Search Results (63)

Increasing plastic waste and limited recycling rates underscore the need for value-added recycling applications. Polymers commonly present in plastic waste streams, including packaging films, bottles, caps, and rigid containers, may provide a practical pathway for developing plastic-modified asphalt binder (PMAB) systems. In this study, virgin high-density polyethylene (HDPE), low-density polyethylene (LDPE), and polypropylene (PP) were selected as reference modifiers to evaluate their intrinsic effects on performance grade (PG) 58-28 and PG 67-22 base binders. Conventional high-, intermediate-, and low-temperature gradings were complemented by $\Delta T_c$, the Christensen–Anderson R-value (R-value), the Glover–Rowe (G-R) parameter, Linear Amplitude Sweep (LAS) fatigue analysis modeled via Viscoelastic Continuum Damage (VECD), rheological master curves, and extended Bending Beam Rheometer (BBR) testing. Modification improved high-temperature grading and LAS-based fatigue response while increasing master-curve stiffness. However, $\Delta T_c$, G-R parameter, and extended BBR results indicated increased low-temperature cracking susceptibility. High-temperature grades increased by 3.4 °C, 2.8 °C, and 2.3 °C per percent HDPE, LDPE, and PP, respectively, whereas low-temperature grade losses reached 7.8 °C; HDPE produced the highest high-temperature grade improvement, while LDPE showed the greatest extended BBR grade loss, and PP exhibited the fastest physical hardening rate. These results provide a controlled binder-level baseline for evaluating HDPE, LDPE, and PP as modifiers for future PMAB development. Full article

High-strength nanofiber yarns exhibit pronounced nonlinear tensile responses arising from their hierarchical fibrous architecture, yet compact constitutive descriptions remain limited. Here, high-strength polyacrylonitrile nanofiber yarns were prepared by post-drawing as-spun yarns above the glass transition temperature, and their aligned, stacked morphology was confirmed by scanning electron microscopy. Monotonic tensile tests at different loading rates were used to quantify the rate-dependent stress–strain response. The tangent modulus derived from the tensile curve varied strongly with strain, confirming clear deviation from linear viscoelasticity. To capture this behavior, two effective models were established: a modified nonlinear three-element model and a structural four-element model incorporating a nonlinear elastic contribution. Closed-form stress–strain expressions were derived for constant strain-rate loading and fitted to experimental data using nonlinear regression. Both models reproduced the measured tensile curves with high accuracy over the investigated loading-rate range, with correlation coefficients close to unity and low fitting errors. The identified parameters were highly consistent between formulations, indicating functional equivalence for the present monotonic tensile dataset. These results provide a compact framework for characterizing and designing hierarchical polymer nanofiber yarns. Full article

To address the lack of systematic quantitative studies on waterborne epoxy resin (WER)-modified emulsified asphalt regarding its rheological optimization and engineering applicability, this study fills the gap by preparing WER-modified emulsified asphalt via a two-step process. New findings reveal that 20% WER content significantly enhances elastic components, creep–recovery, fatigue life, and fracture energy. The main objective is to establish a theoretical basis for high-performance pavement materials. Modified emulsified asphalt specimens with different waterborne epoxy resin contents were prepared using a two-step method of “emulsification followed by compounding”. The stability of the emulsions was quantitatively evaluated by zeta potential, storage stability, particle size distribution, and demulsification time. Their rheological parameters, multi-stress creep–recovery characteristics, fatigue life, and low-temperature crack resistance were systematically tested across the full temperature range using a dynamic shear rheometer and a bending beam rheometer. In addition, the bonding performance, strength development behavior, and water resistance durability were comprehensively assessed through pull-out tests, Marshall stability and splitting strength tests, as well as freeze–thaw cycle tests. These properties were compared with those of unmodified emulsified asphalt (UEA-0) and SBR-modified emulsified asphalt (SBR-EA). With an increase in waterborne epoxy resin content, the elastic component of the modified asphalt improved significantly, and the phase angle continuously decreased. The specimen with 20% waterborne epoxy resin content (WER-EA-20) exhibited the best performance: its phase angle was lower than those of the other groups under high-, medium-, and low-temperature conditions. After seven creep–recovery cycles, its creep–recovery rate remained at 33%, substantially higher than the 8% observed for the unmodified specimen. The fatigue life reached 15,000 cycles under a shear stress of 2.1 MPa. At −10 °C, the fracture strength was 0.92 MPa, and the fracture energy reached 21.4 J. Furthermore, the pull-out strength of WER-EA-20 was 0.86 MPa, with the failure mode identified as asphalt cohesive failure. After 37 days of curing, the Marshall stability reached 22.5 kN, and the splitting strength was 1.36 MPa. After 40 freeze–thaw cycles, the freeze–thaw splitting strength ratio (TSR) of WER-EA-20 remained above 75%, representing an improvement of more than 110% compared to the unmodified UEA-0 (TSR ≈ 35.5%), which highlights the significant enhancement in water resistance imparted by the waterborne epoxy resin. Compared to SBR-EA, WER-EA-20 has a higher softening point, a lower suitable mixing temperature, and better anti-aging properties. Waterborne epoxy resin can effectively improve the viscoelastic properties and overall road performance of emulsified asphalt, and the modification effect increases with increasing dosage. Full article

To explore the fracture performance and crack propagation mechanism of basalt fiber (BF)-reinforced asphalt mixtures and overcome the limitations of single-factor performance evaluations, this study systematically investigates the effects of aggregate gradation, material scale and test conditions on fracture behavior. The semi-circular bending (SCB) test was integrated with digital image correlation (DIC) technology to synchronously obtain macroscopic fracture parameters and full-field displacement/strain fields. The findings showed that fine aggregate particle size could better utilize the bridging effect of BFs, increasing fracture energy by 25.8% versus 15.9% for the coarse aggregate particle size. A consistent enhancement in fracture performance is observed between the asphalt mixture and the asphalt mortar after BF incorporation. Under the same test conditions, the addition of fibers increased the fracture energy by 25.8% for the mixture and by 28.4% for the mortar, while fracture toughness increased by 6.9% and 8.3%, respectively. The lower loading rate reduces the reinforcement effect due to viscoelastic stress relaxation, while low temperatures enhance the relative crack resistance efficiency of BFs. The incorporation of fibers increases the crack tortuosity coefficient by a range of 4–14%, leading to greater energy dissipation. However, low temperatures absolutely dominate the crack morphology. This study provides an experimental reference for the differentiated design of BF-reinforced asphalt mixtures under different gradation types and climatic conditions. Full article

The demand for eco-friendly viscosity modifiers in food, cosmetics, and lubricants has increased, promoting the development of high-performance, sustainable materials. Low-molecular-weight gelators (LMWGs) are promising candidates, though their behavior in complex systems remains underexplored. In this study, a novel alkylamido isophthalic acid-based LMWG (AIPA–gallic acid) was synthesized. Its performance was evaluated in vegetable oil, mineral oil, and cocoa butter using rheological measurements across varying concentrations and temperatures, with all dynamic rheological measurements conducted in the viscoelastic region. Cacao butter is solid at 15 °C, so the flow curve that can be obtained at this temperature should show high values not comparable with the other liquid oils. No slippage phenomenon was observed. Using a step-rate protocol before acquiring the flow curves, no time-dependent behavior (thixotropy) was observed. Frequency and flow sweep tests were used to assess viscoelastic properties, interaction strength, and coordination number. Results revealed that incorporating AIPA–gallic acid at 4 wt% increased the viscosity by 74 times (at 25 °C) in mineral oil, compared to an increase of about four orders of magnitude in vegetable oil. This suggests the formation of intermolecular interactions that lead to an increased momentum transport process, which is significantly higher in vegetable oil. In contrast, cocoa butter exhibited minimal rheological changes, suggesting that no gelation occurred. Analysis using the weak gel model confirmed that viscosity enhancement arises from a structured network in mineral and vegetable oils, but not in cocoa butter. Temperature-dependent variations in structural parameters further highlight the role of molecular interactions between the gelator and the oil matrix. Full article

Aging has a significant influence on the rheological behavior and service performance of asphalt binders. In this study, base asphalt binder (BAB) and rubberized asphalt binder (RAB) with different aging levels were investigated to clarify their aging evolution and performance correlations. Rheological tests were conducted to evaluate high-temperature rutting resistance, intermediate-temperature fatigue performance, and low-temperature cracking resistance. The 2S2P1D viscoelastic model was used to analyze the evolution of viscoelastic parameters, while gel permeation chromatography (GPC) was adopted to characterize molecular weight changes during aging. The results showed that aging increased the rutting resistance of both binders, but reduced fatigue performance and low-temperature cracking resistance. Among the 2S2P1D viscoelastic model parameters, G_∞, δ, and β were more sensitive to aging than the other parameters and exhibited relatively clear variation trends. Selected viscoelastic parameters also showed significant correlations with rheological performance indices. GPC results indicated that both binder systems progressively evolved toward higher molecular weight during aging, with the molecular weight distribution curves shifting toward the high-molecular-weight region. For RAB, M_w was more sensitive to aging than M_n and showed some fluctuation at intermediate aging stages, reflecting a more complex molecular evolution. Overall, the results indicate that selected 2S2P1D viscoelastic parameters can serve as sensitive indicators of aging evolution and provide a useful basis for interpreting the performance correlations and rheological changes of asphalt binders from a viscoelastic perspective. Full article

Poly(ethylene terephthalate) (PET) composites reinforced with reduced graphene oxide (rGO) were investigated in order to elucidate the influence of nanofiller concentration and compatibilization on the viscoelastic relaxation behavior across the glass transition. Composites containing 0.1 and 0.5 wt% rGO were prepared by melt blending, and selected systems incorporated 5 wt% of an ionomeric polyester (PETi) as compatibilizer to enhance interfacial adhesion. The thermomechanical response was characterized using dynamic mechanical analysis (DMA) as a function of temperature. Experimental results revealed a strong dependence of stiffness, damping, and glass transition behavior on filler concentration and interfacial interactions. While low rGO loading produced minor changes, the incorporation of 0.5 wt% rGO significantly increased the glassy modulus and shifted the glass transition temperature, indicating restricted segmental mobility. Compatibilized systems exhibited further stiffness enhancement and modified relaxation dynamics due to improved stress transfer and interphase development. To capture the distributed nature of the relaxation processes, the glass transition region was modeled using a fractional Zener model (FZM) with two spring-pot elements within a cooperative relaxation framework. The model successfully reproduced the experimental $E^{\prime }$ and $tan\delta$ curves and revealed systematic variations in the fractional exponents and cooperative parameters. The results demonstrate that the introduction of rGO and compatibilizer progressively transforms the relaxation spectrum of PET from a relatively uniform segmental process into a heterogeneous, interfacially mediated viscoelastic response that is naturally described by fractional rheology. Full article

To address the lack of systematic comparison regarding rheological properties and the unclear structure–property relationships among three core fracturing fluid materials including synthetic polymers, vegetable gums, and microbial polysaccharides, this study selected acrylamide-based polymers, hydroxypropyl guar gum and xanthan gum as the representative systems. The steady-state viscosity, rheological curves, thixotropy, viscoelasticity, and temperature-shear resistance of the three samples were systematically characterized at concentrations ranging from 0.1 to 0.7 wt% using an MCR301 rotational rheometer. The outcomes indicate that the structural strength values of all three materials increase with rising concentration, but their rheological behaviors and stability differ significantly due to distinct molecular structures. The acrylamide-based copolymer forms a temporary network via weak hydrogen bonds (amide-carboxyl or amide-amide) and physical entanglements, exhibiting thixotropy and a stress pre-elastic response. The most significant effects occur at 0.7 wt%, with a thixotropic loop area of 2.874 Pa·s⁻¹ and a stress overshoot of 4.97 Pa.; hydroxypropyl guar gum has insufficient thermal stability and poor heat resistance. Its viscosity retention rate is as low as 31%, and it always exhibits a solution-type rheological property of G′ < G″; the xanthan gum exhibits elastic gel properties with tanδ < 1 due to its double-helix molecular structure. It has excellent temperature shear tolerance and the viscosity retention value can reach up to 98.6 mPa·s. Two mathematical models were established and demonstrated strong applicability: a modified Carreau model for flow curve fitting yielded a coefficient of determination (R²) greater than 0.95, enabling accurate description of fluid-type transitions; a four-parameter equation for temperature–shear resistance curves also achieved an R² above 0.95, effectively characterizing viscosity evolution with temperature. Full article

Tight conglomerate reservoirs exhibit strong pore-scale heterogeneity and extremely low permeability, in which spontaneous imbibition is primarily governed by capillary and viscoelastic effects. In this study, the imbibition dynamics of four representative fracturing fluid systems, including slickwater, 3% potassium chloride (KCl) brine, hydrolyzed polyacrylamide (HPAM) viscoelastic fluid, and a nanoemulsion (NE), were investigated using a temperature-controlled nuclear magnetic resonance (NMR) monitoring system. This approach enables real-time quantification of fluid uptake and pore-scale redistribution through time-resolved T₂ spectral analysis. The experimental results reveal a three-stage imbibition process consisting of rapid capillary-driven uptake, viscoelastic-retarded transition, and final equilibrium. Among the four fracturing fluid systems, the nanoemulsion exhibits the lowest interfacial tension (1.72 mN/m), the strongest wettability alteration, and the highest equilibrium recovery (0.76), which is nearly 80% greater than that of slickwater. Based on these observations, a multiscale capillary–viscoelastic coupling model was developed by extending the Lucas–Washburn framework to incorporate pore-size distribution, time-dependent wettability evolution, and viscoelastic damping. The model fits the experimental data well (R² > 0.90) and identifies viscosity as the most influential parameter controlling the imbibition rate (sensitivity = 0.78). Energy analysis further indicates that capillary energy dominates the early stage, whereas viscoelastic energy storage sustains fluid transport during the later stage. SEM observations were further used to qualitatively corroborate pore heterogeneity and pore–mineral associations, supporting the NMR-based pore-scale interpretation. This study provides a quantitative framework for describing non-Newtonian capillary flow in tight conglomerate rocks and enhances the understanding of capillary–viscoelastic interactions relevant to multiphase fluid migration. Full article

This study systematically investigates the complex nonlinear rheological behavior of magnetorheological fluids (MRFs) and greases (MRGs) through comparative experiments under two shear modes (steady-state shear and large-amplitude oscillatory shear) at room temperature. Results demonstrate that during steady-state shear tests, the apparent viscosity of both materials decreases with the increasing shear rate, exhibiting shear-thinning behavior at high shear rates that aligns with the Herschel–Bulkley constitutive model. Throughout the logarithmically increasing shear rate range, the viscosity and shear stress of MRF consistently exceed those of MRG. Under low-frequency, large-amplitude oscillatory shear (LAOS) conditions, both materials display pronounced viscoelasticity and hysteresis. At higher current levels, the maximum shear stress of MRF surpasses MRG, but its hysteresis loops exhibit reduced smoothness. The Bouc–Wen model accurately characterizes the nonlinear hysteresis of both materials, with model parameters successfully identified via a genetic algorithm. This work establishes a universal framework for the dynamic mechanical response mechanisms of magnetorheological materials, providing theoretical guidance for designing and predicting the performance of smart damping devices. Full article

In this study, the heat treatment of white kidney beans was optimized by a single-factor experiment and an orthogonal experiment. Taking in vitro digestibility as an index, the optimum technological parameters for heating white kidney beans were determined as follows: water addition of 225%, medium pressure heating for 30 min, and a temperature of 110 °C. The results of scanning electron microscopy showed that the layered structure in white kidney beans disappeared, and the original particle morphology was lost. The protein network was broken, forming an irregular agglomerate or flocculent structure, and the porous structure formed by heat-induced crosslinking effectively delayed the contact of amylase. Heat-treated white kidney beans were added to rice, and their nutritional components were determined, and the glycemic index was estimated in vitro to determine the best addition amount. The results of the in vitro digestion rate showed that the rice treated with 40% white kidney beans significantly reduced the glycemic index (eGI = 41.48), and the texture analysis showed that the viscoelasticity of rice could be improved by compounding 40% white kidney beans. It also effectively improves the taste of 100% white rice. This study can provide interdisciplinary solutions for the development of staple food for diabetes and provide a scientific basis for the development of staple food with a low glycemic index and the improvement of traditional diets. Full article

Bitumen ages during production and in asphalt pavements, leading to structural issues and reduced durability of asphalt pavements. The alteration of bitumen’s viscoelastic properties, predominantly attributable to oxidation phenomena, is a hallmark of these processes. This study analyzed the use of a new generation of synthetic wax (SW_LC), which was selected for its low carbon footprint, ability to reduce binder viscosity, and ability to enable the production of WMA. Tall oil amidopolyamines (TOAs), a renewable raw material-based adhesive and aging inhibitor, was also used in this study. It compensates for the unfavorable effect of stiffening the binder with synthetic wax. SW_LC at concentrations of 1.0%, 1.5%, 2.0%, and 2.5% by mass in bitumen, in conjunction with TOAs at concentrations of 0.0%, 0.2%, 0.4%, and 0.6% by bitumen weight were tested at various concentrations. Short-term and long-term aging effects on penetration, softening point, and viscosity multiple creep and stress recovery tests (MSCR), oscillatory tests for the combined complex modulus |G*| and phase shift angle sin(δ) (DSR), and low-temperature characteristics S_m and m_value (BBR) were analyzed. The chemical composition of the binders was then subjected to Fourier Infrared Spectroscopy (FTIR) analysis, which enabled the determination of carbonyl, sulfoxide, and aromaticity indexes. These results indicated that the additives used inhibit the oxidation and aromatization reactions of the bitumen components. The optimal SW_LC and TOA content determined was 1.5% and 0.4% w/w, respectively. These additives reduce aging and positively affect rheological parameters. Full article

High-modulus asphalt, with its excellent fatigue resistance and high-temperature resistance, is gradually becoming a preferred material for the development of durable asphalt pavements. However, its poor low-temperature performance has become one of the key bottlenecks restricting its wide application. In recent years, in-depth analysis of the mechanism underlying the changes in the low-temperature performance of high-modulus asphalt has gradually become a research focus in the field of asphalt pavements. Accordingly, this study selected four representative high-modulus asphalts, conducted bending beam rheometer (BBR) tests to obtain their low-temperature creep parameters, and used three viscoelastic constitutive models to investigate their low-temperature constitutive relationships. Grey relational analysis (GRA) was further applied to evaluate the models. The results show that, when evaluating the low-temperature performance of high-modulus asphalt, the elastic and viscous parameters variation laws, for the three-parameter solid (TPS) model and four-parameter solid (FPS) model, are not obvious and have large fluctuations, and the accuracy of the fitting curves is relatively low, while the Burgers model has extremely high fitting accuracy, with small parameter fluctuations and significant regularity. The GRA model reveals that the Burgers model is more suitable than the TPS and FPS models for describing the low-temperature creep behavior of high-modulus asphalt, which further confirms the reliability of using the Burgers model to evaluate the low-temperature performance of high-modulus asphalt. Full article

Polymer viscoelasticity is crucial for mechanical performance, but conventional low-frequency methods struggle to isolate viscous loss—a key viscosity indicator. This study introduces a high-frequency ultrasonic method to differentiate the polymer viscous dissipation index by analyzing acoustic phase shifts. We employ ultrasonic phase-shift thermometry to measure localized temperature increases resulting from minute variations in sound velocity during controlled heating. This allows for the quantification of viscous loss, which is then used to distinguish between different polymer formulations. Experimental and simulation results on a series of polyurethane specimens with varying Shore hardness levels demonstrate that decawatt-range (10–20 W) ultrasonic irradiation enables sensitive and precise differentiation. Notably, the Shore A70 polyurethane sample exhibited a significantly higher viscous dissipation index, evidenced by the largest temperature rise (27.5 °C) and the highest proportion of viscous heating to total power dissipation (93.1%) under 17 W acoustic irradiation. While this study focuses on commercially available polymers, the method can be extended to evaluate key performance parameters, such as tensile modulus and glass transition temperature, in polymers fabricated under various processing conditions, thereby offering a powerful tool for material quality assessment. Full article

The thermal, thermomechanical, and viscoelastic properties of continuous unidirectional (UD) glass fiber/high-density polyethylene (GF/HDPE) and ultra-high-molecular-weight polyethylene/high-density polyethylene (UHMWPE/HDPE) tapes are characterized in this paper in order to support their use in extreme environments. Unlike prior studies that focus on short-fiber composites or limited thermal conditions, this work examines continuous fiber architectures under five operational environments derived from Army Regulation 70-38, reflecting realistic defense-relevant extremes. Differential scanning calorimetry (DSC) was used to identify melting transitions for GF/HDPE and UHMWPE/HDPE, which guided the selection of test conditions for thermomechanical analysis (TMA) and dynamic mechanical analysis (DMA). TMA revealed anisotropic thermal expansion consistent with fiber orientation, while DMA, via strain sweep, temperature ramp, frequency sweep, and stress relaxation, quantified their temperature- and time-dependent viscoelastic behavior. The frequency-dependent storage modulus highlighted multiple resonant modes, and stress relaxation data were fitted with high accuracy (R² > 0.99) to viscoelastic models, yielding model parameters that can be used for predictive simulations of time-dependent material behavior. A comparative analysis between the two material systems showed that UHMWPE/HDPE offers enhanced unidirectional stiffness and better low-temperature performance. At the same time, GF/HDPE exhibits lower thermal expansion, better transverse stiffness, and greater stability at elevated temperatures. These differences highlight the impact of fiber type on thermal and mechanical responses, informing material selection for applications that require directional load-bearing or dimensional control under thermal cycling. By integrating thermal and viscoelastic characterization across realistic operational profiles, this study provides a foundational dataset for the application of continuous fiber thermoplastic tapes in structural components exposed to harsh thermal and mechanical conditions. Full article