Search Results (244)

The slurry aluminizing process is widely employed to enhance the oxidation and corrosion resistance of nickel-based superalloys used in high-temperature environments such as gas turbines and aerospace engines. This study investigates the effects of the concentration of Al vapors in the reactor chamber and the initial slurry layer thickness on the microstructure, chemical composition, and phase composition of aluminide coatings. Coatings were manufactured on Ni-based superalloy substrates using CrAl powders as an aluminum source and chloride- and fluoride-based activator salts. The effect of the initial thickness of the slurry layer was studied by varying the amount of deposited slurry in terms of mg_slurry/cm²_sample (with constant mg_slurry/cm³_chamber). The microstructure and phase composition of the produced aluminide coatings were evaluated by SEM, EDS, and XRD analysis. Slurry thickness can affect concentration gradients during diffusion, and the best results were obtained with an initial slurry amount of 100 mg_slurry/cm²_sample. The effect of the Al vapor phase in the reaction chamber was then investigated by varying the mg_slurry/cm³_chamber ratio while keeping the slurry layer thickness constant at 100 mg_slurry/cm²_sample. This parameter influences the amount of Al at the substrate surface before the onset of solid-state diffusion, and the best results were obtained for a 6.50 mg_slurry/cm³_chamber ratio with the formation of 80 µm coatings (excluding the interdiffusion zone) with a β-NiAl phase throughout the thickness. To validate process flexibility, the same parameters were successfully applied to produce platinum-modified aluminides with a bi-phasic ζ-PtAl2 and β-(Ni,Pt)Al microstructure. Full article

Mesoporous silicon dioxide films have been shown to be well suited as adhesion-promoting interlayers for generating high-strength polymer–metal interfaces. These films can be fabricated via microwave plasma-enhanced chemical vapor deposition using the precursor hexamethyldisiloxane and oxygen as working gas. The resulting mesoporous structures enable polymer infiltration during overmolding, which leads to a nanoscale form-locking mechanism after solidification. This mechanism allows for efficient stress transfer across the interface and makes the resulting adhesion highly dependent on the morphology of the deposited film. To gain a deeper understanding of the underlying deposition mechanisms and improve process stability, this work investigates the growth behavior of mesoporous silica films using a multiple regression analysis approach. The seven process parameters coating time, distance, chamber pressure, substrate temperature, flow rate, plasma pulse duration, and pause-to-pulse ratio were systematically varied within a Design of Experiments framework. The resulting films were characterized by their free surface area, mean agglomerate diameter, and film thickness using digital image analysis, white light interferometry, and atomic force microscopy. The deposited films exhibit a wide range of morphological appearances, ranging from quasi-dense to dust-like structures. As part of this research, the free surface area varied from 15 to 55 percent, the mean agglomerate diameter from 17 to 126 nm, and the film thickness from 35 to 1600 nm. The derived growth model describes the deposition process with high statistical accuracy. Furthermore, all coatings were overmolded via injection molding and subjected to mechanical testing, allowing a direct correlation between film morphology and their performance as adhesion-promoting interlayers. Full article

Supercritical combustion is a promising technique for improving the efficiency and reducing the emissions of next-generation gas turbines. However, accurately modeling combustion under these conditions remains a challenge, particularly due to the complexity of chemical kinetics. This study aims to evaluate the applicability of a reduced global reaction mechanism compared to the detailed Foundational Fuel Chemistry Model 1.0 (FFCM-1) when performing hydrogen combustion with supercritical carbon dioxide and argon as diluents. Computational fluid dynamics simulations were conducted in two geometries: a simplified tube for isolating chemical effects and a combustor with cooling channels for practical evaluation. The analysis focuses on the evaluation of velocity, temperature, and the water vapor mass fraction distributions inside the combustion chamber. The results indicate good agreement between the global and detailed mechanisms, with average relative errors below 2% for supercritical argon and 4% for supercritical carbon dioxide. Both models captured key combustion behaviors, including buoyancy-driven flame asymmetry caused by the high density of supercritical fluids. The findings suggest that global chemistry models can serve as efficient tools for simulating supercritical combustion processes, making them valuable for the design and optimization of future supercritical gas turbine systems. Full article

This work presents the recent development of a fiber-coupled multipass near-infrared (NIR) gas sensor used to monitor water vapor desorption of small material coupons. The gas sensor design employs a White cell topology to maximize the optical path length over a compact, hand-size footprint. Water vapor concentrations are quantified over a large dynamic range by simultaneously applying wavelength modulation and tunable diode laser absorption spectroscopy techniques. A custom headspace optimized for material desorption experiments is assembled using commercially available vacuum chamber components. We provide in situ measurements of water vapor desorption from two geometries of the industrially important silicone elastomer Sylgard-184 as a case study for sensor viability. To corroborate the results, the gas sensor data are compared to numerical simulations based on a triple-mode diffusion–sorption model, consisting of Henry, Langmuir, and Pooling modes. Full article

Hybrid Propellant Rocket Motors (HPRMs) have been advancing rapidly in recent years. These improvements are finally increasing their competitiveness in the global launch-vehicle market. However, some topics, such as the pre-combustion chamber design, still require more in-depth studies. Few studies have examined this subject. This work proposes a low-computational-cost algorithm that calculates the minimum pre-combustion chamber length, with a vaporization and feed-system coupled instability model. This type of analysis is a key tool for minimizing a vehicle’s size, weight, losses, and costs. Additionally, coupling with internal ballistics codes can be implemented. Furthermore, the results were compared with real HPRMs to verify the algorithm’s reliability. The shortened pre-chamber architecture trimmed the inert mass and reduced the feed-system pressure requirement, boosting overall propulsive energy efficiency by $\approx 8\%$ relative to conventional L*-based designs. These gains can lower stored-gas enthalpy and reduce life-cycle CO and CO₂-equivalent emissions, strengthening the case for lighter and more sustainable access-to-space technologies. Full article

Climate change is increasing global temperatures and imposing new constraints on tree regeneration, especially in late-successional species exposed to simultaneous drought and low-light conditions. To disentangle the effects of warming from those of atmospheric drought, we conducted a multifactorial growth chamber experiment on Fagus sylvatica seedlings, manipulating temperature (25 °C and +7.5 °C above optimum), soil moisture (well-watered vs. water-stressed), and light intensity (high vs. low), while maintaining constant vapor pressure deficit (VPD). We assessed growth, biomass allocation, leaf gas exchange, water relations, and xylem hydraulic traits. Warming significantly reduced total biomass, leaf area, and water-use efficiency, while increasing transpiration and residual conductance, especially under high light. Under combined warming and drought, seedlings exhibited impaired osmotic adjustment, reduced leaf safety margins, and diminished hydraulic performance. Unexpectedly, warming under shade promoted a resource-acquisitive growth strategy through the production of low-cost leaves. These results demonstrate that elevated temperature, even in the absence of increased VPD, can compromise drought tolerance in beech seedlings and shift their ecological strategies depending on light availability. The findings underscore the need to consider multiple, interacting stressors when evaluating tree regeneration under future climate conditions. Full article

High heat flux brings about severe thermal problems for light-emitting diode (LED) automotive headlamps in narrow heat removal spaces, which will degrade their performance and lifespan. This study proposes an easily fabricated and feasible 1.3 mm thick 2D T-shaped in-plane ultra-thin vapor chamber (UTVC) for cooling the high heat flux of LED automotive headlamps. The effects of heating modes, unequal input heat load, and orientations on the thermal performance of the T-shaped UTVC are investigated. The results show that double-sided heating can improve the temperature uniformity of the T-shaped UTVC and reduce the thermal resistance compared to the single-sided heating. The lowest thermal resistances under single-sided and double-sided heating are 1.127 K/W at 12 W and 0.898 K/W at 16 W, respectively. When the total power is identical, the proposed 2D T-shaped UTVC can work effectively at unequal input power. The orientations have a significant impact on the thermal performance of the 2D T-shaped UTVC, and the thermal performance under different orientations changes with anti-gravity state < horizontal state < gravity-assisted state. The proposed T-shaped UTVC can work effectively under diverse operating ranges. Full article

In plasma-enhanced chemical vapor deposition (PECVD) processes, thin films can accumulate on the inner chamber walls, resulting in particle contamination and process drift. In this study, we investigate the physical and chemical properties of these wall-deposited films to understand their spatial variation and impact on chamber maintenance. A 6-inch capacitively coupled plasma (CCP)-type PECVD system was used to deposit SiO₂ films, whilst long silicon coupons were attached vertically to the chamber side walls to collect contamination samples. The collected contamination samples were comparatively analyzed in terms of their chemical properties and surface morphology. The results reveal significant differences in hydrogen content and Si–O bonding configurations compared to reference films deposited on wafers. The top chamber wall, located near the plasma region, exhibited higher hydrogen incorporation and larger Si–O–Si bonding angles, while the bottom wall exhibited rougher surfaces with larger particulate agglomerates. These variations were closely linked to differences in gas flow dynamics, precursor distribution, and the energy state of the plasma species at different chamber heights. The findings indicate that top-wall contaminants are more readily cleaned due to their high hydrogen content, while bottom-wall residues may be more persistent and pose higher risks for particle generation. This study provides insights into wall contamination behavior in PECVD systems and suggests strategies for spatially optimized chamber cleaning and conditioning in high-throughput semiconductor processes. Full article

The direct measurement of volatile compounds is becoming increasingly important in assessing site contamination, particularly in relation to human health risk assessment and the design of remediation procedures. This study assesses the influence of direct measurements on the human health risk assessment conducted at a petroleum-contaminated site. Specifically, it provides contaminated-site risk managers with a quantitative comparison of the assessed risks by using measured and modeled data. A total of 16 monitoring campaigns were conducted at a Site of National Interest (SNI) located in Sicily (Italy), during which the hydrocarbon vapor concentrations in the subsurface soil porosity were measured using nested soil gas probes, while the related emitted fluxes were quantified with dynamic flux chambers. Measured data were compared with those obtained with a non-reactive diffusive model using the concentrations measured in the soil. The results highlighted significant overestimations of the expected outdoor concentrations obtained using non-reactive diffusive models by up to four orders of magnitude. These findings underscore the intrinsic limitation of non-reactive diffusive models, which provide overly conservative and unrealistic risk scenarios. Therefore, direct measurements might represent a cost-effective option to account for natural attenuation phenomena occurring in the subsurface, leading to a more realistic human health risk assessment (HHRA). Full article

The tribological behavior of molybdenum disulfide (MoS₂) coatings was systematically investigated under various controlled gas environments in a vacuum chamber. A hemispherical steel pin was slid cyclically over a MoS₂-coated steel disk, prepared via high-speed powder spraying. The study measured both dynamic and static friction coefficients under different gaseous atmospheres, including high vacuum, helium, argon, dry air, and water vapor. In high vacuum (10⁻⁵ Pa), an ultra-low dynamic friction coefficient (µ ≈ 0.01) was observed, while increasing values were recorded with helium (µ ≈ 0.03), argon (µ ≈ 0.04), dry air (µ ≈ 0.17), and water vapor (µ ≈ 0.30). Static friction coefficients followed a similar trend, decreasing significantly upon evacuation of water vapor or injection of inert gases. Surface analyses revealed that friction in vacuum or inert gases promoted smooth wear tracks and basal plane alignment of MoS₂ crystallites, while exposure to water vapor led to rougher, more disordered wear surfaces. Mass spectrometry and energetic modeling of physisorption interactions provided further insights into gas–solid interfacial mechanisms. These results demonstrate that the tribological performance of MoS₂ coatings is highly sensitive to the surrounding gas environment, with inert and vacuum conditions favoring low friction through enhanced basal plane orientation and minimal gas–surface interactions. In contrast, water vapor disrupts this structure, increasing friction and surface degradation. Understanding these interactions is crucial for optimizing MoS₂-based lubrication systems in varying atmospheric or sealed environments. Full article

This study introduces the innovative application of a vapor chamber to mitigate fuel freezing and temperature disparity in power generation cabins operating under extreme cold conditions. A vapor chamber was designed and implemented within a low-temperature power generation platform in Daqing, China, where outdoor temperatures were below −20 °C. The research focused on evaluating the thermal performance of the cabin under natural and forced convection conditions, with and without the vapor chamber. The experimental investigations assessed the effects of the vapor chamber on the thermal dynamics of the power generation cabin, particularly the temperature of the bottom fuel oil and the air temperature distribution. The results indicated that without the vapor chamber significant temperature disparities and potential risks to electrical equipment were present. The vapor chamber effectively utilizes the heat generated by the diesel engine, thus accelerating the heating rate of the fuel at the bottom. It reduces the duration of the decrease in the oil temperature of the upper and lower layers during the initial start-up from 0.44 h and 0.5 h to 0.31 h and 0.35 h, respectively, effectively preventing the risk of fuel freezing in the initial start-up stage. In addition, the installation of the vaporization chamber significantly improves the temperature uniformity of the air inside the cabin. The maximum temperature difference between the upper and lower air in the cabin decreases by 33 °C, effectively improving the overall thermal environment. Full article

This study employed low-pressure chemical vapor deposition (LPCVD) SiN_x as both the gate dielectric layer and surface passivation layer, systematically investigating the effects of different growth conditions on the dielectric layer quality, two-dimensional electron gas (2DEG) characteristics, interface trap density, and devices’ performance, thereby optimizing the growth parameters of LPCVD SiN_x. The experiment investigated the effects of growth parameters such as the growth temperature, chamber pressure, and gas flow ratio on the growth rate of SiN_x during the process of growing SiN_x using the LPCVD technique. Further studies were performed to analyze the impact of SiN_x introduction on the 2DEG performance. The results indicated that both Si-rich and N-rich SiN_x compositions could enhance the 2DEG density improvement induced by SiN_x passivation. The impact of the gas flow ratio on the interface trap density is studied. Through the quantitative characterization of the interface trap density using the pulse-mode I_DS-V_GS method and frequency-dependent capacitance–voltage (C-V) measurement, the results show that the interface trap density decreases with an increased Si-to-N ratio. Full article

The evolution of 5G technology necessitates effective thermal management strategies for compact, high-power devices. The potential of aluminum-based vapor chambers (VCs) as thermal management solutions is recognized, yet the heat transfer performance is limited by the capillary constraints of the wick structures. This study proposes a laser-sintered composite wick to address this limitation. Experimental evaluations were conducted on microgroove wicks (MW) and groove–spiral woven mesh composite wicks (GSCW), utilizing ethanol and acetone as the working fluids. The MW, characterized by a laser spacing of 0.2 mm and two passes, demonstrated a capillary rise of 52.90 mm, while the spiral woven mesh (SWM) achieved a rise of 61.48 mm. Notably, the GSCW surpassed both configurations, reaching a capillary height of 84.57 mm and a capillary parameter ($K/R_{eff}$) of 2.769 μm, which corresponds to increases of 90.15% and 43.76% over the MW and SWM, respectively. This study demonstrates an effective approach to enhancing the capillary performance of aluminum wicks, which provides valuable insights for the design of composite wicks, particularly for applications in ultra-thin aluminum VC. Full article

In the quest for more sensitive gas sensors, researchers have studied how heating the sensors, using UV light, and thermally annealing sensors improve performance. During thermal annealing, the heating process can improve the crystallinity of the material while also increasing the electrode and sensing material interactions to create more available active sites and thus improve sensor performance. Hexadecafluorinated iron (II) phthalocyanine (FePcF₁₆) nanowires have high sensitivity towards NH₃ selectively, and thermally annealing the NWs after the deposition can further improve the sensing response and recovery. For this reason, the effect of annealing FePcF₁₆ NWs at different temperatures was studied to optimize these systems. In this work, FePcF₁₆ NWs were synthesized using physical vapor deposition (PVD) to deposit on interdigitated electrodes. The NWs were characterized by SEM, EDS, PXRD, FTIR, and Raman spectroscopy to confirm their purity. The sensors were annealed at different temperatures, inserted into a gas sensing chamber, and exposed to 1 ppm NH₃ in air, and the electrical current was measured. The results show that the optimized FePcF₁₆ NWs have excellent sensing properties, with a 58% increase in response towards NH₃ after a stepwise annealing at 300 °C confirming these systems are good prospective candidates for sensing NH₃ at room temperature. Full article

Vapor chambers (VCs) are efficient heat spreaders that rely on wicks to realize the circulation of a phase-changing working liquid and can be used to address heat dissipation problems in electronic devices, aerospace, and satellite equipment. In this study, we propose a novel vapor chamber with biomimetic wick structures and composite lattice supports to enhance the thermal management and load-bearing performance of vapor chambers. The experiments and COMSOL multiphysics 6.1 simulation results indicate that the biomimetic design can improve the startup performance, thermal management, and load-bearing performance of the VC. Compared to conventional VCs, at a filling ratio of 20% the biomimetic VC reduces the time to reach a steady state by 11.7% and improves the uniformity of temperature by 7.74%. This study provides a novel design concept for VCs and verifies the operating performance of vapor in high heat flux density cases, providing a reference for the innovative design and enhanced heat transfer of phase change-based thermal management equipment. Full article