effects. Full article
(This article belongs to the Section Molecular Informatics)
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32 pages, 9140 KiB  
Article
The Synergistic Evolution and Coordination of the Water–Energy–Food Nexus in Northeast China: An Integrated Multi-Method Assessment
by Huanyu Chang, Yongqiang Cao, Jiaqi Yao, He Ren, Zhen Hong and Naren Fang
Sustainability 2025, 17(15), 6745; https://doi.org/10.3390/su17156745 - 24 Jul 2025
Viewed by 278
Abstract
The interconnections among water, energy, and food (WEF) systems are growing increasingly complex, making it essential to understand their evolutionary mechanisms and coordination barriers to enhance regional resilience and sustainability. In this study, we investigated the WEF system in Northeast China by constructing [...] Read more.
The interconnections among water, energy, and food (WEF) systems are growing increasingly complex, making it essential to understand their evolutionary mechanisms and coordination barriers to enhance regional resilience and sustainability. In this study, we investigated the WEF system in Northeast China by constructing a comprehensive indicator system encompassing resource endowment and utilization efficiency. The coupling coordination degree (CCD) of the WEF system was quantitatively assessed from 2001 to 2022. An obstacle degree model was employed to identify key constraints, while grey relational analysis was used to evaluate the driving influence of individual indicators. Furthermore, a co-evolution model based on logistic growth and competition–cooperation dynamics was developed to simulate system interactions. The results reveal the following: (1) the regional WEF-CCD increased from 0.627 in 2001 to 0.769 in 2022, reaching the intermediate coordination level, with the CCDs of the food, water, and energy subsystems rising from 0.39 to 0.62, 0.38 to 0.60, and 0.40 to 0.55, respectively, highlighting that the food subsystem had the most stable and significant improvement; (2) Jilin Province attained the highest WEF-CCD, 0.850, in 2022, while that for Heilongjiang remained the lowest, at 0.715, indicating substantial interprovincial disparities; (3) key indicators, such as food self-sufficiency rate, electricity generation, and ecological water use, functioned as both core constraints and major drivers of system performance; (4) co-evolution modeling revealed that the food subsystem exhibited the fastest growth, followed by water and energy (α3  > α1 >  α2 > 0), with mutual promotion between water and energy subsystems and inhibitory effects from the food subsystem, ultimately converging toward a stable equilibrium state; and (5) interprovincial co-evolution modeling indicated that Jilin leads in WEF system development, followed by Liaoning and Heilongjiang, with predominantly cooperative interactions among provinces driving convergence toward a stable and coordinated equilibrium despite structural asymmetries. This study proposes a transferable, multi-method analytical framework for evaluating WEF coordination, offering practical insights into bottlenecks, key drivers, and co-evolutionary dynamics for sustainable resource governance. Full article
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19 pages, 41284 KiB  
Article
Coordinated Dual-Fin Actuation of Bionic Ocean Sunfish Robot for Multi-Modal Locomotion
by Lidong Huang, Zhong Huang, Quanchao Liu, Zhihao Song, Yayi Shen and Mengxing Huang
Biomimetics 2025, 10(8), 489; https://doi.org/10.3390/biomimetics10080489 - 24 Jul 2025
Viewed by 432
Abstract
This paper presents a bionic dual-fin underwater robot, inspired by the ocean sunfish, that achieves multiple swimming motions using only two vertically arranged fins. This work demonstrates that a mechanically simple platform can execute complex 2-D and 3-D motions through advanced control strategies, [...] Read more.
This paper presents a bionic dual-fin underwater robot, inspired by the ocean sunfish, that achieves multiple swimming motions using only two vertically arranged fins. This work demonstrates that a mechanically simple platform can execute complex 2-D and 3-D motions through advanced control strategies, eliminating the need for auxiliary actuators. We control the two fins independently so that they can perform cooperative actions in the water, enabling the robot to perform various motions, including high-speed cruising, agile turning, controlled descents, proactive ascents, and continuous spiraling. The swimming performance of the dual-fin robot in executing multi-modal locomotion is experimentally analyzed through visual measurement methods and onboard sensors. Experimental results demonstrate that a minimalist dual-fin propulsion system of the designed ocean sunfish robot can provide speed (maximum cruising speed of 1.16 BL/s), stability (yaw amplitude less than 4.2°), and full three-dimensional maneuverability (minimum turning radius of 0.89 BL). This design, characterized by its simple structure, multiple motion capabilities, and excellent motion performance, offers a promising pathway for developing robust and versatile robots for diverse underwater applications. Full article
(This article belongs to the Special Issue Bionic Robotic Fish: 2nd Edition)
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43 pages, 7260 KiB  
Article
A Solution Method for Non-Linear Underdetermined Equation Systems in Grounding Grid Corrosion Diagnosis Based on an Enhanced Hippopotamus Optimization Algorithm
by Jinhe Chen, Jianyu Qi, Yiyang Ao, Keying Wang and Xin Song
Biomimetics 2025, 10(7), 467; https://doi.org/10.3390/biomimetics10070467 - 16 Jul 2025
Viewed by 466
Abstract
As power grids scale and aging assets edge toward obsolescence, grounding grid corrosion has become a critical vulnerability. Conventional diagnosis must fit high-dimensional electrical data to a physical model, typically yielding a nonlinear under-determined system fraught with computational burden and uncertainty. We propose [...] Read more.
As power grids scale and aging assets edge toward obsolescence, grounding grid corrosion has become a critical vulnerability. Conventional diagnosis must fit high-dimensional electrical data to a physical model, typically yielding a nonlinear under-determined system fraught with computational burden and uncertainty. We propose the Enhanced Biomimetic Hippopotamus Optimization (EBOHO) algorithm, which distills the river-dwelling hippo’s ecological wisdom into three synergistic strategies: a beta-function herd seeding that replicates the genetic diversity of juvenile hippos diffusing through wetlands, an elite–mean cooperative foraging rule that echoes the way dominant bulls steer the herd toward nutrient-rich pastures, and a lens imaging opposition maneuver inspired by moonlit water reflections that spawn mirror candidates to avert premature convergence. Benchmarks on the CEC 2017 suite and four classical design problems show EBOHO’s superior global search, robustness, and convergence speed over numerous state-of-the-art meta-heuristics, including prior hippo variants. An industrial case study on grounding grid corrosion further confirms that EBOHO swiftly resolves the under-determined equations and pinpoints corrosion sites with high precision, underscoring its promise as a nature-inspired diagnostic engine for aging power system infrastructure. Full article
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21 pages, 3403 KiB  
Review
Research Progress on Emerging Pollutants in Watershed Water Bodies: A Bibliometric Approach
by Lei Chen, Yuhan Liu, Chunzhong Wei, Yanbo Jiang, Si Zeng, Chunfang Zhang, Wenjie Zhang and Yue Jin
Water 2025, 17(14), 2076; https://doi.org/10.3390/w17142076 - 11 Jul 2025
Viewed by 322
Abstract
Watershed water bodies, as a key part of the Earth’s water cycle, were identified as an important destination for emerging pollutants. However, existing research primarily focused on single environmental zones, such as lakes or rivers, lacking a comprehensive understanding at the watershed scale. [...] Read more.
Watershed water bodies, as a key part of the Earth’s water cycle, were identified as an important destination for emerging pollutants. However, existing research primarily focused on single environmental zones, such as lakes or rivers, lacking a comprehensive understanding at the watershed scale. Scientific knowledge mapping and tools, such as Bibliometrics, VOSviewer, and CiteSpace, were employed to conduct a comprehensive analysis of literature on emerging pollutants in watershed water bodies from the WOSCC database. The results indicated that, from 2000 to 2024, research themes in this field gradually expanded from the identification and detection of pollutants to source analysis, environmental behavior, ecological effects, risk assessment, and social governance. Keyword co-occurrence analysis revealed high-frequency terms such as “waste-water,” “persistent organic pollutants,” “polycyclic aromatic hydrocarbons,” and pollutants related to sediments. Burst keyword analysis showed that early keywords like “polychlorinated biphenyls” were gradually replaced by more recent terms like “particles.” Additionally, it was found that cooperation between China and the United States was close, and research was increasingly interdisciplinary. Finally, the main challenges in the current research were summarized, and future research directions were proposed, aiming to provide theoretical support and data foundation for scientific studies and policymaking concerning emerging pollutants in watershed water bodies. Full article
(This article belongs to the Special Issue Water Treatment Technology for Emerging Contaminants, 2nd Edition)
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36 pages, 5746 KiB  
Systematic Review
Decentralized Renewable-Energy Desalination: Emerging Trends and Global Research Frontiers—A Comprehensive Bibliometric Review
by Roger Pimienta Barros, Arturo Fajardo and Jaime Lara-Borrero
Water 2025, 17(14), 2054; https://doi.org/10.3390/w17142054 - 9 Jul 2025
Viewed by 710
Abstract
Decentralized desalination systems driven by renewable energy sources have surfaced as a feasible way to alleviate water scarcity in arid and rural areas. This bibliometric study aims to clarify the research trends, conceptual frameworks, and cooperative dynamics in the scientific literature on decentralized [...] Read more.
Decentralized desalination systems driven by renewable energy sources have surfaced as a feasible way to alleviate water scarcity in arid and rural areas. This bibliometric study aims to clarify the research trends, conceptual frameworks, and cooperative dynamics in the scientific literature on decentralized renewable-powered desalination techniques. Using a thorough search approach, 1354 papers were found. Duplicates, thematically unrelated works, and entries with poor information were removed using the PRISMA 2020 framework. A selected 832 relevant papers from a filtered dataset were chosen for in-depth analysis. Quantitative measures were obtained by means of Bibliometrix; network visualisation was obtained by means of VOSviewer (version 1.6.19) and covered co-authorship, keyword co-occurrence, and citation structures. Over the previous 20 years, the data show a steady rise in academic production, especially in the fields of environmental science, renewable energy engineering, and water treatment technologies. Author keyword co-occurrence mapping revealed strong theme clusters centred on solar stills, thermoelectric modules, reverse osmosis, and off-grid systems. Emphasizing current research paths and emerging subject borders, this paper clarifies the intellectual and social structure of the field. The outcomes are expected to help policy creation, cooperative projects, and strategic planning meant to hasten innovation in sustainable and decentralized water desalination. Full article
(This article belongs to the Section Water-Energy Nexus)
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18 pages, 3967 KiB  
Article
Development of Joint Rural Water Services in Finland, 1872–2022
by Tapio S. Katko, Vesa P. Arvonen, Petri S. Juuti, Riikka P. Juuti and Eric J. Nealer
Earth 2025, 6(3), 76; https://doi.org/10.3390/earth6030076 - 9 Jul 2025
Viewed by 734
Abstract
Community-based systems present a key option for water services, especially in rural areas. Our goal is to achieve a state-of-the-art understanding of joint rural water supply development in Finland over 150 years. A mixed-methods approach was used: a literature survey and a questionnaire [...] Read more.
Community-based systems present a key option for water services, especially in rural areas. Our goal is to achieve a state-of-the-art understanding of joint rural water supply development in Finland over 150 years. A mixed-methods approach was used: a literature survey and a questionnaire to selected experts. Based on the literature, a table including 23 decisions considered the most influential strategic events from 1872 to 2022 was produced. The table was sent to 10 selected experts known to be deeply familiar with the theme, all of whom replied. Joint rural water services in Finland have evolved based on demand through co-operative principles. The first documented scheme was constructed in 1872, while governmental financial support to rural water services started in 1951. It expanded in various forms until it dramatically declined in recent years. Multi-locality may increase the need for these services in the future. The expert survey revealed the following most influential long-term decisions: the first official water co-operative established in 1907, the land reform for immigrants and war veterans introduced in 1945, the Committee for Rationalisation of Households established in 1950, the start of domestic manufacturing of plastic pipes in 1954, and the Water Act enacted in 1962 to start water pollution control. This paper reminds us that urban and rural services are not contradictory but can supplement each other. Full article
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18 pages, 12442 KiB  
Article
Properties of Diamond-like Coatings in Tribological Systems Lubricated with Ionic Liquid
by Krystyna Radoń-Kobus and Monika Madej
Coatings 2025, 15(7), 799; https://doi.org/10.3390/coatings15070799 - 8 Jul 2025
Viewed by 362
Abstract
The paper shows the effect of using a lubricant in the form of an ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM-PF6), on the tribological properties of a hydrogenated diamond-like coating (DLC) doped with tungsten a-C:H:W. The coatings were deposited on 100Cr6 steel by [...] Read more.
The paper shows the effect of using a lubricant in the form of an ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM-PF6), on the tribological properties of a hydrogenated diamond-like coating (DLC) doped with tungsten a-C:H:W. The coatings were deposited on 100Cr6 steel by plasma-enhanced chemical vapor deposition PECVD. Tribological tests were carried out on a TRB3 tribometer in a rotary motion in a ball–disc combination. 100Cr6 steel balls were used as a counter-sample. Friction and wear tests were carried out for discs made of 100Cr6 steel and 100Cr6 steel discs with a DLC coating. They were performed under friction conditions with and without lubrication under 10 N and 15 N loads. The ionic liquid BMIM-PF6 was used as a lubricant. Coating thickness was observed on a scanning microscope, and the linear analysis of chemical composition on the cross-section was analyzed using the EDS analyzer. The confocal microscope with an interferometric mode was used for analysis of the geometric structure of the surface before and after the tribological tests. The contact angle of the samples for distilled water, diiodomethane and ionic liquid was tested on an optical tensiometer. The test results showed good cooperation of the DLC coating with the lubricant. It lowered the coefficient of friction in comparison to steel about 20%. This indicates the synergistic nature of the interaction: DLC coating–BMIM-PF6 lubricant–100Cr6 steel. Full article
(This article belongs to the Special Issue Tribological and Mechanical Properties of Coatings)
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22 pages, 2944 KiB  
Article
From Wastewater to Soil Amendment: A Case Study on Sewage Sludge Composting and the Agricultural Application of the Compost
by Csilla Almási, Zoltán Veres, Ibolya Demeter, Viktória Orosz, Tímea Tóth, Mostafa M. Mansour, István Henzsel, Zsolt Bogdányi, Tamás András Szegi and Marianna Makádi
Water 2025, 17(13), 2026; https://doi.org/10.3390/w17132026 - 5 Jul 2025
Viewed by 574
Abstract
The treatment of wastewater and the utilization of the by-products of these processes are an important part of the circular economy. The sewage sludge, a result of wastewater treatment, could be used as a material for plant nutrient supply and/or soil-improving products. The [...] Read more.
The treatment of wastewater and the utilization of the by-products of these processes are an important part of the circular economy. The sewage sludge, a result of wastewater treatment, could be used as a material for plant nutrient supply and/or soil-improving products. The city of Nyíregyháza, Hungary, with 120,000 citizens, has a well-planned water treatment plant operated by Nyírségvíz Ltd., which, in cooperation with the Research Institute of Nyíregyháza, developed a municipal sewage sludge compost (SSC). The closed loop of sewage water treatment and the agricultural utilization of its by-product has been developed and managed. The compost product called Nyírkomposzt was planned for acidic sandy soils. Beyond the agronomic benefits, the sustainable and environmentally sound utilization of SSC reduces sewage sludge disposal. This active involvement of a water utility company demonstrates the potential of cross-sectoral cooperation in solving environmental problems. The quality of the compost fits the Hungarian legislation. To study the effects of 0, 9, 18, and 27 t ha−1 doses of compost on acidic sandy soil, a long-term small plot experiment was started in 2003. The cumulative effects of the regular (every third year, last treatment before sampling in 2021) application of the SSC showed positive changes in basic soil properties, depending on the doses used. Increasing values were found in the case of pH from 4.5 to 6, plant available P2O5 from 240 to 690 ppm, and plant available K2O from 180 to 200 ppm. The plant-available zinc and copper content also increased. Soil organic matter and total N content stabilized at around 0.9% and 0.08%, respectively. The grain yields of winter rye also increased in both investigated years. The yields of 18 t ha−1 treatment were about two times higher compared to the control, but only in 2022 was the difference significant. Our findings underscore the potential of well-planned SSC applications to improve the fertility of ploughed, acidic sandy soil, taking into account the theory of the circular economy by utilizing wastes and decreasing landfilling. Full article
(This article belongs to the Special Issue Treatment and Resource Utilization of Urban Sewage Sludge)
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16 pages, 1229 KiB  
Article
Nonlinear Hydrogen Bond Network in Small Water Clusters: Combining NMR, DFT, FT-IR, and EIS Research
by Ignat Ignatov, Yordan G. Marinov, Paunka Vassileva, Georgi Gluhchev, Ludmila A. Pesotskaya, Ivan P. Jordanov and Mario T. Iliev
Symmetry 2025, 17(7), 1062; https://doi.org/10.3390/sym17071062 - 4 Jul 2025
Cited by 1 | Viewed by 513
Abstract
Water’s unique physicochemical properties arise from its dynamic hydrogen-bonding network, yet the precise molecular threshold at which these cooperative behaviors emerge remains a key question. This study employed nuclear magnetic resonance (NMR) spectroscopy and density functional theory (DFT) calculations to investigate the evolution [...] Read more.
Water’s unique physicochemical properties arise from its dynamic hydrogen-bonding network, yet the precise molecular threshold at which these cooperative behaviors emerge remains a key question. This study employed nuclear magnetic resonance (NMR) spectroscopy and density functional theory (DFT) calculations to investigate the evolution of hydrogen bonding strength in small water clusters, ranging from dimers to pentamers. The observed exponential increase in NMR chemical shift up to the pentamer reflects growing hydrogen bond cooperativity, identifying the (H2O)5 cluster as a critical structural and energetic threshold. At this size, the network achieves sufficient connectivity to support key bulk-like phenomena such as proton transfer and dielectric relaxation. These conclusions were corroborated by complementary FT-IR and electrochemical impedance spectroscopy (EIS) measurements of bulk water. Our results position the water pentamer as the molecular onset of emergent solvent behavior, effectively bridging the divide between discrete clusters and the macroscopic properties of liquid water. Full article
(This article belongs to the Section Chemistry: Symmetry/Asymmetry)
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