Search Results (289)

Current treatment methods for desulfurization wastewater in the ship exhaust gas cleaning (EGC) system face several problems, including process complexity, unstable performance, large spatial requirements, and high energy consumption. This study investigates rotating dynamic filtration (RDF) as an efficient treatment approach through experimental testing, theoretical analysis, and pilot-scale validation. Flux increases with temperature and pressure but decreases with feed concentration, remaining unaffected by circulation flow. For a small membrane (152 mm), flux consistently increases with rotational speed across all pressures. For a large membrane (374 mm), flux increases with rotational speed at 300 kPa but firstly increases and then decreases at 100 kPa. Filtrate turbidity in all experiments complies with regulatory standards. Due to the unique hydrodynamic characteristics of RDF, back pressure reduces the effective transmembrane pressure, whereas shear force mitigates concentration polarization and cake layer formation. Separation performance is governed by the balance between these two forces. The specific energy consumption of RDF is only 10–30% that of cross-flow filtration (CFF). Under optimized pilot-scale conditions, the wastewater was concentrated 30-fold, with filtrate turbidity consistently below 2 NTU, outperforming CFF. Moreover, continuous operation proves more suitable for marine environments. Full article

This study focuses on the design and optimization of a monopolar electrode configuration for the hybrid electrochemical treatment of real washing machine wastewater. A combined electrocoagulation (EC) and electro-oxidation (EO) system was optimized to maximize pollutant removal efficiency while minimizing energy consumption. The monopolar setup employed mixed metal oxide (MMO) and aluminum anodes, along with a stainless steel cathode, operating under controlled conditions with sodium chloride as the supporting electrolyte. An applied current density of 15 mA cm⁻² achieved 90% chemical oxygen demand (COD) removal, 98% surfactant degradation, complete turbidity reduction within 120 min, and pH stabilization near 8. Additionally, electrochemical disinfection achieved <2 MPN/100 mL, with no detectable phenols and the presence of organic anions such as oxalate and acetate. These results demonstrate the effectiveness of an optimized monopolar EC–EO system as a cost-efficient and sustainable strategy for wastewater treatment and potential water reuse. Further studies should focus on refining energy consumption and monitoring reaction by-products to enhance large-scale applicability. Full article

The ecological consequences of the construction and operation of the Three Gorges Reservoir, particularly its unique operation strategy of storing clear water and releasing turbid water, exerts a profound influence on the composition and dynamics of local fish communities. To date, detailed and comprehensive research on seasonal changes in the fish community across the entire reservoir remains scarce. This study aims to fill this research gap by systematically investigating fish diversity through a comprehensive assessment of six main river reaches and eight major tributaries. The investigation employs environmental DNA (eDNA) technology across three critical life-cycle stages: breeding, feeding, and overwintering periods. A total of 124 fish species were recorded, comprising 10 orders, 20 families, and 80 genera. The comparative analyses of historical data suggest a significant decline in lotic and endemic fish populations, accompanied by a concurrent increase in lentic, eurytopic, and non-native fish species. Notably, the composition of fish communities exhibited similarities between breeding and overwintering periods. This study highlights the occurrence of significant seasonal fluctuations in the fish communities, showing a preference for reservoir tails and tributaries as optimal habitats. Water temperature has a predominant influence on structuring fish communities within aquatic ecosystems. This study investigates variations in the biodiversity of fish communities using historical data, with a focus on changes linked to reservoir operations and water impoundment activities. By integrating historical data, this research examines changes in fish diversity that are associated with water storage processes. It provides foundational data on the current composition and diversity of fish communities within the watershed, elucidating the spatiotemporal variations in fish diversity and the mechanisms by which environmental factors influence these communities. Furthermore, the current study serves as a valuable reference for understanding the changes in fish communities within other large reservoirs. Full article

Historical earthquake records are crucial for analyzing high-intensity earthquakes that occur over long periods. Since good instrumental data only date back to 1980, there are gaps in our knowledge, and qualitative assessments remain essential to expand our knowledge and integrate more information into the number of variables under analysis. This study examined the hydrological and hydrogeological effects of the 1755 Lisbon earthquake, focusing on regions near rivers and proposing new insights for intensity scales. This information is relevant for seismic risk management and mitigation, to be discussed in regional and national territorial planning strategies. Mapping revealed that most phenomena occurred along the Porto–Tomar tectonic fault, with some extending to other probable faults or geological contrasts. A comparative chart between existing intensity scales and the proposed descriptors highlights agreements and discrepancies, emphasizing the need for more detailed descriptors for intensity levels below X for river-related phenomena. The proposed descriptors include a flow increase with course alterations (intensities VI–VIII), flow suppression and eventual reset (intensity VIII or higher), abnormal current agitation and vertical wave movements (intensities VI–VIII), and cloudy (turbid) water (intensities V–VIII). This work also highlights the need to cross-reference data and the complexity of establishing correlations between effects, ancient descriptions, and descriptors for these intensity scales. Full article

This study investigates the effectiveness of electrocoagulation (EC) with locally sourced iron electrodes for treating olive mill wastewater (OMW) prior to adsorption with olive stone (OS). Using Response Surface Methodology (RSM), 60 experiments were conducted to evaluate various operational parameters, including current density (CD), reaction time (T), distance between electrodes (D), and the number of electrodes (N). The optimal conditions identified were a reaction time of 53.49 min, a current density of 15.1104 mA/cm², 1 cm electrode spacing, and six electrodes. Under these conditions, the removal efficiencies achieved were 54.46% for total phenols (TPh), 73.25% for total Kjeldahl nitrogen (TKN), 92% for turbidity, 58.91% for soluble chemical oxygen demand (COD_soluble), and 58.55% for total COD (COD_total), with an energy consumption of 14.3146 kWh/m³ and a projected cost of USD 3.92/m³. Following the EC process, the treated OMW underwent further adsorption using OS, enhancing pollutant removal. The combined EC and adsorption (ECA) method demonstrated superior performance, achieving TPh removal at 62.63%, TKN removal at 77.52%, and turbidity reduction at 83.73%. Additionally, COD_total removal increased to 72.88% with COD_soluble removal at 70.04%. This integrated approach significantly improves pollutant removal, presenting a promising solution for effective OMW treatment. Full article

Objective: The research on turbid current deposition in shallow Marine shelf environments is relatively weak. Method: Based on three-dimensional seismic, drilling and logging data, etc., the spatio-temporal characterization of the shallow sea turbidity current sedimentary system was carried out by using seismic geomorphology and sedimentary numerical simulation techniques. Results and Conclusions: (1) A set of standards for identifying sedimentary units in the X Gas Field was established, identifying four sedimentary units: channel, mound body, channel-side accumulation body, and shelf mud; (2) The vertical evolution and planar distribution of the sedimentary units in the painting were precisely engraved. Along with the weakly–strongly–weak succession of turbidity current energy, the lithological combination of argillaceous siltstone–siltstone–mudstone developed vertically. On the plane, the clusters showed an evolution of isolation–connection–superposition. The scale of the river channel continued to expand, and the phenomena of oscillation and lateral accumulation occurred. (3) Three factors were analyzed: sea level, material sources, and sedimentary substrates (paleo landforms), and a shallow Marine turbidity current sedimentary system was established in the Honghe area in the northwest direction under the background of Marine receding, which is controlled by sedimentary slope folds and blocked by the high part of the diapause during the downward accumulation process of material sources along the shelf. (4) The numerical simulation results reconstructed the process of lateral migration of waterways, evolution of branch waterways into clusters, expansion of the scale of isolated clusters, and connection and superposition to form cluster complexes on a three-dimensional scale. The simulation results are in high agreement with the actual geological data. Full article

In tight reservoirs deposited in diverse sedimentary settings, the pore structure governs tight oil enrichment features and sweet-spot distribution. Taking the tight sandstone reservoirs of the lower third member of the Shahejie Formation in the Linnan Subsag of Bohai Bay Basin in China as an example, this study employs XRD to delineate petrological characteristics, while porosity and permeability measurements are used to quantify physical properties. In addition, thin section, SEM, HPMI, NMR, fractal theory, and cathodoluminescence experiments are applied to investigate pore structure characteristics and influencing factors. The results reveal two sedimentary systems: turbidity current and delta front deposits. Turbidite reservoirs exhibit the coarse pore-coarse throats (Type A), medium pore-medium throats (Type B), and fine pore-medium throats (Type C) pore structures. Delta front reservoirs are characterized by medium-pore-coarse-throat (Type D), medium-pore-fine-throat (Type E), and fine-pore-fine-throat (Type F) pore structures. Turbidite reservoirs show more favorable pore structures for oil exploration compared to delta fronts, in which lithofacies and diagenetic facies are the key influences. A genetic model identifies the highest-quality Type A forms in fine sandstone lithofacies under medium compaction–medium cementation–strong dissolution, with pore diameters averaging 10.84 μm in turbidite reservoirs. Conversely, the poorest Type F forms in argillaceous layered siltstone lithofacies under strong compaction, cementation, and weak dissolution diagenetic facies in delta fronts, with pore diameters averaging 0.88 μm. Consequently, the control effect of the pore quality means that Type A has the highest and Type F has the lowest oil-bearing capacity. These findings provide valuable guidance for the classification, evaluation, and exploration of tight oil sweet spots. Full article

The enzymatic hydrolysis process is important in the field of textile waste reuse in the circular economy context. Currently, enzymatic cellulase treatment of waste textiles, such as bamboo mixture with spandex samples (BS), cotton jeans (CJ), linen (L), and cotton T-shirts (CT), has been tested, in which glucose production was measured at the presence of 6 and 8% NaOH solution. The characteristics of the textiles and hydrolysis capacity were evaluated by the amount of glucose (g) obtained from each textile. The following indicators were also measured during the experiment: temperature, pH, enzymatic cellulase solution composition, final glucose concentrations, turbidity, and color intensity. The temperature of the mixture was maintained at 50 °C, and a pH level of 5–7 along with a contact time of 48–94 min were controlled. The experiments demonstrated that when the enzymatic hydrolysis was active, turbidity increased from 86 nephelometric turbidity unit (NTU) to >1000 NTU; the color of the hydrolyzed samples was obtained from 86 NTU to >1000 NTU; and the final glucose concentration was approximately between 0.49 and 33.9 mmol/L for L, CT, and CJ samples measured to produce up to one gram of glucose from 3.330 g of textile, and a BS samples produced one gram of glucose from 3.164 g of textile. The findings show that recycled glucose obtained from textile waste materials is environmentally sustainable. Such textile waste can then be reused rather than being dumped in already overloaded landfills. Full article

Lake Taihu has highly turbid inland waters with complex optical properties. Due to the bottom effect of submerged aquatic plants in optically shallow waters, currently available phytoplankton chlorophyll-a retrieval algorithms tend to overestimate chlorophyll-a concentrations in the eastern part of Lake Taihu. This overestimation can distort the eutrophication evaluation of the entire lake. This paper identifies submerged and emergent plants, determines the retrieval models for the upwelling (K_u) and downwelling (K_d) irradiance attenuation coefficients, and proposes a phytoplankton chlorophyll-a retrieval model using a water depth optimization-based method to remove the bottom effect. The results show the following: (1) The normalized difference vegetation index (NDVI) method can distinguish the bottom mud (NDVI < −0.46) and submerged aquatic plants (−0.46 ≤ NDVI < 0.52) from the emergent plants (NDVI ≥ 0.52) with 90% accuracy. (2) The downwelling and upwelling irradiance attenuation coefficients are highly correlated with the suspended sediments, and retrieval models for these coefficients in three visible bands with high accuracy are presented. (3) Compared to traditional algorithms without bottom effect removal, the proposed chlorophyll-a concentration estimation algorithm based on the water depth-optimized bottom effect removal method efficiently reduces the bottom effect of the submerged aquatic plants. The root mean square error (RMSE) for the obtained chlorophyll-a concentrations decreases from 45.61 ${\mathsf{\mu }\mathrm{g}·\mathrm{L}}^{-1}$ to 8.69 ${\mathsf{\mu }\mathrm{g}·\mathrm{L}}^{-1}$, and the mean absolute percentage error (MAPE) is reduced from 245.12% to 19.58%. In the validation step, the obtained RMSE of 10.89 ${\mathsf{\mu }\mathrm{g}·\mathrm{L}}^{-1}$ and MAPE of 17.52% are consistent with the proposed algorithm. This research provides a good reference for the determination of chlorophyll-a concentrations in phytoplankton in complex inland water bodies. The findings are potentially useful for the operational monitoring of harmful algal blooms in the future. Full article

The presence of dissolved sulfides in feed seawater causes severe elemental sulfur fouling in the reverse osmosis (RO) process. However, current pretreatment methods suffer from large footprint, high energy consumption, and limitations in effluent quality. In this study, adsorption and microfiltration are merged into a single process for the pretreatment of sulfide-containing seawater. Powdered activated carbon (PAC) was selected for its superior adsorption capacity (14.6-fold) and faster kinetics (3.9-fold) for sulfide removal compared to granular activated carbon. The high surface area and multiple pore structures of PAC facilitate surface and intraparticle diffusion, as well as anion–π conjugation likely occur between PAC and sulfide. Polypropylene microporous membranes, capable of tolerating high PAC dosages, were used in the hybrid process. Long-term pilot tests demonstrated that the effluent (turbidity < 1 NTU and SDI₁₅ ≈ 2.50) met the quality requirements for RO unit feedwater, achieving 100% sulfide removal efficiency over 101 h, with no risk of PAC leakage throughout the entire operation process. The formation of a loose, porous PAC cake layer alleviates membrane fouling and enhances the retention and adsorption of metal(loid)s and sulfide. Moreover, the low permeate flux of the polymeric membranes significantly mitigates filter cake formation. The hybrid system adapts to variations in feedwater quality, making it highly suitable for desalination plants with limited space and budget. These findings offer valuable insights and practical guidance for advancing seawater desalination pretreatment. Full article

Estuarine benthos, among other lifeforms of interest to water quality, can be sensitive to size-distributed suspended cohesive flocs. In such a context, tide-dependent floc mass distributions in the Tamar Estuary in the UK are revisited. At the field site close to maximum turbidity, time-series of the water level, current velocity, salinity, and suspended sediment concentration (SSC) were recorded in 1998 over several tidal cycles. Concurrently, at selected times and elevation, floc mass distributions were derived from in situ observations of the SSC, floc diameters, and settling velocities. A previously developed time-dependent model, revised to account for both multiclass floc aggregation/disaggregation and bed sediment exchange by erosion and deposition, is applied to simulate mass distributions during ebb/flood cycles on 24 June and 5 August. Although the model does not account for the density effects of salinity or sediment advection, limited comparisons between simulated and observed mass distributions indicate generally good agreement in median diameter prediction on both days. This concurrence is due to the primary role of suspended floc dynamics and only a secondary contribution from bed sediment exchange in governing floc properties. For a better prediction of the SSC variation with the tide, the effects of salinity and advection can be incorporated by coupling the modeled floc dynamics with a suitable multi-dimensional hydrodynamic code. Full article

Seismic data reveal that the shelf edge of the Pearl River Mouth Basin in the northern South China Sea is characterized by slope channels that have consistently migrated in a north-easterly direction over millions of years. Previous research suggests that the channel migration is driven by the interplay between along-slope bottom currents and downslope turbidity currents. Here, we propose an alternative interpretation, suggesting the migrating channels are actually a series of channel–levee systems and the migration is driven by their own evolution of erosion–deposition under the influence of the Coriolis force. A detailed interpretation of high-resolution seismic data reveals seven types of architectural elements, characteristic of channel–levee systems, which are erosional bases, outer levees, inner levees, channel-axis fills, marginal slumps, drapes, and lobes. An analysis of the sequence stratigraphy and stacking pattern of channels suggests that channel migration from the middle Miocene to the present is discontinuous with at least three regional discontinuities within the channel migration sequence marked by regional drapes. Down-dipping reflections along the margin of channels, previously interpreted as bottom-currents deposits, are here reinterpreted as mass-transport processes along steep channel walls. The migration is most prominent in the middle reach, where erosion and deposition coexist and dominate alternately in two different phases. During the long-term canyon-filling turbidity currents prevailing phase, deposition dominates, leading to the development of a prominent asymmetric right-hand (west) inner levee due to the Coriolis force. In contrast, during the canyon-flushing turbidity currents prevailing phase, erosion dominates and the preferred right-hand (west) inner levee enforces the flow to erode eastward, then drives the channel migrating eastward. The alternating effects of erosion and deposition ultimately result in unidirectional channel migration. Full article

Sea surface currents (SSCs) play a pivotal role in material transport, energy exchange, and ecosystem dynamics in coastal marine environments. While traditional methods to obtain wide-range SSCs, such as satellite altimetry, often struggle with limited performance in coastal regions due to waveform contamination, deriving SSCs from sequential ocean color data using maximum cross-correlation (MCC) has emerged as a promising approach. In this study, we proposed a novel SSC estimation method, called tide-restricted maximum cross-correlation (TRMCC), and implemented it on hourly ocean color data obtained from the Geostationary Ocean Color Imager II (GOCI-II) and the global tide model FES2014 to derive SSCs in coastal seas and turbid estuaries. Cross-comparison over three years with buoy data, high-frequency radar, and numerical model products shows that TRMCC is capable of obtaining high-resolution SSCs with good accuracy in coastal and estuarine areas. Both large-scale ocean circulation patterns in seas and fine-scale surface current structures in estuaries can be effectively captured. The deriving accuracy, especially in coastal and estuarine areas, can be significantly improved by integrating tidal current data into the MCC workflow, and the influence of invalid data can be minimized by using a flexible reference window size and normalized cross-correlation in the Fourier domain technique. Seasonal SSC structure in the Bohai Sea and diurnal SSC variation in the Yangtze River Estuary were depicted via the satellite method, for the first time. Our study highlights the vast potential of TRMCC to improve the understanding of current dynamics in complex coastal regions. Full article

Submerged macrophytes can profoundly influence interactions between aquatic predators and their prey due to changes in foraging efficiencies, pursuit time and swimming behaviors of predator–prey participants. Water hyacinth, Eichhornia crassipes (Mart.) Solms-Laub. (Pontederiaceae), is the most widely distributed of the aquatic invasive weeds in South Africa. This invasive weed contributes to changes in physicochemical (turbidity, temperature and water column stratification) and biological (total chlorophyll-a (Chl-a) concentrations and species composition and distribution of vertebrates and invertebrates) variables within freshwater systems of the region. The current study assessed the influence of varying levels of water hyacinth cover (0, 25, 50 and 100% treatments) on the total Chl-a concentration, size structure of the phytoplankton community and the strength of the interaction between a predatory notonectid, Enithares sobria, and zooplankton using a short-term 10-day long mesocosm study. There were no significant differences in selected physicochemical (temperature, dissolved oxygen, total nitrogen and total phosphate) variables in these different treatments over the duration of this study (ANOVA; p > 0.05 in all cases). Results of this study indicate that treatment had a significant effect on total Chl-a concentrations and total zooplankton abundances. The increased surface cover of water hyacinth contributed to a significant reduction in total Chl-a concentrations and a significant increase in total zooplankton abundances (ANCOVA; p < 0.05 in both cases). The increased habitat complexity conferred by the water hyacinth root system provided refugia for zooplankton. The decline in total Chl-a concentration and the size structure of the phytoplankton community under elevated levels of water hyacinth cover can therefore probably be related to both the unfavorable light environment conferred by the plant cover and the increased grazing activity of zooplankton. The presence of the water hyacinth thus suppressed a predator–prey cascade at the base of the food web. Water hyacinth may, therefore, have important implications for the plankton food web dynamics of freshwater systems by reducing food availability (Chl-a), changing energy flow and alternating the strength of interactions between predators and their prey. Full article

The enhancement of the treatment of municipal wastewater treatment plants is limited by poor sludge settling qualities, and the excessive discharge of nitrogen and phosphorus exacerbate water eutrophication. The goal of the current work was to remove phosphorus from fresh sewage-activated sludge by developing a new conditioning and flocculation mechanism that included a coagulant and cationic polyelectrolytes in a dual conditioning system. The coagulant (CaCl₂) and the high molecular weight polyacrylamide (CPAM-10) were chosen to be utilized singly or in pairs as cationic–coagulant combinations. The collected results showed that, in comparison to utilizing the coagulant (CaCl₂), conditioning with the high molecular weight polymer (CPAM-10) produced improved settling and less turbidity. Only sludge with a lower solid content (TSS) exhibited better settling when pure CaCl₂ was used for conditioning. CaCl₂ conditioning enhanced settling by just 3%, while CPAM-10 improved the sludge setting by 60% for higher sludge TSSs. According to the results, conditioning settings using a dual mixture including 20 mL CPAM-10 and 50 mL CaCl₂ improved settling by 80%. The amount of phosphorus in the supernatant was decreased by 15% and 9%, respectively, by using the coagulant (CaCl₂) and 50 mL/L polyacrylamide (CPAM-10). As a result, there was a significant amount of phosphorus in the resultant supernatant. This suggested that the polymer had a significant impact on sludge settling because of its high positive charge, but had less of an impact on attracting phosphorus metal. Despite the lower positive charge of CaCl₂, it has a dual action of settling and removing phosphorus. A considerable amount of phosphorus was removed from the sludge and leached to the supernatant during treatment. This treatment was coupled with less sludge settling. However, 90% phosphorus removal was achieved when mixed conditioning agents (20 mL CPAM-10 and 50 mL CaCl₂) were used. Furthermore, phosphorus was reduced by 33 and 39%, respectively, by adding 20 milliliters of CaCl₂ to 100 milliliters of the pre-conditioned supernatant with pure CPAM-10 and CaCl₂. Using the CPAM-10 agent for sludge conditioning has a major impact on settling, because of the high positive charge, and because when a small amount of Ca++ is added to the polymer solution for conditioning to attract fine sludge particles and accelerate their combination, this results in flocculation and rapid dewatering. This mechanism allows for more phosphorus to be released to the supernatant, which has not been reported previously to the best of our knowledge. Full article