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104 pages, 2313 KB  
Review
Twist Fields in Many-Body Physics
by Benjamin Doyon
Entropy 2025, 27(12), 1230; https://doi.org/10.3390/e27121230 - 4 Dec 2025
Viewed by 206
Abstract
The notion of twist fields has played a fundamental role in many-body physics. It is used to construct the so-called disorder parameter for the study of phase transitions in the classical Ising model of statistical mechanics, it is involved in the Jordan–Wigner transformation [...] Read more.
The notion of twist fields has played a fundamental role in many-body physics. It is used to construct the so-called disorder parameter for the study of phase transitions in the classical Ising model of statistical mechanics, it is involved in the Jordan–Wigner transformation in quantum chains and bosonisation in quantum field theory, and it is related to measures of entanglement in many-body quantum systems. I provide a pedagogical introduction to the notion of twist field and the concepts at its roots, and review some of its applications, focussing on the 1 + 1 dimension. This includes locality and extensivity, internal symmetries, semi-locality, the standard exponential form and HEGT fields, path-integral defects and Riemann surfaces, topological invariance, and twist families. Additional topics touched upon include renormalisation and form factors in relativistic quantum field theory, tau functions of integrable PDEs, thermodynamic and hydrodynamic principles, and branch-point twist fields for entanglement entropy. One-dimensional quantum systems such as chains (e.g., quantum Heisenberg model) and field theory (e.g., quantum sine-Gordon model) are the main focus, but I also explain how the notion applies to equilibrium statistical mechanics (e.g., classical Ising lattice model), and how some aspects can be adapted to one-dimensional classical dynamical systems (e.g., classical Toda chain). Full article
(This article belongs to the Special Issue Entanglement Entropy in Quantum Field Theory)
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21 pages, 590 KB  
Article
Nonrelativistic Quantum Dynamics in a Twisted Screw Spacetime
by Faizuddin Ahmed and Edilberto O. Silva
Universe 2025, 11(12), 391; https://doi.org/10.3390/universe11120391 - 27 Nov 2025
Viewed by 277
Abstract
We investigate the nonrelativistic quantum dynamics of a spinless particle in a screw-type spacetime endowed with two independent twist controls that interpolate between a pure screw dislocation and a homogeneous twist. From the induced spatial metric, we build the covariant Schrödinger operator, separate [...] Read more.
We investigate the nonrelativistic quantum dynamics of a spinless particle in a screw-type spacetime endowed with two independent twist controls that interpolate between a pure screw dislocation and a homogeneous twist. From the induced spatial metric, we build the covariant Schrödinger operator, separate variables to obtain a single radial eigenproblem, and include a uniform axial magnetic field and an Aharonov–Bohm (AB) flux by minimal coupling. Analytically, we identify a clean separation between a global, AB-like reindexing set by the screw parameter and a local, curvature-driven mixing generated by the distributed twist. We derive the continuity equation and closed expressions for the azimuthal and axial probability currents, establish practical parameter scalings, and recover limiting benchmarks (AB, Landau, and flat space). Numerically, a finite-difference Sturm–Liouville solver (with core excision near the axis and Langer transform) resolves spectra, wave functions, and currents. The results reveal AB periodicity and reindexing with the screw parameter, Landau fan trends, twist-induced level tilts and avoided crossings, and a geometry-induced near-axis backflow of the axial current with negligible weight in cross-section integrals. The framework maps the geometry and fields directly onto measurable spectral shifts, interferometric phases, and persistent-current signals. Full article
(This article belongs to the Section Foundations of Quantum Mechanics and Quantum Gravity)
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17 pages, 8013 KB  
Article
On the Hardening and Softening Behaviors of Additively Manufactured and Forged Inconel 718 Alloys Under Non-Isothermal Heat Treatments
by Yufeng Dong, Yetao Cheng, Jie Tang, Yubin Ke, Jie Teng and Fulin Jiang
Materials 2025, 18(22), 5174; https://doi.org/10.3390/ma18225174 - 14 Nov 2025
Cited by 1 | Viewed by 429
Abstract
During the heat treatment of nickel-based superalloy (for instance Inconel 718 alloy), the non-isothermal heating and cooling processes significantly influenced precipitation behaviors as well as the final mechanical properties. This study compared the precipitation behaviors and the resulting hardening and softening behaviors of [...] Read more.
During the heat treatment of nickel-based superalloy (for instance Inconel 718 alloy), the non-isothermal heating and cooling processes significantly influenced precipitation behaviors as well as the final mechanical properties. This study compared the precipitation behaviors and the resulting hardening and softening behaviors of additively manufactured and conventionally forged Inconel 718 alloys under non-isothermal heat treatment processes. The results indicated that additively manufactured Inconel 718 alloy accelerated aging precipitation behavior due to the fine dendritic structure during both heating and cooling processes. As a result, the additively manufactured alloy reached peak hardness of ~480 HV at ~650 °C (~100 °C earlier than the forged alloy’s peak hardness of ~460 HV at ~750 °C) during heating and gained almost constant hardness during cooling. Further, the heating rate significantly affected the precipitation behaviors of γ″ and γ′ phases in both alloys. Slower heating rates provided sufficient time for phase transformation, leading to a more pronounced precipitation., e.g., the volume fraction of precipitates in the SLM alloy increased from 1.5% at 5 °C/min to 5.9% at 0.5 °C/min when heated to 850 °C. During cooling process, the twisted grain boundaries of additively manufactured alloy facilitated the precipitation of δ-phase, which in turn inhibited the formation of γ/γ′/γ″ phase. Both alloys exhibited minimum hardness of ~380–390 HV at 1000 °C due to complete dissolution of strengthening phases. This study provides a comparative understanding of non-isothermal phase evolution in AM and forged Inconel 718, which is critical for optimizing heat treatment in aerospace applications. Full article
(This article belongs to the Special Issue New Advances in High-Temperature Structural Materials)
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17 pages, 8237 KB  
Article
Injection-Locked Frequency Multipliers with Single Inductor Component
by Sheng-Lyang Jang, Cheng-Yi Lee and Yun-Chien Lee
Electronics 2025, 14(17), 3360; https://doi.org/10.3390/electronics14173360 - 24 Aug 2025
Viewed by 844
Abstract
This paper proposes a compact inductor design for LC-tank injection-locked frequency multipliers (ILFMs) fabricated using a 0.18 μm CMOS process. The ILFMs use an 8-shaped inductor with two lobes, suppressing the magnetic field generation. Its contents cover one ×2, one ×3, and [...] Read more.
This paper proposes a compact inductor design for LC-tank injection-locked frequency multipliers (ILFMs) fabricated using a 0.18 μm CMOS process. The ILFMs use an 8-shaped inductor with two lobes, suppressing the magnetic field generation. Its contents cover one ×2, one ×3, and one ×6 ILFM. The first ×2 ILFM circuit uses the orthogonal transformer consisting of an 8-shaped inductor and a non-twisted inductor. The total area is 1.137 × 0.797 mm2. The input locking range is from the incident frequency of 1.6 to 3.0 GHz to provide a signal source from 3.2 GHz to 6 GHz. The second ×3 ILFM uses the orthogonal transformer and occupies an area of 1.29 × 0.76 mm2. The output locking range is from 9 GHz to 19.8 GHz. This third ×6 ILFM uses a trifilar consisting of two 8-shaped inductors in perpendicular layout and a non-twisted inductor. The ×6 ILFMs show interference noise suppression via a core two-turn 8-shaped inductor and save die area. The die area is 0.843 × 0.981 mm2. At VDD = 1.3 V and an input power of 0 dBm, the output locking range is from 5.16 GHz to 5.388 GHz. In all the investigated ILFMs, no varactors are added to the LC resonator for a wide-band locking range design. The phase noises of the input signal and the output signal of the ILFM are in agreement with the theoretical value. Full article
(This article belongs to the Special Issue Advances in Frontend Electronics for Millimeter-Wave Systems)
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23 pages, 12472 KB  
Article
Fixed-Time Active Disturbance Rejection Temperature–Pressure Decoupling Control for a High-Flow Air Intake System
by Louyue Zhang, Hehong Zhang, Duoqi Shi, Zhihong Dan, Xi Wang, Chao Zhai, Gaoxi Xiao and Zhouzhe Xu
Entropy 2025, 27(8), 880; https://doi.org/10.3390/e27080880 - 20 Aug 2025
Viewed by 866
Abstract
High-flow aeroengine transient tests involve strong coupling and external disturbances, which pose significant challenges for intake environment simulation systems (IESSs). This study proposes a compound control scheme that combines fixed-time active disturbance rejection with static decoupling methods. The scheme integrates a fixed-time sliding-mode [...] Read more.
High-flow aeroengine transient tests involve strong coupling and external disturbances, which pose significant challenges for intake environment simulation systems (IESSs). This study proposes a compound control scheme that combines fixed-time active disturbance rejection with static decoupling methods. The scheme integrates a fixed-time sliding-mode controller (FT-SMC) and a super-twisting fixed-time extended-state observer (ST-FT-ESO). A decoupling transformation separates pressure and temperature dynamics into two independent loops. The observer estimates system states and total disturbances, including residual coupling, while the controller ensures fixed-time convergence. The method is deployed on a real-time programmable logic controller (PLC) and validated through hardware-in-the-loop (HIL) simulations under representative high-flow scenarios. Compared to conventional linear active disturbance rejection decoupling control (LADRDC), the proposed scheme reduces the absolute integral error (AIE) in pressure and temperature tracking by 71.9% and 77.9%, respectively, and reduces the mean-squared error (MSE) by 46.0% and 41.3%. The settling time improves from over 5 s to under 2 s. These results demonstrate improved tracking accuracy, faster convergence, and enhanced robustness against disturbances. Full article
(This article belongs to the Section Complexity)
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16 pages, 5796 KB  
Article
Microstructural Evolution and Mechanical Properties of an Additively Manufactured AlSi10Mg Alloy Post-Processed by Twist Equal Channel Angular Pressing
by Przemysław Snopiński, Augustine Appiah, Ondřej Hilšer and Jiři Hajnyš
Symmetry 2025, 17(8), 1289; https://doi.org/10.3390/sym17081289 - 11 Aug 2025
Viewed by 1111
Abstract
This study investigates the microstructural evolution and mechanical response of an additively manufactured (PBF-LB/M) AlSi10Mg alloy subjected to severe plastic deformation via two passes of twist channel angular pressing (TCAP). Processing was conducted using Route Bc, with the first pass at 150 °C [...] Read more.
This study investigates the microstructural evolution and mechanical response of an additively manufactured (PBF-LB/M) AlSi10Mg alloy subjected to severe plastic deformation via two passes of twist channel angular pressing (TCAP). Processing was conducted using Route Bc, with the first pass at 150 °C and the second at 250 °C. For the first time, the evolution from the initial hierarchical AM structure to a refined state was characterized in high-fidelity detail using a novel EBSD detector. The two-pass process transformed the initial structure into a heterogeneous, bimodal microstructure existing in a non-equilibrium state, characterized by a high fraction of low-angle grain boundaries (63%) and significant internal lattice distortion. The mechanical properties were dictated by the processing temperature: a single pass at 150 °C induced work hardening, increasing the yield strength from 450 MPa to 482 MPa. Conversely, the second pass at an elevated temperature of 250 °C promoted significant dynamic recovery. This led to a decrease in yield strength to 422 MPa but concurrently resulted in a substantial increase in ultimate compressive strength to 731 MPa. Full article
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18 pages, 7499 KB  
Article
Transformer Winding Fault Locating Using Frequency Domain Reflectometry (FDR) Technology
by Hao Yun, Yizhou Zhang, Yufei Sun, Liang Wang, Lulin Xu, Daning Zhang and Jialu Cheng
Electronics 2025, 14(15), 3117; https://doi.org/10.3390/electronics14153117 - 5 Aug 2025
Viewed by 744
Abstract
Detecting power transformer winding degradations at an early stage is very important for the safe operation of nuclear power plants. Most transformer failures are caused by insulation breakdown; the winding turn-to-turn short circuit fault is frequently encountered. Experience has shown that routine testing [...] Read more.
Detecting power transformer winding degradations at an early stage is very important for the safe operation of nuclear power plants. Most transformer failures are caused by insulation breakdown; the winding turn-to-turn short circuit fault is frequently encountered. Experience has shown that routine testing techniques, e.g., winding resistance, leakage inductance, and sweep frequency response analysis (SFRA), are not sensitive enough to identify minor turn-to-turn short defects. The SFRA technique is effective only if the fault is in such a condition that the flux distribution in the core is prominently distorted. This paper proposes the frequency domain reflectometry (FDR) technique for detecting and locating transformer winding defects. FDR measures the wave impedance and its change along the measured windings. The wire over a plane model is selected as the transmission line model for the transformer winding. The effectiveness is verified through lab experiments on a twist pair cable simulating the transformer winding and field testing on a real transformer. The FDR technique successfully identified and located the turn-to-turn short fault that was not detected by other testing techniques. Using FDR as a complementary tool for winding condition assessment will be beneficial. Full article
(This article belongs to the Section Power Electronics)
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25 pages, 681 KB  
Review
Insights into the Molecular Mechanisms and Signaling Pathways of Epithelial to Mesenchymal Transition (EMT) in the Pathophysiology of Endometriosis
by Hossein Hosseinirad, Jae-Wook Jeong and Breton F. Barrier
Int. J. Mol. Sci. 2025, 26(15), 7460; https://doi.org/10.3390/ijms26157460 - 1 Aug 2025
Viewed by 2252
Abstract
Endometriosis is a disease characterized by the presence of endometrial glands and stroma outside of the uterine corpus, often clinically presenting with pain and/or infertility. Ectopic lesions exhibit features characteristic of epithelial-to-mesenchymal transition (EMT), a process in which epithelial cells lose polarity and [...] Read more.
Endometriosis is a disease characterized by the presence of endometrial glands and stroma outside of the uterine corpus, often clinically presenting with pain and/or infertility. Ectopic lesions exhibit features characteristic of epithelial-to-mesenchymal transition (EMT), a process in which epithelial cells lose polarity and acquire mesenchymal traits, including migratory and invasive capabilities. During the process of EMT, epithelial traits are downregulated, while mesenchymal traits are acquired, with cells developing migratory ability, increasing proliferation, and resistance to apoptosis. EMT is promoted by exposure to hypoxia and stimulation by transforming growth factor-β (TGF-β), platelet-derived growth factor (PDGF), and estradiol. Signaling pathways that promote EMT are activated in most ectopic lesions and involve transcription factors such as Snail, Slug, ZEB-1/2, and TWIST-1/2. EMT-specific molecules present in the serum of women with endometriosis appear to have diagnostic potential. Strategies targeting EMT in animal models of endometriosis have demonstrated regression of ectopic lesions, opening the door for novel therapeutic approaches. This review summarizes the current understanding of the role of EMT in endometriosis and highlights potential targets for EMT-related diagnosis and therapeutic interventions. Full article
(This article belongs to the Special Issue Endometriosis: Focusing on Molecular and Cellular Research)
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17 pages, 7162 KB  
Article
Microbeam X-Ray Investigation of the Structural Transition from Circularly Banded to Ringless Dendritic Assemblies in Poly(Butylene Adipate) Through Dilution with Poly(Ethylene Oxide)
by Selvaraj Nagarajan, Chia-I Chang, I-Chuan Lin, Yu-Syuan Chen, Chean-Cheng Su, Li-Ting Lee and Eamor M. Woo
Polymers 2025, 17(15), 2040; https://doi.org/10.3390/polym17152040 - 26 Jul 2025
Viewed by 602
Abstract
In this study, growth mechanisms are proposed to understand how banded dendritic crystal aggregates in poly(1,4-butylene adipate) (PBA) transform into straight dendrites upon dilution with a large quantity of poly(ethylene oxide) (PEO) (25–90 wt.%). In growth packing, crystal plates are deformed in numerous [...] Read more.
In this study, growth mechanisms are proposed to understand how banded dendritic crystal aggregates in poly(1,4-butylene adipate) (PBA) transform into straight dendrites upon dilution with a large quantity of poly(ethylene oxide) (PEO) (25–90 wt.%). In growth packing, crystal plates are deformed in numerous ways, such as bending, scrolling, and twisting in self-assembly, into final aggregated morphologies of periodic bands or straight dendrites. Diluting PBA with a significant amount of PEO uncovers intricate periodic banded assemblies, facilitating better structural analysis. Both circularly banded and straight dendritic PBA aggregates have similar basic lamellar patterns. In straight dendritic PBA spherulites, crystal plates can twist from edge-on to flat-on, similar to those in ring-banded spherulites. Therefore, twists—whether continuous or discontinuous—are not limited to the conventional models proposed for classical periodic-banded spherulites. Thus, it would not be universally accurate to claim that the periodic circular bands observed in polymers or small-molecule compounds are caused by continuous lamellar helix twists. Straight dendrites, which do not exhibit optical bands, may also involve alternate crystal twists or scrolls during growth. Iridescence tests are used to compare the differences in crystal assemblies of straight dendrites vs. circularly banded PBA crystals. Full article
(This article belongs to the Section Polymer Physics and Theory)
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14 pages, 27914 KB  
Article
Inversion Motion of Xanthene and Detection of Its Oxidation Product Xanthone from Gas-Phase Rotational Spectroscopy
by Celina Bermúdez, Manuel Goubet and Elias M. Neeman
Molecules 2025, 30(13), 2801; https://doi.org/10.3390/molecules30132801 - 29 Jun 2025
Viewed by 797
Abstract
The rotational spectra of xanthene and its oxidation product xanthone were investigated by combining quantum chemical calculations with Fourier transform microwave spectroscopy in a jet-cooled environment. Xanthone was unexpectedly generated in the experiment when water was present in the reservoir of xanthene leading [...] Read more.
The rotational spectra of xanthene and its oxidation product xanthone were investigated by combining quantum chemical calculations with Fourier transform microwave spectroscopy in a jet-cooled environment. Xanthone was unexpectedly generated in the experiment when water was present in the reservoir of xanthene leading to the total disappearance of xanthene after few hours. Structurally, xanthone shows a near planar disposition, whereas xanthene exhibits a non-planar geometry with both benzene rings twisted out of the molecular plane. This geometry enables an inversion motion between two equivalent conformers, giving rise to a splitting in the ground vibrational state. A two-state analysis of the vibration–rotation interaction for the v=0 and v=1 states gives an energy separation between these states (inversion splitting) of ΔE01=4689.7095(10)MHz. This large-amplitude motion leads to vibration–rotation coupling of energy levels. A symmetric double-minimum inversion potential function was determined, resulting in a barrier of about 45 cm−1 in good agreement with that obtained by DFT quantum chemical calculations. Full article
(This article belongs to the Special Issue Exclusive Feature Papers in Physical Chemistry, 3rd Edition)
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14 pages, 4931 KB  
Article
State-of-the-Art VCO with Eight-Shaped Resonator-Type Transmission Line
by Sheng-Lyang Jang, Zi-Jun Lin and Miin-Horng Juang
Electronics 2025, 14(12), 2322; https://doi.org/10.3390/electronics14122322 - 6 Jun 2025
Cited by 4 | Viewed by 1483
Abstract
A closed-loop transmission line (TL) coupled to an LCR resonator is used in this study for a fully-integrated CMOS rotary traveling wave oscillator (RTWO) based on the rotary traveling wave principle. A technique for the suppression of magnetic coupling noise is presented with [...] Read more.
A closed-loop transmission line (TL) coupled to an LCR resonator is used in this study for a fully-integrated CMOS rotary traveling wave oscillator (RTWO) based on the rotary traveling wave principle. A technique for the suppression of magnetic coupling noise is presented with eight-shaped inductors. The design and measurement of an 8.53 GHz oscillator in the TSMC 0.18 μm CMOS technology are discussed. The fully-integrated chip occupies a die area of 1.2 × 1.2 mm2. The oscillator consists of four sub-oscillators and uses four 1:1 symmetric twisted transformers, with the secondary inductors connected to form a twisted closed-loop transmission line for coupling the sub-oscillators. The transformers are configured as eight-shaped structures to minimize the far-field magnetic field radiation from each transformer and the whole transformer. At a supply voltage of 1.7 V, the power consumption is 5.84 mW. The free-running oscillation frequency of the RTWO is tunable from 8.53 GHz to 10.0 GHz. The measured phase noise at a 1 MHz frequency offset is −122.4 dBc/Hz at an oscillation frequency of 8.53 GHz, and the figure of merit (FOM) of the proposed VCO with a specific inductor layout is −193.4 dBc/Hz, surpassing other similar RTWOs. The FOM with a tuning range (FOMT) is −195.96 dBc/Hz. Full article
(This article belongs to the Special Issue Advances in Frontend Electronics for Millimeter-Wave Systems)
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19 pages, 2153 KB  
Review
Molecular Mechanisms Regulating Epithelial Mesenchymal Transition (EMT) to Promote Cancer Progression
by Saima Ghafoor, Elizabeth Garcia, Daniel J. Jay and Sujata Persad
Int. J. Mol. Sci. 2025, 26(9), 4364; https://doi.org/10.3390/ijms26094364 - 3 May 2025
Cited by 14 | Viewed by 5798
Abstract
The process of epithelial–mesenchymal transition (EMT) is crucial in various physiological/pathological circumstances such as development, wound healing, stem cell behavior, and cancer progression. It involves the conversion of epithelial cells into a mesenchymal phenotype, which causes the cells to become highly motile. This [...] Read more.
The process of epithelial–mesenchymal transition (EMT) is crucial in various physiological/pathological circumstances such as development, wound healing, stem cell behavior, and cancer progression. It involves the conversion of epithelial cells into a mesenchymal phenotype, which causes the cells to become highly motile. This reprogramming is initiated and controlled by various signaling pathways and governed by several key transcription factors, including Snail 1, Snail 2 (Slug), TWIST 1, TWIST2, ZEB1, ZEB2, PRRX1, GOOSECOID, E47, FOXC2, SOX4, SOX9, HAND1, and HAND2. The intracellular signaling pathways are activated/inactivated by signals received from the extracellular environment and the transcription factors are carefully regulated at the transcriptional, translational, and post-translational levels to maintain tight regulatory control of EMT. One of the most important pathways involved in this process is the transforming growth factor-β (TGFβ) family signaling pathway. This review will discuss the role of EMT in promoting epithelial cancer progression and the convergence/interplay of multiple signaling pathways and transcription factors that regulate this phenomenon. Full article
(This article belongs to the Special Issue Cellular Plasticity and EMT in Cancer and Fibrotic Diseases)
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11 pages, 2168 KB  
Article
Wrinkle Improvement in HanDam (Twist) on Ultraviolet B Irradiation-Induced Skin Photoaging in Hairless Mice
by Inbong Song, Judong Song, Ilseok Jang, Dayoung Noh, Chaemyeong Lee and Jungkee Kwon
Appl. Sci. 2025, 15(9), 4879; https://doi.org/10.3390/app15094879 - 28 Apr 2025
Viewed by 1592
Abstract
Background: Skin photoaging caused by ultraviolet B (UV-B) irradiation leads to the formation of wrinkles. A method to lessen wrinkles is the application of Polydioxanone (PDO) lifting threads. HanDam (Twist) is a PDO lifting thread with a unique morphological twisted shape. Objective: The [...] Read more.
Background: Skin photoaging caused by ultraviolet B (UV-B) irradiation leads to the formation of wrinkles. A method to lessen wrinkles is the application of Polydioxanone (PDO) lifting threads. HanDam (Twist) is a PDO lifting thread with a unique morphological twisted shape. Objective: The aim of this study was to evaluate the wrinkle improvement ability of HanDam (Twist) on UV-B irradiation-induced skin photoaging in a hairless mouse model. Methods: Wrinkles were induced by UV-B irradiation to the backs of female hairless mice for six weeks. After induction, the wrinkles were treated with threads, and the mice were monitored for six weeks post-treatment. Results: Our results showed that treatment with HanDam (Twist) effectively ameliorated UV-B irradiation-induced wrinkle depth and significantly increased collagen density by 13% compared to HanDam (non-Twist) in the histological analysis. In measuring protein expression related to collagen production, HanDam (Twist) significantly increased transforming growth factor beta (TGF-β) and collagen type 1 (COL1) by 46% and 67% compared to HanDam (non-Twist). Matrix metalloproteinase-1 (MMP-1) protein expression showed similar density and no significance compared to HanDam (non-Twist). Conclusions: These findings suggest that HanDam (Twist) improves the effectiveness of lifting threads for skin care compared to that of existing products. Full article
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15 pages, 4448 KB  
Article
Crystal Form Diversity of 2-(4-(Diphenylamino)benzylidene) Malononitrile
by Haorui Gu and Qingwen Lin
Crystals 2025, 15(4), 380; https://doi.org/10.3390/cryst15040380 - 21 Apr 2025
Cited by 1 | Viewed by 1092
Abstract
In the present work, we report the synthesis and characterization of 2-(4-(diphenylamino)benzylidene) malononitrile (DPAM) via a piperidine-catalyzed Knoevenagel condensation reaction. Two distinct crystal forms (A-1 and A-2) of this product were obtained by controlling the crystallization conditions, exhibiting orthorhombic and monoclinic [...] Read more.
In the present work, we report the synthesis and characterization of 2-(4-(diphenylamino)benzylidene) malononitrile (DPAM) via a piperidine-catalyzed Knoevenagel condensation reaction. Two distinct crystal forms (A-1 and A-2) of this product were obtained by controlling the crystallization conditions, exhibiting orthorhombic and monoclinic crystal systems, respectively. Single-crystal X-ray diffraction revealed that both forms exhibited highly twisted benzene rings, which suppressed exciplex or excimer formation, enhancing luminescence. Crystal A-1, with a higher density, showed stronger hydrogen bonding and more rigid molecular packing, while A-2, with a lower density, exhibited weaker π–π interactions. Both crystals demonstrated high thermal stability. Notably, the A-2 crystal displayed a mechanochromic behavior: grinding or applying pressure induced a structural transformation into A-1, accompanied by a fluorescence shift from red to yellow. This transformation was attributed to increased steric hindrance and changes in molecular packing. This study highlights the relationship between crystal structure and optoelectronic properties, offering insights into the design of organic crystalline materials for applications in pressure sensing, anti-counterfeiting, and information encryption. Full article
(This article belongs to the Section Crystal Engineering)
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33 pages, 11917 KB  
Article
Multi-Fidelity Surrogate-Assisted Aerodynamic Optimization of Aircraft Wings
by Eleftherios Nikolaou, Spyridon Kilimtzidis and Vassilis Kostopoulos
Aerospace 2025, 12(4), 359; https://doi.org/10.3390/aerospace12040359 - 20 Apr 2025
Cited by 1 | Viewed by 2358
Abstract
This paper presents a multi-fidelity optimization procedure for aircraft wing design, implemented in the early stages of the aircraft design process. Since wing shape is a key factor that influences aerodynamic performance, having an accurate estimate of its efficiency at the conceptual design [...] Read more.
This paper presents a multi-fidelity optimization procedure for aircraft wing design, implemented in the early stages of the aircraft design process. Since wing shape is a key factor that influences aerodynamic performance, having an accurate estimate of its efficiency at the conceptual design phase is highly beneficial for aircraft designers. This study introduces a comprehensive optimization framework for designing the wing of a Class I fixed-wing mini-UAV with electric propulsion, focusing on maximizing aerodynamic efficiency and operational performance. Utilizing Class-Shape Transformation (CST) in combination with Surrogate-Based Optimization (SBO) techniques, the research first optimizes the airfoil shape to identify the most suitable airfoil for the UAV wing. Subsequently, SBO techniques are applied to generate wing geometries with varying characteristics, including aspect ratio (AR), taper ratio (λ), quarter-chord sweep angle (Λ0.25), and tip twist angle (ε). These geometries are then evaluated using both low- and high-fidelity aerodynamic simulations. The integration of SBO techniques enables an efficient exploration of the design space while minimizing the computational costs associated with iterative simulations. Specifically, the proposed SBO framework enhances the wing’s aerodynamic characteristics by optimizing the lift-to-drag ratio and reducing drag. Full article
(This article belongs to the Section Aeronautics)
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